Articles | Volume 18, issue 3
https://doi.org/10.5194/cp-18-631-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/cp-18-631-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
01 Apr 2022
Research article |
| 01 Apr 2022
| 01 Apr 2022
Northern Hemisphere atmospheric history of carbon monoxide since preindustrial times reconstructed from multiple Greenland ice cores
Xavier Faïn
CORRESPONDING AUTHOR
Univ. Grenoble Alpes, CNRS, IRD, Grenoble INP, IGE, 38000 Grenoble, France
Rachael H. Rhodes
Department of Earth Sciences, University of Cambridge, Cambridge CB2 3EQ, UK
Philip Place
Department of Earth and Environmental Sciences, University of Rochester, Rochester, NY 14627, USA
Vasilii V. Petrenko
Department of Earth and Environmental Sciences, University of Rochester, Rochester, NY 14627, USA
Kévin Fourteau
Univ. Grenoble Alpes, Université de Toulouse, Météo-France, CNRS, CNRM, Centre d'Études de la Neige,38000 Grenoble, France
Nathan Chellman
Division of Hydrologic Sciences, Desert Research Institute, Reno, NV 89512, USA
Edward Crosier
Department of Earth and Environmental Sciences, University of Rochester, Rochester, NY 14627, USA
Joseph R. McConnell
Division of Hydrologic Sciences, Desert Research Institute, Reno, NV 89512, USA
Edward J. Brook
College of Earth, Ocean, and Atmospheric Sciences, Oregon State University, Corvallis, OR 97331, USA
Thomas Blunier
Physics of Ice, Climate and Earth, Niels Bohr Institute, University of Copenhagen, 2200 Copenhagen, Denmark
Michel Legrand
Laboratoire Interuniversitaire des Systèmes Atmosphériques, Université de Paris and Université Paris-Est Créteil, CNRS, LISA, 75013, France
Jérôme Chappellaz
Univ. Grenoble Alpes, CNRS, IRD, Grenoble INP, IGE, 38000 Grenoble, France
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Kévin Fourteau, Julien Brondex, Clément Cancès, and Marie Dumont
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The percolation of liquid water down snowpacks is a complex phenomenon, and its representation can sometimes be complicated for snowpack models. The goal of this article is to transpose some state-of-the-art strategies used for modeling liquid percolation in other media (such as rocks or soil) into snowpack models. With this, snowpack models can be made more efficient, requiring less time and power to perform their computation.
Abigail Hudak, Asmita Banerjee, Christo Buizert, Edward Brook, Michael Kalk, Lindsey Davidge, Andrew J. Schauer, Eric J. Steig, Noah Brown, Liam Kirkpatrick, John-Morgan Manos, Jacob I. Chalif, Erich Osterberg, Miranda Helena Miranda, Eric Saltzman, Yuzhen Yan, Valens Hishamunda, and John Higgins
EGUsphere, https://doi.org/10.5194/egusphere-2026-2045, https://doi.org/10.5194/egusphere-2026-2045, 2026
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Kevin Fourteau, Kaoane Jondeau, Clément Cancès, and Marie Dumont
EGUsphere, https://doi.org/10.5194/egusphere-2026-510, https://doi.org/10.5194/egusphere-2026-510, 2026
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Margaret Harlan, Helle Astrid Kjær, Aylin de Campo, Anders Svensson, Thomas Blunier, Vasileios Gkinis, Sarah Jackson, Christopher Plummer, and Tessa Vance
Earth Syst. Sci. Data, 17, 6255–6271, https://doi.org/10.5194/essd-17-6255-2025, https://doi.org/10.5194/essd-17-6255-2025, 2025
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This paper provides high-resolution chemistry and impurity measurements from the Mount Brown South ice core in East Antarctica, from 873 to 2008 CE. Measurements include sodium, ammonium, hydrogen peroxide, electrolytic conductivity, and insoluble microparticles. Data are provided on three scales: 1 mm and 3 cm averaged depth resolution and decadally averaged. The paper also describes the continuous flow analysis systems used to collect the data and characterizes uncertainties and data quality.
