Articles | Volume 16, issue 6
https://doi.org/10.5194/cp-16-2431-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/cp-16-2431-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
The SP19 chronology for the South Pole Ice Core – Part 2: gas chronology, Δage, and smoothing of atmospheric records
Jenna A. Epifanio
CORRESPONDING AUTHOR
College of Earth, Ocean, and Atmospheric Sciences, Oregon State
University, Corvallis, OR, USA
Edward J. Brook
College of Earth, Ocean, and Atmospheric Sciences, Oregon State
University, Corvallis, OR, USA
Christo Buizert
College of Earth, Ocean, and Atmospheric Sciences, Oregon State
University, Corvallis, OR, USA
Jon S. Edwards
College of Earth, Ocean, and Atmospheric Sciences, Oregon State
University, Corvallis, OR, USA
Todd A. Sowers
The Earth and Environmental Systems Institute, Pennsylvania State
University, University Park, PA, USA
Emma C. Kahle
Department of Earth and Space Science, University of Washington,
Seattle, WA, USA
Jeffrey P. Severinghaus
Scripps Institution of Oceanography, University of California San
Diego, La Jolla, CA, USA
Eric J. Steig
Department of Earth and Space Science, University of Washington,
Seattle, WA, USA
Dominic A. Winski
School of Earth and Climate Sciences, University of Maine, Orono,
ME, USA
Climate Change Institute, University of Maine, Orono, ME, USA
Erich C. Osterberg
Department of Earth Sciences, Dartmouth College, Hanover, NH, USA
Tyler J. Fudge
Department of Earth and Space Science, University of Washington,
Seattle, WA, USA
Murat Aydin
Department of Earth System Science, University of California, Irvine, CA, USA
Ekaterina Hood
Rosenstiel School of Marine and Atmospheric Science, University of Miami, Miami, FL, USA
Michael Kalk
College of Earth, Ocean, and Atmospheric Sciences, Oregon State
University, Corvallis, OR, USA
Karl J. Kreutz
School of Earth and Climate Sciences, University of Maine, Orono,
ME, USA
Climate Change Institute, University of Maine, Orono, ME, USA
David G. Ferris
Department of Earth Sciences, Dartmouth College, Hanover, NH, USA
Joshua A. Kennedy
Department of Chemistry and Biochemistry, South Dakota State
University, Brookings, SD, USA
Related authors
Jenna A. Epifanio, Edward J. Brook, Christo Buizert, Erin C. Pettit, Jon S. Edwards, John M. Fegyveresi, Todd A. Sowers, Jeffrey P. Severinghaus, and Emma C. Kahle
The Cryosphere, 17, 4837–4851, https://doi.org/10.5194/tc-17-4837-2023, https://doi.org/10.5194/tc-17-4837-2023, 2023
Short summary
Short summary
The total air content (TAC) of polar ice cores has long been considered a potential proxy for past ice sheet elevation. This study presents a high-resolution record of TAC from the South Pole ice core. The record reveals orbital- and millennial-scale variability that cannot be explained by elevation changes. The orbital- and millennial-scale changes are likely a product of firn grain metamorphism near the surface of the ice sheet, due to summer insolation changes or local accumulation changes.
Helene M. Hoffmann, Mackenzie M. Grieman, Amy C. F. King, Jenna A. Epifanio, Kaden Martin, Diana Vladimirova, Helena V. Pryer, Emily Doyle, Axel Schmidt, Jack D. Humby, Isobel F. Rowell, Christoph Nehrbass-Ahles, Elizabeth R. Thomas, Robert Mulvaney, and Eric W. Wolff
Clim. Past, 18, 1831–1847, https://doi.org/10.5194/cp-18-1831-2022, https://doi.org/10.5194/cp-18-1831-2022, 2022
Short summary
Short summary
The WACSWAIN project (WArm Climate Stability of the West Antarctic ice sheet in the last INterglacial) investigates the fate of the West Antarctic Ice Sheet during the last warm period on Earth (115 000–130 000 years before present). Within this framework an ice core was recently drilled at Skytrain Ice Rise. In this study we present a stratigraphic chronology of that ice core based on absolute age markers and annual layer counting for the last 2000 years.
Eric S. Saltzman, Miranda H. Miranda, John D. Patterson, and Murat Aydin
EGUsphere, https://doi.org/10.5194/egusphere-2025-3587, https://doi.org/10.5194/egusphere-2025-3587, 2025
This preprint is open for discussion and under review for Atmospheric Measurement Techniques (AMT).
Short summary
Short summary
This study describes a system for analysis of hydrogen (H2) and neon (Ne) in polar ice core samples in the field immediately after drilling. The motivation is to reconstruct the atmospheric history of H2 to improve understanding of global H2 biogeochemistry and how it has varied over time. This knowledge will help inform models used to project future atmospheric levels of H2 and assess the climate impacts of widespread utilization of H2 as an energy source.
Lison Soussaintjean, Jochen Schmitt, Joël Savarino, J. Andy Menking, Edward J. Brook, Barbara Seth, Vladimir Lipenkov, Thomas Röckmann, and Hubertus Fischer
EGUsphere, https://doi.org/10.5194/egusphere-2025-3108, https://doi.org/10.5194/egusphere-2025-3108, 2025
This preprint is open for discussion and under review for Biogeosciences (BG).
Short summary
Short summary
Nitrous oxide (N2O) produced in dust-rich Antarctic ice complicates the reconstruction of past atmospheric levels from ice core records. Using isotope analysis, we show that N2O forms from two nitrogen precursors, one being nitrate. For the first time, we demonstrate that the site preference (SP) of N2O reflects the isotopic difference between these precursors, not the production pathway, which challenges the common interpretation of SP.
Marc J. Sailer, Tyler J. Fudge, John D. Patterson, Shuai Yan, Duncan A. Young, Shivangini Singh, Don Blankenship, and Megan Kerr
EGUsphere, https://doi.org/10.5194/egusphere-2025-2104, https://doi.org/10.5194/egusphere-2025-2104, 2025
Short summary
Short summary
In this study, we model vertical atmospheric gas diffusion in ice older than 1 million years in the Antarctic ice sheet. We estimate climate signal preservation and help identify a potential region for a future deep ice core in East Antarctica. We find that regions with low accumulation rates and moderate ice thickness result in lower diffusion rates. In particular, the foothills of Dome A is a promising location for a deep ice core that extends the present ice core record.
Felix S. L. Ng, Rachael H. Rhodes, Tyler J. Fudge, and Eric W. Wolff
EGUsphere, https://doi.org/10.5194/egusphere-2025-1566, https://doi.org/10.5194/egusphere-2025-1566, 2025
Short summary
Short summary
Impurity diffusion in ice causes loss of climate history. We give a new method of finding the diffusion rate from ice-core records. Its use on sulphate data from the EPICA Dome C core reveals rapid diffusion in snow that suggests H2SO4 vapour diffusion in air pores, and much slower diffusion in the ice below that indicates signal relocation between crystal interfaces. We estimate a maximum sulphate diffusion length of 2 cm for ice 1–2 Myr old sought by the ice-coring projects on Little Dome C.
Aaron Chesler, Dominic Winski, Karl Kreutz, Bess Koffman, Erich Osterberg, David Ferris, Zayta Thundercloud, Jihong Cole-Dai, Mark Wells, Aaron Putnam, and Katherine Anderson
EGUsphere, https://doi.org/10.5194/egusphere-2025-1897, https://doi.org/10.5194/egusphere-2025-1897, 2025
Short summary
Short summary
The Southern Hemisphere Westerly Winds impact global climate and Antarctic ice sheet stability; however, there are few complete records over the past 12,000 years. We use a new mineral dust record from a South Pole ice core and identify a decrease in particle concentration and an increase in coarse particle percentage over the past ~11,000 years. Together with other records, our data suggests a southward shift in the winds starting ~6,500 years ago related to warming in the Southern Hemisphere.
Ursula A. Jongebloed, Jacob I. Chalif, Linia Tashmim, William C. Porter, Kelvin H. Bates, Qianjie Chen, Erich C. Osterberg, Bess G. Koffman, Jihong Cole-Dai, Dominic A. Winski, David G. Ferris, Karl J. Kreutz, Cameron P. Wake, and Becky Alexander
Atmos. Chem. Phys., 25, 4083–4106, https://doi.org/10.5194/acp-25-4083-2025, https://doi.org/10.5194/acp-25-4083-2025, 2025
Short summary
Short summary
Marine phytoplankton emit dimethyl sulfide (DMS), which forms methanesulfonic acid (MSA) and sulfate. MSA concentrations in ice cores decreased over the industrial era, which has been attributed to pollution-driven changes in DMS chemistry. We use a model to investigate DMS chemistry compared to observations of DMS, MSA, and sulfate. We find that modeled DMS, MSA, and sulfate are influenced by pollution-sensitive oxidant concentrations, characterization of DMS chemistry, and other variables.
