Articles | Volume 20, issue 9
https://doi.org/10.5194/cp-20-2031-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/cp-20-2031-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
16 Sep 2024
Research article |
| 16 Sep 2024
| 16 Sep 2024
New estimates of sulfate diffusion rates in the EPICA Dome C ice core
Department of Earth Sciences, University of Cambridge, Cambridge, UK
Yvan Bollet-Quivogne
Department of Earth Sciences, University of Cambridge, Cambridge, UK
Piers Barnes
Department of Physics, Imperial College London, London, UK
Mirko Severi
Chemistry Department, University of Florence, Sesto F.no (FI) 50019, Italy
Eric W. Wolff
Department of Earth Sciences, University of Cambridge, Cambridge, UK
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Helene Hoffmann, Jason Day, Rachael H. Rhodes, Mackenzie Grieman, Jack Humby, Isobel Rowell, Christoph Nehrbass-Ahles, Robert Mulvaney, Sally Gibson, and Eric Wolff
The Cryosphere, 18, 4993–5013, https://doi.org/10.5194/tc-18-4993-2024, https://doi.org/10.5194/tc-18-4993-2024, 2024
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Ice cores are archives of past atmospheric conditions. In deep and old ice, the layers containing this information get thinned to the millimetre scale or below. We installed a setup for high-resolution (182 μm) chemical impurity measurements in ice cores using the laser ablation technique at the University of Cambridge. In a first application to the Skytrain ice core from Antarctica, we discuss the potential to detect fine-layered structures in ice up to an age of 26 000 years.
Piers Larkman, Rachael H. Rhodes, Nicolas Stoll, Carlo Barbante, and Pascal Bohleber
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Impurities in ice cores can be preferentially located at the boundaries between crystals of ice, impacting the interpretation of high-resolution data collected from ice core samples. This work finds that one dimensional signals can be significantly effected by this association, meaning experiments collecting data at high resolution must be carefully designed. Accounting for this effect is important for interpreting ice core data, especially for deep ice samples.
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Marine sediment and ice core records suggest a warmer Southern Ocean and Antarctica at the early last interglacial, ~127 thousand years ago. However, when only forced by orbital parameters and greenhouse gas concentrations during that period, state-of-the-art climate models do not reproduce the magnitude of warming. Here we show that much of the warming at southern mid-to-high latitudes can be reproduced by a UK climate model HadCM3 with a 3000-year freshwater forcing over the North Atlantic.
Xavier Faïn, Sophie Szopa, Vaishali Naïk, Patricia Martinerie, David M. Etheridge, Rachael H. Rhodes, Cathy M. Trudinger, Vasilii V. Petrenko, Kévin Fourteau, and Phillip Place
EGUsphere, https://doi.org/10.5194/egusphere-2024-653, https://doi.org/10.5194/egusphere-2024-653, 2024
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Carbon monoxide (CO) plays a crucial role in the atmosphere's oxidizing capacity. In this study, we analyse how historical (1850–2014) [CO] outputs from state-of-the-art global chemistry-climate models over Greenland and Antarctica are able to capture both absolute values and trends recorded in multi-site ice archives. A disparity in [CO] growth rates emerges in the Northern Hemisphere between models and observations from 1920–1975 CE, possibly linked to uncertainties in CO emission factors.
Qinggang Gao, Louise C. Sime, Alison J. McLaren, Thomas J. Bracegirdle, Emilie Capron, Rachael H. Rhodes, Hans Christian Steen-Larsen, Xiaoxu Shi, and Martin Werner
The Cryosphere, 18, 683–703, https://doi.org/10.5194/tc-18-683-2024, https://doi.org/10.5194/tc-18-683-2024, 2024
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Antarctic precipitation is a crucial component of the climate system. Its spatio-temporal variability impacts sea level changes and the interpretation of water isotope measurements in ice cores. To better understand its climatic drivers, we developed water tracers in an atmospheric model to identify moisture source conditions from which precipitation originates. We find that mid-latitude surface winds exert an important control on moisture availability for Antarctic precipitation.
Xavier Faïn, David M. Etheridge, Kévin Fourteau, Patricia Martinerie, Cathy M. Trudinger, Rachael H. Rhodes, Nathan J. Chellman, Ray L. Langenfelds, Joseph R. McConnell, Mark A. J. Curran, Edward J. Brook, Thomas Blunier, Grégory Teste, Roberto Grilli, Anthony Lemoine, William T. Sturges, Boris Vannière, Johannes Freitag, and Jérôme Chappellaz
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We report on a 3000-year record of carbon monoxide (CO) levels in the Southern Hemisphere's high latitudes by combining ice core and firn air measurements with modern direct atmospheric samples. Antarctica [CO] remained stable (–835 to 1500 CE), decreased during the Little Ice Age, and peaked around 1985 CE. Such evolution reflects stable biomass burning CO emissions before industrialization, followed by growth from CO anthropogenic sources, which decline after 1985 due to improved combustion.
Robert Mulvaney, Eric W. Wolff, Mackenzie M. Grieman, Helene H. Hoffmann, Jack D. Humby, Christoph Nehrbass-Ahles, Rachael H. Rhodes, Isobel F. Rowell, Frédéric Parrenin, Loïc Schmidely, Hubertus Fischer, Thomas F. Stocker, Marcus Christl, Raimund Muscheler, Amaelle Landais, and Frédéric Prié
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We present an age scale for a new ice core drilled at Skytrain Ice Rise, an ice rise facing the Ronne Ice Shelf in Antarctica. Various measurements in the ice and air phases are used to match the ice core to other Antarctic cores that have already been dated, and a new age scale is constructed. The 651 m ice core includes ice that is confidently dated to 117 000–126 000 years ago, in the last interglacial. Older ice is found deeper down, but there are flow disturbances in the deeper ice.