Felix S. L. Ng, Rachael H. Rhodes, Tyler J. Fudge, and Eric W. Wolff
The Cryosphere, 19, 5693–5717, https://doi.org/10.5194/tc-19-5693-2025, https://doi.org/10.5194/tc-19-5693-2025, 2025
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Pascal Bohleber, Nicolas Stoll, Piers Larkman, Rachael H. Rhodes, and David Clases
The Cryosphere, 19, 5485–5498, https://doi.org/10.5194/tc-19-5485-2025, https://doi.org/10.5194/tc-19-5485-2025, 2025
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The Cryosphere, 19, 5201–5230, https://doi.org/10.5194/tc-19-5201-2025, https://doi.org/10.5194/tc-19-5201-2025, 2025
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Piers Larkman, Rachael H. Rhodes, Nicolas Stoll, Carlo Barbante, and Pascal Bohleber
The Cryosphere, 19, 1373–1390, https://doi.org/10.5194/tc-19-1373-2025, https://doi.org/10.5194/tc-19-1373-2025, 2025
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Impurities in ice cores can be preferentially located at the boundaries between crystals of ice, impacting the interpretation of high-resolution data collected from ice core samples. Through use of a modelling framework, we demonstrate that one-dimensional signals can be significantly affected by this association, meaning high-resolution measurements must be carefully designed. Accounting for this effect is important for interpreting ice core data, especially for deep ice samples.
Sindhu Vudayagiri, Bo Vinther, Johannes Freitag, Peter L. Langen, and Thomas Blunier
Clim. Past, 21, 517–528, https://doi.org/10.5194/cp-21-517-2025, https://doi.org/10.5194/cp-21-517-2025, 2025
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Air trapped in polar ice during snowfall reflects atmospheric pressure at the time of occlusion, serving as a proxy for elevation. However, melting, firn structure changes, and air pressure variability complicate this relationship. We measured total air content (TAC) in the RECAP ice core from Renland ice cap, eastern Greenland, spanning 121 000 years. Melt layers and short-term TAC variations, whose origins remain unclear, present challenges in interpreting elevation changes.
Qinggang Gao, Emilie Capron, Louise C. Sime, Rachael H. Rhodes, Rahul Sivankutty, Xu Zhang, Bette L. Otto-Bliesner, and Martin Werner
Clim. Past, 21, 419–440, https://doi.org/10.5194/cp-21-419-2025, https://doi.org/10.5194/cp-21-419-2025, 2025
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Marine sediment and ice core records suggest a warmer Southern Ocean and Antarctica at the early last interglacial, ~127 000 years ago. However, when only forced by orbital parameters and greenhouse gas concentrations during that period, state-of-the-art climate models do not reproduce the magnitude of warming. Here we show that much of the warming at southern middle to high latitudes can be reproduced by a UK climate model, HadCM3, with a 3000-year freshwater forcing over the North Atlantic.
Michel Legrand, Mstislav Vorobyev, Daria Bokuchava, Stanislav Kutuzov, Andreas Plach, Andreas Stohl, Alexandra Khairedinova, Vladimir Mikhalenko, Maria Vinogradova, Sabine Eckhardt, and Susanne Preunkert
Atmos. Chem. Phys., 25, 1385–1399, https://doi.org/10.5194/acp-25-1385-2025, https://doi.org/10.5194/acp-25-1385-2025, 2025
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Past atmospheric NH3 pollution in south-eastern Europe was reconstructed by analysing ammonium in an ice core drilled at the Mount Elbrus (Caucasus, Russia). The observed 3.5-fold increase in ice concentrations between 1750 and 1990 CE is in good agreement with estimated past dominant ammonia emissions from agriculture, mainly from south European Russia and Türkiye. In contrast to present-day conditions, the ammonium level observed in 1750 CE indicates significant natural emissions at that time.
Xavier Faïn, Sophie Szopa, Vaishali Naïk, Patricia Martinerie, David M. Etheridge, Rachael H. Rhodes, Cathy M. Trudinger, Vasilii V. Petrenko, Kévin Fourteau, and Philip Place
Atmos. Chem. Phys., 25, 1105–1119, https://doi.org/10.5194/acp-25-1105-2025, https://doi.org/10.5194/acp-25-1105-2025, 2025
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Carbon monoxide (CO) plays a crucial role in the atmosphere's oxidizing capacity. In this study, we analyse how historical (1850–2014) [CO] outputs from state-of-the-art global chemistry–climate models over Greenland and Antarctica are able to capture both absolute values and trends recorded in multi-site ice archives. A disparity in [CO] growth rates emerges in the Northern Hemisphere between models and observations from 1920–1975 CE, possibly linked to uncertainties in CO emission factors.
Helene Hoffmann, Jason Day, Rachael H. Rhodes, Mackenzie Grieman, Jack Humby, Isobel Rowell, Christoph Nehrbass-Ahles, Robert Mulvaney, Sally Gibson, and Eric Wolff
The Cryosphere, 18, 4993–5013, https://doi.org/10.5194/tc-18-4993-2024, https://doi.org/10.5194/tc-18-4993-2024, 2024
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Ice cores are archives of past atmospheric conditions. In deep and old ice, the layers containing this information get thinned to the millimetre scale or below. We installed a setup for high-resolution (182 μm) chemical impurity measurements in ice cores using the laser ablation technique at the University of Cambridge. In a first application to the Skytrain ice core from Antarctica, we discuss the potential to detect fine-layered structures in ice up to an age of 26 000 years.
