Articles | Volume 17, issue 5
https://doi.org/10.5194/cp-17-1881-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/cp-17-1881-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
23 Sep 2021
Research article |
| 23 Sep 2021
| 23 Sep 2021
The triple oxygen isotope composition of phytoliths, a new proxy of atmospheric relative humidity: controls of soil water isotope composition, temperature, CO2 concentration and relative humidity
Clément Outrequin
CNRS, Aix Marseille Univ, IRD, INRA, CEREGE, Aix-en-Provence, France
CNRS, Aix Marseille Univ, IRD, INRA, CEREGE, Aix-en-Provence, France
Christine Vallet-Coulomb
CNRS, Aix Marseille Univ, IRD, INRA, CEREGE, Aix-en-Provence, France
Clément Piel
Ecotron Européen de Montpellier, Univ. Montpellier, UPS 3248 CNRS, Campus Baillarguet, Montferrier-sur-Lez, France
Sébastien Devidal
Ecotron Européen de Montpellier, Univ. Montpellier, UPS 3248 CNRS, Campus Baillarguet, Montferrier-sur-Lez, France
Amaelle Landais
Laboratoire des Sciences du Climat et de l'Environnement
(LSCE/IPSL/CEA/CNRS/UVSQ), Gif-sur-Yvette, France
Martine Couapel
CNRS, Aix Marseille Univ, IRD, INRA, CEREGE, Aix-en-Provence, France
Jean-Charles Mazur
CNRS, Aix Marseille Univ, IRD, INRA, CEREGE, Aix-en-Provence, France
Christophe Peugeot
Hydrosciences Montpellier, IRD, CNRS, Univ. Montpellier, Montpellier, France
Monique Pierre
Laboratoire des Sciences du Climat et de l'Environnement
(LSCE/IPSL/CEA/CNRS/UVSQ), Gif-sur-Yvette, France
Frédéric Prié
Laboratoire des Sciences du Climat et de l'Environnement
(LSCE/IPSL/CEA/CNRS/UVSQ), Gif-sur-Yvette, France
Jacques Roy
Ecotron Européen de Montpellier, Univ. Montpellier, UPS 3248 CNRS, Campus Baillarguet, Montferrier-sur-Lez, France
Corinne Sonzogni
CNRS, Aix Marseille Univ, IRD, INRA, CEREGE, Aix-en-Provence, France
Claudia Voigt
CNRS, Aix Marseille Univ, IRD, INRA, CEREGE, Aix-en-Provence, France
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This calibration study shows that despite isotope heterogeneity along grass leaves, the triple oxygen isotope composition of bulk leaf phytoliths can be estimated from the Craig and Gordon model, a mixing equation and a mean leaf water–phytolith fractionation exponent (lambda) of 0.521. The results strengthen the reliability of the 17O–excess of phytoliths to be used as a proxy of atmospheric relative humidity and open tracks for its use as an imprint of leaf water 17O–excess.
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Titouan Tcheng, Elise Fourré, Christophe Leroy-Dos-Santos, Frédéric Parrenin, Emmanuel Le Meur, Frédéric Prié, Olivier Jossoud, Roxanne Jacob, Bénédicte Minster, Olivier Magand, Cécile Agosta, Niels Dutrievoz, Vincent Favier, Léa Baubant, Coralie Lassalle-Bernard, Mathieu Casado, Martin Werner, Alexandre Cauquoin, Laurent Arnaud, Bruno Jourdain, Ghislain Picard, Marie Bouchet, and Amaëlle Landais
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Studying Antarctic ice cores is crucial to assess past climate changes, as they hold historical climate data. This study examines multiple ice cores from three sites in coastal Adélie Land to see if combining cores improves data interpretability. It does at two sites, but at a third, wind-driven snow layer mixing limited benefits. We show that using multiple ice cores from one location can better uncover climate history, especially in areas with less wind disturbance.
Erwan Le Roux, Valentin Wendling, Gérémy Panthou, Océane Dubas, Jean-Pierre Vandervaere, Basile Hector, Guillaume Favreau, Jean-Martial Cohard, Caroline Pierre, Luc Descroix, Eric Mougin, Manuela Grippa, Laurent Kergoat, Jérôme Demarty, Nathalie Rouche, Jordi Etchanchu, and Christophe Peugeot
EGUsphere, https://doi.org/10.5194/egusphere-2025-1965, https://doi.org/10.5194/egusphere-2025-1965, 2025
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Clémence Paul, Clément Piel, Joana Sauze, Olivier Jossoud, Arnaud Dapoigny, Daniele Romanini, Frédéric Prié, Sébastien Devidal, Roxanne Jacob, Alexandru Milcu, and Amaëlle Landais
Geosci. Instrum. Method. Data Syst., 14, 91–101, https://doi.org/10.5194/gi-14-91-2025, https://doi.org/10.5194/gi-14-91-2025, 2025
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Our study investigated the influence of plant processes on oxygen dynamics, crucial for paleoclimatology. By examining maize respiration and photosynthesis using advanced techniques, we enhanced our understanding of past climates through ice core analysis.
Inès Ollivier, Thomas Lauwers, Niels Dutrievoz, Cécile Agosta, Mathieu Casado, Elise Fourré, Christophe Genthon, Olivier Jossoud, Frédéric Prié, Hans Christian Steen-Larsen, and Amaëlle Landais
Earth Syst. Sci. Data Discuss., https://doi.org/10.5194/essd-2025-35, https://doi.org/10.5194/essd-2025-35, 2025
Preprint under review for ESSD
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We present a novel 2.5-month record of the atmospheric water vapour isotopic composition during the austral summer 2023–2024 at Concordia Station on the Antarctic Plateau. We show that two independent laser spectrometers accurately record the diurnal variability of the atmospheric water vapour 𝛿18O, 𝛿D, and d-excess. We compare the measurements against outputs of the isotope-enabled general circulation model LMDZ6-iso to show how the data can be used to evaluate such models.
Claudia Voigt, Fernando Gázquez, Lucía Martegani, Ana Isabel Sánchez Villanueva, Antonio Medina, Rosario Jiménez-Espinosa, Juan Jiménez-Millán, and Miguel Rodríguez-Rodríguez
Hydrol. Earth Syst. Sci., 29, 1783–1806, https://doi.org/10.5194/hess-29-1783-2025, https://doi.org/10.5194/hess-29-1783-2025, 2025
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This research explores the use of a new isotope tracer, 17O excess, to better understand how hydrological processes drive large seasonal water level changes in small lakes in semiarid regions. The study shows that triple oxygen isotopes offer a more detailed understanding of these changes compared to traditional methods. These findings are valuable for reconstructing past climates and predicting how climate change, influenced by human activity, will affect small lakes in these dry areas.
Thomas Lauwers, Elise Fourré, Olivier Jossoud, Daniele Romanini, Frédéric Prié, Giordano Nitti, Mathieu Casado, Kévin Jaulin, Markus Miltner, Morgane Farradèche, Valérie Masson-Delmotte, and Amaëlle Landais
Atmos. Meas. Tech., 18, 1135–1147, https://doi.org/10.5194/amt-18-1135-2025, https://doi.org/10.5194/amt-18-1135-2025, 2025
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Water vapour isotopes are important tools to better understand processes governing the atmospheric hydrological cycle. In polar regions, their measurement helps to improve the interpretation of water isotopic records in ice cores. However, in situ water vapour isotopic monitoring is an important challenge, especially in dry places of East Antarctica. We present here an alternative laser spectroscopy technique adapted for such measurements, with a limit of detection down to 10 ppm humidity.
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Our research compares three CFA-CRDS systems from Venice, Paris, and Grenoble for measuring water isotopes in ice cores, crucial for reconstructing past climate. We quantify each system’s mixing and measurement noise effects, which impact the achievable resolution of isotope continuous records. Our findings reveal specific configurations and procedures to enhance measurement accuracy, providing a framework to optimise water isotope analysis.
Inès Ollivier, Hans Christian Steen-Larsen, Barbara Stenni, Laurent Arnaud, Mathieu Casado, Alexandre Cauquoin, Giuliano Dreossi, Christophe Genthon, Bénédicte Minster, Ghislain Picard, Martin Werner, and Amaëlle Landais
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Frédéric Parrenin, Marie Bouchet, Christo Buizert, Emilie Capron, Ellen Corrick, Russell Drysdale, Kenji Kawamura, Amaëlle Landais, Robert Mulvaney, Ikumi Oyabu, and Sune Olander Rasmussen
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The Paleochrono-1.1 probabilistic dating model allows users to derive a common and optimized chronology for several paleoclimatic sites from various archives (ice cores, speleothems, marine cores, lake cores, etc.). It combines prior sedimentation scenarios with chronological information such as dated horizons, dated intervals, stratigraphic links and (for ice cores) Δdepth observations. Paleochrono-1.1 is available under an open-source license.
Clément Piel, Daniele Romanini, Morgane Farradèche, Justin Chaillot, Clémence Paul, Nicolas Bienville, Thomas Lauwers, Joana Sauze, Kévin Jaulin, Frédéric Prié, and Amaëlle Landais
Atmos. Meas. Tech., 17, 6647–6658, https://doi.org/10.5194/amt-17-6647-2024, https://doi.org/10.5194/amt-17-6647-2024, 2024
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This paper introduces a new optical gas analyzer based on an optical-feedback cavity-enhanced absorption spectroscopy (OF-CEAS) technique enabling high-temporal-resolution and high-precision measurements of oxygen isotopes (δ18O) and dioxygen (O2) concentration of atmospheric O2 (respectively 0.06 ‰ and 0.002 % over 10 min integration). The results underscore the good agreement with isotope ratio mass spectrometry measurements and the ability of the instrument to monitor biological processes.
Giuliano Dreossi, Mauro Masiol, Barbara Stenni, Daniele Zannoni, Claudio Scarchilli, Virginia Ciardini, Mathieu Casado, Amaëlle Landais, Martin Werner, Alexandre Cauquoin, Giampietro Casasanta, Massimo Del Guasta, Vittoria Posocco, and Carlo Barbante
The Cryosphere, 18, 3911–3931, https://doi.org/10.5194/tc-18-3911-2024, https://doi.org/10.5194/tc-18-3911-2024, 2024
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Oxygen and hydrogen stable isotopes have been extensively used to reconstruct past temperatures, with precipitation representing the input signal of the isotopic records in ice cores. We present a 10-year record of stable isotopes in daily precipitation at Concordia Station: this is the longest record for inland Antarctica and represents a benchmark for quantifying post-depositional processes and improving the paleoclimate interpretation of ice cores.
Romilly Harris Stuart, Amaëlle Landais, Laurent Arnaud, Christo Buizert, Emilie Capron, Marie Dumont, Quentin Libois, Robert Mulvaney, Anaïs Orsi, Ghislain Picard, Frédéric Prié, Jeffrey Severinghaus, Barbara Stenni, and Patricia Martinerie
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Ice core δO2/N2 records are useful dating tools due to their local insolation pacing. A precise understanding of the physical mechanism driving this relationship, however, remain ambiguous. By compiling data from 15 polar sites, we find a strong dependence of mean δO2/N2 on accumulation rate and temperature in addition to the well-documented insolation dependence. Snowpack modelling is used to investigate which physical properties drive the mechanistic dependence on these local parameters.
Mathieu Casado, Amaelle Landais, Tim Stoltmann, Justin Chaillot, Mathieu Daëron, Fréderic Prié, Baptiste Bordet, and Samir Kassi
Atmos. Meas. Tech., 17, 4599–4612, https://doi.org/10.5194/amt-17-4599-2024, https://doi.org/10.5194/amt-17-4599-2024, 2024
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Measuring water isotopic composition in Antarctica is difficult because of the extremely cold temperature in winter. Here, we designed a new infrared spectrometer able to measure the vapour isotopic composition during more than 95 % of the year in the coldest locations of Antarctica, whereas current commercial instruments are only able to measure during the warm summer months in the interior.
Amaelle Landais, Cécile Agosta, Françoise Vimeux, Olivier Magand, Cyrielle Solis, Alexandre Cauquoin, Niels Dutrievoz, Camille Risi, Christophe Leroy-Dos Santos, Elise Fourré, Olivier Cattani, Olivier Jossoud, Bénédicte Minster, Frédéric Prié, Mathieu Casado, Aurélien Dommergue, Yann Bertrand, and Martin Werner
Atmos. Chem. Phys., 24, 4611–4634, https://doi.org/10.5194/acp-24-4611-2024, https://doi.org/10.5194/acp-24-4611-2024, 2024
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We have monitored water vapor isotopes since January 2020 on Amsterdam Island in the Indian Ocean. We show 11 periods associated with abrupt negative excursions of water vapor δ18Ο. Six of these events show a decrease in gaseous elemental mercury, suggesting subsidence of air from a higher altitude. Accurately representing the water isotopic signal during these cold fronts is a real challenge for the atmospheric components of Earth system models equipped with water isotopes.