François Burgay, Rafael Pedro Fernández, Delia Segato, Clara Turetta, Christopher S. Blaszczak-Boxe, Rachael H. Rhodes, Claudio Scarchilli, Virginia Ciardini, Carlo Barbante, Alfonso Saiz-Lopez, and Andrea Spolaor
The Cryosphere, 17, 391–405, https://doi.org/10.5194/tc-17-391-2023, https://doi.org/10.5194/tc-17-391-2023, 2023
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The paper presents the first ice-core record of bromine (Br) in the Antarctic plateau. By the observation of the ice core and the application of atmospheric chemical models, we investigate the behaviour of bromine after its deposition into the snowpack, with interest in the effect of UV radiation change connected to the formation of the ozone hole, the role of volcanic deposition, and the possible use of Br to reconstruct past sea ice changes from ice core collect in the inner Antarctic plateau.
Xavier Crosta, Karen E. Kohfeld, Helen C. Bostock, Matthew Chadwick, Alice Du Vivier, Oliver Esper, Johan Etourneau, Jacob Jones, Amy Leventer, Juliane Müller, Rachael H. Rhodes, Claire S. Allen, Pooja Ghadi, Nele Lamping, Carina B. Lange, Kelly-Anne Lawler, David Lund, Alice Marzocchi, Katrin J. Meissner, Laurie Menviel, Abhilash Nair, Molly Patterson, Jennifer Pike, Joseph G. Prebble, Christina Riesselman, Henrik Sadatzki, Louise C. Sime, Sunil K. Shukla, Lena Thöle, Maria-Elena Vorrath, Wenshen Xiao, and Jiao Yang
Clim. Past, 18, 1729–1756, https://doi.org/10.5194/cp-18-1729-2022, https://doi.org/10.5194/cp-18-1729-2022, 2022
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Despite its importance in the global climate, our knowledge of Antarctic sea-ice changes throughout the last glacial–interglacial cycle is extremely limited. As part of the Cycles of Sea Ice Dynamics in the Earth system (C-SIDE) Working Group, we review marine- and ice-core-based sea-ice proxies to provide insights into their applicability and limitations. By compiling published records, we provide information on Antarctic sea-ice dynamics over the past 130 000 years.
Xavier Faïn, Rachael H. Rhodes, Philip Place, Vasilii V. Petrenko, Kévin Fourteau, Nathan Chellman, Edward Crosier, Joseph R. McConnell, Edward J. Brook, Thomas Blunier, Michel Legrand, and Jérôme Chappellaz
Clim. Past, 18, 631–647, https://doi.org/10.5194/cp-18-631-2022, https://doi.org/10.5194/cp-18-631-2022, 2022
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Carbon monoxide (CO) is a regulated pollutant and one of the key components determining the oxidizing capacity of the atmosphere. In this study, we analyzed five ice cores from Greenland at high resolution for CO concentrations by coupling laser spectrometry with continuous melting. By combining these new datasets, we produced an upper-bound estimate of past atmospheric CO abundance since preindustrial times for the Northern Hemisphere high latitudes, covering the period from 1700 to 1957 CE.
James A. Menking, Edward J. Brook, Sarah A. Shackleton, Jeffrey P. Severinghaus, Michael N. Dyonisius, Vasilii Petrenko, Joseph R. McConnell, Rachael H. Rhodes, Thomas K. Bauska, Daniel Baggenstos, Shaun Marcott, and Stephen Barker
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During the last glacial–interglacial climate transition (120 000 to 10 000 years before present), Greenland climate and midlatitude North Atlantic climate and water cycle vary in phase over the succession of millennial events. We identify here one notable exception to this behavior with a decoupling unambiguously identified through a combination of water isotopic tracers measured in a Greenland ice core. The midlatitude moisture source becomes warmer and wetter at 16 200 years before present.
Rachael H. Rhodes, Xin Yang, Eric W. Wolff, Joseph R. McConnell, and Markus M. Frey
Atmos. Chem. Phys., 17, 9417–9433, https://doi.org/10.5194/acp-17-9417-2017, https://doi.org/10.5194/acp-17-9417-2017, 2017
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Sea salt aerosol comes from the open ocean or the sea ice surface. In the polar regions, this opens up the possibility of reconstructing sea ice history using sea salt recorded in ice cores. We use a chemical transport model to demonstrate that the sea ice source of aerosol is important in the Arctic. For the first time, we simulate realistic Greenland ice core sea salt in a process-based model. The importance of the sea ice source increases from south to north across the Greenland ice sheet.
Olivia J. Maselli, Nathan J. Chellman, Mackenzie Grieman, Lawrence Layman, Joseph R. McConnell, Daniel Pasteris, Rachael H. Rhodes, Eric Saltzman, and Michael Sigl
Clim. Past, 13, 39–59, https://doi.org/10.5194/cp-13-39-2017, https://doi.org/10.5194/cp-13-39-2017, 2017
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We analysed two Greenland ice cores for methanesulfonate (MSA) and bromine (Br) and concluded that both species are suitable proxies for local sea ice conditions. Interpretation of the records reveals that there have been sharp declines in sea ice in these areas in the past 250 years. However, at both sites the Br record deviates from MSA during the industrial period, raising questions about the value of Br as a sea ice proxy during recent periods of high, industrial, atmospheric acid pollution.
Rachael H. Rhodes, Xavier Faïn, Edward J. Brook, Joseph R. McConnell, Olivia J. Maselli, Michael Sigl, Jon Edwards, Christo Buizert, Thomas Blunier, Jérôme Chappellaz, and Johannes Freitag
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Local artifacts in ice core methane data are superimposed on consistent records of past atmospheric variability. These artifacts are not related to past atmospheric history and care should be taken to avoid interpreting them as such. By investigating five polar ice cores from sites with different conditions, we relate isolated methane spikes to melt layers and decimetre-scale variations as "trapping signal" associated with a difference in timing of air bubble closure in adjacent firn layers.