Chloe A. Brashear, Tyler R. Jones, Valerie Morris, Bruce H. Vaughn, William H. G. Roberts, William B. Skorski, Abigail G. Hughes, Richard Nunn, Sune Olander Rasmussen, Kurt M. Cuffey, Bo M. Vinther, Todd Sowers, Christo Buizert, Vasileios Gkinis, Christian Holme, Mari F. Jensen, Sofia E. Kjellman, Petra M. Langebroek, Florian Mekhaldi, Kevin S. Rozmiarek, Jonathan W. Rheinlænder, Margit H. Simon, Giulia Sinnl, Silje Smith-Johnsen, and James W. C. White
Clim. Past, 21, 529–546, https://doi.org/10.5194/cp-21-529-2025, https://doi.org/10.5194/cp-21-529-2025, 2025
Short summary
Short summary
We use a series of spectral techniques to quantify the strength of high-frequency climate variability in northeastern Greenland to 50 000 ka before present. Importantly, we find that variability consistently decreases hundreds of years prior to Dansgaard–Oeschger warming events. Model simulations suggest a change in North Atlantic sea ice behavior contributed to this pattern, thus providing new information on the conditions which preceded abrupt climate change during the Last Glacial Period.
Ingalise Kindstedt, Dominic Winski, C. Max Stevens, Emma Skelton, Luke Copland, Karl Kreutz, Mikaila Mannello, Renée Clavette, Jacob Holmes, Mary Albert, and Scott N. Williamson
EGUsphere, https://doi.org/10.5194/egusphere-2024-3807, https://doi.org/10.5194/egusphere-2024-3807, 2025
Short summary
Short summary
Atmospheric warming over mountain glaciers is leading to increased warming and melting of snow as it compresses into glacier ice. This affects both regional hydrology and climate records contained in the ice. Here we use field observations and modeling to show that surface melting and percolation at Eclipse Icefield (Yukon, Canada) is increasing with an increase in extreme melt events, and that compressing snow at Eclipse is likely to continue warming even if air temperatures remain stable.
Frédéric Parrenin, Marie Bouchet, Christo Buizert, Emilie Capron, Ellen Corrick, Russell Drysdale, Kenji Kawamura, Amaëlle Landais, Robert Mulvaney, Ikumi Oyabu, and Sune Olander Rasmussen
Geosci. Model Dev., 17, 8735–8750, https://doi.org/10.5194/gmd-17-8735-2024, https://doi.org/10.5194/gmd-17-8735-2024, 2024
Short summary
Short summary
The Paleochrono-1.1 probabilistic dating model allows users to derive a common and optimized chronology for several paleoclimatic sites from various archives (ice cores, speleothems, marine cores, lake cores, etc.). It combines prior sedimentation scenarios with chronological information such as dated horizons, dated intervals, stratigraphic links and (for ice cores) Δdepth observations. Paleochrono-1.1 is available under an open-source license.
Mira Berdahl, Gunter R. Leguy, William H. Lipscomb, Bette L. Otto-Bliesner, Esther C. Brady, Robert A. Tomas, Nathan M. Urban, Ian Miller, Harriet Morgan, and Eric J. Steig
Clim. Past, 20, 2349–2371, https://doi.org/10.5194/cp-20-2349-2024, https://doi.org/10.5194/cp-20-2349-2024, 2024
Short summary
Short summary
Studying climate conditions near the Antarctic ice sheet (AIS) during Earth’s past warm periods informs us about how global warming may influence AIS ice loss. Using a global climate model, we investigate climate conditions near the AIS during the Last Interglacial (129 to 116 kyr ago), a period with warmer global temperatures and higher sea level than today. We identify the orbital and freshwater forcings that could cause ice loss and probe the mechanisms that lead to warmer climate conditions.
Robert G. Bingham, Julien A. Bodart, Marie G. P. Cavitte, Ailsa Chung, Rebecca J. Sanderson, Johannes C. R. Sutter, Olaf Eisen, Nanna B. Karlsson, Joseph A. MacGregor, Neil Ross, Duncan A. Young, David W. Ashmore, Andreas Born, Winnie Chu, Xiangbin Cui, Reinhard Drews, Steven Franke, Vikram Goel, John W. Goodge, A. Clara J. Henry, Antoine Hermant, Benjamin H. Hills, Nicholas Holschuh, Michelle R. Koutnik, Gwendolyn J.-M. C. Leysinger Vieli, Emma J. Mackie, Elisa Mantelli, Carlos Martín, Felix S. L. Ng, Falk M. Oraschewski, Felipe Napoleoni, Frédéric Parrenin, Sergey V. Popov, Therese Rieckh, Rebecca Schlegel, Dustin M. Schroeder, Martin J. Siegert, Xueyuan Tang, Thomas O. Teisberg, Kate Winter, Shuai Yan, Harry Davis, Christine F. Dow, Tyler J. Fudge, Tom A. Jordan, Bernd Kulessa, Kenichi Matsuoka, Clara J. Nyqvist, Maryam Rahnemoonfar, Matthew R. Siegfried, Shivangini Singh, Verjan Višnjević, Rodrigo Zamora, and Alexandra Zuhr
EGUsphere, https://doi.org/10.5194/egusphere-2024-2593, https://doi.org/10.5194/egusphere-2024-2593, 2024
Short summary
Short summary
The ice sheets covering Antarctica have built up over millenia through successive snowfall events which become buried and preserved as internal surfaces of equal age detectable with ice-penetrating radar. This paper describes an international initiative to work together on this archival data to build a comprehensive 3-D picture of how old the ice is everywhere across Antarctica, and how this will be used to reconstruct past and predict future ice and climate behaviour.
Murat Aydin, Melinda R. Nicewonger, Gregory L. Britten, Dominic Winski, Mary Whelan, John D. Patterson, Erich Osterberg, Christopher F. Lee, Tara Harder, Kyle J. Callahan, David Ferris, and Eric S. Saltzman
Clim. Past, 20, 1885–1917, https://doi.org/10.5194/cp-20-1885-2024, https://doi.org/10.5194/cp-20-1885-2024, 2024
Short summary
Short summary
We present a new ice core carbonyl sulfide (COS) record from the South Pole, Antarctica, yielding a 52 000-year atmospheric record after correction for production in the ice sheet. The results display a large increase in atmospheric COS concurrent with the last deglaciation. The deglacial COS rise results from an overall strengthening of atmospheric COS sources, implying a large increase in ocean sulfur gas emissions. Atmospheric sulfur gases have negative climate feedbacks.
Romilly Harris Stuart, Amaëlle Landais, Laurent Arnaud, Christo Buizert, Emilie Capron, Marie Dumont, Quentin Libois, Robert Mulvaney, Anaïs Orsi, Ghislain Picard, Frédéric Prié, Jeffrey Severinghaus, Barbara Stenni, and Patricia Martinerie
The Cryosphere, 18, 3741–3763, https://doi.org/10.5194/tc-18-3741-2024, https://doi.org/10.5194/tc-18-3741-2024, 2024
Short summary
Short summary
Ice core δO2/N2 records are useful dating tools due to their local insolation pacing. A precise understanding of the physical mechanism driving this relationship, however, remain ambiguous. By compiling data from 15 polar sites, we find a strong dependence of mean δO2/N2 on accumulation rate and temperature in addition to the well-documented insolation dependence. Snowpack modelling is used to investigate which physical properties drive the mechanistic dependence on these local parameters.
Vasilii V. Petrenko, Segev BenZvi, Michael Dyonisius, Benjamin Hmiel, Andrew M. Smith, and Christo Buizert
The Cryosphere, 18, 3439–3451, https://doi.org/10.5194/tc-18-3439-2024, https://doi.org/10.5194/tc-18-3439-2024, 2024
Short summary
Short summary
This manuscript presents the concept for a new proxy for past variations in the galactic cosmic ray flux (GCR). Past variations in GCR flux are important to understand for interpretation of records of isotopes produced by cosmic rays; these records are used for reconstructing solar variations and past land ice extent. The proxy involves using measurements of 14CO in ice cores, which should provide an uncomplicated and precise estimate of past GCR flux variations for the past few thousand years.
Benjamin Hmiel, Vasilii V. Petrenko, Christo Buizert, Andrew M. Smith, Michael N. Dyonisius, Philip Place, Bin Yang, Quan Hua, Ross Beaudette, Jeffrey P. Severinghaus, Christina Harth, Ray F. Weiss, Lindsey Davidge, Melisa Diaz, Matthew Pacicco, James A. Menking, Michael Kalk, Xavier Faïn, Alden Adolph, Isaac Vimont, and Lee T. Murray
The Cryosphere, 18, 3363–3382, https://doi.org/10.5194/tc-18-3363-2024, https://doi.org/10.5194/tc-18-3363-2024, 2024
Short summary
Short summary
The main aim of this research is to improve understanding of carbon-14 that is produced by cosmic rays in ice sheets. Measurements of carbon-14 in ice cores can provide a range of useful information (age of ice, past atmospheric chemistry, past cosmic ray intensity). Our results show that almost all (>99 %) of carbon-14 that is produced in the upper layer of ice sheets is rapidly lost to the atmosphere. Our results also provide better estimates of carbon-14 production rates in deeper ice.