Philip Meister, Anne Alexandre, Hannah Bailey, Philip Barker, Boris K. Biskaborn, Ellie Broadman, Rosine Cartier, Bernhard Chapligin, Martine Couapel, Jonathan R. Dean, Bernhard Diekmann, Poppy Harding, Andrew C. G. Henderson, Armand Hernandez, Ulrike Herzschuh, Svetlana S. Kostrova, Jack Lacey, Melanie J. Leng, Andreas Lücke, Anson W. Mackay, Eniko Katalin Magyari, Biljana Narancic, Cécile Porchier, Gunhild Rosqvist, Aldo Shemesh, Corinne Sonzogni, George E. A. Swann, Florence Sylvestre, and Hanno Meyer
Clim. Past, 20, 363–392, https://doi.org/10.5194/cp-20-363-2024, https://doi.org/10.5194/cp-20-363-2024, 2024
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This paper presents the first comprehensive compilation of diatom oxygen isotope records in lake sediments (δ18OBSi), supported by lake basin parameters. We infer the spatial and temporal coverage of δ18OBSi records and discuss common hemispheric trends on centennial and millennial timescales. Key results are common patterns for hydrologically open lakes in Northern Hemisphere extratropical regions during the Holocene corresponding to known climatic epochs, i.e. the Holocene Thermal Maximum.
Jérôme Texier, Julio Gonçalvès, Thomas Stieglitz, Christine Vallet-Coulomb, Jérôme Labille, Vincent Marc, Angélique Poulain, and Philippe Dussouillez
Hydrol. Earth Syst. Sci. Discuss., https://doi.org/10.5194/hess-2023-239, https://doi.org/10.5194/hess-2023-239, 2024
Manuscript not accepted for further review
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Understanding the relationship between rivers and alluvial aquifers is crucial, yet challenging. Through a combined approach of tracing and modeling in a French Rhône River site, we reveal significant insights. We quantify the impact of pumping on water flow and identify the primary water sources. Our findings aid sustainable water management in regions facing similar challenges, offering practical guidance for policymakers on groundwater use.
Christophe Leroy-Dos Santos, Elise Fourré, Cécile Agosta, Mathieu Casado, Alexandre Cauquoin, Martin Werner, Benedicte Minster, Frédéric Prié, Olivier Jossoud, Leila Petit, and Amaëlle Landais
The Cryosphere, 17, 5241–5254, https://doi.org/10.5194/tc-17-5241-2023, https://doi.org/10.5194/tc-17-5241-2023, 2023
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In the face of global warming, understanding the changing water cycle and temperatures in polar regions is crucial. These factors directly impact the balance of ice sheets in the Arctic and Antarctic. By studying the composition of water vapor, we gain insights into climate variations. Our 2-year study at Dumont d’Urville station, Adélie Land, offers valuable data to refine models. Additionally, we demonstrate how modeling aids in interpreting signals from ice core samples in the region.
Marie Bouchet, Amaëlle Landais, Antoine Grisart, Frédéric Parrenin, Frédéric Prié, Roxanne Jacob, Elise Fourré, Emilie Capron, Dominique Raynaud, Vladimir Ya Lipenkov, Marie-France Loutre, Thomas Extier, Anders Svensson, Etienne Legrain, Patricia Martinerie, Markus Leuenberger, Wei Jiang, Florian Ritterbusch, Zheng-Tian Lu, and Guo-Min Yang
Clim. Past, 19, 2257–2286, https://doi.org/10.5194/cp-19-2257-2023, https://doi.org/10.5194/cp-19-2257-2023, 2023
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A new federative chronology for five deep polar ice cores retrieves 800 000 years of past climate variations with improved accuracy. Precise ice core timescales are key to studying the mechanisms linking changes in the Earth’s orbit to the diverse climatic responses (temperature and atmospheric greenhouse gas concentrations). To construct the chronology, new measurements from the oldest continuous ice core as well as glaciological modeling estimates were combined in a statistical model.
Claudia Voigt, Anne Alexandre, Ilja M. Reiter, Jean-Philippe Orts, Christine Vallet-Coulomb, Clément Piel, Jean-Charles Mazur, Julie C. Aleman, Corinne Sonzogni, Helene Miche, and Jérôme Ogée
Biogeosciences, 20, 2161–2187, https://doi.org/10.5194/bg-20-2161-2023, https://doi.org/10.5194/bg-20-2161-2023, 2023
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Data on past relative humidity (RH) ARE needed to improve its representation in Earth system models. A novel isotope parameter (17O-excess) of plant silica has been developed to quantify past RH. Using comprehensive monitoring and novel methods, we show how environmental and plant physiological parameters influence the 17O-excess of plant silica and leaf water, i.e. its source water. The insights gained from this study will help to improve estimates of RH from fossil plant silica deposits.
Aymeric P. M. Servettaz, Anaïs J. Orsi, Mark A. J. Curran, Andrew D. Moy, Amaelle Landais, Joseph R. McConnell, Trevor J. Popp, Emmanuel Le Meur, Xavier Faïn, and Jérôme Chappellaz
Clim. Past, 19, 1125–1152, https://doi.org/10.5194/cp-19-1125-2023, https://doi.org/10.5194/cp-19-1125-2023, 2023
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The temperature of the past 2000 years is still poorly known in vast parts of the East Antarctic plateau. In this study, we present temperature reconstructions based on water and gas stable isotopes from the Aurora Basin North ice core. Spatial and temporal significance of each proxy differs, and we can identify some cold periods in the snow temperature up to 2°C cooler in the 1000–1400 CE period, which could not be determined with water isotopes only.
Robert Mulvaney, Eric W. Wolff, Mackenzie M. Grieman, Helene H. Hoffmann, Jack D. Humby, Christoph Nehrbass-Ahles, Rachael H. Rhodes, Isobel F. Rowell, Frédéric Parrenin, Loïc Schmidely, Hubertus Fischer, Thomas F. Stocker, Marcus Christl, Raimund Muscheler, Amaelle Landais, and Frédéric Prié
Clim. Past, 19, 851–864, https://doi.org/10.5194/cp-19-851-2023, https://doi.org/10.5194/cp-19-851-2023, 2023
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We present an age scale for a new ice core drilled at Skytrain Ice Rise, an ice rise facing the Ronne Ice Shelf in Antarctica. Various measurements in the ice and air phases are used to match the ice core to other Antarctic cores that have already been dated, and a new age scale is constructed. The 651 m ice core includes ice that is confidently dated to 117 000–126 000 years ago, in the last interglacial. Older ice is found deeper down, but there are flow disturbances in the deeper ice.
Clémence Paul, Clément Piel, Joana Sauze, Nicolas Pasquier, Frédéric Prié, Sébastien Devidal, Roxanne Jacob, Arnaud Dapoigny, Olivier Jossoud, Alexandru Milcu, and Amaëlle Landais
Biogeosciences, 20, 1047–1062, https://doi.org/10.5194/bg-20-1047-2023, https://doi.org/10.5194/bg-20-1047-2023, 2023
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To improve the interpretation of the δ18Oatm and Δ17O of O2 in air bubbles in ice cores, we need to better quantify the oxygen fractionation coefficients associated with biological processes. We performed a simplified analogue of the terrestrial biosphere in a closed chamber. We found a respiration fractionation in agreement with the previous estimates at the microorganism scale, and a terrestrial photosynthetic fractionation was found. This has an impact on the estimation of the Dole effect.
Antoine Grisart, Mathieu Casado, Vasileios Gkinis, Bo Vinther, Philippe Naveau, Mathieu Vrac, Thomas Laepple, Bénédicte Minster, Frederic Prié, Barbara Stenni, Elise Fourré, Hans Christian Steen-Larsen, Jean Jouzel, Martin Werner, Katy Pol, Valérie Masson-Delmotte, Maria Hoerhold, Trevor Popp, and Amaelle Landais
Clim. Past, 18, 2289–2301, https://doi.org/10.5194/cp-18-2289-2022, https://doi.org/10.5194/cp-18-2289-2022, 2022
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This paper presents a compilation of high-resolution (11 cm) water isotopic records, including published and new measurements, for the last 800 000 years from the EPICA Dome C ice core, Antarctica. Using this new combined water isotopes (δ18O and δD) dataset, we study the variability and possible influence of diffusion at the multi-decadal to multi-centennial scale. We observe a stronger variability at the onset of the interglacial interval corresponding to a warm period.
Christophe Leroy-Dos Santos, Mathieu Casado, Frédéric Prié, Olivier Jossoud, Erik Kerstel, Morgane Farradèche, Samir Kassi, Elise Fourré, and Amaëlle Landais
Atmos. Meas. Tech., 14, 2907–2918, https://doi.org/10.5194/amt-14-2907-2021, https://doi.org/10.5194/amt-14-2907-2021, 2021
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We developed an instrument that can generate water vapor at low humidity at a very stable level. This instrument was conceived to calibrate water vapor isotopic records obtained in very dry places such as central Antarctica. Here, we provide details on the instrument as well as results obtained for correcting water isotopic records for diurnal variability during a long field season at the Concordia station in East Antarctica.
Yves Tramblay, Nathalie Rouché, Jean-Emmanuel Paturel, Gil Mahé, Jean-François Boyer, Ernest Amoussou, Ansoumana Bodian, Honoré Dacosta, Hamouda Dakhlaoui, Alain Dezetter, Denis Hughes, Lahoucine Hanich, Christophe Peugeot, Raphael Tshimanga, and Patrick Lachassagne
Earth Syst. Sci. Data, 13, 1547–1560, https://doi.org/10.5194/essd-13-1547-2021, https://doi.org/10.5194/essd-13-1547-2021, 2021
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This dataset provides a set of hydrometric indices for about 1500 stations across Africa with daily discharge data. These indices represent mean flow characteristics and extremes (low flows and floods), allowing us to study the long-term evolution of hydrology in Africa and support the modeling efforts that aim at reducing the vulnerability of African countries to hydro-climatic variability.
Claudia Voigt, Daniel Herwartz, Cristina Dorador, and Michael Staubwasser
Hydrol. Earth Syst. Sci., 25, 1211–1228, https://doi.org/10.5194/hess-25-1211-2021, https://doi.org/10.5194/hess-25-1211-2021, 2021
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Evaporation trends in the stable isotope composition (18O/16O, 17O/16O, 2H/1H) of throughflow ponds in a hydrologically complex and seasonally dynamic lake system can be reliably predicted by the classic Craig–Gordon isotope evaporation model. We demonstrate that the novel 17O-excess parameter is capable of resolving different types of evaporation with and without recharge and of identifying mixing processes that cannot be resolved using the classic δ2H–δ18O system alone.
Jinhwa Shin, Christoph Nehrbass-Ahles, Roberto Grilli, Jai Chowdhry Beeman, Frédéric Parrenin, Grégory Teste, Amaelle Landais, Loïc Schmidely, Lucas Silva, Jochen Schmitt, Bernhard Bereiter, Thomas F. Stocker, Hubertus Fischer, and Jérôme Chappellaz
Clim. Past, 16, 2203–2219, https://doi.org/10.5194/cp-16-2203-2020, https://doi.org/10.5194/cp-16-2203-2020, 2020
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We reconstruct atmospheric CO2 from the EPICA Dome C ice core during Marine Isotope Stage 6 (185–135 ka) to understand carbon mechanisms under the different boundary conditions of the climate system. The amplitude of CO2 is highly determined by the Northern Hemisphere stadial duration. Carbon dioxide maxima show different lags with respect to the corresponding abrupt CH4 jumps, the latter reflecting rapid warming in the Northern Hemisphere.
Anders Svensson, Dorthe Dahl-Jensen, Jørgen Peder Steffensen, Thomas Blunier, Sune O. Rasmussen, Bo M. Vinther, Paul Vallelonga, Emilie Capron, Vasileios Gkinis, Eliza Cook, Helle Astrid Kjær, Raimund Muscheler, Sepp Kipfstuhl, Frank Wilhelms, Thomas F. Stocker, Hubertus Fischer, Florian Adolphi, Tobias Erhardt, Michael Sigl, Amaelle Landais, Frédéric Parrenin, Christo Buizert, Joseph R. McConnell, Mirko Severi, Robert Mulvaney, and Matthias Bigler
Clim. Past, 16, 1565–1580, https://doi.org/10.5194/cp-16-1565-2020, https://doi.org/10.5194/cp-16-1565-2020, 2020
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We identify signatures of large bipolar volcanic eruptions in Greenland and Antarctic ice cores during the last glacial period, which allows for a precise temporal alignment of the ice cores. Thereby the exact timing of unexplained, abrupt climatic changes occurring during the last glacial period can be determined in a global context. The study thus provides a step towards a full understanding of elements of the climate system that may also play an important role in the future.