Michael Sigl, Tyler J. Fudge, Mai Winstrup, Jihong Cole-Dai, David Ferris, Joseph R. McConnell, Ken C. Taylor, Kees C. Welten, Thomas E. Woodruff, Florian Adolphi, Marion Bisiaux, Edward J. Brook, Christo Buizert, Marc W. Caffee, Nelia W. Dunbar, Ross Edwards, Lei Geng, Nels Iverson, Bess Koffman, Lawrence Layman, Olivia J. Maselli, Kenneth McGwire, Raimund Muscheler, Kunihiko Nishiizumi, Daniel R. Pasteris, Rachael H. Rhodes, and Todd A. Sowers
Clim. Past, 12, 769–786, https://doi.org/10.5194/cp-12-769-2016, https://doi.org/10.5194/cp-12-769-2016, 2016
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Here we present a chronology (WD2014) for the upper part (0–2850 m; 31.2 ka BP) of the West Antarctic Ice Sheet (WAIS) Divide ice core, which is based on layer counting of distinctive annual cycles preserved in the elemental, chemical and electrical conductivity records. We validated the chronology by comparing it to independent high-accuracy, absolutely dated chronologies. Given its demonstrated high accuracy, WD2014 can become a reference chronology for the Southern Hemisphere.
C. Buizert, K. M. Cuffey, J. P. Severinghaus, D. Baggenstos, T. J. Fudge, E. J. Steig, B. R. Markle, M. Winstrup, R. H. Rhodes, E. J. Brook, T. A. Sowers, G. D. Clow, H. Cheng, R. L. Edwards, M. Sigl, J. R. McConnell, and K. C. Taylor
Clim. Past, 11, 153–173, https://doi.org/10.5194/cp-11-153-2015, https://doi.org/10.5194/cp-11-153-2015, 2015
X. Faïn, J. Chappellaz, R. H. Rhodes, C. Stowasser, T. Blunier, J. R. McConnell, E. J. Brook, S. Preunkert, M. Legrand, T. Debois, and D. Romanini
Clim. Past, 10, 987–1000, https://doi.org/10.5194/cp-10-987-2014, https://doi.org/10.5194/cp-10-987-2014, 2014
Helene Hoffmann, Jason Day, Rachael H. Rhodes, Mackenzie Grieman, Jack Humby, Isobel Rowell, Christoph Nehrbass-Ahles, Robert Mulvaney, Sally Gibson, and Eric Wolff
The Cryosphere, 18, 4993–5013, https://doi.org/10.5194/tc-18-4993-2024, https://doi.org/10.5194/tc-18-4993-2024, 2024
Short summary
Short summary
Ice cores are archives of past atmospheric conditions. In deep and old ice, the layers containing this information get thinned to the millimetre scale or below. We installed a setup for high-resolution (182 μm) chemical impurity measurements in ice cores using the laser ablation technique at the University of Cambridge. In a first application to the Skytrain ice core from Antarctica, we discuss the potential to detect fine-layered structures in ice up to an age of 26 000 years.
Piers Larkman, Rachael H. Rhodes, Nicolas Stoll, Carlo Barbante, and Pascal Bohleber
EGUsphere, https://doi.org/10.5194/egusphere-2024-1723, https://doi.org/10.5194/egusphere-2024-1723, 2024
Short summary
Short summary
Impurities in ice cores can be preferentially located at the boundaries between crystals of ice, impacting the interpretation of high-resolution data collected from ice core samples. This work finds that one dimensional signals can be significantly effected by this association, meaning experiments collecting data at high resolution must be carefully designed. Accounting for this effect is important for interpreting ice core data, especially for deep ice samples.
Dorothea Elisabeth Moser, Elizabeth R. Thomas, Christoph Nehrbass-Ahles, Anja Eichler, and Eric Wolff
The Cryosphere, 18, 2691–2718, https://doi.org/10.5194/tc-18-2691-2024, https://doi.org/10.5194/tc-18-2691-2024, 2024
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Increasing temperatures worldwide lead to more melting of glaciers and ice caps, even in the polar regions. This is why ice-core scientists need to prepare to analyse records affected by melting and refreezing. In this paper, we present a summary of how near-surface melt forms, what structural imprints it leaves in snow, how various signatures used for ice-core climate reconstruction are altered, and how we can still extract valuable insights from melt-affected ice cores.
Qinggang Gao, Emilie Capron, Louise C. Sime, Rachael H. Rhodes, Rahul Sivankutty, Xu Zhang, Bette L. Otto-Bliesner, and Martin Werner
EGUsphere, https://doi.org/10.5194/egusphere-2024-1261, https://doi.org/10.5194/egusphere-2024-1261, 2024
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Marine sediment and ice core records suggest a warmer Southern Ocean and Antarctica at the early last interglacial, ~127 thousand years ago. However, when only forced by orbital parameters and greenhouse gas concentrations during that period, state-of-the-art climate models do not reproduce the magnitude of warming. Here we show that much of the warming at southern mid-to-high latitudes can be reproduced by a UK climate model HadCM3 with a 3000-year freshwater forcing over the North Atlantic.
Xavier Faïn, Sophie Szopa, Vaishali Naïk, Patricia Martinerie, David M. Etheridge, Rachael H. Rhodes, Cathy M. Trudinger, Vasilii V. Petrenko, Kévin Fourteau, and Phillip Place
EGUsphere, https://doi.org/10.5194/egusphere-2024-653, https://doi.org/10.5194/egusphere-2024-653, 2024
Short summary
Short summary
Carbon monoxide (CO) plays a crucial role in the atmosphere's oxidizing capacity. In this study, we analyse how historical (1850–2014) [CO] outputs from state-of-the-art global chemistry-climate models over Greenland and Antarctica are able to capture both absolute values and trends recorded in multi-site ice archives. A disparity in [CO] growth rates emerges in the Northern Hemisphere between models and observations from 1920–1975 CE, possibly linked to uncertainties in CO emission factors.