Jessica Ng, Jeffrey Severinghaus, Ryan Bay, and Delia Tosi
Clim. Past, 20, 1437–1449, https://doi.org/10.5194/cp-20-1437-2024, https://doi.org/10.5194/cp-20-1437-2024, 2024
Short summary
Short summary
The pattern of Earth’s ice age cycles shifted around a million years ago, becoming more extreme and longer in duration. Multiple projects are underway to obtain an Antarctic ice core that covers this time period, as ice cores contain important clues to why the transition happened. To make sure the ice is old enough at the bottom, we demonstrate how to use new technology to quickly measure dust patterns in the ice and compare them to dust in deep-ocean sediments whose ages are known.
Ian E. McDowell, Kaitlin M. Keegan, S. McKenzie Skiles, Christopher P. Donahue, Erich C. Osterberg, Robert L. Hawley, and Hans-Peter Marshall
The Cryosphere, 18, 1925–1946, https://doi.org/10.5194/tc-18-1925-2024, https://doi.org/10.5194/tc-18-1925-2024, 2024
Short summary
Short summary
Accurate knowledge of firn grain size is crucial for many ice sheet research applications. Unfortunately, collecting detailed measurements of firn grain size is difficult. We demonstrate that scanning firn cores with a near-infrared imager can quickly produce high-resolution maps of both grain size and ice layer distributions. We map grain size and ice layer stratigraphy in 14 firn cores from Greenland and document changes to grain size and ice layer content from the extreme melt summer of 2012.
Tyler J. Fudge, Raphael Sauvage, Linh Vu, Benjamin H. Hills, Mirko Severi, and Edwin D. Waddington
Clim. Past, 20, 297–312, https://doi.org/10.5194/cp-20-297-2024, https://doi.org/10.5194/cp-20-297-2024, 2024
Short summary
Short summary
We use the oldest Antarctic ice core to estimate the rate of diffusion of sulfuric acid. Sulfuric acid is a marker of past volcanic activity and is critical in developing ice core timescales. The rate of diffusion is uncertain and is important to know, both for selecting future ice core locations and interpreting ice core records. We find the effective diffusivity of sulfate is 10 times smaller than previously estimated, indicating that the sulfuric acid signals will persist for longer.
John D. Patterson, Murat Aydin, Andrew M. Crotwell, Gabrielle Pétron, Jeffery P. Severinghaus, Paul B. Krummel, Ray L. Langenfelds, Vasilii V. Petrenko, and Eric S. Saltzman
Clim. Past, 19, 2535–2550, https://doi.org/10.5194/cp-19-2535-2023, https://doi.org/10.5194/cp-19-2535-2023, 2023
Short summary
Short summary
Atmospheric levels of molecular hydrogen (H2) can impact climate and air quality. Constraining past changes to atmospheric H2 is useful for understanding how H2 cycles through the Earth system and predicting the impacts of increasing anthropogenic emissions under the
hydrogen economy. Here, we use the aging air found in the polar snowpack to reconstruct H2 levels over the past 100 years. We find that H2 levels increased by 30 % over Greenland and 60 % over Antarctica during the 20th century.
Xavier Faïn, David M. Etheridge, Kévin Fourteau, Patricia Martinerie, Cathy M. Trudinger, Rachael H. Rhodes, Nathan J. Chellman, Ray L. Langenfelds, Joseph R. McConnell, Mark A. J. Curran, Edward J. Brook, Thomas Blunier, Grégory Teste, Roberto Grilli, Anthony Lemoine, William T. Sturges, Boris Vannière, Johannes Freitag, and Jérôme Chappellaz
Clim. Past, 19, 2287–2311, https://doi.org/10.5194/cp-19-2287-2023, https://doi.org/10.5194/cp-19-2287-2023, 2023
Short summary
Short summary
We report on a 3000-year record of carbon monoxide (CO) levels in the Southern Hemisphere's high latitudes by combining ice core and firn air measurements with modern direct atmospheric samples. Antarctica [CO] remained stable (–835 to 1500 CE), decreased during the Little Ice Age, and peaked around 1985 CE. Such evolution reflects stable biomass burning CO emissions before industrialization, followed by growth from CO anthropogenic sources, which decline after 1985 due to improved combustion.
Jenna A. Epifanio, Edward J. Brook, Christo Buizert, Erin C. Pettit, Jon S. Edwards, John M. Fegyveresi, Todd A. Sowers, Jeffrey P. Severinghaus, and Emma C. Kahle
The Cryosphere, 17, 4837–4851, https://doi.org/10.5194/tc-17-4837-2023, https://doi.org/10.5194/tc-17-4837-2023, 2023
Short summary
Short summary
The total air content (TAC) of polar ice cores has long been considered a potential proxy for past ice sheet elevation. This study presents a high-resolution record of TAC from the South Pole ice core. The record reveals orbital- and millennial-scale variability that cannot be explained by elevation changes. The orbital- and millennial-scale changes are likely a product of firn grain metamorphism near the surface of the ice sheet, due to summer insolation changes or local accumulation changes.
Gemma K. O'Connor, Paul R. Holland, Eric J. Steig, Pierre Dutrieux, and Gregory J. Hakim
The Cryosphere, 17, 4399–4420, https://doi.org/10.5194/tc-17-4399-2023, https://doi.org/10.5194/tc-17-4399-2023, 2023
Short summary
Short summary
Glaciers in West Antarctica are rapidly melting, but the causes are unknown due to limited observations. A leading hypothesis is that an unusually large wind event in the 1940s initiated the ocean-driven melting. Using proxy reconstructions (e.g., using ice cores) and climate model simulations, we find that wind events similar to the 1940s event are relatively common on millennial timescales, implying that ocean variability or climate trends are also necessary to explain the start of ice loss.
Ling Fang, Theo M. Jenk, Dominic Winski, Karl Kreutz, Hanna L. Brooks, Emma Erwin, Erich Osterberg, Seth Campbell, Cameron Wake, and Margit Schwikowski
The Cryosphere, 17, 4007–4020, https://doi.org/10.5194/tc-17-4007-2023, https://doi.org/10.5194/tc-17-4007-2023, 2023
Short summary
Short summary
Understanding the behavior of ocean–atmosphere teleconnections in the North Pacific during warm intervals can aid in predicting future warming scenarios. However, majority ice core records from Alaska–Yukon region only provide data for the last few centuries. This study introduces a continuous chronology for Denali ice core from Begguya, Alaska, using multiple dating methods. The early-Holocene-origin Denali ice core will facilitate future investigations of hydroclimate in the North Pacific.
Benoit S. Lecavalier, Lev Tarasov, Greg Balco, Perry Spector, Claus-Dieter Hillenbrand, Christo Buizert, Catherine Ritz, Marion Leduc-Leballeur, Robert Mulvaney, Pippa L. Whitehouse, Michael J. Bentley, and Jonathan Bamber
Earth Syst. Sci. Data, 15, 3573–3596, https://doi.org/10.5194/essd-15-3573-2023, https://doi.org/10.5194/essd-15-3573-2023, 2023
Short summary
Short summary
The Antarctic Ice Sheet Evolution constraint database version 2 (AntICE2) consists of a large variety of observations that constrain the evolution of the Antarctic Ice Sheet over the last glacial cycle. This includes observations of past ice sheet extent, past ice thickness, past relative sea level, borehole temperature profiles, and present-day bedrock displacement rates. The database is intended to improve our understanding of past Antarctic changes and for ice sheet model calibrations.
Michaela Mühl, Jochen Schmitt, Barbara Seth, James E. Lee, Jon S. Edwards, Edward J. Brook, Thomas Blunier, and Hubertus Fischer
Clim. Past, 19, 999–1025, https://doi.org/10.5194/cp-19-999-2023, https://doi.org/10.5194/cp-19-999-2023, 2023
Short summary
Short summary
Our ice core measurements show that methane, ethane, and propane concentrations are significantly elevated above their past atmospheric background for Greenland ice samples containing mineral dust. The underlying co-production process happens during the classical discrete wet extraction of air from the ice sample and affects previous reconstructions of the inter-polar difference of methane as well as methane stable isotope records derived from dust-rich Greenland ice.