Julien Westhoff, Johannes Freitag, Anaïs Orsi, Patricia Martinerie, Ilka Weikusat, Michael Dyonisius, Xavier Faïn, Kevin Fourteau, and Thomas Blunier
The Cryosphere, 18, 4379–4397, https://doi.org/10.5194/tc-18-4379-2024, https://doi.org/10.5194/tc-18-4379-2024, 2024
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We study the EastGRIP area, Greenland, in detail with traditional and novel techniques. Due to the compaction of the ice, at a certain depth, atmospheric gases can no longer exchange, and the atmosphere is trapped in air bubbles in the ice. We find this depth by pumping air from a borehole, modeling, and using a new technique based on the optical appearance of the ice. Our results suggest that the close-off depth lies at around 58–61 m depth and more precisely at 58.3 m depth.
Rachael H. Rhodes, Yvan Bollet-Quivogne, Piers Barnes, Mirko Severi, and Eric W. Wolff
Clim. Past, 20, 2031–2043, https://doi.org/10.5194/cp-20-2031-2024, https://doi.org/10.5194/cp-20-2031-2024, 2024
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Some ionic components slowly move through glacier ice by diffusion, but the rate of this diffusion, its exact mechanism(s), and the factors that might influence it are poorly understood. In this study, we model how peaks in sulfate, deposited at Dome C on the Antarctic ice sheet after volcanic eruptions, change with depth and time. We find that the sulfate diffusion rate in ice is relatively fast in young ice near the surface, but the rate is markedly reduced over time.
Vasilii V. Petrenko, Segev BenZvi, Michael Dyonisius, Benjamin Hmiel, Andrew M. Smith, and Christo Buizert
The Cryosphere, 18, 3439–3451, https://doi.org/10.5194/tc-18-3439-2024, https://doi.org/10.5194/tc-18-3439-2024, 2024
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This manuscript presents the concept for a new proxy for past variations in the galactic cosmic ray flux (GCR). Past variations in GCR flux are important to understand for interpretation of records of isotopes produced by cosmic rays; these records are used for reconstructing solar variations and past land ice extent. The proxy involves using measurements of 14CO in ice cores, which should provide an uncomplicated and precise estimate of past GCR flux variations for the past few thousand years.
Benjamin Hmiel, Vasilii V. Petrenko, Christo Buizert, Andrew M. Smith, Michael N. Dyonisius, Philip Place, Bin Yang, Quan Hua, Ross Beaudette, Jeffrey P. Severinghaus, Christina Harth, Ray F. Weiss, Lindsey Davidge, Melisa Diaz, Matthew Pacicco, James A. Menking, Michael Kalk, Xavier Faïn, Alden Adolph, Isaac Vimont, and Lee T. Murray
The Cryosphere, 18, 3363–3382, https://doi.org/10.5194/tc-18-3363-2024, https://doi.org/10.5194/tc-18-3363-2024, 2024
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The main aim of this research is to improve understanding of carbon-14 that is produced by cosmic rays in ice sheets. Measurements of carbon-14 in ice cores can provide a range of useful information (age of ice, past atmospheric chemistry, past cosmic ray intensity). Our results show that almost all (>99 %) of carbon-14 that is produced in the upper layer of ice sheets is rapidly lost to the atmosphere. Our results also provide better estimates of carbon-14 production rates in deeper ice.
Kévin Fourteau, Johannes Freitag, Mika Malinen, and Henning Löwe
The Cryosphere, 18, 2831–2846, https://doi.org/10.5194/tc-18-2831-2024, https://doi.org/10.5194/tc-18-2831-2024, 2024
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Understanding the settling of snow under its own weight has applications from avalanche forecasts to ice core interpretations. We study how this settling can be modeled using 3D images of the internal structure of snow and ice deformation mechanics. We found that classical ice mechanics, as used, for instance, in glacier flow, explain the compaction of dense polar snow but not that of lighter seasonal snow. How, exactly, the ice deforms during light snow compaction thus remains an open question.