Anne Alexandre, Elizabeth Webb, Amaelle Landais, Clément Piel, Sébastien Devidal, Corinne Sonzogni, Martine Couapel, Jean-Charles Mazur, Monique Pierre, Frédéric Prié, Christine Vallet-Coulomb, Clément Outrequin, and Jacques Roy
Biogeosciences, 16, 4613–4625, https://doi.org/10.5194/bg-16-4613-2019, https://doi.org/10.5194/bg-16-4613-2019, 2019
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This calibration study shows that despite isotope heterogeneity along grass leaves, the triple oxygen isotope composition of bulk leaf phytoliths can be estimated from the Craig and Gordon model, a mixing equation and a mean leaf water–phytolith fractionation exponent (lambda) of 0.521. The results strengthen the reliability of the 17O–excess of phytoliths to be used as a proxy of atmospheric relative humidity and open tracks for its use as an imprint of leaf water 17O–excess.
Laurie Menviel, Emilie Capron, Aline Govin, Andrea Dutton, Lev Tarasov, Ayako Abe-Ouchi, Russell N. Drysdale, Philip L. Gibbard, Lauren Gregoire, Feng He, Ruza F. Ivanovic, Masa Kageyama, Kenji Kawamura, Amaelle Landais, Bette L. Otto-Bliesner, Ikumi Oyabu, Polychronis C. Tzedakis, Eric Wolff, and Xu Zhang
Geosci. Model Dev., 12, 3649–3685, https://doi.org/10.5194/gmd-12-3649-2019, https://doi.org/10.5194/gmd-12-3649-2019, 2019
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As part of the Past Global Changes (PAGES) working group on Quaternary Interglacials, we propose a protocol to perform transient simulations of the penultimate deglaciation for the Paleoclimate Modelling Intercomparison Project (PMIP4). This design includes time-varying changes in orbital forcing, greenhouse gas concentrations, continental ice sheets as well as freshwater input from the disintegration of continental ice sheets. Key paleo-records for model-data comparison are also included.
Chloé Poulin, Bruno Hamelin, Christine Vallet-Coulomb, Guinbe Amngar, Bichara Loukman, Jean-François Cretaux, Jean-Claude Doumnang, Abdallah Mahamat Nour, Guillemette Menot, Florence Sylvestre, and Pierre Deschamps
Hydrol. Earth Syst. Sci., 23, 1705–1724, https://doi.org/10.5194/hess-23-1705-2019, https://doi.org/10.5194/hess-23-1705-2019, 2019
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This study investigates the water budget of two intertropical lake systems in the absence of long-term hydrological monitoring. By coupling dry season isotopic data with satellite imagery, we were able to provide quantitative constrains on the hydrological balance and show that these two lake systems can be considered miniature analogs of Lake Chad, making them important targets in the future setup of any large-scale program on the hydro-climatic evolution in the Sahel region.
Rosine Cartier, Florence Sylvestre, Christine Paillès, Corinne Sonzogni, Martine Couapel, Anne Alexandre, Jean-Charles Mazur, Elodie Brisset, Cécile Miramont, and Frédéric Guiter
Clim. Past, 15, 253–263, https://doi.org/10.5194/cp-15-253-2019, https://doi.org/10.5194/cp-15-253-2019, 2019
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A major environmental change, 4200 years ago, was recorded in the lacustrine sediments of Lake Petit (Mediterranean Alps). The regime shift was described by a modification in erosion processes in the watershed and aquatic species in the lake. This study, based on the analysis of the lake water balance by using oxygen isotopes in diatoms, revealed that these environmental responses were due to a rapid change in precipitation regime, lasting ca. 500 years.
Basile Hector, Jean-Martial Cohard, Luc Séguis, Sylvie Galle, and Christophe Peugeot
Hydrol. Earth Syst. Sci., 22, 5867–5888, https://doi.org/10.5194/hess-22-5867-2018, https://doi.org/10.5194/hess-22-5867-2018, 2018
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The hydrological functioning of western African headwater wetlands remains poorly understood, despite their potential for small-scale farming and their role in streamflow production. We found that land cover changes significantly affect water budgets, and pedo-geological features control dry season baseflow. These are the results of virtual experiments with a physically based critical zone model evaluated against streamflow, evapotranspiration, soil moisture, water table and water storage data.
Amaëlle Landais, Emilie Capron, Valérie Masson-Delmotte, Samuel Toucanne, Rachael Rhodes, Trevor Popp, Bo Vinther, Bénédicte Minster, and Frédéric Prié
Clim. Past, 14, 1405–1415, https://doi.org/10.5194/cp-14-1405-2018, https://doi.org/10.5194/cp-14-1405-2018, 2018
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During the last glacial–interglacial climate transition (120 000 to 10 000 years before present), Greenland climate and midlatitude North Atlantic climate and water cycle vary in phase over the succession of millennial events. We identify here one notable exception to this behavior with a decoupling unambiguously identified through a combination of water isotopic tracers measured in a Greenland ice core. The midlatitude moisture source becomes warmer and wetter at 16 200 years before present.
Laurie Menviel, Emilie Capron, Aline Govin, Andrea Dutton, Lev Tarasov, Ayako Abe-Ouchi, Russell Drysdale, Philip Gibbard, Lauren Gregoire, Feng He, Ruza Ivanovic, Masa Kageyama, Kenji Kawamura, Amaelle Landais, Bette L. Otto-Bliesner, Ikumi Oyabu, Polychronis Tzedakis, Eric Wolff, and Xu Zhang
Clim. Past Discuss., https://doi.org/10.5194/cp-2018-106, https://doi.org/10.5194/cp-2018-106, 2018
Preprint withdrawn
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The penultimate deglaciation (~ 138–128 ka), which represents the transition into the Last Interglacial period, provides a framework to investigate the climate and environmental response to large changes in boundary conditions. Here, as part of the PAGES-PMIP working group on Quaternary Interglacials, we propose a protocol to perform transient simulations of the penultimate deglaciation as well as a selection of paleo records for upcoming model-data comparisons.
Alexandra Touzeau, Amaëlle Landais, Samuel Morin, Laurent Arnaud, and Ghislain Picard
Geosci. Model Dev., 11, 2393–2418, https://doi.org/10.5194/gmd-11-2393-2018, https://doi.org/10.5194/gmd-11-2393-2018, 2018
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We introduced a new module of water vapor diffusion into the snowpack model Crocus. Vapor transport locally modifies the density of snow layers, possibly influencing compaction. It also affects the original isotopic signature of snow layers. We also introduced water isotopes (𝛿18O) in the model. Over 10 years, the modeled attenuation of isotopic variations due to vapor diffusion is 7–18 % lower than the observations. Thus, other processes are required to explain the total attenuation.
Anne Alexandre, Amarelle Landais, Christine Vallet-Coulomb, Clément Piel, Sébastien Devidal, Sandrine Pauchet, Corinne Sonzogni, Martine Couapel, Marine Pasturel, Pauline Cornuault, Jingming Xin, Jean-Charles Mazur, Frédéric Prié, Ilhem Bentaleb, Elizabeth Webb, Françoise Chalié, and Jacques Roy
Biogeosciences, 15, 3223–3241, https://doi.org/10.5194/bg-15-3223-2018, https://doi.org/10.5194/bg-15-3223-2018, 2018
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There is a lack of proxies suitable for reconstructing, in a quantitative way, past changes in continental atmospheric humidity, which is a key climate parameter. Here, we demonstrate through climate chamber and climate transect calibrations that the triple oxygen isotope composition of phytoliths offers a potential for reconstructing changes in relative humidity.
Mathieu Casado, Amaelle Landais, Ghislain Picard, Thomas Münch, Thomas Laepple, Barbara Stenni, Giuliano Dreossi, Alexey Ekaykin, Laurent Arnaud, Christophe Genthon, Alexandra Touzeau, Valerie Masson-Delmotte, and Jean Jouzel
The Cryosphere, 12, 1745–1766, https://doi.org/10.5194/tc-12-1745-2018, https://doi.org/10.5194/tc-12-1745-2018, 2018
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Ice core isotopic records rely on the knowledge of the processes involved in the archival processes of the snow. In the East Antarctic Plateau, post-deposition processes strongly affect the signal found in the surface and buried snow compared to the initial climatic signal. We evaluate the different contributions to the surface snow isotopic composition between the precipitation and the exchanges with the atmosphere and the variability of the isotopic signal found in profiles from snow pits.
Thomas Laepple, Thomas Münch, Mathieu Casado, Maria Hoerhold, Amaelle Landais, and Sepp Kipfstuhl
The Cryosphere, 12, 169–187, https://doi.org/10.5194/tc-12-169-2018, https://doi.org/10.5194/tc-12-169-2018, 2018
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We explain why snow pits across different sites in East Antarctica show visually similar isotopic variations. We argue that the similarity and the apparent cycles of around 20 cm in the δD and δ18O variations are the result of a seasonal cycle in isotopes, noise, for example from precipitation intermittency, and diffusion. The near constancy of the diffusion length across many ice-coring sites explains why the structure and cycle length is largely independent of the accumulation conditions.
Kévin Fourteau, Xavier Faïn, Patricia Martinerie, Amaëlle Landais, Alexey A. Ekaykin, Vladimir Ya. Lipenkov, and Jérôme Chappellaz
Clim. Past, 13, 1815–1830, https://doi.org/10.5194/cp-13-1815-2017, https://doi.org/10.5194/cp-13-1815-2017, 2017
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We measured methane concentrations from a polar ice core to quantify the differences between the ice record and the past true atmospheric conditions. Two effects were investigated by combining data analysis and modeling: the stratification of polar snow before gas enclosure driving chronological hiatuses in the record and the gradual formation of bubbles in the ice attenuating fast atmospheric variations. This study will contribute to improving future climatic interpretations from ice archives.
Camille Bréant, Patricia Martinerie, Anaïs Orsi, Laurent Arnaud, and Amaëlle Landais
Clim. Past, 13, 833–853, https://doi.org/10.5194/cp-13-833-2017, https://doi.org/10.5194/cp-13-833-2017, 2017
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All firn densification models applied to deglaciations show a large disagreement with δ15N measurements at sites in East Antarctica, predicting larger firn thickness during the Last Glacial Maximum, whereas δ15N suggests a reduced firn thickness compared to the Holocene. Here we present modifications, which significantly reduce the model–data mismatch for the gas trapping depth evolution over the last deglaciation at the coldest sites in East Antarctica, to the LGGE firn densification model.
Grant M. Raisbeck, Alexandre Cauquoin, Jean Jouzel, Amaelle Landais, Jean-Robert Petit, Vladimir Y. Lipenkov, Juerg Beer, Hans-Arno Synal, Hans Oerter, Sigfus J. Johnsen, Jorgen P. Steffensen, Anders Svensson, and Françoise Yiou
Clim. Past, 13, 217–229, https://doi.org/10.5194/cp-13-217-2017, https://doi.org/10.5194/cp-13-217-2017, 2017
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Using records of a long-lived radioactive nuclide (10Be) that is formed globally in the atmosphere and deposited within a few years to the earth’s surface, we have synchronized three Antarctic ice cores to one from Greenland. This permits the climate and other environmental parameters registered in these ice cores to be put on a common timescale with a precision of a few decades, thus allowing different models and mechanisms associated with these parameters to be tested with the same precision.
Mathieu Casado, Amaelle Landais, Ghislain Picard, Thomas Münch, Thomas Laepple, Barbara Stenni, Giuliano Dreossi, Alexey Ekaykin, Laurent Arnaud, Christophe Genthon, Alexandra Touzeau, Valérie Masson-Delmotte, and Jean Jouzel
The Cryosphere Discuss., https://doi.org/10.5194/tc-2016-263, https://doi.org/10.5194/tc-2016-263, 2016
Revised manuscript not accepted
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Ice core isotopic records rely on the knowledge of the processes involved in the archival of the snow. In the East Antarctic Plateau, post-deposition processes strongly affect the signal found in the surface and buried snow compared to the initial climatic signal. We evaluate the different contributions to the surface snow isotopic composition between the precipitation and the exchanges with the atmosphere and the variability of the isotopic signal found in profiles from snow pits.