Christo Buizert, Sarah Shackleton, Jeffrey P. Severinghaus, William H. G. Roberts, Alan Seltzer, Bernhard Bereiter, Kenji Kawamura, Daniel Baggenstos, Anaïs J. Orsi, Ikumi Oyabu, Benjamin Birner, Jacob D. Morgan, Edward J. Brook, David M. Etheridge, David Thornton, Nancy Bertler, Rebecca L. Pyne, Robert Mulvaney, Ellen Mosley-Thompson, Peter D. Neff, and Vasilii V. Petrenko
Clim. Past, 19, 579–606, https://doi.org/10.5194/cp-19-579-2023, https://doi.org/10.5194/cp-19-579-2023, 2023
Short summary
Short summary
It is unclear how different components of the global atmospheric circulation, such as the El Niño effect, respond to large-scale climate change. We present a new ice core gas proxy, called krypton-86 excess, that reflects past storminess in Antarctica. We present data from 11 ice cores that suggest the new proxy works. We present a reconstruction of changes in West Antarctic storminess over the last 24 000 years and suggest these are caused by north–south movement of the tropical rain belt.
Aaron Chesler, Dominic Winski, Karl Kreutz, Bess Koffman, Erich Osterberg, David Ferris, Zayta Thundercloud, Joseph Mohan, Jihong Cole-Dai, Mark Wells, Michael Handley, Aaron Putnam, Katherine Anderson, and Natalie Harmon
Clim. Past, 19, 477–492, https://doi.org/10.5194/cp-19-477-2023, https://doi.org/10.5194/cp-19-477-2023, 2023
Short summary
Short summary
Ice core microparticle data typically use geometry assumptions to calculate particle mass and flux. We use dynamic particle imaging, a novel technique for ice core dust analyses, combined with traditional laser particle counting and Coulter counter techniques to assess particle shape in the South Pole Ice Core (SPC14) spanning 50–16 ka. Our results suggest that particles are dominantly ellipsoidal in shape and that spherical assumptions overestimate particle mass and flux.
Michael N. Dyonisius, Vasilii V. Petrenko, Andrew M. Smith, Benjamin Hmiel, Peter D. Neff, Bin Yang, Quan Hua, Jochen Schmitt, Sarah A. Shackleton, Christo Buizert, Philip F. Place, James A. Menking, Ross Beaudette, Christina Harth, Michael Kalk, Heidi A. Roop, Bernhard Bereiter, Casey Armanetti, Isaac Vimont, Sylvia Englund Michel, Edward J. Brook, Jeffrey P. Severinghaus, Ray F. Weiss, and Joseph R. McConnell
The Cryosphere, 17, 843–863, https://doi.org/10.5194/tc-17-843-2023, https://doi.org/10.5194/tc-17-843-2023, 2023
Short summary
Short summary
Cosmic rays that enter the atmosphere produce secondary particles which react with surface minerals to produce radioactive nuclides. These nuclides are often used to constrain Earth's surface processes. However, the production rates from muons are not well constrained. We measured 14C in ice with a well-known exposure history to constrain the production rates from muons. 14C production in ice is analogous to quartz, but we obtain different production rates compared to commonly used estimates.
Lindsey Davidge, Eric J. Steig, and Andrew J. Schauer
Atmos. Meas. Tech., 15, 7337–7351, https://doi.org/10.5194/amt-15-7337-2022, https://doi.org/10.5194/amt-15-7337-2022, 2022
Short summary
Short summary
We describe a continuous-flow analysis (CFA) method to measure Δ17O by laser spectroscopy, and we show that centimeter-scale information can be measured reliably in ice cores by this method. We present seasonally resolved Δ17O data from Greenland and demonstrate that the measurement precision is not reduced by the CFA process. Our results encourage the development and use of CFA methods for Δ17O, and they identify calibration strategies as a target for method improvement.
Paul R. Holland, Gemma K. O'Connor, Thomas J. Bracegirdle, Pierre Dutrieux, Kaitlin A. Naughten, Eric J. Steig, David P. Schneider, Adrian Jenkins, and James A. Smith
The Cryosphere, 16, 5085–5105, https://doi.org/10.5194/tc-16-5085-2022, https://doi.org/10.5194/tc-16-5085-2022, 2022
Short summary
Short summary
The Antarctic Ice Sheet is losing ice, causing sea-level rise. However, it is not known whether human-induced climate change has contributed to this ice loss. In this study, we use evidence from climate models and palaeoclimate measurements (e.g. ice cores) to suggest that the ice loss was triggered by natural climate variations but is now sustained by human-forced climate change. This implies that future greenhouse-gas emissions may influence sea-level rise from Antarctica.
Jinhwa Shin, Jinho Ahn, Jai Chowdhry Beeman, Hun-Gyu Lee, Jaemyeong Mango Seo, and Edward J. Brook
Clim. Past, 18, 2063–2075, https://doi.org/10.5194/cp-18-2063-2022, https://doi.org/10.5194/cp-18-2063-2022, 2022
Short summary
Short summary
We present a new and highly resolved atmospheric CO2 record from the Siple Dome ice core, Antarctica, over the early Holocene (11.7–7.4 ka). Atmospheric CO2 decreased by ~10 ppm from 10.9 to 7.3 ka, but the decrease was punctuated by local minima at 11.1, 10.1, 9.1, and 8.3 ka. We found millennial CO2 variability of 2–6 ppm, and the millennial CO2 variations correlate with proxies for solar forcing and local climate in the Southern Ocean, North Atlantic, and eastern equatorial Pacific.
Helene M. Hoffmann, Mackenzie M. Grieman, Amy C. F. King, Jenna A. Epifanio, Kaden Martin, Diana Vladimirova, Helena V. Pryer, Emily Doyle, Axel Schmidt, Jack D. Humby, Isobel F. Rowell, Christoph Nehrbass-Ahles, Elizabeth R. Thomas, Robert Mulvaney, and Eric W. Wolff
Clim. Past, 18, 1831–1847, https://doi.org/10.5194/cp-18-1831-2022, https://doi.org/10.5194/cp-18-1831-2022, 2022
Short summary
Short summary
The WACSWAIN project (WArm Climate Stability of the West Antarctic ice sheet in the last INterglacial) investigates the fate of the West Antarctic Ice Sheet during the last warm period on Earth (115 000–130 000 years before present). Within this framework an ice core was recently drilled at Skytrain Ice Rise. In this study we present a stratigraphic chronology of that ice core based on absolute age markers and annual layer counting for the last 2000 years.
Ingalise Kindstedt, Kristin M. Schild, Dominic Winski, Karl Kreutz, Luke Copland, Seth Campbell, and Erin McConnell
The Cryosphere, 16, 3051–3070, https://doi.org/10.5194/tc-16-3051-2022, https://doi.org/10.5194/tc-16-3051-2022, 2022
Short summary
Short summary
We show that neither the large spatial footprint of the MODIS sensor nor poorly constrained snow emissivity values explain the observed cold offset in MODIS land surface temperatures (LSTs) in the St. Elias. Instead, the offset is most prominent under conditions associated with near-surface temperature inversions. This work represents an advance in the application of MODIS LSTs to glaciated alpine regions, where we often depend solely on remote sensing products for temperature information.
Jacob D. Morgan, Christo Buizert, Tyler J. Fudge, Kenji Kawamura, Jeffrey P. Severinghaus, and Cathy M. Trudinger
The Cryosphere, 16, 2947–2966, https://doi.org/10.5194/tc-16-2947-2022, https://doi.org/10.5194/tc-16-2947-2022, 2022
Short summary
Short summary
The composition of air bubbles in Antarctic ice cores records information about past changes in properties of the snowpack. We find that, near the South Pole, thinner snowpack in the past is often due to steeper surface topography, in which faster winds erode the snow and deposit it in flatter areas. The slope and wind seem to also cause a seasonal bias in the composition of air bubbles in the ice core. These findings will improve interpretation of other ice cores from places with steep slopes.
Bradley R. Markle and Eric J. Steig
Clim. Past, 18, 1321–1368, https://doi.org/10.5194/cp-18-1321-2022, https://doi.org/10.5194/cp-18-1321-2022, 2022
Short summary
Short summary
The geochemistry preserved in polar ice can provide detailed histories of Earth’s climate over millennia. Here we use the stable isotope ratios of ice from many Antarctic ice cores to reconstruct temperature variability of Antarctica and the midlatitude Southern Hemisphere over tens of thousands of years. We improve upon existing methods to estimate temperature from the geochemical measurements and investigate the patterns of climate change in the past.
Giyoon Lee, Jinho Ahn, Hyeontae Ju, Florian Ritterbusch, Ikumi Oyabu, Christo Buizert, Songyi Kim, Jangil Moon, Sambit Ghosh, Kenji Kawamura, Zheng-Tian Lu, Sangbum Hong, Chang Hee Han, Soon Do Hur, Wei Jiang, and Guo-Min Yang
The Cryosphere, 16, 2301–2324, https://doi.org/10.5194/tc-16-2301-2022, https://doi.org/10.5194/tc-16-2301-2022, 2022
Short summary
Short summary
Blue-ice areas (BIAs) have several advantages for reconstructing past climate. However, the complicated ice flow in the area hinders constraining the age. We applied state-of-the-art techniques and found that the ages cover the last deglaciation period. Our study demonstrates that the BIA in northern Victoria Land may help reconstruct the past climate during the termination of the last glacial period.