Qinggang Gao, Louise C. Sime, Alison J. McLaren, Thomas J. Bracegirdle, Emilie Capron, Rachael H. Rhodes, Hans Christian Steen-Larsen, Xiaoxu Shi, and Martin Werner
The Cryosphere, 18, 683–703, https://doi.org/10.5194/tc-18-683-2024, https://doi.org/10.5194/tc-18-683-2024, 2024
Short summary
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Antarctic precipitation is a crucial component of the climate system. Its spatio-temporal variability impacts sea level changes and the interpretation of water isotope measurements in ice cores. To better understand its climatic drivers, we developed water tracers in an atmospheric model to identify moisture source conditions from which precipitation originates. We find that mid-latitude surface winds exert an important control on moisture availability for Antarctic precipitation.
Tyler J. Fudge, Raphael Sauvage, Linh Vu, Benjamin H. Hills, Mirko Severi, and Edwin D. Waddington
Clim. Past, 20, 297–312, https://doi.org/10.5194/cp-20-297-2024, https://doi.org/10.5194/cp-20-297-2024, 2024
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We use the oldest Antarctic ice core to estimate the rate of diffusion of sulfuric acid. Sulfuric acid is a marker of past volcanic activity and is critical in developing ice core timescales. The rate of diffusion is uncertain and is important to know, both for selecting future ice core locations and interpreting ice core records. We find the effective diffusivity of sulfate is 10 times smaller than previously estimated, indicating that the sulfuric acid signals will persist for longer.
Xavier Faïn, David M. Etheridge, Kévin Fourteau, Patricia Martinerie, Cathy M. Trudinger, Rachael H. Rhodes, Nathan J. Chellman, Ray L. Langenfelds, Joseph R. McConnell, Mark A. J. Curran, Edward J. Brook, Thomas Blunier, Grégory Teste, Roberto Grilli, Anthony Lemoine, William T. Sturges, Boris Vannière, Johannes Freitag, and Jérôme Chappellaz
Clim. Past, 19, 2287–2311, https://doi.org/10.5194/cp-19-2287-2023, https://doi.org/10.5194/cp-19-2287-2023, 2023
Short summary
Short summary
We report on a 3000-year record of carbon monoxide (CO) levels in the Southern Hemisphere's high latitudes by combining ice core and firn air measurements with modern direct atmospheric samples. Antarctica [CO] remained stable (–835 to 1500 CE), decreased during the Little Ice Age, and peaked around 1985 CE. Such evolution reflects stable biomass burning CO emissions before industrialization, followed by growth from CO anthropogenic sources, which decline after 1985 due to improved combustion.
Isobel Rowell, Carlos Martin, Robert Mulvaney, Helena Pryer, Dieter Tetzner, Emily Doyle, Hara Madhav Talasila, Jilu Li, and Eric Wolff
Clim. Past, 19, 1699–1714, https://doi.org/10.5194/cp-19-1699-2023, https://doi.org/10.5194/cp-19-1699-2023, 2023
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We present an age scale for a new type of ice core from a vulnerable region in West Antarctic, which is lacking in longer-term (greater than a few centuries) ice core records. The Sherman Island core extends to greater than 1 kyr. We provide modelling evidence for the potential of a 10 kyr long core. We show that this new type of ice core can be robustly dated and that climate records from this core will be a significant addition to existing regional climate records.
Elizabeth R. Thomas, Diana O. Vladimirova, Dieter R. Tetzner, B. Daniel Emanuelsson, Nathan Chellman, Daniel A. Dixon, Hugues Goosse, Mackenzie M. Grieman, Amy C. F. King, Michael Sigl, Danielle G. Udy, Tessa R. Vance, Dominic A. Winski, V. Holly L. Winton, Nancy A. N. Bertler, Akira Hori, Chavarukonam M. Laluraj, Joseph R. McConnell, Yuko Motizuki, Kazuya Takahashi, Hideaki Motoyama, Yoichi Nakai, Franciéle Schwanck, Jefferson Cardia Simões, Filipe Gaudie Ley Lindau, Mirko Severi, Rita Traversi, Sarah Wauthy, Cunde Xiao, Jiao Yang, Ellen Mosely-Thompson, Tamara V. Khodzher, Ludmila P. Golobokova, and Alexey A. Ekaykin
Earth Syst. Sci. Data, 15, 2517–2532, https://doi.org/10.5194/essd-15-2517-2023, https://doi.org/10.5194/essd-15-2517-2023, 2023
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The concentration of sodium and sulfate measured in Antarctic ice cores is related to changes in both sea ice and winds. Here we have compiled a database of sodium and sulfate records from 105 ice core sites in Antarctica. The records span all, or part, of the past 2000 years. The records will improve our understanding of how winds and sea ice have changed in the past and how they have influenced the climate of Antarctica over the past 2000 years.
Robert Mulvaney, Eric W. Wolff, Mackenzie M. Grieman, Helene H. Hoffmann, Jack D. Humby, Christoph Nehrbass-Ahles, Rachael H. Rhodes, Isobel F. Rowell, Frédéric Parrenin, Loïc Schmidely, Hubertus Fischer, Thomas F. Stocker, Marcus Christl, Raimund Muscheler, Amaelle Landais, and Frédéric Prié
Clim. Past, 19, 851–864, https://doi.org/10.5194/cp-19-851-2023, https://doi.org/10.5194/cp-19-851-2023, 2023
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We present an age scale for a new ice core drilled at Skytrain Ice Rise, an ice rise facing the Ronne Ice Shelf in Antarctica. Various measurements in the ice and air phases are used to match the ice core to other Antarctic cores that have already been dated, and a new age scale is constructed. The 651 m ice core includes ice that is confidently dated to 117 000–126 000 years ago, in the last interglacial. Older ice is found deeper down, but there are flow disturbances in the deeper ice.