Amaelle Landais, Valérie Masson-Delmotte, Emilie Capron, Petra M. Langebroek, Pepijn Bakker, Emma J. Stone, Niklaus Merz, Christoph C. Raible, Hubertus Fischer, Anaïs Orsi, Frédéric Prié, Bo Vinther, and Dorthe Dahl-Jensen
Clim. Past, 12, 1933–1948, https://doi.org/10.5194/cp-12-1933-2016, https://doi.org/10.5194/cp-12-1933-2016, 2016
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The last lnterglacial (LIG; 116 000 to 129 000 years before present) surface temperature at the upstream Greenland NEEM deposition site is estimated to be warmer by +7 to +11 °C compared to the preindustrial period. We show that under such warm temperatures, melting of snow probably led to a significant surface melting. There is a paradox between the extent of the Greenland ice sheet during the LIG and the strong warming during this period that models cannot solve.
Timothé Bolliet, Patrick Brockmann, Valérie Masson-Delmotte, Franck Bassinot, Valérie Daux, Dominique Genty, Amaelle Landais, Marlène Lavrieux, Elisabeth Michel, Pablo Ortega, Camille Risi, Didier M. Roche, Françoise Vimeux, and Claire Waelbroeck
Clim. Past, 12, 1693–1719, https://doi.org/10.5194/cp-12-1693-2016, https://doi.org/10.5194/cp-12-1693-2016, 2016
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This paper presents a new database of past climate proxies which aims to facilitate the distribution of data by using a user-friendly interface. Available data from the last 40 years are often fragmented, with lots of different formats, and online libraries are sometimes nonintuitive. We thus built a new dynamic web portal for data browsing, visualizing, and batch downloading of hundreds of datasets presenting a homogeneous format.
Delphine J. Leroux, Thierry Pellarin, Théo Vischel, Jean-Martial Cohard, Tania Gascon, François Gibon, Arnaud Mialon, Sylvie Galle, Christophe Peugeot, and Luc Seguis
Hydrol. Earth Syst. Sci., 20, 2827–2840, https://doi.org/10.5194/hess-20-2827-2016, https://doi.org/10.5194/hess-20-2827-2016, 2016
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Water is one of the most valuable resources and has an undeniable influence on every aspect of life. Being a very good indicator of the water cycle, the soil water content can be monitored by satellites from space. The region studied here is located in Benin, West Africa, where people have to face major water-related risks every year during the monsoon season. By adjusting the model simulations with satellite observations, river discharge and water table levels have greatly been improved.
Mathieu Casado, Amaelle Landais, Valérie Masson-Delmotte, Christophe Genthon, Erik Kerstel, Samir Kassi, Laurent Arnaud, Ghislain Picard, Frederic Prie, Olivier Cattani, Hans-Christian Steen-Larsen, Etienne Vignon, and Peter Cermak
Atmos. Chem. Phys., 16, 8521–8538, https://doi.org/10.5194/acp-16-8521-2016, https://doi.org/10.5194/acp-16-8521-2016, 2016
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Climatic conditions in Concordia are very cold (−55 °C in average) and very dry, imposing difficult conditions to measure the water vapour isotopic composition. New developments in infrared spectroscopy enable now the measurement of isotopic composition in water vapour traces (down to 20 ppmv). Here we present the results results of a first campaign of measurement of isotopic composition of water vapour in Concordia, the site where the 800 000 years long ice core was drilled.
Inga Labuhn, Valérie Daux, Olivier Girardclos, Michel Stievenard, Monique Pierre, and Valérie Masson-Delmotte
Clim. Past, 12, 1101–1117, https://doi.org/10.5194/cp-12-1101-2016, https://doi.org/10.5194/cp-12-1101-2016, 2016
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This article presents a reconstruction of summer droughts in France for the last 680 years, based on oxygen isotope ratios in tree ring cellulose from living trees and building timbers at two sites, Fontainebleau and Angoulême. Both sites show coherent drought patterns during the 19th and 20th century, and are characterized by increasing drought in recent decades. A decoupling between sites points to a more heterogeneous climate in France during earlier centuries.
Camille Bouchez, Julio Goncalves, Pierre Deschamps, Christine Vallet-Coulomb, Bruno Hamelin, Jean-Claude Doumnang, and Florence Sylvestre
Hydrol. Earth Syst. Sci., 20, 1599–1619, https://doi.org/10.5194/hess-20-1599-2016, https://doi.org/10.5194/hess-20-1599-2016, 2016
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Flows out of Lake Chad are constrained by a modeling of the hydrological, chemical, and isotopic budgets, based on a review of existing data along with new data. This innovative approach allows one to determine the proportions of evaporation, transpiration, and infiltration out of the lake while the two last flows are often neglected in semi-arid environments. Moreover, it allows to investigate the lake hydrological and chemical regulations under the large climatic changes in Sahel since 1950.
Alexandra Touzeau, Amaëlle Landais, Barbara Stenni, Ryu Uemura, Kotaro Fukui, Shuji Fujita, Sarah Guilbaud, Alexey Ekaykin, Mathieu Casado, Eugeni Barkan, Boaz Luz, Olivier Magand, Grégory Teste, Emmanuel Le Meur, Mélanie Baroni, Joël Savarino, Ilann Bourgeois, and Camille Risi
The Cryosphere, 10, 837–852, https://doi.org/10.5194/tc-10-837-2016, https://doi.org/10.5194/tc-10-837-2016, 2016
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The relationship between water isotope ratios and temperature is investigated in precipitation snow at Vostok and Dome C, as well as in surface snow along traverses. The temporal slope of the linear regression for the precipitation is smaller than the geographical slope. Thus, using the latter could lead to an underestimation of past temperature changes. The processes active at remote sites (best glacial analogs) are explored through a combination of water isotopes in short snow pits.
Lucie Bazin, Amaelle Landais, Emilie Capron, Valérie Masson-Delmotte, Catherine Ritz, Ghislain Picard, Jean Jouzel, Marie Dumont, Markus Leuenberger, and Frédéric Prié
Clim. Past, 12, 729–748, https://doi.org/10.5194/cp-12-729-2016, https://doi.org/10.5194/cp-12-729-2016, 2016
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We present new measurements of δO2⁄N2 and δ18Oatm performed on well-conserved ice from EDC covering MIS5 and between 380 and 800 ka. The combination of the observation of a 100 ka periodicity in the new δO2⁄N2 record with a MIS5 multi-site multi-proxy study has revealed a potential influence of local climatic parameters on δO2⁄N2. Moreover, we propose that the varying delay between d18Oatm and precession for the last 800 ka is affected by the occurrence of ice sheet discharge events.
Anne Alexandre, Jérôme Balesdent, Patrick Cazevieille, Claire Chevassus-Rosset, Patrick Signoret, Jean-Charles Mazur, Araks Harutyunyan, Emmanuel Doelsch, Isabelle Basile-Doelsch, Hélène Miche, and Guaciara M. Santos
Biogeosciences, 13, 1693–1703, https://doi.org/10.5194/bg-13-1693-2016, https://doi.org/10.5194/bg-13-1693-2016, 2016
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This 13C labeling experiment demonstrates that carbon can be absorbed by the roots, translocated in the plant, and ultimately fixed in organic compounds subject to occlusion in silica particles that form inside plant cells (phytoliths). Plausible forms of carbon absorbed, translocated, and fixed in phytoliths are assessed. Implications for our understanding of the C cycle at the plant-soil-atmosphere interface are discussed.
Paul E. Reyerson, Anne Alexandre, Araks Harutyunyan, Remi Corbineau, Hector A. Martinez De La Torre, Franz Badeck, Luigi Cattivelli, and Guaciara M. Santos
Biogeosciences, 13, 1269–1286, https://doi.org/10.5194/bg-13-1269-2016, https://doi.org/10.5194/bg-13-1269-2016, 2016
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We characterize the origin of carbon (C) in phytoliths (biosilica of higher plants) by a multi-isotope approach. We show that phytoliths occlude soil organic C adsorbed through the roots, making them unsuitable for paleo-proxy studies, 14C dating or atmospheric CO2 sequestration. Our findings are in parallel with recent soil paradigm shifts showing that soil microbes access old C and therefore call for further investigations on the role of old C in root–plant interactions and biomineralization.
C. Reutenauer, A. Landais, T. Blunier, C. Bréant, M. Kageyama, M.-N. Woillez, C. Risi, V. Mariotti, and P. Braconnot
Clim. Past, 11, 1527–1551, https://doi.org/10.5194/cp-11-1527-2015, https://doi.org/10.5194/cp-11-1527-2015, 2015
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Isotopes of atmospheric O2 undergo millennial-scale variations during the last glacial period, and systematically increase during Heinrich stadials.
Such variations are mostly due to vegetation and water cycle processes.
Our modeling approach reproduces the main observed features of Heinrich stadials in terms of climate, vegetation and rainfall.
It highlights the strong role of hydrology on O2 isotopes, which can be seen as a global integrator of precipitation changes over vegetated areas.
H. Delattre, C. Vallet-Coulomb, and C. Sonzogni
Atmos. Chem. Phys., 15, 10167–10181, https://doi.org/10.5194/acp-15-10167-2015, https://doi.org/10.5194/acp-15-10167-2015, 2015
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Based on summer measurements of δ18O and δD in the atmospheric vapour of a Mediterranean coastal wetland exposed to high evaporation, this paper explores the main drivers of isotopic signal variability. After having classified the data according to the main regional air mass trajectories, average diurnal cycles are discussed with regards to the contribution of local evaporation to the ground level atmospheric vapour.
J.-L. Tison, M. de Angelis, G. Littot, E. Wolff, H. Fischer, M. Hansson, M. Bigler, R. Udisti, A. Wegner, J. Jouzel, B. Stenni, S. Johnsen, V. Masson-Delmotte, A. Landais, V. Lipenkov, L. Loulergue, J.-M. Barnola, J.-R. Petit, B. Delmonte, G. Dreyfus, D. Dahl-Jensen, G. Durand, B. Bereiter, A. Schilt, R. Spahni, K. Pol, R. Lorrain, R. Souchez, and D. Samyn
The Cryosphere, 9, 1633–1648, https://doi.org/10.5194/tc-9-1633-2015, https://doi.org/10.5194/tc-9-1633-2015, 2015
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The oldest paleoclimatic information is buried within the lowermost layers of deep ice cores. It is therefore essential to judge how deep these records remain unaltered. We study the bottom 60 meters of the EPICA Dome C ice core from central Antarctica to show that the paleoclimatic signal is only affected at the small scale (decimeters) in terms of some of the global ice properties. However our data suggest that the time scale has been considerably distorted by mechanical stretching.
V. Masson-Delmotte, H. C. Steen-Larsen, P. Ortega, D. Swingedouw, T. Popp, B. M. Vinther, H. Oerter, A. E. Sveinbjornsdottir, H. Gudlaugsdottir, J. E. Box, S. Falourd, X. Fettweis, H. Gallée, E. Garnier, V. Gkinis, J. Jouzel, A. Landais, B. Minster, N. Paradis, A. Orsi, C. Risi, M. Werner, and J. W. C. White
The Cryosphere, 9, 1481–1504, https://doi.org/10.5194/tc-9-1481-2015, https://doi.org/10.5194/tc-9-1481-2015, 2015
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The deep NEEM ice core provides the oldest Greenland ice core record, enabling improved understanding of the response of ice core records to local climate. Here, we focus on shallow ice cores providing a stack record of accumulation and water-stable isotopes spanning the past centuries. For the first time, we document the ongoing warming in a Greenland ice core. By combining our data with other Greenland ice cores and model results, we characterise the spatio-temporal patterns of variability.
B. Lemieux-Dudon, L. Bazin, A. Landais, H. Toyé Mahamadou Kele, M. Guillevic, P. Kindler, F. Parrenin, and P. Martinerie
Clim. Past, 11, 959–978, https://doi.org/10.5194/cp-11-959-2015, https://doi.org/10.5194/cp-11-959-2015, 2015
F. Parrenin, L. Bazin, E. Capron, A. Landais, B. Lemieux-Dudon, and V. Masson-Delmotte
Geosci. Model Dev., 8, 1473–1492, https://doi.org/10.5194/gmd-8-1473-2015, https://doi.org/10.5194/gmd-8-1473-2015, 2015
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This manuscript describes a probabilistic model which aims at optimizing the chronology of ice cores by combining different sources of information.