Xavier Faïn, Rachael H. Rhodes, Philip Place, Vasilii V. Petrenko, Kévin Fourteau, Nathan Chellman, Edward Crosier, Joseph R. McConnell, Edward J. Brook, Thomas Blunier, Michel Legrand, and Jérôme Chappellaz
Clim. Past, 18, 631–647, https://doi.org/10.5194/cp-18-631-2022, https://doi.org/10.5194/cp-18-631-2022, 2022
Short summary
Short summary
Carbon monoxide (CO) is a regulated pollutant and one of the key components determining the oxidizing capacity of the atmosphere. In this study, we analyzed five ice cores from Greenland at high resolution for CO concentrations by coupling laser spectrometry with continuous melting. By combining these new datasets, we produced an upper-bound estimate of past atmospheric CO abundance since preindustrial times for the Northern Hemisphere high latitudes, covering the period from 1700 to 1957 CE.
Ikumi Oyabu, Kenji Kawamura, Tsutomu Uchida, Shuji Fujita, Kyotaro Kitamura, Motohiro Hirabayashi, Shuji Aoki, Shinji Morimoto, Takakiyo Nakazawa, Jeffrey P. Severinghaus, and Jacob D. Morgan
The Cryosphere, 15, 5529–5555, https://doi.org/10.5194/tc-15-5529-2021, https://doi.org/10.5194/tc-15-5529-2021, 2021
Short summary
Short summary
We present O2/N2 and Ar/N2 records from the Dome Fuji ice core through the bubbly ice, bubble–clathrate transition, and clathrate ice zones without gas-loss fractionation. The insolation signal is preserved through the clathrate formation. The relationship between Ar/Ν2 and Ο2/Ν2 suggests that the fractionation for the bubble–clathrate transition is mass independent, while the bubble close-off process involves a combination of mass-independent and mass-dependent fractionation for O2 and Ar.
Sarah Shackleton, James A. Menking, Edward Brook, Christo Buizert, Michael N. Dyonisius, Vasilii V. Petrenko, Daniel Baggenstos, and Jeffrey P. Severinghaus
Clim. Past, 17, 2273–2289, https://doi.org/10.5194/cp-17-2273-2021, https://doi.org/10.5194/cp-17-2273-2021, 2021
Short summary
Short summary
In this study, we measure atmospheric noble gases trapped in ice cores to reconstruct ocean temperature during the last glaciation. Comparing the new reconstruction to other climate records, we show that the ocean reached its coldest temperatures before ice sheets reached maximum volumes and atmospheric CO2 reached its lowest concentrations. Ocean cooling played a major role in lowering atmospheric CO2 early in the glaciation, but it only played a minor role later.
Yuzhen Yan, Nicole E. Spaulding, Michael L. Bender, Edward J. Brook, John A. Higgins, Andrei V. Kurbatov, and Paul A. Mayewski
Clim. Past, 17, 1841–1855, https://doi.org/10.5194/cp-17-1841-2021, https://doi.org/10.5194/cp-17-1841-2021, 2021
Short summary
Short summary
Here we reconstruct the rate of snow accumulation during the Last Interglacial period in an East Antarctic ice core located near the present-day northern edge of the Ross Ice Shelf. We find an order-of-magnitude increase in the accumulation rate during the peak warming in the Last Interglacial. This large increase in mass accumulation is compatible with less ice cover in the Ross Sea, perhaps created by a partly collapsed West Antarctic Ice Sheet, whose stability in a warming world is uncertain.
Benjamin Birner, William Paplawsky, Jeffrey Severinghaus, and Ralph F. Keeling
Atmos. Meas. Tech., 14, 2515–2527, https://doi.org/10.5194/amt-14-2515-2021, https://doi.org/10.5194/amt-14-2515-2021, 2021
Short summary
Short summary
The atmospheric helium-to-nitrogen ratio is a promising indicator for circulation changes in the upper atmosphere and fossil fuel burning by humans. We present a very precise analysis method to determine changes in the helium-to-nitrogen ratio of air samples. The method relies on stabilizing the gas flow to a mass spectrometer and continuous removal of reactive gases. These advances enable new insights and monitoring possibilities for anthropogenic and natural processes.
Ikumi Oyabu, Kenji Kawamura, Kyotaro Kitamura, Remi Dallmayr, Akihiro Kitamura, Chikako Sawada, Jeffrey P. Severinghaus, Ross Beaudette, Anaïs Orsi, Satoshi Sugawara, Shigeyuki Ishidoya, Dorthe Dahl-Jensen, Kumiko Goto-Azuma, Shuji Aoki, and Takakiyo Nakazawa
Atmos. Meas. Tech., 13, 6703–6731, https://doi.org/10.5194/amt-13-6703-2020, https://doi.org/10.5194/amt-13-6703-2020, 2020
Short summary
Short summary
Air in polar ice cores provides information on past atmosphere and climate. We present a new method for simultaneously measuring eight gases (CH4, N2O and CO2 concentrations; isotopic ratios of N2 and O2; elemental ratios between N2, O2 and Ar; and total air content) from single ice-core samples with high precision.
Benjamin Birner, Martyn P. Chipperfield, Eric J. Morgan, Britton B. Stephens, Marianna Linz, Wuhu Feng, Chris Wilson, Jonathan D. Bent, Steven C. Wofsy, Jeffrey Severinghaus, and Ralph F. Keeling
Atmos. Chem. Phys., 20, 12391–12408, https://doi.org/10.5194/acp-20-12391-2020, https://doi.org/10.5194/acp-20-12391-2020, 2020
Short summary
Short summary
With new high-precision observations from nine aircraft campaigns and 3-D chemical transport modeling, we show that the argon-to-nitrogen ratio (Ar / N2) in the lowermost stratosphere provides a useful constraint on the “age of air” (the time elapsed since entry of an air parcel into the stratosphere). Therefore, Ar / N2 in combination with traditional age-of-air indicators, such as CO2 and N2O, could provide new insights into atmospheric mixing and transport.
C. Max Stevens, Vincent Verjans, Jessica M. D. Lundin, Emma C. Kahle, Annika N. Horlings, Brita I. Horlings, and Edwin D. Waddington
Geosci. Model Dev., 13, 4355–4377, https://doi.org/10.5194/gmd-13-4355-2020, https://doi.org/10.5194/gmd-13-4355-2020, 2020
Short summary
Short summary
Understanding processes in snow (firn), including compaction and airflow, is important for calculating how much mass the ice sheets are losing and for interpreting climate records from ice cores. We have developed the open-source Community Firn Model to simulate these processes. We used it to compare 13 different firn compaction equations and found that they do not agree within 10 %. We also show that including firn compaction in a firn-air model improves the match with data from ice cores.
James E. Lee, Edward J. Brook, Nancy A. N. Bertler, Christo Buizert, Troy Baisden, Thomas Blunier, V. Gabriela Ciobanu, Howard Conway, Dorthe Dahl-Jensen, Tyler J. Fudge, Richard Hindmarsh, Elizabeth D. Keller, Frédéric Parrenin, Jeffrey P. Severinghaus, Paul Vallelonga, Edwin D. Waddington, and Mai Winstrup
Clim. Past, 16, 1691–1713, https://doi.org/10.5194/cp-16-1691-2020, https://doi.org/10.5194/cp-16-1691-2020, 2020
Short summary
Short summary
The Roosevelt Island ice core was drilled to investigate climate from the eastern Ross Sea, West Antarctica. We describe the ice age-scale and gas age-scale of the ice core for 0–763 m (83 000 years BP). Old ice near the bottom of the core implies the ice dome existed throughout the last glacial period and that ice streaming was active in the region. Variations in methane, similar to those used as evidence of early human influence on climate, were observed prior to significant human populations.
Cited articles
Arnaud, L., Barnola, J. M., and Duval, P.: Physical modeling of the
densification of snow/firn and ice in the upper part of polar ice sheets,
Physics of Ice Core Records, 25, 285–305, 2000.
Aydin, M., Saltzman, E. S., Bruyn, W. J. D., Montzka, S. A., Butler, J. H.,
and Battle, M.: Atmospheric variability of methyl chloride during the last
300 years from an Antarctic ice core and firn air, Geophys. Res. Lett.,
31, L02109, https://doi.org/10.1029/2003GL018750, 2004.
Barnola, J.-M., Pimienta, P., Raynaud, D., and Korotkevich, Y. S.:
CO2-climate relationship as deduced from the Vostok ice core: a
re-examination based on new measurements and on a re-evaluation of the air
dating, Tellus B, 43, 83–90, https://doi.org/10.1034/j.1600-0889.1991.t01-1-00002.x,
1991.