Susanne Preunkert, Pascal Bohleber, Michel Legrand, Adrien Gilbert, Tobias Erhardt, Roland Purtschert, Lars Zipf, Astrid Waldner, Joseph R. McConnell, and Hubertus Fischer
The Cryosphere, 18, 2177–2194, https://doi.org/10.5194/tc-18-2177-2024, https://doi.org/10.5194/tc-18-2177-2024, 2024
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Ice cores from high-elevation Alpine glaciers are an important tool to reconstruct the past atmosphere. However, since crevasses are common at these glacier sites, rigorous investigations of glaciological conditions upstream of drill sites are needed before interpreting such ice cores. On the basis of three ice cores extracted at Col du Dôme (4250 m a.s.l; French Alps), an overall picture of a dynamic crevasse formation is drawn, which disturbs the depth–age relation of two of the three cores.
Anna Braun, Kévin Fourteau, and Henning Löwe
The Cryosphere, 18, 1653–1668, https://doi.org/10.5194/tc-18-1653-2024, https://doi.org/10.5194/tc-18-1653-2024, 2024
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The specific surface of snow dictates key physical properties and continuously evolves in natural snowpacks. This is referred to as metamorphism. This work develops a rigorous physical model for this evolution, which is able to reproduce X-ray tomography measurements without using unphysical tuning parameters. Our results emphasize that snow crystal growth at the micrometer scale ultimately controls the pace of metamorphism.
Kavitha Sundu, Johannes Freitag, Kévin Fourteau, and Henning Löwe
The Cryosphere, 18, 1579–1596, https://doi.org/10.5194/tc-18-1579-2024, https://doi.org/10.5194/tc-18-1579-2024, 2024
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Ice crystals often show a rod-like, vertical orientation in snow and firn; they are said to be anisotropic. The stiffness in the vertical direction therefore differs from the horizontal, which, for example, impacts the propagation of seismic waves. To quantify this anisotropy, we conducted finite-element simulations of 391 snow, firn, and ice core microstructures obtained from X-ray tomography. We then derived a parameterization that may be employed for advanced seismic studies in polar regions.
Kévin Fourteau, Julien Brondex, Fanny Brun, and Marie Dumont
Geosci. Model Dev., 17, 1903–1929, https://doi.org/10.5194/gmd-17-1903-2024, https://doi.org/10.5194/gmd-17-1903-2024, 2024
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In this paper, we provide a novel numerical implementation for solving the energy exchanges at the surface of snow and ice. By combining the strong points of previous models, our solution leads to more accurate and robust simulations of the energy exchanges, surface temperature, and melt while preserving a reasonable computation time.
Qinggang Gao, Louise C. Sime, Alison J. McLaren, Thomas J. Bracegirdle, Emilie Capron, Rachael H. Rhodes, Hans Christian Steen-Larsen, Xiaoxu Shi, and Martin Werner
The Cryosphere, 18, 683–703, https://doi.org/10.5194/tc-18-683-2024, https://doi.org/10.5194/tc-18-683-2024, 2024
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Antarctic precipitation is a crucial component of the climate system. Its spatio-temporal variability impacts sea level changes and the interpretation of water isotope measurements in ice cores. To better understand its climatic drivers, we developed water tracers in an atmospheric model to identify moisture source conditions from which precipitation originates. We find that mid-latitude surface winds exert an important control on moisture availability for Antarctic precipitation.
Vladimir Mikhalenko, Stanislav Kutuzov, Pavel Toropov, Michel Legrand, Sergey Sokratov, Gleb Chernyakov, Ivan Lavrentiev, Susanne Preunkert, Anna Kozachek, Mstislav Vorobiev, Aleksandra Khairedinova, and Vladimir Lipenkov
Clim. Past, 20, 237–255, https://doi.org/10.5194/cp-20-237-2024, https://doi.org/10.5194/cp-20-237-2024, 2024
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In this paper, we present a reconstruction of snow accumulation for both summer and winter over the past 260 years using ice-core records obtained from Mt. Elbrus in the Caucasus region. The accumulation record represents the historical precipitation patterns in a vast region encompassing the northern Caucasus, Black Sea, and southeastern Europe. Our findings show that the North Atlantic plays a crucial role in determining precipitation levels in this region.
John D. Patterson, Murat Aydin, Andrew M. Crotwell, Gabrielle Pétron, Jeffery P. Severinghaus, Paul B. Krummel, Ray L. Langenfelds, Vasilii V. Petrenko, and Eric S. Saltzman
Clim. Past, 19, 2535–2550, https://doi.org/10.5194/cp-19-2535-2023, https://doi.org/10.5194/cp-19-2535-2023, 2023
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Atmospheric levels of molecular hydrogen (H2) can impact climate and air quality. Constraining past changes to atmospheric H2 is useful for understanding how H2 cycles through the Earth system and predicting the impacts of increasing anthropogenic emissions under the
hydrogen economy. Here, we use the aging air found in the polar snowpack to reconstruct H2 levels over the past 100 years. We find that H2 levels increased by 30 % over Greenland and 60 % over Antarctica during the 20th century.