A. Cauquoin, A. Landais, G. M. Raisbeck, J. Jouzel, L. Bazin, M. Kageyama, J.-Y. Peterschmitt, M. Werner, E. Bard, and ASTER Team
Clim. Past, 11, 355–367, https://doi.org/10.5194/cp-11-355-2015, https://doi.org/10.5194/cp-11-355-2015, 2015
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We present a new 10Be record at EDC between 269 and 355ka. Our 10Be-based accumulation rate is in good agreement with the one associated with the EDC3 timescale except for the warm MIS 9.3 optimum. This suggests that temperature reconstruction from water isotopes may be underestimated by 2.4K for the difference between the MIS 9.3 and present day. The CMIP5-PMIP3 models do not quantitatively reproduce changes in precipitation vs. temperature increase during glacial–interglacial transitions.
A. Alexandre, I. Basile-Doelsch, T. Delhaye, D. Borshneck, J. C. Mazur, P. Reyerson, and G. M. Santos
Biogeosciences, 12, 863–873, https://doi.org/10.5194/bg-12-863-2015, https://doi.org/10.5194/bg-12-863-2015, 2015
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Phytoliths contain occluded organic compounds called phytC. The nature and location of phytC in biogenic silica structures is poorly understood. Here, we reconstructed the 3-D structure of phytoliths using 3-D Xray microscopy. We further evidenced a pool of phytC, continuously distributed in the silica structure, using nanoscale secondary ion mass spectrometry (NanoSIMS). Our findings allowed the re-evaluation of previous suggestions regarding phytC quantification and environmental meaning.
F. Lohou, L. Kergoat, F. Guichard, A. Boone, B. Cappelaere, J.-M. Cohard, J. Demarty, S. Galle, M. Grippa, C. Peugeot, D. Ramier, C. M. Taylor, and F. Timouk
Atmos. Chem. Phys., 14, 3883–3898, https://doi.org/10.5194/acp-14-3883-2014, https://doi.org/10.5194/acp-14-3883-2014, 2014
O. Mamadou, J. M. Cohard, S. Galle, C. N. Awanou, A. Diedhiou, B. Kounouhewa, and C. Peugeot
Hydrol. Earth Syst. Sci., 18, 893–914, https://doi.org/10.5194/hess-18-893-2014, https://doi.org/10.5194/hess-18-893-2014, 2014
H. C. Steen-Larsen, V. Masson-Delmotte, M. Hirabayashi, R. Winkler, K. Satow, F. Prié, N. Bayou, E. Brun, K. M. Cuffey, D. Dahl-Jensen, M. Dumont, M. Guillevic, S. Kipfstuhl, A. Landais, T. Popp, C. Risi, K. Steffen, B. Stenni, and A. E. Sveinbjörnsdottír
Clim. Past, 10, 377–392, https://doi.org/10.5194/cp-10-377-2014, https://doi.org/10.5194/cp-10-377-2014, 2014
A. Richard, S. Galle, M. Descloitres, J.-M. Cohard, J.-P. Vandervaere, L. Séguis, and C. Peugeot
Hydrol. Earth Syst. Sci., 17, 5079–5096, https://doi.org/10.5194/hess-17-5079-2013, https://doi.org/10.5194/hess-17-5079-2013, 2013
M. C. Matteuzzo, A. Alexandre, A. F. D. C. Varajão, C. Volkmer-Ribeiro, A. C. S. Almeida, C. A. C. Varajão, C. Vallet-Coulomb, C. Sonzogni, and H. Miche
Biogeosciences Discuss., https://doi.org/10.5194/bgd-10-12887-2013, https://doi.org/10.5194/bgd-10-12887-2013, 2013
Revised manuscript not accepted
D. Veres, L. Bazin, A. Landais, H. Toyé Mahamadou Kele, B. Lemieux-Dudon, F. Parrenin, P. Martinerie, E. Blayo, T. Blunier, E. Capron, J. Chappellaz, S. O. Rasmussen, M. Severi, A. Svensson, B. Vinther, and E. W. Wolff
Clim. Past, 9, 1733–1748, https://doi.org/10.5194/cp-9-1733-2013, https://doi.org/10.5194/cp-9-1733-2013, 2013
E. Capron, A. Landais, D. Buiron, A. Cauquoin, J. Chappellaz, M. Debret, J. Jouzel, M. Leuenberger, P. Martinerie, V. Masson-Delmotte, R. Mulvaney, F. Parrenin, and F. Prié
Clim. Past, 9, 983–999, https://doi.org/10.5194/cp-9-983-2013, https://doi.org/10.5194/cp-9-983-2013, 2013
Related subject area
Subject: Proxy Use-Development-Validation | Archive: Terrestrial Archives | Timescale: Pleistocene
Newly dated permafrost deposits and their paleoecological inventory reveal an Eemian much warmer than today in Arctic Siberia
Tropical temperature evolution across two glacial cycles derived from speleothem fluid inclusion microthermometry
Towards quantitative reconstruction of past monsoon precipitation based on tetraether membrane lipids in Chinese loess
The Indo–Pacific Pollen Database – a Neotoma constituent database
Can machine-learning algorithms improve upon classical palaeoenvironmental reconstruction models?
Distinguishing the combined vegetation and soil component of δ13C variation in speleothem records from subsequent degassing and prior calcite precipitation effects
Multi-proxy speleothem-based reconstruction of mid-MIS 3 climate in South Africa
Biomarker proxy records of Arctic climate change during the Mid-Pleistocene transition from Lake El'gygytgyn (Far East Russia)
Hydroclimatic variability of opposing Late Pleistocene climates in the Levant revealed by deep Dead Sea sediments
Different facets of dry–wet patterns in south-western China over the past 27 000 years
The speleothem oxygen record as a proxy for thermal or moisture changes: a case study of multiproxy records from MIS 5–MIS 6 speleothems from the Demänová Cave system
A new multivariable benchmark for Last Glacial Maximum climate simulations
The Last Glacial Maximum in the central North Island, New Zealand: palaeoclimate inferences from glacier modelling
Late-glacial to late-Holocene shifts in global precipitation δ18O
Climate history of the Southern Hemisphere Westerlies belt during the last glacial–interglacial transition revealed from lake water oxygen isotope reconstruction of Laguna Potrok Aike (52° S, Argentina)
New online method for water isotope analysis of speleothem fluid inclusions using laser absorption spectroscopy (WS-CRDS)
Inorganic geochemistry data from Lake El'gygytgyn sediments: marine isotope stages 6–11
A 350 ka record of climate change from Lake El'gygytgyn, Far East Russian Arctic: refining the pattern of climate modes by means of cluster analysis
Dynamic diatom response to changing climate 0–1.2 Ma at Lake El'gygytgyn, Far East Russian Arctic
Amplified bioproductivity during Transition IV (332 000–342 000 yr ago): evidence from the geochemical record of Lake El'gygytgyn
Potential and limits of OSL, TT-OSL, IRSL and pIRIR290 dating methods applied on a Middle Pleistocene sediment record of Lake El'gygytgyn, Russia
Rock magnetic properties, magnetic susceptibility, and organic geochemistry comparison in core LZ1029-7 Lake El'gygytgyn, Russia Far East
High-temperature thermomagnetic properties of vivianite nodules, Lake El'gygytgyn, Northeast Russia
Reconstruction of drip-water δ18O based on calcite oxygen and clumped isotopes of speleothems from Bunker Cave (Germany)
A biomarker record of Lake El'gygytgyn, Far East Russian Arctic: investigating sources of organic matter and carbon cycling during marine isotope stages 1–3
Climate warming and vegetation response after Heinrich event 1 (16 700–16 000 cal yr BP) in Europe south of the Alps
A 250 ka oxygen isotope record from diatoms at Lake El'gygytgyn, far east Russian Arctic
The oxygen isotopic composition of phytolith assemblages from tropical rainforest soil tops (Queensland, Australia): validation of a new paleoenvironmental tool
Terrestrial mollusc records from Xifeng and Luochuan L9 loess strata and their implications for paleoclimatic evolution in the Chinese Loess Plateau during marine Oxygen Isotope Stages 24-22
Lutz Schirrmeister, Margret C. Fuchs, Thomas Opel, Andrei Andreev, Frank Kienast, Andrea Schneider, Larisa Nazarova, Larisa Frolova, Svetlana Kuzmina, Tatiana Kuznetsova, Vladimir Tumskoy, Heidrun Matthes, Gerrit Lohmann, Guido Grosse, Viktor Kunitsky, Hanno Meyer, Heike H. Zimmermann, Ulrike Herzschuh, Thomas Böhmer, Stuart Umbo, Sevi Modestou, Sebastian F. M. Breitenbach, Anfisa Pismeniuk, Georg Schwamborn, Stephanie Kusch, and Sebastian Wetterich
Clim. Past, 21, 1143–1184, https://doi.org/10.5194/cp-21-1143-2025, https://doi.org/10.5194/cp-21-1143-2025, 2025
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Geochronological, cryolithological, paleoecological, and modeling data reconstruct the Last Interglacial (LIG) climate around the New Siberian Islands and reveal significantly warmer conditions compared to today. The critical challenges in predicting future ecosystem responses lie in the fact that the land–ocean distribution during the LIG was markedly different from today, affecting the degree of continentality, which played a major role in modulating climate and ecosystem dynamics.
Yves Krüger, Leonardo Pasqualetto, Alvaro Fernandez, Kim M. Cobb, and Anna Nele Meckler
EGUsphere, https://doi.org/10.5194/egusphere-2025-668, https://doi.org/10.5194/egusphere-2025-668, 2025
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Using a stalagmite from Whiterock Cave (Gunung Mulu National Park, Northern Borneo), covering the time interval from 460000 to 333000 years B.P., including two glacial terminations, we employed nucleation-assisted fluid inclusion microthermometry to reconstruct a tropical land temperature record. The record reveals an amplitude of glacial-interglacial temperature changes of 4.2 °C and a strong linear correlation with Antarctic temperature anomalies, yielding a polar amplification factor of 2.3.
Jingjing Guo, Martin Ziegler, Louise Fuchs, Youbin Sun, and Francien Peterse
Clim. Past, 21, 343–355, https://doi.org/10.5194/cp-21-343-2025, https://doi.org/10.5194/cp-21-343-2025, 2025
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In this study, we use the distribution of soil bacterial membrane lipids stored on the Chinese Loess Plateau (CLP) to quantitatively reconstruct variations in precipitation amount over the past 130 kyr. The precipitation record shows orbital- and millennial-scale variations and varies at precession and obliquity scale. The application of this precipitation proxy across the CLP indicates a more pronounced spatial gradient during glacials, when the western CLP experiences more arid conditions.
Annika V. Herbert, Simon G. Haberle, Suzette G. A. Flantua, Ondrej Mottl, Jessica L. Blois, John W. Williams, Adrian George, and Geoff S. Hope
Clim. Past, 20, 2473–2485, https://doi.org/10.5194/cp-20-2473-2024, https://doi.org/10.5194/cp-20-2473-2024, 2024
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The Indo-Pacific Pollen Database is a large collection of pollen samples from across the Indo-Pacific region, with most samples coming from Australia. This is a valuable collection that can be used to analyse vegetation dynamics going back thousands of years. It is now being fully shared via Neotoma for the first time, opening up many exciting new avenues of research. This paper presents key aspects of this database, including geographical distribution, age control and deposition times.
Peng Sun, Philip B. Holden, and H. John B. Birks
Clim. Past, 20, 2373–2398, https://doi.org/10.5194/cp-20-2373-2024, https://doi.org/10.5194/cp-20-2373-2024, 2024
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We develop the Multi Ensemble Machine Learning Model (MEMLM) for reconstructing palaeoenvironments from microfossil assemblages. The machine-learning approaches, which include random tree and natural language processing techniques, substantially outperform classical approaches under cross-validation, but they can fail when applied to reconstruct past environments. Statistical significance testing is found sufficient to identify these unreliable reconstructions.
Heather M. Stoll, Chris Day, Franziska Lechleitner, Oliver Kost, Laura Endres, Jakub Sliwinski, Carlos Pérez-Mejías, Hai Cheng, and Denis Scholz
Clim. Past, 19, 2423–2444, https://doi.org/10.5194/cp-19-2423-2023, https://doi.org/10.5194/cp-19-2423-2023, 2023
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Stalagmites formed in caves provide valuable information about past changes in climate and vegetation conditions. In this contribution, we present a new method to better estimate past changes in soil and vegetation productivity using carbon isotopes and trace elements measured in stalagmites. Applying this method to other stalagmites should provide a better indication of past vegetation feedbacks to climate change.