Simone Ventisette, Samuele Baldini, Claudio Artoni, Silvia Becagli, Laura Caiazzo, Barbara Delmonte, Massimo Frezzotti, Raffaello Nardin, Joel Savarino, Mirko Severi, Andrea Spolaor, Barbara Stenni, and Rita Traversi
EGUsphere, https://doi.org/10.5194/egusphere-2023-393, https://doi.org/10.5194/egusphere-2023-393, 2023
Preprint archived
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The paper reports the spatial variability of concentration and fluxes of chemical impurities in superficial snow over unexplored area of the East Antarctic ice sheet. Pinatubo and Puyehue-Cordón Caulle volcanic eruptions in non-sea salt sulfate and dust snow pits record were used to achieve the accumulation rates. Deposition (wet, dry and uptake from snow surface) and post deposition processes are constrained. These knowledges are fundamental in Antarctic ice cores stratigraphies interpretation.
David A. Hodell, Simon J. Crowhurst, Lucas Lourens, Vasiliki Margari, John Nicolson, James E. Rolfe, Luke C. Skinner, Nicola C. Thomas, Polychronis C. Tzedakis, Maryline J. Mleneck-Vautravers, and Eric W. Wolff
Clim. Past, 19, 607–636, https://doi.org/10.5194/cp-19-607-2023, https://doi.org/10.5194/cp-19-607-2023, 2023
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We produced a 1.5-million-year-long history of climate change at International Ocean Discovery Program Site U1385 of the Iberian margin, a well-known location for rapidly accumulating sediments on the seafloor. Our record demonstrates that longer-term orbital changes in Earth's climate were persistently overprinted by abrupt millennial-to-centennial climate variability. The occurrence of abrupt climate change is modulated by the slower variations in Earth's orbit and climate background state.
François Burgay, Rafael Pedro Fernández, Delia Segato, Clara Turetta, Christopher S. Blaszczak-Boxe, Rachael H. Rhodes, Claudio Scarchilli, Virginia Ciardini, Carlo Barbante, Alfonso Saiz-Lopez, and Andrea Spolaor
The Cryosphere, 17, 391–405, https://doi.org/10.5194/tc-17-391-2023, https://doi.org/10.5194/tc-17-391-2023, 2023
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The paper presents the first ice-core record of bromine (Br) in the Antarctic plateau. By the observation of the ice core and the application of atmospheric chemical models, we investigate the behaviour of bromine after its deposition into the snowpack, with interest in the effect of UV radiation change connected to the formation of the ozone hole, the role of volcanic deposition, and the possible use of Br to reconstruct past sea ice changes from ice core collect in the inner Antarctic plateau.
Eric W. Wolff, Andrea Burke, Laura Crick, Emily A. Doyle, Helen M. Innes, Sue H. Mahony, James W. B. Rae, Mirko Severi, and R. Stephen J. Sparks
Clim. Past, 19, 23–33, https://doi.org/10.5194/cp-19-23-2023, https://doi.org/10.5194/cp-19-23-2023, 2023
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Large volcanic eruptions leave an imprint of a spike of sulfate deposition that can be measured in ice cores. Here we use a method that logs the number and size of large eruptions recorded in an Antarctic core in a consistent way through the last 200 000 years. The rate of recorded eruptions is variable but shows no trends. In particular, there is no increase in recorded eruptions during deglaciation periods. This is consistent with most recorded eruptions being from lower latitudes.
Takahito Mitsui, Polychronis C. Tzedakis, and Eric W. Wolff
Clim. Past, 18, 1983–1996, https://doi.org/10.5194/cp-18-1983-2022, https://doi.org/10.5194/cp-18-1983-2022, 2022
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We provide simple quantitative models for the interglacial and glacial intensities over the last 800 000 years. Our results suggest that the memory of previous climate states and the time course of the insolation in both hemispheres are crucial for understanding interglacial and glacial intensities. In our model, the shift in interglacial intensities at the Mid-Brunhes Event (~430 ka) is ultimately attributed to the amplitude modulation of obliquity.
Helene M. Hoffmann, Mackenzie M. Grieman, Amy C. F. King, Jenna A. Epifanio, Kaden Martin, Diana Vladimirova, Helena V. Pryer, Emily Doyle, Axel Schmidt, Jack D. Humby, Isobel F. Rowell, Christoph Nehrbass-Ahles, Elizabeth R. Thomas, Robert Mulvaney, and Eric W. Wolff
Clim. Past, 18, 1831–1847, https://doi.org/10.5194/cp-18-1831-2022, https://doi.org/10.5194/cp-18-1831-2022, 2022
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The WACSWAIN project (WArm Climate Stability of the West Antarctic ice sheet in the last INterglacial) investigates the fate of the West Antarctic Ice Sheet during the last warm period on Earth (115 000–130 000 years before present). Within this framework an ice core was recently drilled at Skytrain Ice Rise. In this study we present a stratigraphic chronology of that ice core based on absolute age markers and annual layer counting for the last 2000 years.
Fabio Giardi, Silvia Nava, Giulia Calzolai, Giulia Pazzi, Massimo Chiari, Andrea Faggi, Bianca Patrizia Andreini, Chiara Collaveri, Elena Franchi, Guido Nincheri, Alessandra Amore, Silvia Becagli, Mirko Severi, Rita Traversi, and Franco Lucarelli
Atmos. Chem. Phys., 22, 9987–10005, https://doi.org/10.5194/acp-22-9987-2022, https://doi.org/10.5194/acp-22-9987-2022, 2022
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The restriction measures adopted to contain the COVID-19 virus offered a unique opportunity to study urban particulate emissions in the near absence of traffic, which is one of the main emission sources in the urban environment. However, the drastic decrease in this source of particulate matter during the months of national lockdown did not lead to an equal decrease in the total particulate load. This is due to the inverse behavior shown by different sources, especially secondary sources.