Julien Brondex, Kévin Fourteau, Marie Dumont, Pascal Hagenmuller, Neige Calonne, François Tuzet, and Henning Löwe
Geosci. Model Dev., 16, 7075–7106, https://doi.org/10.5194/gmd-16-7075-2023, https://doi.org/10.5194/gmd-16-7075-2023, 2023
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Vapor diffusion is one of the main processes governing snowpack evolution, and it must be accounted for in models. Recent attempts to represent vapor diffusion in numerical models have faced several difficulties regarding computational cost and mass and energy conservation. Here, we develop our own finite-element software to explore numerical approaches and enable us to overcome these difficulties. We illustrate the capability of these approaches on established numerical benchmarks.
Jenna A. Epifanio, Edward J. Brook, Christo Buizert, Erin C. Pettit, Jon S. Edwards, John M. Fegyveresi, Todd A. Sowers, Jeffrey P. Severinghaus, and Emma C. Kahle
The Cryosphere, 17, 4837–4851, https://doi.org/10.5194/tc-17-4837-2023, https://doi.org/10.5194/tc-17-4837-2023, 2023
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The total air content (TAC) of polar ice cores has long been considered a potential proxy for past ice sheet elevation. This study presents a high-resolution record of TAC from the South Pole ice core. The record reveals orbital- and millennial-scale variability that cannot be explained by elevation changes. The orbital- and millennial-scale changes are likely a product of firn grain metamorphism near the surface of the ice sheet, due to summer insolation changes or local accumulation changes.
Xavier Faïn, David M. Etheridge, Kévin Fourteau, Patricia Martinerie, Cathy M. Trudinger, Rachael H. Rhodes, Nathan J. Chellman, Ray L. Langenfelds, Joseph R. McConnell, Mark A. J. Curran, Edward J. Brook, Thomas Blunier, Grégory Teste, Roberto Grilli, Anthony Lemoine, William T. Sturges, Boris Vannière, Johannes Freitag, and Jérôme Chappellaz
Clim. Past, 19, 2287–2311, https://doi.org/10.5194/cp-19-2287-2023, https://doi.org/10.5194/cp-19-2287-2023, 2023
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We report on a 3000-year record of carbon monoxide (CO) levels in the Southern Hemisphere's high latitudes by combining ice core and firn air measurements with modern direct atmospheric samples. Antarctica [CO] remained stable (–835 to 1500 CE), decreased during the Little Ice Age, and peaked around 1985 CE. Such evolution reflects stable biomass burning CO emissions before industrialization, followed by growth from CO anthropogenic sources, which decline after 1985 due to improved combustion.
Fanny Brun, Owen King, Marion Réveillet, Charles Amory, Anton Planchot, Etienne Berthier, Amaury Dehecq, Tobias Bolch, Kévin Fourteau, Julien Brondex, Marie Dumont, Christoph Mayer, Silvan Leinss, Romain Hugonnet, and Patrick Wagnon
The Cryosphere, 17, 3251–3268, https://doi.org/10.5194/tc-17-3251-2023, https://doi.org/10.5194/tc-17-3251-2023, 2023
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The South Col Glacier is a small body of ice and snow located on the southern ridge of Mt. Everest. A recent study proposed that South Col Glacier is rapidly losing mass. In this study, we examined the glacier thickness change for the period 1984–2017 and found no thickness change. To reconcile these results, we investigate wind erosion and surface energy and mass balance and find that melt is unlikely a dominant process, contrary to previous findings.
Elizabeth R. Thomas, Diana O. Vladimirova, Dieter R. Tetzner, B. Daniel Emanuelsson, Nathan Chellman, Daniel A. Dixon, Hugues Goosse, Mackenzie M. Grieman, Amy C. F. King, Michael Sigl, Danielle G. Udy, Tessa R. Vance, Dominic A. Winski, V. Holly L. Winton, Nancy A. N. Bertler, Akira Hori, Chavarukonam M. Laluraj, Joseph R. McConnell, Yuko Motizuki, Kazuya Takahashi, Hideaki Motoyama, Yoichi Nakai, Franciéle Schwanck, Jefferson Cardia Simões, Filipe Gaudie Ley Lindau, Mirko Severi, Rita Traversi, Sarah Wauthy, Cunde Xiao, Jiao Yang, Ellen Mosely-Thompson, Tamara V. Khodzher, Ludmila P. Golobokova, and Alexey A. Ekaykin
Earth Syst. Sci. Data, 15, 2517–2532, https://doi.org/10.5194/essd-15-2517-2023, https://doi.org/10.5194/essd-15-2517-2023, 2023
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The concentration of sodium and sulfate measured in Antarctic ice cores is related to changes in both sea ice and winds. Here we have compiled a database of sodium and sulfate records from 105 ice core sites in Antarctica. The records span all, or part, of the past 2000 years. The records will improve our understanding of how winds and sea ice have changed in the past and how they have influenced the climate of Antarctica over the past 2000 years.