Jenny Maccali, Anna Nele Meckler, Stein-Erik Lauritzen, Torill Brekken, Helen Aase Rokkan, Alvaro Fernandez, Yves Krüger, Jane Adigun, Stéphane Affolter, and Markus Leuenberger
Clim. Past, 19, 1847–1862, https://doi.org/10.5194/cp-19-1847-2023, https://doi.org/10.5194/cp-19-1847-2023, 2023
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The southern coast of South Africa hosts some key archeological sites for the study of early human evolution. Here we present a short but high-resolution record of past changes in the hydroclimate and temperature on the southern coast of South Africa based on the study of a speleothem collected from Bloukrantz Cave. Overall, the paleoclimate indicators suggest stable temperature from 48.3 to 45.2 ka, whereas precipitation was variable, with marked short drier episodes.
Kurt R. Lindberg, William C. Daniels, Isla S. Castañeda, and Julie Brigham-Grette
Clim. Past, 18, 559–577, https://doi.org/10.5194/cp-18-559-2022, https://doi.org/10.5194/cp-18-559-2022, 2022
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Earth experiences regular ice ages resulting in shifts between cooler and warmer climates. Around 1 million years ago, the ice age cycles grew longer and stronger. We used bacterial and plant lipids preserved in an Arctic lake to reconstruct temperature and vegetation during this climate transition. We find that Arctic land temperatures did not cool much compared to ocean records from this period, and that vegetation shifts correspond with a long-term drying previously reported in the region.
Yoav Ben Dor, Francesco Marra, Moshe Armon, Yehouda Enzel, Achim Brauer, Markus Julius Schwab, and Efrat Morin
Clim. Past, 17, 2653–2677, https://doi.org/10.5194/cp-17-2653-2021, https://doi.org/10.5194/cp-17-2653-2021, 2021
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Laminated sediments from the deepest part of the Dead Sea unravel the hydrological response of the eastern Mediterranean to past climate changes. This study demonstrates the importance of geological archives in complementing modern hydrological measurements that do not fully capture natural hydroclimatic variability, which is crucial to configure for understanding the impact of climate change on the hydrological cycle in subtropical regions.
Mengna Liao, Kai Li, Weiwei Sun, and Jian Ni
Clim. Past, 17, 2291–2303, https://doi.org/10.5194/cp-17-2291-2021, https://doi.org/10.5194/cp-17-2291-2021, 2021
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The long-term trajectories of precipitation, hydrological balance and soil moisture are not completely consistent in southwest China. Hydrological balance was more sensitive to temperature change on a millennial scale. For soil moisture, plant processes also played a big role in addition to precipitation and temperature. Under future climate warming, surface water shortage in southwest China can be even more serious and efforts at reforestation may bring some relief to the soil moisture deficit.
Jacek Pawlak
Clim. Past, 17, 1051–1064, https://doi.org/10.5194/cp-17-1051-2021, https://doi.org/10.5194/cp-17-1051-2021, 2021
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Presently, central Europe is under the influence of two types of climate, transitional and continental. The 60 ka long multiproxy speleothem dataset from Slovakia records the climate of the Last Interglacial cycle and its transition to the Last Glacial. The interpretation of stable isotopic composition and trace element content proxies helps to distinguish which factor had the strongest influence on the δ18O record shape: the local temperature, the humidity or the source effect.
Sean F. Cleator, Sandy P. Harrison, Nancy K. Nichols, I. Colin Prentice, and Ian Roulstone
Clim. Past, 16, 699–712, https://doi.org/10.5194/cp-16-699-2020, https://doi.org/10.5194/cp-16-699-2020, 2020
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We present geographically explicit reconstructions of seasonal temperature and annual moisture variables at the Last Glacial Maximum (LGM), 21 000 years ago. The reconstructions use existing site-based estimates of climate, interpolated in space and time in a physically consistent way using climate model simulations. The reconstructions give a much better picture of the LGM climate and will provide a robust evaluation of how well state-of-the-art climate models simulate large climate changes.
Shaun R. Eaves, Andrew N. Mackintosh, Brian M. Anderson, Alice M. Doughty, Dougal B. Townsend, Chris E. Conway, Gisela Winckler, Joerg M. Schaefer, Graham S. Leonard, and Andrew T. Calvert
Clim. Past, 12, 943–960, https://doi.org/10.5194/cp-12-943-2016, https://doi.org/10.5194/cp-12-943-2016, 2016
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Geological evidence for past changes in glacier length provides a useful source of information about pre-historic climate change. We have used glacier modelling to show that air temperature reductions of −5 to −7 °C, relative to present, are required to simulate the glacial extent in the North Island, New Zealand, during the last ice age (approx. 20000 years ago). Our results provide data to assess climate model simulations, with the aim of determining the drivers of past natural climate change.
S. Jasechko, A. Lechler, F. S. R. Pausata, P. J. Fawcett, T. Gleeson, D. I. Cendón, J. Galewsky, A. N. LeGrande, C. Risi, Z. D. Sharp, J. M. Welker, M. Werner, and K. Yoshimura
Clim. Past, 11, 1375–1393, https://doi.org/10.5194/cp-11-1375-2015, https://doi.org/10.5194/cp-11-1375-2015, 2015
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In this study we compile global isotope proxy records of climate changes from the last ice age to the late-Holocene preserved in cave calcite, glacial ice and groundwater aquifers. We show that global patterns of late-Pleistocene to late-Holocene precipitation isotope shifts are consistent with stronger-than-modern isotopic distillation of air masses during the last ice age, likely impacted by larger global temperature differences between the tropics and the poles.
J. Zhu, A. Lücke, H. Wissel, C. Mayr, D. Enters, K. Ja Kim, C. Ohlendorf, F. Schäbitz, and B. Zolitschka
Clim. Past, 10, 2153–2169, https://doi.org/10.5194/cp-10-2153-2014, https://doi.org/10.5194/cp-10-2153-2014, 2014
S. Affolter, D. Fleitmann, and M. Leuenberger
Clim. Past, 10, 1291–1304, https://doi.org/10.5194/cp-10-1291-2014, https://doi.org/10.5194/cp-10-1291-2014, 2014
P. S. Minyuk, V. Y. Borkhodoev, and V. Wennrich
Clim. Past, 10, 467–485, https://doi.org/10.5194/cp-10-467-2014, https://doi.org/10.5194/cp-10-467-2014, 2014
U. Frank, N. R. Nowaczyk, P. Minyuk, H. Vogel, P. Rosén, and M. Melles
Clim. Past, 9, 1559–1569, https://doi.org/10.5194/cp-9-1559-2013, https://doi.org/10.5194/cp-9-1559-2013, 2013
J. A. Snyder, M. V. Cherepanova, and A. Bryan
Clim. Past, 9, 1309–1319, https://doi.org/10.5194/cp-9-1309-2013, https://doi.org/10.5194/cp-9-1309-2013, 2013
L. Cunningham, H. Vogel, V. Wennrich, O. Juschus, N. Nowaczyk, and P. Rosén
Clim. Past, 9, 679–686, https://doi.org/10.5194/cp-9-679-2013, https://doi.org/10.5194/cp-9-679-2013, 2013
A. Zander and A. Hilgers
Clim. Past, 9, 719–733, https://doi.org/10.5194/cp-9-719-2013, https://doi.org/10.5194/cp-9-719-2013, 2013
K. J. Murdock, K. Wilkie, and L. L. Brown
Clim. Past, 9, 467–479, https://doi.org/10.5194/cp-9-467-2013, https://doi.org/10.5194/cp-9-467-2013, 2013
P. S. Minyuk, T. V. Subbotnikova, L. L. Brown, and K. J. Murdock
Clim. Past, 9, 433–446, https://doi.org/10.5194/cp-9-433-2013, https://doi.org/10.5194/cp-9-433-2013, 2013
T. Kluge, H. P. Affek, T. Marx, W. Aeschbach-Hertig, D. F. C. Riechelmann, D. Scholz, S. Riechelmann, A. Immenhauser, D. K. Richter, J. Fohlmeister, A. Wackerbarth, A. Mangini, and C. Spötl
Clim. Past, 9, 377–391, https://doi.org/10.5194/cp-9-377-2013, https://doi.org/10.5194/cp-9-377-2013, 2013
A. R. Holland, S. T. Petsch, I. S. Castañeda, K. M. Wilkie, S. J. Burns, and J. Brigham-Grette
Clim. Past, 9, 243–260, https://doi.org/10.5194/cp-9-243-2013, https://doi.org/10.5194/cp-9-243-2013, 2013
S. Samartin, O. Heiri, A. F. Lotter, and W. Tinner
Clim. Past, 8, 1913–1927, https://doi.org/10.5194/cp-8-1913-2012, https://doi.org/10.5194/cp-8-1913-2012, 2012
B. Chapligin, H. Meyer, G. E. A. Swann, C. Meyer-Jacob, and H.-W. Hubberten
Clim. Past, 8, 1621–1636, https://doi.org/10.5194/cp-8-1621-2012, https://doi.org/10.5194/cp-8-1621-2012, 2012
A. Alexandre, J. Crespin, F. Sylvestre, C. Sonzogni, and D. W. Hilbert
Clim. Past, 8, 307–324, https://doi.org/10.5194/cp-8-307-2012, https://doi.org/10.5194/cp-8-307-2012, 2012
B. Wu and N. Q. Wu
Clim. Past, 7, 349–359, https://doi.org/10.5194/cp-7-349-2011, https://doi.org/10.5194/cp-7-349-2011, 2011
Cited articles
Aemisegger, F., Sturm, P., Graf, P., Sodemann, H., Pfahl, S., Knohl, A., and Wernli, H.: Measuring variations of δ18O and δ2H in atmospheric water vapour using two commercial laser-based spectrometers: an instrument characterisation study, Atmos. Meas. Tech., 5, 1491–1511, https://doi.org/10.5194/amt-5-1491-2012, 2012.
Ainsworth, E. A. and Rogers, A.: The response of photosynthesis and stomatal
conductance to rising [CO2]: mechanisms and environmental interactions, Plant Cell Environ., 30, 258–270,
https://doi.org/10.1111/j.1365-3040.2007.01641.x, 2007.
Alexandre, A., Basile-Doelsch, I., Sonzogni, C., Sylvestre, F., Parron, C.,
Meunier, J.-D., and Colin, F.: Oxygen isotope analyses of fine silica grains
using laser-extraction technique: Comparison with oxygen isotope data
obtained from ion microprobe analyses and application to quartzite and
silcrete cement investigation, Geochim. Cosmochim. Ac., 70,
2827–2835, https://doi.org/10.1016/j.gca.2006.03.003, 2006.
Alexandre, A., Crespin, J., Sylvestre, F., Sonzogni, C., and Hilbert, D. W.:
The oxygen isotopic composition of phytolith assemblages from tropical
rainforest soil tops (Queensland, Australia): validation of a new
paleoenvironmental tool, Geochim. Cosmochim. Ac., 8, 307–324, 2012.
Alexandre, A., Landais, A., Vallet-Coulomb, C., Piel, C., Devidal, S., Pauchet, S., Sonzogni, C., Couapel, M., Pasturel, M., Cornuault, P., Xin, J., Mazur, J.-C., Prié, F., Bentaleb, I., Webb, E., Chalié, F., and Roy, J.: The triple oxygen isotope composition of phytoliths as a proxy of continental atmospheric humidity: insights from climate chamber and climate transect calibrations, Biogeosciences, 15, 3223–3241, https://doi.org/10.5194/bg-15-3223-2018, 2018.
Alexandre, A., Webb, E., Landais, A., Piel, C., Devidal, S., Sonzogni, C., Couapel, M., Mazur, J.-C., Pierre, M., Prié, F., Vallet-Coulomb, C., Outrequin, C., and Roy, J.: Effects of leaf length and development stage on the triple oxygen isotope signature of grass leaf water and phytoliths: insights for a proxy of continental atmospheric humidity, Biogeosciences, 16, 4613–4625, https://doi.org/10.5194/bg-16-4613-2019, 2019.
Angert, A., Rachmilevitch, S., Barkan, E., and Luz, B.: Effects of
photorespiration, the cytochrome pathway, and the alternative pathway on the
triple isotopic composition of atmospheric O2, Global Biogeochem. Cy., 17, 1030, https://doi.org/10.1029/2002GB001933, 2003.
Aron, P. G., Levin, N. E., Beverly, E. J., Huth, T. E., Passey, B. H.,
Pelletier, E. M., Poulsen, C. J., Winkelstern, I. Z., and Yarian, D. A.:
Triple oxygen isotopes in the water cycle, Chem. Geol., 565, 120026,
https://doi.org/10.1016/j.chemgeo.2020.120026, 2020.