Battle, M., Bender, M., Sowers, T., Tans, P. P., Butler, J. H., Elkins, J.
W., Ellis, J. T., Conway, T., Zhang, N., Lang, P., and Clarket, A. D.:
Atmospheric gas concentrations over the past century measured in air from
firn at the South Pole, Nature, 383, 231–235, https://doi.org/10.1038/383231a0,
1996.
Battle, M. O., Severinghaus, J. P., Sofen, E. D., Plotkin, D., Orsi, A. J., Aydin, M., Montzka, S. A., Sowers, T., and Tans, P. P.: Controls on the movement and composition of firn air at the West Antarctic Ice Sheet Divide, Atmos. Chem. Phys., 11, 11007–11021, https://doi.org/10.5194/acp-11-11007-2011, 2011.
Baumgartner, M., Kindler, P., Eicher, O., Floch, G., Schilt, A., Schwander, J., Spahni, R., Capron, E., Chappellaz, J., Leuenberger, M., Fischer, H., and Stocker, T. F.: NGRIP CH4 concentration from 120 to 10 kyr before present and its relation to a δ15N temperature reconstruction from the same ice core, Clim. Past, 10, 903–920, https://doi.org/10.5194/cp-10-903-2014, 2014.
Bazin, L., Landais, A., Lemieux-Dudon, B., Toyé Mahamadou Kele, H., Veres, D., Parrenin, F., Martinerie, P., Ritz, C., Capron, E., Lipenkov, V., Loutre, M.-F., Raynaud, D., Vinther, B., Svensson, A., Rasmussen, S. O., Severi, M., Blunier, T., Leuenberger, M., Fischer, H., Masson-Delmotte, V., Chappellaz, J., and Wolff, E.: An optimized multi-proxy, multi-site Antarctic ice and gas orbital chronology (AICC2012): 120–800 ka, Clim. Past, 9, 1715–1731, https://doi.org/10.5194/cp-9-1715-2013, 2013.
Blunier, T. and Brook, E. J.: Timing of millennial-scale climate change in
Antarctica and Greenland during the last glacial period, Science, 291,
109–112, 2001.
Blunier, T., Spahni, R., Barnola, J.-M., Chappellaz, J., Loulergue, L., and Schwander, J.: Synchronization of ice core records via atmospheric gases, Clim. Past, 3, 325–330, https://doi.org/10.5194/cp-3-325-2007, 2007.
Bréant, C., Martinerie, P., Orsi, A., Arnaud, L., and Landais, A.: Modelling firn thickness evolution during the last deglaciation: constraints on sensitivity to temperature and impurities, Clim. Past, 13, 833–853, https://doi.org/10.5194/cp-13-833-2017, 2017.
Brook, E. J. and Buizert, C.: Antarctic and global climate history viewed
from ice cores, Nature, 558, 200–208, https://doi.org/10.1038/s41586-018-0172-5,
2018.
Brook, E. J., Sowers, T., and Orchardo, J.: Rapid variations in atmospheric
methane concentration during the past 110,000 years, Science, 273, 1087–1090, 1996.
Buizert, C. and Severinghaus, J. P.: Dispersion in deep polar firn driven by synoptic-scale surface pressure variability, The Cryosphere, 10, 2099–2111, https://doi.org/10.5194/tc-10-2099-2016, 2016.
Buizert, C., Martinerie, P., Petrenko, V. V., Severinghaus, J. P., Trudinger, C. M., Witrant, E., Rosen, J. L., Orsi, A. J., Rubino, M., Etheridge, D. M., Steele, L. P., Hogan, C., Laube, J. C., Sturges, W. T., Levchenko, V. A., Smith, A. M., Levin, I., Conway, T. J., Dlugokencky, E. J., Lang, P. M., Kawamura, K., Jenk, T. M., White, J. W. C., Sowers, T., Schwander, J., and Blunier, T.: Gas transport in firn: multiple-tracer characterisation and model intercomparison for NEEM, Northern Greenland, Atmos. Chem. Phys., 12, 4259–4277, https://doi.org/10.5194/acp-12-4259-2012, 2012.
Buizert, C., Sowers, T., and Blunier, T.: Assessment of diffusive isotopic
fractionation in polar firn, and application to ice core trace gas records,
Earth Planet. Sc. Lett., 361, 110–119, https://doi.org/10.1016/j.epsl.2012.11.039,
2013.
Buizert, C., Cuffey, K. M., Severinghaus, J. P., Baggenstos, D., Fudge, T. J., Steig, E. J., Markle, B. R., Winstrup, M., Rhodes, R. H., Brook, E. J., Sowers, T. A., Clow, G. D., Cheng, H., Edwards, R. L., Sigl, M., McConnell, J. R., and Taylor, K. C.: The WAIS Divide deep ice core WD2014 chronology – Part 1: Methane synchronization (68–31 ka BP) and the gas age–ice age difference, Clim. Past, 11, 153–173, https://doi.org/10.5194/cp-11-153-2015, 2015.
Buizert, C., Sigl, M., Severi, M., Markle, B. R., Wettstein, J. J.,
McConnell, J. R., Pedro, J. B., Sodemann, H., Goto-Azuma, K., Kawamura, K.,
Fujita, S., Motoyama, H., Hirabayashi, M., Uemura, R., Stenni, B., Parrenin,
F., He, F., Fudge, T. J., and Steig, E. J.: Abrupt ice-age shifts in southern
westerly winds and Antarctic climate forced from the north, Nature,
563, 681–685, https://doi.org/10.1038/s41586-018-0727-5, 2018.
Casey, K. A., Fudge, T. J., Neumann, T. A., Steig, E. J., Cavitte, M. G. P., and Blankenship, D. D.: The 1500 m South Pole ice core: recovering a 40 ka environmental record, Ann. Glaciol., 55, 137–146, 2014.
Casey, K. A., Kaspari, S. D., Skiles, S. M., Kreutz, K., and Handley, M. J.:
The spectral and chemical measurement of pollutants on snow near South Pole,
Antarctica, J. Geophys. Res.-Atmos., 122, 6592–6610,
https://doi.org/10.1002/2016JD026418, 2017.
Craig, H., Horibe, Y., and Sowers, T.: Gravitational Separation of Gases and
Isotopes in Polar Ice Caps, Science, 242, 1675–1678,
https://doi.org/10.1126/science.242.4886.1675, 1988.
Dlugokencky, E. J., Myers, R. C., Lang, P. M., Masarie, K. A., Crotwell, A.
M., Thoning, K. W., Hall, B. D., Elkins, J. W., and Steele, L. P.: Conversion
of NOAA atmospheric dry air CH4 mole fractions to a gravimetrically prepared
standard scale, J. Geophys. Res.-Atmos., 110, D18306, https://doi.org/10.1029/2005JD006035, 2005.
Elderfield, H., Ferretti, P., Greaves, M., Crowhurst, S., McCave, I. N.,
Hodell, D. A., and Piotrowski, A. M.: Evolution of ocean temperature and ice
volume through the mid-Pleistocene climate transition, Science, 337,
704–709, 2012.
Epifanio, J.: SP19 Gas Chronology, U.S. Antarctic Program (USAP) Data Center, https://doi.org/10.15784/601380, 2020.
Epifanio, J., Brook, E. J., Buizert, C., Severinghaus, J., Kreutz, K., Aydin, M., Edwards, J. S., Sowers, T. A., Kahle, E., Steig, E. J., Winski, D. A., Osterberg, E., Fudge, T. J., Hood, E., Kalk, M., Ferris, D. G., and Kennedy, J. A.: South Pole ice core (SPC14) discrete methane data, U.S. Antarctic Program (USAP) Data Center, https://doi.org/10.15784/601381, 2020.
Epifanio, J. A., Brook, E. J., Buizert, C., Edwards, J. S., Sowers, T. A., Kahle, E. C., Severinghaus, J. P., Steig, E. J., Winski, D. A., Osterberg, E. C., Fudge, T. J., Aydin, M., Hood, E., Kalk, M., Kreutz, K. J., Ferris, D. G., and Kennedy, J. A.: South Pole Ice Core 52,000 Year SP19 Gas Age Chronology and Methane Data, available at: https://www.ncdc.noaa.gov/paleo-search/study/31532 (last access: 1 December 2020), National Centers for Environmental Information, 2020.
Ferretti, D. F.: Unexpected Changes to the Global Methane Budget over the
Past 2000 Years, Science, 309, 1714–1717,
https://doi.org/10.1126/science.1115193, 2005.
Fourteau, K., Faïn, X., Martinerie, P., Landais, A., Ekaykin, A. A., Lipenkov, V. Ya., and Chappellaz, J.: Analytical constraints on layered gas trapping and smoothing of atmospheric variability in ice under low-accumulation conditions, Clim. Past, 13, 1815–1830, https://doi.org/10.5194/cp-13-1815-2017, 2017.