Aymeric P. M. Servettaz, Anaïs J. Orsi, Mark A. J. Curran, Andrew D. Moy, Amaelle Landais, Joseph R. McConnell, Trevor J. Popp, Emmanuel Le Meur, Xavier Faïn, and Jérôme Chappellaz
Clim. Past, 19, 1125–1152, https://doi.org/10.5194/cp-19-1125-2023, https://doi.org/10.5194/cp-19-1125-2023, 2023
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The temperature of the past 2000 years is still poorly known in vast parts of the East Antarctic plateau. In this study, we present temperature reconstructions based on water and gas stable isotopes from the Aurora Basin North ice core. Spatial and temporal significance of each proxy differs, and we can identify some cold periods in the snow temperature up to 2°C cooler in the 1000–1400 CE period, which could not be determined with water isotopes only.
Anja Eichler, Michel Legrand, Theo M. Jenk, Susanne Preunkert, Camilla Andersson, Sabine Eckhardt, Magnuz Engardt, Andreas Plach, and Margit Schwikowski
The Cryosphere, 17, 2119–2137, https://doi.org/10.5194/tc-17-2119-2023, https://doi.org/10.5194/tc-17-2119-2023, 2023
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We investigate how a 250-year history of the emission of air pollutants (major inorganic aerosol constituents, black carbon, and trace species) is preserved in ice cores from four sites in the European Alps. The observed uniform timing in species-dependent longer-term concentration changes reveals that the different ice-core records provide a consistent, spatially representative signal of the pollution history from western European countries.
Michaela Mühl, Jochen Schmitt, Barbara Seth, James E. Lee, Jon S. Edwards, Edward J. Brook, Thomas Blunier, and Hubertus Fischer
Clim. Past, 19, 999–1025, https://doi.org/10.5194/cp-19-999-2023, https://doi.org/10.5194/cp-19-999-2023, 2023
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Our ice core measurements show that methane, ethane, and propane concentrations are significantly elevated above their past atmospheric background for Greenland ice samples containing mineral dust. The underlying co-production process happens during the classical discrete wet extraction of air from the ice sample and affects previous reconstructions of the inter-polar difference of methane as well as methane stable isotope records derived from dust-rich Greenland ice.
Robert Mulvaney, Eric W. Wolff, Mackenzie M. Grieman, Helene H. Hoffmann, Jack D. Humby, Christoph Nehrbass-Ahles, Rachael H. Rhodes, Isobel F. Rowell, Frédéric Parrenin, Loïc Schmidely, Hubertus Fischer, Thomas F. Stocker, Marcus Christl, Raimund Muscheler, Amaelle Landais, and Frédéric Prié
Clim. Past, 19, 851–864, https://doi.org/10.5194/cp-19-851-2023, https://doi.org/10.5194/cp-19-851-2023, 2023
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We present an age scale for a new ice core drilled at Skytrain Ice Rise, an ice rise facing the Ronne Ice Shelf in Antarctica. Various measurements in the ice and air phases are used to match the ice core to other Antarctic cores that have already been dated, and a new age scale is constructed. The 651 m ice core includes ice that is confidently dated to 117 000–126 000 years ago, in the last interglacial. Older ice is found deeper down, but there are flow disturbances in the deeper ice.
Christo Buizert, Sarah Shackleton, Jeffrey P. Severinghaus, William H. G. Roberts, Alan Seltzer, Bernhard Bereiter, Kenji Kawamura, Daniel Baggenstos, Anaïs J. Orsi, Ikumi Oyabu, Benjamin Birner, Jacob D. Morgan, Edward J. Brook, David M. Etheridge, David Thornton, Nancy Bertler, Rebecca L. Pyne, Robert Mulvaney, Ellen Mosley-Thompson, Peter D. Neff, and Vasilii V. Petrenko
Clim. Past, 19, 579–606, https://doi.org/10.5194/cp-19-579-2023, https://doi.org/10.5194/cp-19-579-2023, 2023
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It is unclear how different components of the global atmospheric circulation, such as the El Niño effect, respond to large-scale climate change. We present a new ice core gas proxy, called krypton-86 excess, that reflects past storminess in Antarctica. We present data from 11 ice cores that suggest the new proxy works. We present a reconstruction of changes in West Antarctic storminess over the last 24 000 years and suggest these are caused by north–south movement of the tropical rain belt.