Carlton Xavier, Metin Baykara, Robin Wollesen de Jonge, Barbara Altstädter, Petri Clusius, Ville Vakkari, Roseline Thakur, Lisa Beck, Silvia Becagli, Mirko Severi, Rita Traversi, Radovan Krejci, Peter Tunved, Mauro Mazzola, Birgit Wehner, Mikko Sipilä, Markku Kulmala, Michael Boy, and Pontus Roldin
Atmos. Chem. Phys., 22, 10023–10043, https://doi.org/10.5194/acp-22-10023-2022, https://doi.org/10.5194/acp-22-10023-2022, 2022
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The focus of this work is to study and improve our understanding of processes involved in the formation and growth of new particles in a remote Arctic marine environment. We run the 1D model ADCHEM along air mass trajectories arriving at Ny-Ålesund in May 2018. The model finds that ion-mediated H2SO4–NH3 nucleation can explain the observed new particle formation at Ny-Ålesund. The growth of particles is driven via H2SO4 condensation and formation of methane sulfonic acid in the aqueous phase.
Xavier Crosta, Karen E. Kohfeld, Helen C. Bostock, Matthew Chadwick, Alice Du Vivier, Oliver Esper, Johan Etourneau, Jacob Jones, Amy Leventer, Juliane Müller, Rachael H. Rhodes, Claire S. Allen, Pooja Ghadi, Nele Lamping, Carina B. Lange, Kelly-Anne Lawler, David Lund, Alice Marzocchi, Katrin J. Meissner, Laurie Menviel, Abhilash Nair, Molly Patterson, Jennifer Pike, Joseph G. Prebble, Christina Riesselman, Henrik Sadatzki, Louise C. Sime, Sunil K. Shukla, Lena Thöle, Maria-Elena Vorrath, Wenshen Xiao, and Jiao Yang
Clim. Past, 18, 1729–1756, https://doi.org/10.5194/cp-18-1729-2022, https://doi.org/10.5194/cp-18-1729-2022, 2022
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Despite its importance in the global climate, our knowledge of Antarctic sea-ice changes throughout the last glacial–interglacial cycle is extremely limited. As part of the Cycles of Sea Ice Dynamics in the Earth system (C-SIDE) Working Group, we review marine- and ice-core-based sea-ice proxies to provide insights into their applicability and limitations. By compiling published records, we provide information on Antarctic sea-ice dynamics over the past 130 000 years.
Silvia Becagli, Elena Barbaro, Simone Bonamano, Laura Caiazzo, Alcide di Sarra, Matteo Feltracco, Paolo Grigioni, Jost Heintzenberg, Luigi Lazzara, Michel Legrand, Alice Madonia, Marco Marcelli, Chiara Melillo, Daniela Meloni, Caterina Nuccio, Giandomenico Pace, Ki-Tae Park, Suzanne Preunkert, Mirko Severi, Marco Vecchiato, Roberta Zangrando, and Rita Traversi
Atmos. Chem. Phys., 22, 9245–9263, https://doi.org/10.5194/acp-22-9245-2022, https://doi.org/10.5194/acp-22-9245-2022, 2022
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Measurements of phytoplanktonic dimethylsulfide and its oxidation products in the Antarctic atmosphere allow us to understand the role of the oceanic (sea ice melting, Chl α and dimethylsulfoniopropionate) and atmospheric (wind direction and speed, humidity, solar radiation and transport processes) factors in the biogenic aerosol formation, concentration and characteristic ratio between components in an Antarctic coastal site facing the polynya of the Ross Sea.
Michael Sigl, Matthew Toohey, Joseph R. McConnell, Jihong Cole-Dai, and Mirko Severi
Earth Syst. Sci. Data, 14, 3167–3196, https://doi.org/10.5194/essd-14-3167-2022, https://doi.org/10.5194/essd-14-3167-2022, 2022
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Volcanism is a key driver of climate. Based on ice cores from Greenland and Antarctica, we reconstruct its climate impact potential over the Holocene. By aligning records on a well-dated chronology from Antarctica, we resolve long-standing inconsistencies in the dating of past volcanic eruptions. We reconstruct 850 eruptions (which, in total, injected 7410 Tg of sulfur in the stratosphere) and estimate how they changed the opacity of the atmosphere, a prerequisite for climate model simulations.
Eric W. Wolff, Hubertus Fischer, Tas van Ommen, and David A. Hodell
Clim. Past, 18, 1563–1577, https://doi.org/10.5194/cp-18-1563-2022, https://doi.org/10.5194/cp-18-1563-2022, 2022
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Projects are underway to drill ice cores in Antarctica reaching 1.5 Myr back in time. Dating such cores will be challenging. One method is to match records from the new core against datasets from existing marine sediment cores. Here we explore the options for doing this and assess how well the ice and marine records match over the existing 800 000-year time period. We are able to recommend a strategy for using marine data to place an age scale on the new ice cores.
Aki Virkkula, Henrik Grythe, John Backman, Tuukka Petäjä, Maurizio Busetto, Christian Lanconelli, Angelo Lupi, Silvia Becagli, Rita Traversi, Mirko Severi, Vito Vitale, Patrick Sheridan, and Elisabeth Andrews
Atmos. Chem. Phys., 22, 5033–5069, https://doi.org/10.5194/acp-22-5033-2022, https://doi.org/10.5194/acp-22-5033-2022, 2022
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Optical properties of surface aerosols at Dome C, Antarctica, in 2007–2013 and their potential source areas are presented. The equivalent black carbon (eBC) mass concentrations were compared with eBC measured at three other Antarctic sites: the South Pole (SPO) and two coastal sites, Neumayer and Syowa. Transport analysis suggests that South American BC emissions are the largest contributor to eBC at Dome C.