Barillot, R., Frak, E., Combes, D., Durand, J.-L., and
Escobar-Gutiérrez, A. J.: What determines the complex kinetics of
stomatal conductance under blueless PAR in Festuca arundinacea? Subsequent effects on leaf transpiration, J. Exp. Bot., 61, 2795–2806,
https://doi.org/10.1093/jxb/erq115, 2010.
Barkan, E. and Luz, B.: High precision measurements of
Barkan, E. and Luz, B.: Diffusivity fractionations of
Blunier, T., Barnett, B., Bender, M. L., and Hendricks, M. B.: Biological
oxygen productivity during the last 60,000 years from triple oxygen isotope
measurements, Global Biogeochem. Cy., 16, 3-1–3-13, https://doi.org/10.1029/2001GB001460, 2002.
Bony, S., Colman, R., Kattsov, V. M., Allan, R. P., Bretherton, C. S.,
Dufresne, J.-L., Hall, A., Hallegatte, S., Holland, M. M., Ingram, W.,
Randall, D. A., Soden, B. J., Tselioudis, G., and Webb, M. J.: How Well Do
We Understand and Evaluate Climate Change Feedback Processes?, J. Climate,
19, 3445–3482, https://doi.org/10.1175/JCLI3819.1, 2006.
Bowen, G. J., Wassenaar, L. I., and Hobson, K. A.: Global application of
stable hydrogen and oxygen isotopes to wildlife forensics, Oecologia, 143,
337–348, https://doi.org/10.1007/s00442-004-1813-y, 2005.
Brady, M. P. and Hodell, D. A.: Continuous and simultaneous measurement of triple-oxygen and hydrogen isotopes of liquid and vapor during evaporation experiments, Rapid Commun. Mass Sp., 35, e9078, https://doi.org/10.1002/rcm.9078, 2021.
Brandon, M., Landais, A., Duchamp-Alphonse, S., Favre, V., Schmitz, L.,
Abrial, H., Prié, F., Extier, T., and Blunier, T.: Exceptionally high
biosphere productivity at the beginning of Marine Isotopic Stage, Nat. Commun., 11, 2112, https://doi.org/10.1038/s41467-020-15739-2, 2020.
Cao, X. and Liu, Y.: Equilibrium mass-dependent fractionation relationships
for triple oxygen isotopes, Geochim. Cosmochim. Ac., 75, 7435–7445,
https://doi.org/10.1016/j.gca.2011.09.048, 2011.
Cernusak, L. A., Barbour, M. M., Arndt, S. K., Cheesman, A. W., English, N.
B., Feild, T. S., Helliker, B. R., Holloway-Phillips, M. M., Holtum, J. A.
M., Kahmen, A., McInerney, F. A., Munksgaard, N. C., Simonin, K. A., Song,
X., Stuart-Williams, H., West, J. B., and Farquhar, G. D.: Stable isotopes
in leaf water of terrestrial plants, Plant Cell Environ., 39, 1087–1102, https://doi.org/10.1111/pce.12703, 2016.
Chapligin, B., Meyer, H., Friedrichsen, H., Marent, A., Sohns, E., and
Hubberten, H.-W.: A high-performance, safer and semi-automated approach for
the delta18O analysis of diatom silica and new methods for removing
exchangeable oxygen, Rapid Commun. Mass Sp., 24, 2655–2664,
https://doi.org/10.1002/rcm.4689, 2010.
Chapligin, B., Leng, M. J., Webb, E., Alexandre, A., Dodd, J. P., Ijiri, A.,
Lücke, A., Shemesh, A., Abelmann, A., Herzschuh, U., Longstaffe, F. J.,
Meyer, H., Moschen, R., Okazaki, Y., Rees, N. H., Sharp, Z. D., Sloane, H.
J., Sonzogni, C., Swann, G. E. A., Sylvestre, F., Tyler, J. J., and Yam, R.:
Inter-laboratory comparison of oxygen isotope compositions from biogenic
silica, Geochim. Cosmochim. Ac., 75, 7242–7256, 2011.
Chung, E.-S., Soden, B., Sohn, B. J., and Shi, L.: Upper-tropospheric
moistening in response to anthropogenic warming, P. Natl. Acad. Sci. USA, 111, 11636–11641, https://doi.org/10.1073/pnas.1409659111, 2014.
Corbineau, R., Reyerson, P. E., Alexandre, A., and Santos, G. M.: Towards
producing pure phytolith concentrates from plants that are suitable for
carbon isotopic analysis, Rev. Palaeobot. Palyno., 197, 179–185, https://doi.org/10.1016/j.revpalbo.2013.06.001, 2013.
Craig, H. and Gordon, L. I.: Deuterium and Oxygen 18 Variations in the Ocean
and the Marine Atmosphere, Consiglio nazionale delle richerche, Laboratorio
de geologia nucleare, Pisa, 128 pp., 1965.
Crespin, J., Alexandre, A., Sylvestre, F., Sonzogni, C., Paillès, C.,
and Garreta, V.: IR laser extraction technique applied to oxygen isotope
analysis of small biogenic silica samples, Anal. Chem., 80, 2372–2378,
https://doi.org/10.1021/ac071475c, 2008.
Dessler, A. E. and Davis, S. M.: Trends in tropospheric humidity from
reanalysis systems, J. Geophys. Res., 115, D19127,
https://doi.org/10.1029/2010JD014192, 2010.
Dodd, J. P. and Sharp, Z. D.: A laser fluorination method for oxygen isotope
analysis of biogenic silica and a new oxygen isotope calibration of modern
diatoms in freshwater environments, Geochim. Cosmochim. Ac., 74,
1381–1390, https://doi.org/10.1016/j.gca.2009.11.023, 2010.
Evans, N. P., Bauska, T. K., Gázquez-Sánchez, F., Brenner, M.,
Curtis, J. H., and Hodell, D. A.: Quantification of drought during the
collapse of the classic Maya civilization, Science, 361, 498–501,
https://doi.org/10.1126/science.aas9871, 2018.
Extier, T., Landais, A., Bréant, C., Prié, F., Bazin, L., Dreyfus,
G., Roche, D. M., and Leuenberger, M.: On the use of δ18Oatm for ice core dating, Quaternary Sci. Rev., 185, 244–257,
https://doi.org/10.1016/j.quascirev.2018.02.008, 2018.
Farquhar, G. D. and Gan, K. S.: On the progressive enrichment of the oxygen
isotopic composition of water along a leaf, Plant Cell Environ., 26,
801–819, 2003.
Farquhar, G. D. and Lloyd, J.: 5 – Carbon and Oxygen Isotope Effects in the
Exchange of Carbon Dioxide between Terrestrial Plants and the Atmosphere,
in: Stable Isotopes and Plant Carbon-water Relations, edited by: Ehleringer,
J. R., Hall, A. E., and Farquhar, G. D., Academic Press, San Diego, 47–70,
https://doi.org/10.1016/B978-0-08-091801-3.50011-8, 1993.
Farquhar, G. D., Cernusak, L. A., and Barnes, B.: Heavy Water Fractionation
during Transpiration, Plant Physiol., 143, 11–18, https://doi.org/10.1104/pp.106.093278, 2007.
Galle, S., Grippa, M., Peugeot, C., Moussa, I. B., Cappelaere, B., Demarty,
J., Mougin, E., Panthou, G., Adjomayi, P., Agbossou, E. K., Ba, A., Boucher,
M., Cohard, J.-M., Descloitres, M., Descroix, L., Diawara, M., Dossou, M.,
Favreau, G., Gangneron, F., Gosset, M., Hector, B., Hiernaux, P., Issoufou,
B.-A., Kergoat, L., Lawin, E., Lebel, T., Legchenko, A., Abdou, M. M.,
Malam-Issa, O., Mamadou, O., Nazoumou, Y., Pellarin, T., Quantin, G.,
Sambou, B., Seghieri, J., Séguis, L., Vandervaere, J.-P., Vischel, T.,
Vouillamoz, J.-M., Zannou, A., Afouda, S., Alhassane, A., Arjounin, M.,
Barral, H., Biron, R., Cazenave, F., Chaffard, V., Chazarin, J.-P., Guyard,
H., Koné, A., Mainassara, I., Mamane, A., Oi, M., Ouani, T., Soumaguel,
N., Wubda, M., Ago, E. E., Alle, I. C., Allies, A., Arpin-Pont, F., Awessou,
B., Cassé, C., Charvet, G., Dardel, C., Depeyre, A., Diallo, F. B., Do,
T., Fatras, C., Frappart, F., Gal, L., Gascon, T., Gibon, F., Guiro, I.,
Ingatan, A., Kempf, J., Kotchoni, D. O. V., Lawson, F. M. A., Leauthaud, C.,
Louvet, S., Mason, E., Nguyen, C. C., Perrimond, B., Pierre, C., Richard,
A., Robert, E., Román-Cascón, C., Velluet, C., and Wilcox, C.:
AMMA-CATCH, a Critical Zone Observatory in West Africa Monitoring a Region
in Transition, Vadose Zone J., 17, 180062, https://doi.org/10.2136/vzj2018.03.0062, 2018.
Gan, K. S., Wong, S. C., Yong, J. W. H., and Farquhar, G. D.: Evaluation of
models of leaf water 18O enrichment using measurements of spatial patterns of vein xylem water, leaf water and dry matter in maize leaves, Plant Cell Environ., 26, 1479–1495, https://doi.org/10.1046/j.1365-3040.2003.01070.x, 2003.
Garcin, Y., Schwab, V. F., Gleixner, G., Kahmen, A., Todou, G.,
Séné, O., Onana, J.-M., Achoundong, G., and Sachse, D.: Hydrogen
isotope ratios of lacustrine sedimentary n-alkanes as proxies of tropical
African hydrology: Insights from a calibration transect across Cameroon,
Geochim. Cosmochim. Ac., 79, 106–126, https://doi.org/10.1016/j.gca.2011.11.039, 2012.
Gázquez, F., Morellón, M., Bauska, T., Herwartz, D., Surma, J.,
Moreno, A., Staubwasser, M., Valero-Garcés, B., Delgado-Huertas, A., and
Hodell, D. A.: Triple oxygen and hydrogen isotopes of gypsum hydration water
for quantitative paleo-humidity reconstruction, Earth Planet. Sc. Lett., 481, 177–188, https://doi.org/10.1016/j.epsl.2017.10.020, 2018.
Gibson, D. J. and Newman, J. A.: Festuca arundinacea Schreber (F. elatior L. ssp. arundinacea (Schreber) Hackel), J. Ecol., 89, 304–324, https://doi.org/10.1046/j.1365-2745.2001.00561.x, 2001.
Govin, A., Varma, V., and Prange, M.: Astronomically forced variations in
western African rainfall (21∘ N–20∘ S) during the Last
Interglacial period, Geophys. Res. Lett., 41, 2117–2125, https://doi.org/10.1002/2013GL058999, 2014.
Haimson, M. and Knauth, L. P.: Stepwise fluorination – a useful approach for
the isotopic analysis of hydrous minerals, Geochim. Cosmochim. Ac., 47, 1589–1595, https://doi.org/10.1016/0016-7037(83)90185-0, 1983.
Held, I. M. and Soden, B. J.: Water Vapor Feedback and Global Warming, Annu. Rev. Energ. Env., 25, 441–475, https://doi.org/10.1146/annurev.energy.25.1.441, 2000.
Herwartz, D.: Triple Oxygen Isotope Variations in Earth's Crust, Rev. Mineral. Geochem., 86, 291–322, https://doi.org/10.2138/rmg.2021.86.09, 2021.
Herwartz, D., Surma, J., Voigt, C., Assonov, S., and Staubwasser, M.: Triple
oxygen isotope systematics of structurally bonded water in gypsum, Geochim. Cosmochim. Ac., 209, 254–266, https://doi.org/10.1016/j.gca.2017.04.026, 2017.
Hirl, R. T., Schnyder, H., Ostler, U., Schäufele, R., Schleip, I., Vetter, S. H., Auerswald, K., Baca Cabrera, J. C., Wingate, L., Barbour, M. M., and Ogée, J.: The 18O ecohydrology of a grassland ecosystem – predictions and observations, Hydrol. Earth Syst. Sci., 23, 2581–2600, https://doi.org/10.5194/hess-23-2581-2019, 2019.