Fourteau, K., Martinerie, P., Faïn, X., Schaller, C. F., Tuckwell, R. J., Löwe, H., Arnaud, L., Magand, O., Thomas, E. R., Freitag, J., Mulvaney, R., Schneebeli, M., and Lipenkov, V. Ya.: Multi-tracer study of gas trapping in an East Antarctic ice core, The Cryosphere, 13, 3383–3403, https://doi.org/10.5194/tc-13-3383-2019, 2019.
Freitag, J., Kipfstuhl, S., Laepple, T., and Wilhelms, F.:
Impurity-controlled densification: a new model for stratified polar firn, J.
Glaciol., 59, 1163–1169, https://doi.org/10.3189/2013JoG13J042, 2013.
Fudge, T. J., Waddington, E. D., Conway, H., Lundin, J. M. D., and Taylor, K.: Interpolation methods for Antarctic ice-core timescales: application to Byrd, Siple Dome and Law Dome ice cores, Clim. Past, 10, 1195–1209, https://doi.org/10.5194/cp-10-1195-2014, 2014.
Goujon, C., Barnola, J.-M., and Ritz, C.: Modeling the densification of polar
firn including heat diffusion: Application to close-off characteristics and
gas isotopic fractionation for Antarctica and Greenland sites, J. Geophys.
Res.-Atmos., 108, https://doi.org/10.1029/2002JD003319, 2003.
Grachev, A. M., Brook, E. J., Severinghaus, J. P., and Pisias, N. G.:
Relative timing and variability of atmospheric methane and GISP2 oxygen
isotopes between 68 and 86 ka, Global Biogeochem. Cy., 23, GB2009, https://doi.org/10.1029/2008GB003330, 2009.
Gregory, S. A., Albert, M. R., and Baker, I.: Impact of physical properties and accumulation rate on pore close-off in layered firn, The Cryosphere, 8, 91–105, https://doi.org/10.5194/tc-8-91-2014, 2014.
Herron, M. M. and Langway, C. C.: Firn densification: an empirical model, J.
Glaciol., 25, 373–385, 1980.
Hodell, D. A., Nicholl, J. A., Bontognali, T. R., Danino, S., Dorador, J.,
Dowdeswell, J. A., Einsle, J., Kuhlmann, H., Martrat, B., and
Mleneck-Vautravers, M. J.: Anatomy of Heinrich Layer 1 and its role in the
last deglaciation, Paleoceanography, 32, 284–303, 2017.
Huber, C., Leuenberger, M., Spahni, R., Flückiger, J., Schwander, J.,
Stocker, T. F., Johnsen, S., Landais, A., and Jouzel, J.: Isotope calibrated
Greenland temperature record over Marine Isotope Stage 3 and its relation to
CH4, Earth Planet. Sci. Lett., 243, 504–519,
https://doi.org/10.1016/j.epsl.2006.01.002, 2006.
Kawamura, K., Severinghaus, J. P., Ishidoya, S., Sugawara, S., Hashida, G.,
Motoyama, H., Fujii, Y., Aoki, S., and Nakazawa, T.: Convective mixing of air
in firn at four polar sites, Earth Planet. Sci. Lett., 244, 672–682,
https://doi.org/10.1016/j.epsl.2006.02.017, 2006.
Keenan, E., Wever, N., Dattler, M., Lenaerts, J. T. M., Medley, B., Kuipers Munneke, P., and Reijmer, C.: Physics-based modeling of Antarctic snow and firn density, The Cryosphere Discuss., https://doi.org/10.5194/tc-2020-175, in review, 2020.
Köhler, P., Knorr, G., Buiron, D., Lourantou, A., and Chappellaz, J.: Abrupt rise in atmospheric CO2 at the onset of the Bølling/Allerød: in-situ ice core data versus true atmospheric signals, Clim. Past, 7, 473–486, https://doi.org/10.5194/cp-7-473-2011, 2011.
Lee, J. E., Brook, E. J., Bertler, N. A. N., Buizert, C., Baisden, T., Blunier, T., Ciobanu, V. G., Conway, H., Dahl-Jensen, D., Fudge, T. J., Hindmarsh, R., Keller, E. D., Parrenin, F., Severinghaus, J. P., Vallelonga, P., Waddington, E. D., and Winstrup, M.: An 83 000-year-old ice core from Roosevelt Island, Ross Sea, Antarctica, Clim. Past, 16, 1691–1713, https://doi.org/10.5194/cp-16-1691-2020, 2020a.
Lee, J. E., Edwards, J. S., Schmitt, J., Fischer, H., Bock, M., and Brook, E.
J.: Excess methane in Greenland ice cores associated with high dust
concentrations, Geochim. Cosmochim. Ac., 270, 409–430,
https://doi.org/10.1016/j.gca.2019.11.020, 2020b.
Lilien, D. A., Fudge, T. J., Koutnik, M. R., Conway, H., Osterberg, E. C.,
Ferris, D. G., Waddington, E. D., and Stevens, C. M.: Holocene Ice-Flow
Speedup in the Vicinity of the South Pole, Geophys. Res. Lett., 45,
6557–6565, https://doi.org/10.1029/2018GL078253, 2018.
Loulergue, L., Parrenin, F., Blunier, T., Barnola, J.-M., Spahni, R., Schilt, A., Raisbeck, G., and Chappellaz, J.: New constraints on the gas age-ice age difference along the EPICA ice cores, 0–50 kyr, Clim. Past, 3, 527–540, https://doi.org/10.5194/cp-3-527-2007, 2007.
Lundin, J. M. D., Stevens, C. M., Arthern, R., Buizert, C., Orsi, A.,
Ligtenberg, S. R. M., Simonsen, S. B., Cummings, E., Essery, R., Leahy, W.,
Harris, P., Helsen, M. M., and Waddington, E. D.: Firn Model Intercomparison
Experiment (FirnMICE), J. Glaciol., 63, 401–422,
https://doi.org/10.1017/jog.2016.114, 2017.
Marcott, S. A., Shakun, J. D., Clark, P. U., and Mix, A. C.: A Reconstruction
of Regional and Global Temperature for the Past 11,300 Years, Science,
339, 1198–1201, https://doi.org/10.1126/science.1228026, 2013.
Mischler, J. A., Sowers, T. A., Alley, R. B., Battle, M., McConnell, J. R.,
Mitchell, L., Popp, T., Sofen, E., and Spencer, M. K.: Carbon and hydrogen
isotopic composition of methane over the last 1000 years, Global Biogeochem.
Cy., 23, GB4024, https://doi.org/10.1029/2009GB003460, 2009.
Mitchell, L., Brook, E., Lee, J. E., Buizert, C., and Sowers, T.: Constraints
on the late Holocene anthropogenic contribution to the atmospheric methane
budget, Science, 342, 964–966, 2013.
Mitchell, L. E., Brook, E. J., Sowers, T., McConnell, J. R., and Taylor, K.:
Multidecadal variability of atmospheric methane, 1000–1800 CE, J. Geophys.
Res.-Biogeo., 116, G02007, https://doi.org/10.1029/2010JG001441, 2011.
Mitchell, L. E., Buizert, C., Brook, E. J., Breton, D. J., Fegyveresi, J.,
Baggenstos, D., Orsi, A., Severinghaus, J., Alley, R. B., Albert, M.,
Rhodes, R. H., McConnell, J. R., Sigl, M., Maselli, O., Gregory, S., and Ahn,
J.: Observing and modeling the influence of layering on bubble trapping in
polar firn, J. Geophys. Res.-Atmos., 120, 2558–2574,
https://doi.org/10.1002/2014jd022766, 2015.
Mosley-Thompson, E., Paskievitch, J. F., Gow, A. J., and Thompson, L. G.:
Late 20th Century increase in South Pole snow accumulation, J. Geophys. Res.-Atmos., 104, 3877–3886, https://doi.org/10.1029/1998JD200092, 1999.
Nicewonger, M. R., Aydin, M., Prather, M. J., and Saltzman, E. S.: Large
changes in biomass burning over the last millennium inferred from
paleoatmospheric ethane in polar ice cores, P. Natl. Acad. Sci. USA, 115,
12413–12418, https://doi.org/10.1073/pnas.1807172115, 2018.
Petit, J. R., Jouzel, J., Raynaud, D., Barkov, N. I., Barnola, J.-M.,
Basile, I., Bender, M., Chappellaz, J., Davis, M., Delaygue, G., Delmotte,
M., Kotlyakov, V. M., Legrand, M., Lipenkov, V. Y., Lorius, C., PÉpin,
L., Ritz, C., Saltzman, E., and Stievenard, M.: Climate and atmospheric
history of the past 420,000 years from the Vostok ice core, Antarctica,
Nature, 399, 429–436, https://doi.org/10.1038/20859, 1999.