Xavier Faïn, Rachael H. Rhodes, Philip Place, Vasilii V. Petrenko, Kévin Fourteau, Nathan Chellman, Edward Crosier, Joseph R. McConnell, Edward J. Brook, Thomas Blunier, Michel Legrand, and Jérôme Chappellaz
Clim. Past, 18, 631–647, https://doi.org/10.5194/cp-18-631-2022, https://doi.org/10.5194/cp-18-631-2022, 2022
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Carbon monoxide (CO) is a regulated pollutant and one of the key components determining the oxidizing capacity of the atmosphere. In this study, we analyzed five ice cores from Greenland at high resolution for CO concentrations by coupling laser spectrometry with continuous melting. By combining these new datasets, we produced an upper-bound estimate of past atmospheric CO abundance since preindustrial times for the Northern Hemisphere high latitudes, covering the period from 1700 to 1957 CE.
Jiamei Lin, Anders Svensson, Christine S. Hvidberg, Johannes Lohmann, Steffen Kristiansen, Dorthe Dahl-Jensen, Jørgen Peder Steffensen, Sune Olander Rasmussen, Eliza Cook, Helle Astrid Kjær, Bo M. Vinther, Hubertus Fischer, Thomas Stocker, Michael Sigl, Matthias Bigler, Mirko Severi, Rita Traversi, and Robert Mulvaney
Clim. Past, 18, 485–506, https://doi.org/10.5194/cp-18-485-2022, https://doi.org/10.5194/cp-18-485-2022, 2022
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We employ acidity records from Greenland and Antarctic ice cores to estimate the emission strength, frequency and climatic forcing for large volcanic eruptions from the last half of the last glacial period. A total of 25 volcanic eruptions are found to be larger than any eruption in the last 2500 years, and we identify more eruptions than obtained from geological evidence. Towards the end of the glacial period, there is a notable increase in volcanic activity observed for Greenland.
Laura Crick, Andrea Burke, William Hutchison, Mika Kohno, Kathryn A. Moore, Joel Savarino, Emily A. Doyle, Sue Mahony, Sepp Kipfstuhl, James W. B. Rae, Robert C. J. Steele, R. Stephen J. Sparks, and Eric W. Wolff
Clim. Past, 17, 2119–2137, https://doi.org/10.5194/cp-17-2119-2021, https://doi.org/10.5194/cp-17-2119-2021, 2021
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The ~ 74 ka eruption of Toba was one of the largest eruptions of the last 100 ka. We have measured the sulfur isotopic composition for 11 Toba eruption candidates in two Antarctic ice cores. Sulfur isotopes allow us to distinguish between large eruptions that have erupted material into the stratosphere and smaller ones that reach lower altitudes. Using this we have identified the events most likely to be Toba and place the eruption on the transition into a cold period in the Northern Hemisphere.
Raffaello Nardin, Mirko Severi, Alessandra Amore, Silvia Becagli, Francois Burgay, Laura Caiazzo, Virginia Ciardini, Giuliano Dreossi, Massimo Frezzotti, Sang-Bum Hong, Ishaq Khan, Bianca Maria Narcisi, Marco Proposito, Claudio Scarchilli, Enricomaria Selmo, Andrea Spolaor, Barbara Stenni, and Rita Traversi
Clim. Past, 17, 2073–2089, https://doi.org/10.5194/cp-17-2073-2021, https://doi.org/10.5194/cp-17-2073-2021, 2021
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The first step to exploit all the potential information buried in ice cores is to produce a reliable age scale. Based on chemical and isotopic records from the 197 m Antarctic GV7(B) ice core, accurate dating was achieved and showed that the archive spans roughly the last 830 years. The relatively high accumulation rate allowed us to use the non-sea-salt sulfate seasonal pattern to count annual layers. The accumulation rate reconstruction exhibited a slight increase since the 18th century.
Bette L. Otto-Bliesner, Esther C. Brady, Anni Zhao, Chris M. Brierley, Yarrow Axford, Emilie Capron, Aline Govin, Jeremy S. Hoffman, Elizabeth Isaacs, Masa Kageyama, Paolo Scussolini, Polychronis C. Tzedakis, Charles J. R. Williams, Eric Wolff, Ayako Abe-Ouchi, Pascale Braconnot, Silvana Ramos Buarque, Jian Cao, Anne de Vernal, Maria Vittoria Guarino, Chuncheng Guo, Allegra N. LeGrande, Gerrit Lohmann, Katrin J. Meissner, Laurie Menviel, Polina A. Morozova, Kerim H. Nisancioglu, Ryouta O'ishi, David Salas y Mélia, Xiaoxu Shi, Marie Sicard, Louise Sime, Christian Stepanek, Robert Tomas, Evgeny Volodin, Nicholas K. H. Yeung, Qiong Zhang, Zhongshi Zhang, and Weipeng Zheng
Clim. Past, 17, 63–94, https://doi.org/10.5194/cp-17-63-2021, https://doi.org/10.5194/cp-17-63-2021, 2021
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The CMIP6–PMIP4 Tier 1 lig127k experiment was designed to address the climate responses to strong orbital forcing. We present a multi-model ensemble of 17 climate models, most of which have also completed the CMIP6 DECK experiments and are thus important for assessing future projections. The lig127ksimulations show strong summer warming over the NH continents. More than half of the models simulate a retreat of the Arctic minimum summer ice edge similar to the average for 2000–2018.
Anders Svensson, Dorthe Dahl-Jensen, Jørgen Peder Steffensen, Thomas Blunier, Sune O. Rasmussen, Bo M. Vinther, Paul Vallelonga, Emilie Capron, Vasileios Gkinis, Eliza Cook, Helle Astrid Kjær, Raimund Muscheler, Sepp Kipfstuhl, Frank Wilhelms, Thomas F. Stocker, Hubertus Fischer, Florian Adolphi, Tobias Erhardt, Michael Sigl, Amaelle Landais, Frédéric Parrenin, Christo Buizert, Joseph R. McConnell, Mirko Severi, Robert Mulvaney, and Matthias Bigler
Clim. Past, 16, 1565–1580, https://doi.org/10.5194/cp-16-1565-2020, https://doi.org/10.5194/cp-16-1565-2020, 2020
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We identify signatures of large bipolar volcanic eruptions in Greenland and Antarctic ice cores during the last glacial period, which allows for a precise temporal alignment of the ice cores. Thereby the exact timing of unexplained, abrupt climatic changes occurring during the last glacial period can be determined in a global context. The study thus provides a step towards a full understanding of elements of the climate system that may also play an important role in the future.