Hofmann, M. E. G., Horvath, B., Schneider, L., Peters, W.,
Schützenmeister, K., and Pack, A.: Atmospheric measurements of Δ17O in CO2 in Göttingen, Germany reveal a seasonal cycle driven by biospheric uptake, Geochim. Cosmochim. Ac., 199, 143–163, https://doi.org/10.1016/j.gca.2016.11.019, 2017.
IPCC: Climate Change 2007: Synthesis Report. Contribution of Working Groups I, II and III to the Fourth Assessment Report of the Intergovernmental Panel on Climate Change, edited by: Core Writing Team, Pachauri, R. K, and Reisinger, A., IPCC, Geneva, Switzerland, 104 pp., 2007.
Koren, G., Schneider, L., van der Velde, I. R., van Schaik, E., Gromov, S.
S., Adnew, G. A., Mrozek Martino, D. J., Hofmann, M. E. G., Liang, M.-C.,
Mahata, S., Bergamaschi, P., van der Laan-Luijkx, I. T., Krol, M. C.,
Röckmann, T., and Peters, W.: Global 3-D Simulations of the Triple
Oxygen Isotope Signature Δ17O in Atmospheric CO2, J.
Geophys. Res.-Atmos., 124, 8808–8836, https://doi.org/10.1029/2019JD030387, 2019.
Kumar, S., Soukup, M., and Elbaum, R.: Silicification in Grasses: Variation
between Different Cell Types, Front. Plant Sci., 8, 438,
https://doi.org/10.3389/fpls.2017.00438, 2017.
Labeyrie, L. and Juillet, A.: Oxygen isotopic exchangeability of diatom vave
silica; interpretations and consequences for paleoclimatic studies, Geochim.
Cosmochim. Acta, 46, 967–975, 1982.
Landais, A., Barkan, E., Yakir, D., and Luz, B.: The triple isotopic composition of oxygen in leaf water, Geochim. Cosmochim. Ac., 70, 4105–4115, https://doi.org/10.1016/j.gca.2006.06.1545, 2006.
Landais, A., Barkan, E., and Luz, B.: Record of δ18O and 17O-excess in ice from Vostok Antarctica during the last 150,000 years, Geophys. Res. Lett., 35, L02709, https://doi.org/10.1029/2007GL032096, 2008.
Landais, A., Risi, C., Bony, S., Vimeux, F., Descroix, L., Falourd, S., and
Bouygues, A.: Combined measurements of 17Oexcess and d-excess in African monsoon precipitation: Implications for evaluating convective
parameterizations, Earth Planet. Sc. Lett., 298, 104–112,
https://doi.org/10.1016/j.epsl.2010.07.033, 2010.
Leaney, F. W., Osmond, C. B., Allison, G. B., and Ziegler, H.:
Hydrogen-isotope composition of leaf water in C3 and C4 plants: its
relationship to the hydrogen-isotope composition of dry matter, Planta, 164,
215–220, https://doi.org/10.1007/BF00396084, 1985.
Leclerc, A. J. and Labeyrie, L.: Temperature dependence of the oxygen
isotopic fractionation between diatom silica and water, Earth Planet. Sc. Lett., 84, 69–74, https://doi.org/10.1016/0012-821X(87)90177-4, 1987.
Li, S., Levin, N. E., and Chesson, L. A.: Continental scale variation in
17O-excess of meteoric waters in the United States, Geochim. Cosmochim. Ac., 164, 110–126, https://doi.org/10.1016/j.gca.2015.04.047, 2015.
Li, S., Levin, N. E., Soderberg, K., Dennis, K. J., and Caylor, K. K.:
Triple oxygen isotope composition of leaf waters in Mpala, central Kenya,
Earth Planet. Sc. Lett., 468, 38–50, https://doi.org/10.1016/j.epsl.2017.02.015, 2017.
Lin, Y., Clayton, R. N., Huang, L., Nakamura, N., and Lyons, J. R.: Oxygen
isotope anomaly observed in water vapor from Alert, Canada and the
implication for the stratosphere, P. Natl. Acad. Sci. USA, 110, 15608–15613,
https://doi.org/10.1073/pnas.1313014110, 2013.
Luz, B. and Barkan, E.: Variations of
Luz, B., Barkan, E., Bender, M. L., Thiemens, M. H., and Boering, K. A.:
Triple-isotope composition of atmospheric oxygen as a tracer of biosphere
productivity, Nature, 400, 547–550, https://doi.org/10.1038/22987, 1999.
Majoube, M.: Fractionnement en oxygène 18 et en deutérium entre
l'eau et sa vapeur, J. Chim. Phys., 68, 1423–1436,
https://doi.org/10.1051/jcp/1971681423, 1971 (in French).
Rach, O., Kahmen, A., Brauer, A., and Sachse, D.: A dual-biomarker approach for quantification of changes in relative humidity from sedimentary lipid
Ranjan, S., Ramanathan, A. L., Keesari, T., Singh, V. B., Kumar, N., Pandey, M., and Leuenberger, M. C.: Triple Water Vapour–Isotopologues Record from Chhota Shigri, Western Himalaya, India: A Unified Interpretation based on δ17O, δ18O, δD and Comparison to Meteorological Parameters, Front. Earth Sci., 8, 599632, https://doi.org/10.3389/feart.2020.599632, 2021.
Sachse, D., Billault, I., Bowen, G. J., Chikaraishi, Y., Dawson, T. E.,
Feakins, S. J., Freeman, K. H., Magill, C. R., McInerney, F. A., Van der
Meer, M. T., Polissar, P., Robins, R. J., Sachs, J. P., Schmidt, H.-L., Sessions, A. L., White, J. W. C., West, J. B., and Kahmen, A.: Molecular paleohydrology: interpreting the hydrogen-isotopic composition of lipid biomarkers from photosynthesizing organisms, Annu. Rev. Earth Pl. Sc., 40, 221–249, 2012.
Schoenemann, S. W., Schauer, A. J., and Steig, E. J.: Measurement of SLAP2 and GISP δ17O and proposed VSMOW-SLAP normalization for δ17O and 17Oexcess, Rapid Commun. Mass Sp., 27, 582–590, https://doi.org/10.1002/rcm.6486, 2013.
Schwab, V. F., Garcin, Y., Sachse, D., Todou, G., Séné, O., Onana,
J.-M., Achoundong, G., and Gleixner, G.: Effect of aridity on δ13C and δD values of C3 plant- and C4 graminoid-derived leaf wax lipids from soils along an environmental gradient in Cameroon (Western Central Africa), Org. Geochem., 78, 99–109,
https://doi.org/10.1016/j.orggeochem.2014.09.007, 2015.
Sharp, Z. D. and Wostbrock, J. A. G.: Standardization for the Triple Oxygen
Isotope System: Waters, Silicates, Carbonates, Air, and Sulfates, Rev.
Mineral. Geochem., 86, 179–196, https://doi.org/10.2138/rmg.2021.86.05, 2021.
Sharp, Z. D., Gibbons, J. A., Maltsev, O., Atudorei, V., Pack, A., Sengupta,
S., Shock, E. L., and Knauth, L. P.: A calibration of the triple oxygen
isotope fractionation in the SiO2–H2O system and applications to natural
samples, Geochim. Cosmochim. Ac., 186, 105–119, https://doi.org/10.1016/j.gca.2016.04.047, 2016.
Sharp, Z. D., Wostbrock, J. A. G., and Pack, A.: Mass-dependent triple
oxygen isotope variations in terrestrial materials, Geochemical Perspectives Letters, 7, 27–31, https://doi.org/10.7185/geochemlet.1815, 2018.
Stevens, B., Brogniez, H., Kiemle, C., Lacour, J.-L., Crevoisier, C., and
Kiliani, J.: Structure and dynamical influence of water vapor in the lower
tropical troposphere, Surv. Geophys., 38, 1371–1397, https://doi.org/10.1007/s10712-017-9420-8, 2017.
Suavet, C., Alexandre, A., Franchi, I. A., Gattacceca, J., Sonzogni, C.,
Greenwood, R. C., Folco, L., and Rochette, P.: Solving the parent bodies of
micrometeorites with high-precision oxygen isotope ratios, Earth Planet. Sc. Lett., 44, A197–A197, 2009.
Suavet, C., Alexandre, A., Franchi, I. A., Gattacceca, J., Sonzogni, C.,
Greenwood, R. C., Folco, L., and Rochette, P.: Identification of the parent
bodies of micrometeorites with high-precision oxygen isotope ratios, Earth Planet. Sc. Lett., 293, 313–320, https://doi.org/10.1016/j.epsl.2010.02.046, 2010.
Surma, J., Assonov, S., and Staubwasser, M.: Triple Oxygen Isotope
Systematics in the Hydrologic Cycle, Rev. Mineral. Geochem., 86, 401–428, https://doi.org/10.2138/rmg.2021.86.12, 2021.
Tian, C., Wang, L., Tian, F., Zhao, S., and Jiao, W.: Spatial and temporal
variations of tap water 17O-excess in China, Geochim. Cosmochim. Ac., 260, 1–14, https://doi.org/10.1016/j.gca.2019.06.015, 2019.
Tuthorn, M., Zech, R., Ruppenthal, M., Oelmann, Y., Kahmen, A., del Valle, H. F., Eglinton, T., Rozanski, K., and Zech, M.: Coupling δ2H and δ18O biomarker results yields information on relative humidity and isotopic composition of precipitation – a climate transect validation study, Biogeosciences, 12, 3913–3924, https://doi.org/10.5194/bg-12-3913-2015, 2015.
Uechi, Y. and Uemura, R.: Dominant influence of the humidity in the moisture
source region on the 17O-excess in precipitation on a subtropical island, Earth Planet. Sc. Lett., 513, 20–28,
https://doi.org/10.1016/j.epsl.2019.02.012, 2019.
Uemura, R., Barkan, E., Abe, O., and Luz, B.: Triple isotope composition of
oxygen in atmospheric water vapor, Geophys. Res. Lett., 37, L04402,
https://doi.org/10.1029/2009GL041960, 2010.
Vallet-Coulomb, C., Couapel, M., and Sonzogni, C.: Improving memory effect correction to achieve high-precision analysis of δ17O, δ18O, δ2H, 17O-excess and d-excess in water using cavity ring-down laser spectroscopy, Rapid Commun. Mass Sp., 35, e9108, https://doi.org/10.1002/rcm.9108, 2021.
Valley, J. W., Kitchen, N., Kohn, M. J., Niendorf, C. R., and Spicuzza, M.
J.: UWG-2, a garnet standard for oxygen isotope ratios: Strategies for high
precision and accuracy with laser heating, Geochim. Cosmochim. Ac., 59, 5223–5231, 1995.
Webb, E. A. and Longstaffe, F. J.: The relationship between phytolith- and
plant-water δ18O values in grasses, Geochim. Cosmochim. Ac., 67, 1437–1449, https://doi.org/10.1016/s0016-7037(02)01300-5, 2003.
Webb, E. A. and Longstaffe, F. J.: Identifying the δ18O signature of precipitation in grass cellulose and phytoliths: Refining the
paleoclimate model, Geochim. Cosmochim. Ac., 70, 2417–2426,
https://doi.org/10.1016/j.gca.2006.02.024, 2006.
Welp, L. R., Lee, X., Kim, K., Griffis, T. J., Billmark, K. A., and Baker,
J. M.: δ18O of water vapour, evapotranspiration and the sites of leaf water evaporation in a soybean canopy, Plant Cell Environ., 31, 1214–1228, https://doi.org/10.1111/j.1365-3040.2008.01826.x, 2008.
Weng, Y., Touzeau, A., and Sodemann, H.: Correcting the impact of the isotope composition on the mixing ratio dependency of water vapour isotope measurements with cavity ring-down spectrometers, Atmos. Meas. Tech., 13, 3167–3190, https://doi.org/10.5194/amt-13-3167-2020, 2020.
Wostbrock, J. A. G., Cano, E. J., and Sharp, Z. D.: An internally consistent
triple oxygen isotope calibration of standards for silicates, carbonates and
air relative to VSMOW2 and SLAP2, Chem. Geol., 533, 119432,
https://doi.org/10.1016/j.chemgeo.2019.119432, 2020.
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Short summary
Continental atmospheric humidity is a key climate parameter poorly captured by global climate models. Model–data comparison approaches that are applicable beyond the instrumental period are essential to progress on this issue but face a lack of quantitative relative humidity proxies. Here, we calibrate the triple oxygen isotope composition of phytoliths as a new quantitative proxy of continental relative humidity suitable for past climate reconstructions.
Continental atmospheric humidity is a key climate parameter poorly captured by global climate...