Michael N. Dyonisius, Vasilii V. Petrenko, Andrew M. Smith, Benjamin Hmiel, Peter D. Neff, Bin Yang, Quan Hua, Jochen Schmitt, Sarah A. Shackleton, Christo Buizert, Philip F. Place, James A. Menking, Ross Beaudette, Christina Harth, Michael Kalk, Heidi A. Roop, Bernhard Bereiter, Casey Armanetti, Isaac Vimont, Sylvia Englund Michel, Edward J. Brook, Jeffrey P. Severinghaus, Ray F. Weiss, and Joseph R. McConnell
The Cryosphere, 17, 843–863, https://doi.org/10.5194/tc-17-843-2023, https://doi.org/10.5194/tc-17-843-2023, 2023
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Cosmic rays that enter the atmosphere produce secondary particles which react with surface minerals to produce radioactive nuclides. These nuclides are often used to constrain Earth's surface processes. However, the production rates from muons are not well constrained. We measured 14C in ice with a well-known exposure history to constrain the production rates from muons. 14C production in ice is analogous to quartz, but we obtain different production rates compared to commonly used estimates.
François Burgay, Rafael Pedro Fernández, Delia Segato, Clara Turetta, Christopher S. Blaszczak-Boxe, Rachael H. Rhodes, Claudio Scarchilli, Virginia Ciardini, Carlo Barbante, Alfonso Saiz-Lopez, and Andrea Spolaor
The Cryosphere, 17, 391–405, https://doi.org/10.5194/tc-17-391-2023, https://doi.org/10.5194/tc-17-391-2023, 2023
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The paper presents the first ice-core record of bromine (Br) in the Antarctic plateau. By the observation of the ice core and the application of atmospheric chemical models, we investigate the behaviour of bromine after its deposition into the snowpack, with interest in the effect of UV radiation change connected to the formation of the ozone hole, the role of volcanic deposition, and the possible use of Br to reconstruct past sea ice changes from ice core collect in the inner Antarctic plateau.
Jinhwa Shin, Jinho Ahn, Jai Chowdhry Beeman, Hun-Gyu Lee, Jaemyeong Mango Seo, and Edward J. Brook
Clim. Past, 18, 2063–2075, https://doi.org/10.5194/cp-18-2063-2022, https://doi.org/10.5194/cp-18-2063-2022, 2022
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We present a new and highly resolved atmospheric CO2 record from the Siple Dome ice core, Antarctica, over the early Holocene (11.7–7.4 ka). Atmospheric CO2 decreased by ~10 ppm from 10.9 to 7.3 ka, but the decrease was punctuated by local minima at 11.1, 10.1, 9.1, and 8.3 ka. We found millennial CO2 variability of 2–6 ppm, and the millennial CO2 variations correlate with proxies for solar forcing and local climate in the Southern Ocean, North Atlantic, and eastern equatorial Pacific.
Xavier Crosta, Karen E. Kohfeld, Helen C. Bostock, Matthew Chadwick, Alice Du Vivier, Oliver Esper, Johan Etourneau, Jacob Jones, Amy Leventer, Juliane Müller, Rachael H. Rhodes, Claire S. Allen, Pooja Ghadi, Nele Lamping, Carina B. Lange, Kelly-Anne Lawler, David Lund, Alice Marzocchi, Katrin J. Meissner, Laurie Menviel, Abhilash Nair, Molly Patterson, Jennifer Pike, Joseph G. Prebble, Christina Riesselman, Henrik Sadatzki, Louise C. Sime, Sunil K. Shukla, Lena Thöle, Maria-Elena Vorrath, Wenshen Xiao, and Jiao Yang
Clim. Past, 18, 1729–1756, https://doi.org/10.5194/cp-18-1729-2022, https://doi.org/10.5194/cp-18-1729-2022, 2022
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Despite its importance in the global climate, our knowledge of Antarctic sea-ice changes throughout the last glacial–interglacial cycle is extremely limited. As part of the Cycles of Sea Ice Dynamics in the Earth system (C-SIDE) Working Group, we review marine- and ice-core-based sea-ice proxies to provide insights into their applicability and limitations. By compiling published records, we provide information on Antarctic sea-ice dynamics over the past 130 000 years.