Rhodes, R. H., Brook, E. J., Chiang, J. C. H., Blunier, T., Maselli, O. J.,
McConnell, J. R., Romanini, D., and Severinghaus, J. P.: Enhanced tropical
methane production in response to iceberg discharge in the North Atlantic,
Science, 348, 1016–1019, https://doi.org/10.1126/science.1262005, 2015.
Rhodes, R. H., Brook, E. J., McConnell, J. R., Blunier, T., Sime, L. C.,
Faïn, X., and Mulvaney, R.: Atmospheric methane variability:
Centennial-scale signals in the Last Glacial Period: Centennial-Scale
Methane Variability, Global Biogeochem. Cy., 31, 575–590,
https://doi.org/10.1002/2016GB005570, 2017.
Rosen, J. L., Brook, E. J., Severinghaus, J. P., Blunier, T., Mitchell, L.
E., Lee, J. E., Edwards, J. S., and Gkinis, V.: An ice core record of
near-synchronous global climate changes at the Bølling transition, Nat.
Geosci., 7, 459–463, https://doi.org/10.1038/ngeo2147, 2014.
Saltzman, E. S., Aydin, M., Bruyn, W. J. D., King, D. B., and Yvon-Lewis, S.
A.: Methyl bromide in preindustrial air: Measurements from an Antarctic ice
core, J. Geophys. Res.-Atmos., 109, D05302, https://doi.org/10.1029/2003JD004157, 2004.
Sapart, C. J., Monteil, G., Prokopiou, M., van de Wal, R. S. W., Kaplan, J.
O., Sperlich, P., Krumhardt, K. M., van der Veen, C., Houweling, S., Krol,
M. C., Blunier, T., Sowers, T., Martinerie, P., Witrant, E., Dahl-Jensen, D.,
and Röckmann, T.: Natural and anthropogenic variations in methane
sources during the past two millennia, Nature, 490, 85–88,
https://doi.org/10.1038/nature11461, 2012.
Schwander, J. and Stauffer, B.: Age difference between polar ice and the air
trapped in its bubbles, Nature, 311, 45–47, 1984.
Schwander, J., Barnola, J.-M., Andrié, C., Leuenberger, M., Ludin, A.,
Raynaud, D., and Stauffer, B.: The age of the air in the firn and the ice at
Summit, Greenland, J. Geophys. Res.-Atmos., 98, 2831–2838,
https://doi.org/10.1029/92JD02383, 1993.
Schwander, J., Sowers, T., Barnola, J.-M., Blunier, T., Fuchs, A., and
Malaizé, B.: Age scale of the air in the summit ice: Implication for
glacial-interglacial temperature change, J. Geophys. Res.-Atmos.,
102, 19483–19493, 1997.
Severinghaus, J. P. and Battle, M. O.: Fractionation of gases in polar ice
during bubble close-off: New constraints from firn air Ne, Kr and Xe
observations, Earth Planet. Sc. Lett., 244, 474–500,
https://doi.org/10.1016/j.epsl.2006.01.032, 2006.
Severinghaus, J. P. and Brook, E. J.: Abrupt Climate Change at the End of the Last 40 Glacial Period Inferred from Trapped Air in Polar Ice, Science,
286, 930–934, https://doi.org/10.1126/science.286.5441.930,
1999.
Severinghaus, J. P., Sowers, T., Brook, E. J., Alley, R. B., and Bender, M.
L.: Timing of abrupt climate change at the end of the Younger Dryas interval
from thermally fractionated gases in polar ice, Nature, 391, 141–146,
1998.
Severinghaus, J. P., Grachev, A., and Battle, M.: Thermal fractionation of
air in polar firn by seasonal temperature gradients: Thermal Fractionation
of Air, Geochem. Geophy. Geosy., 2, n/a–n/a,
https://doi.org/10.1029/2000GC000146, 2001.
Sigl, M., Fudge, T. J., Winstrup, M., Cole-Dai, J., Ferris, D., McConnell, J. R., Taylor, K. C., Welten, K. C., Woodruff, T. E., Adolphi, F., Bisiaux, M., Brook, E. J., Buizert, C., Caffee, M. W., Dunbar, N. W., Edwards, R., Geng, L., Iverson, N., Koffman, B., Layman, L., Maselli, O. J., McGwire, K., Muscheler, R., Nishiizumi, K., Pasteris, D. R., Rhodes, R. H., and Sowers, T. A.: The WAIS Divide deep ice core WD2014 chronology – Part 2: Annual-layer counting (0–31 ka BP), Clim. Past, 12, 769–786, https://doi.org/10.5194/cp-12-769-2016, 2016.
Sowers, T., Bender, M., Raynaud, D., and Korotkevich, Y. S.: δ15N of
N2 in air trapped in polar ice: A tracer of gas transport in the firn and a
possible constraint on ice age-gas age differences, J. Geophys. Res.-Atmos., 97, 15683–15697, https://doi.org/10.1029/92JD01297, 1992.
Spahni, R., Schwander, J., Flückiger, J., Stauffer, B., Chappellaz, J.,
and Raynaud, D.: The attenuation of fast atmospheric CH4 variations recorded
in polar ice cores, Geophys. Res. Lett., 30, 1571, https://doi.org/10.1029/2003GL017093,
2003.
Trudinger, C. M., Etheridge, D. M., Rayner, P. J., Enting, I. G., Sturrock,
G. A., and Langenfelds, R. L.: Reconstructing atmospheric histories from
measurements of air composition in firn, J. Geophys. Res.-Atmos.,
107, ACH 15-1–ACH 15-13, https://doi.org/10.1029/2002JD002545, 2002.
Veres, D., Bazin, L., Landais, A., Toyé Mahamadou Kele, H., Lemieux-Dudon, B., Parrenin, F., Martinerie, P., Blayo, E., Blunier, T., Capron, E., Chappellaz, J., Rasmussen, S. O., Severi, M., Svensson, A., Vinther, B., and Wolff, E. W.: The Antarctic ice core chronology (AICC2012): an optimized multi-parameter and multi-site dating approach for the last 120 thousand years, Clim. Past, 9, 1733–1748, https://doi.org/10.5194/cp-9-1733-2013, 2013.
WAIS Divide Project Members (Fudge, T. J., Steig, E. J., Markle, B. R.,
Schoenemann, S. W., Ding, Q., Taylor, K. C., McConnell, J. R., Brook, E. J.,
Sowers, T., White, J. W. C., Alley, R. B., Cheng, H., Clow, G. D., Cole-Dai,
J., Conway, H., Cuffey, K. M., Edwards, J. S., Lawrence Edwards, R.,
Edwards, R., Fegyveresi, J. M., Ferris, D., Fitzpatrick, J. J., Johnson, J.,
Hargreaves, G., Lee, J. E., Maselli, O. J., Mason, W., McGwire, K. C.,
Mitchell, L. E., Mortensen, N., Neff, P., Orsi, A. J., Popp, T. J., Schauer,
A. J., Severinghaus, J. P., Sigl, M., Spencer, M. K., Vaughn, B. H., Voigt,
D. E., Waddington, E. D., Wang, X., and Wong, G. J.): Onset of deglacial
warming in West Antarctica driven by local orbital forcing, Nature,
500, 440–444, https://doi.org/10.1038/nature12376, 2013.
WAIS Divide Project Members: Precise Interpolar Phasing of Abrupt Climate
Change during the Last Ice Age, Nature, 520, 661–65, https://doi.org/10.1038/nature14401, 2015.
Winski, D. A., Fudge, T. J., Ferris, D. G., Osterberg, E. C., Fegyveresi, J. M., Cole-Dai, J., Thundercloud, Z., Cox, T. S., Kreutz, K. J., Ortman, N., Buizert, C., Epifanio, J., Brook, E. J., Beaudette, R., Severinghaus, J., Sowers, T., Steig, E. J., Kahle, E. C., Jones, T. R., Morris, V., Aydin, M., Nicewonger, M. R., Casey, K. A., Alley, R. B., Waddington, E. D., Iverson, N. A., Dunbar, N. W., Bay, R. C., Souney, J. M., Sigl, M., and McConnell, J. R.: The SP19 chronology for the South Pole Ice Core – Part 1: volcanic matching and annual layer counting, Clim. Past, 15, 1793–1808, https://doi.org/10.5194/cp-15-1793-2019, 2019.
Short summary
A new ice core drilled at the South Pole provides a 54 000-year paleo-environmental record including the composition of the past atmosphere. This paper describes the gas chronology for the South Pole ice core, based on a high-resolution methane record. The new gas chronology, in combination with the existing ice age scale from Winski et al. (2019), allows a model-independent reconstruction of the delta age record.
A new ice core drilled at the South Pole provides a 54 000-year paleo-environmental record...