Silvia Becagli, Elena Barbaro, Simone Bonamano, Laura Caiazzo, Alcide di Sarra, Matteo Feltracco, Paolo Grigioni, Jost Heintzenberg, Luigi Lazzara, Michel Legrand, Alice Madonia, Marco Marcelli, Chiara Melillo, Daniela Meloni, Caterina Nuccio, Giandomenico Pace, Ki-Tae Park, Suzanne Preunkert, Mirko Severi, Marco Vecchiato, Roberta Zangrando, and Rita Traversi
Atmos. Chem. Phys., 22, 9245–9263, https://doi.org/10.5194/acp-22-9245-2022, https://doi.org/10.5194/acp-22-9245-2022, 2022
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Measurements of phytoplanktonic dimethylsulfide and its oxidation products in the Antarctic atmosphere allow us to understand the role of the oceanic (sea ice melting, Chl α and dimethylsulfoniopropionate) and atmospheric (wind direction and speed, humidity, solar radiation and transport processes) factors in the biogenic aerosol formation, concentration and characteristic ratio between components in an Antarctic coastal site facing the polynya of the Ross Sea.
Michael Sigl, Matthew Toohey, Joseph R. McConnell, Jihong Cole-Dai, and Mirko Severi
Earth Syst. Sci. Data, 14, 3167–3196, https://doi.org/10.5194/essd-14-3167-2022, https://doi.org/10.5194/essd-14-3167-2022, 2022
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Volcanism is a key driver of climate. Based on ice cores from Greenland and Antarctica, we reconstruct its climate impact potential over the Holocene. By aligning records on a well-dated chronology from Antarctica, we resolve long-standing inconsistencies in the dating of past volcanic eruptions. We reconstruct 850 eruptions (which, in total, injected 7410 Tg of sulfur in the stratosphere) and estimate how they changed the opacity of the atmosphere, a prerequisite for climate model simulations.
Markus Stoffel, Christophe Corona, Francis Ludlow, Michael Sigl, Heli Huhtamaa, Emmanuel Garnier, Samuli Helama, Sébastien Guillet, Arlene Crampsie, Katrin Kleemann, Chantal Camenisch, Joseph McConnell, and Chaochao Gao
Clim. Past, 18, 1083–1108, https://doi.org/10.5194/cp-18-1083-2022, https://doi.org/10.5194/cp-18-1083-2022, 2022
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The mid-17th century saw several volcanic eruptions, deteriorating climate, political instability, and famine in Europe, China, and Japan. We analyze impacts of the eruptions on climate but also study their socio-political context. We show that an unambiguous distinction of volcanic cooling or wetting from natural climate variability is not straightforward. It also shows that political instability, poor harvest, and famine cannot only be attributed to volcanic climatic impacts.
Gill Plunkett, Michael Sigl, Hans F. Schwaiger, Emma L. Tomlinson, Matthew Toohey, Joseph R. McConnell, Jonathan R. Pilcher, Takeshi Hasegawa, and Claus Siebe
Clim. Past, 18, 45–65, https://doi.org/10.5194/cp-18-45-2022, https://doi.org/10.5194/cp-18-45-2022, 2022
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We report the identification of volcanic ash associated with a sulfate layer in Greenland ice cores previously thought to have been from the Vesuvius 79 CE eruption and which had been used to confirm the precise dating of the Greenland ice-core chronology. We find that the tephra was probably produced by an eruption in Alaska. We show the importance of verifying sources of volcanic signals in ice cores through ash analysis to avoid errors in dating ice cores and interpreting volcanic impacts.
Merve Polat, Jesper Baldtzer Liisberg, Morten Krogsbøll, Thomas Blunier, and Matthew S. Johnson
Atmos. Meas. Tech., 14, 8041–8067, https://doi.org/10.5194/amt-14-8041-2021, https://doi.org/10.5194/amt-14-8041-2021, 2021
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We have designed a process for removing methane from a gas stream so that nitrous oxide can be measured without interference. These are both key long-lived greenhouse gases frequently studied in relation to ice cores, plants, water treatment and so on. However, many researchers are not aware of the problem of methane interference, and in addition there have not been good methods available for solving the problem. Here we present and evaluate such a method.
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Short summary
Carbon monoxide (CO) is a regulated pollutant and one of the key components determining the oxidizing capacity of the atmosphere. In this study, we analyzed five ice cores from Greenland at high resolution for CO concentrations by coupling laser spectrometry with continuous melting. By combining these new datasets, we produced an upper-bound estimate of past atmospheric CO abundance since preindustrial times for the Northern Hemisphere high latitudes, covering the period from 1700 to 1957 CE.
Carbon monoxide (CO) is a regulated pollutant and one of the key components determining the...
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