Markus M. Frey, Sarah J. Norris, Ian M. Brooks, Philip S. Anderson, Kouichi Nishimura, Xin Yang, Anna E. Jones, Michelle G. Nerentorp Mastromonaco, David H. Jones, and Eric W. Wolff
Atmos. Chem. Phys., 20, 2549–2578, https://doi.org/10.5194/acp-20-2549-2020, https://doi.org/10.5194/acp-20-2549-2020, 2020
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A winter sea ice expedition to Antarctica provided the first direct observations of sea salt aerosol (SSA) production during snow storms above sea ice, thereby validating a model hypothesis to account for winter time SSA maxima in Antarctica not explained otherwise. Defining SSA sources is important given the critical roles that aerosol plays for climate, for air quality and as a potential ice core proxy for sea ice conditions in the past.
Laurie Menviel, Emilie Capron, Aline Govin, Andrea Dutton, Lev Tarasov, Ayako Abe-Ouchi, Russell N. Drysdale, Philip L. Gibbard, Lauren Gregoire, Feng He, Ruza F. Ivanovic, Masa Kageyama, Kenji Kawamura, Amaelle Landais, Bette L. Otto-Bliesner, Ikumi Oyabu, Polychronis C. Tzedakis, Eric Wolff, and Xu Zhang
Geosci. Model Dev., 12, 3649–3685, https://doi.org/10.5194/gmd-12-3649-2019, https://doi.org/10.5194/gmd-12-3649-2019, 2019
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As part of the Past Global Changes (PAGES) working group on Quaternary Interglacials, we propose a protocol to perform transient simulations of the penultimate deglaciation for the Paleoclimate Modelling Intercomparison Project (PMIP4). This design includes time-varying changes in orbital forcing, greenhouse gas concentrations, continental ice sheets as well as freshwater input from the disintegration of continental ice sheets. Key paleo-records for model-data comparison are also included.
James A. Menking, Edward J. Brook, Sarah A. Shackleton, Jeffrey P. Severinghaus, Michael N. Dyonisius, Vasilii Petrenko, Joseph R. McConnell, Rachael H. Rhodes, Thomas K. Bauska, Daniel Baggenstos, Shaun Marcott, and Stephen Barker
Clim. Past, 15, 1537–1556, https://doi.org/10.5194/cp-15-1537-2019, https://doi.org/10.5194/cp-15-1537-2019, 2019
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An ice core from Taylor Glacier, Antarctica, spans a period ~ 70 000 years ago when Earth entered the last ice age. Chemical analyses of the ice and air bubbles allow for an independent determination of the ages of the ice and gas bubbles. The difference between the age of the ice and the bubbles at any given depth, called ∆age, is unusually high in the Taylor Glacier core compared to the Taylor Dome ice core situated to the south. This implies a dramatic accumulation gradient between the sites.
Xin Yang, Markus M. Frey, Rachael H. Rhodes, Sarah J. Norris, Ian M. Brooks, Philip S. Anderson, Kouichi Nishimura, Anna E. Jones, and Eric W. Wolff
Atmos. Chem. Phys., 19, 8407–8424, https://doi.org/10.5194/acp-19-8407-2019, https://doi.org/10.5194/acp-19-8407-2019, 2019
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This is a comprehensive model–data comparison aiming to evaluate the proposed mechanism of sea salt aerosol (SSA) production from blowing snow on sea ice. Some key parameters such as snow salinity and blowing-snow size distribution were constrained by data collected in the Weddell Sea. The good agreement between modelled SSA and the cruise data strongly indicates that sea ice surface is a large SSA source in polar regions, a process which has not been considered in current climate models.
Amaëlle Landais, Emilie Capron, Valérie Masson-Delmotte, Samuel Toucanne, Rachael Rhodes, Trevor Popp, Bo Vinther, Bénédicte Minster, and Frédéric Prié
Clim. Past, 14, 1405–1415, https://doi.org/10.5194/cp-14-1405-2018, https://doi.org/10.5194/cp-14-1405-2018, 2018
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During the last glacial–interglacial climate transition (120 000 to 10 000 years before present), Greenland climate and midlatitude North Atlantic climate and water cycle vary in phase over the succession of millennial events. We identify here one notable exception to this behavior with a decoupling unambiguously identified through a combination of water isotopic tracers measured in a Greenland ice core. The midlatitude moisture source becomes warmer and wetter at 16 200 years before present.
Laurie Menviel, Emilie Capron, Aline Govin, Andrea Dutton, Lev Tarasov, Ayako Abe-Ouchi, Russell Drysdale, Philip Gibbard, Lauren Gregoire, Feng He, Ruza Ivanovic, Masa Kageyama, Kenji Kawamura, Amaelle Landais, Bette L. Otto-Bliesner, Ikumi Oyabu, Polychronis Tzedakis, Eric Wolff, and Xu Zhang
Clim. Past Discuss., https://doi.org/10.5194/cp-2018-106, https://doi.org/10.5194/cp-2018-106, 2018
Preprint withdrawn
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The penultimate deglaciation (~ 138–128 ka), which represents the transition into the Last Interglacial period, provides a framework to investigate the climate and environmental response to large changes in boundary conditions. Here, as part of the PAGES-PMIP working group on Quaternary Interglacials, we propose a protocol to perform transient simulations of the penultimate deglaciation as well as a selection of paleo records for upcoming model-data comparisons.
Michel Legrand, Susanne Preunkert, Eric Wolff, Rolf Weller, Bruno Jourdain, and Dietmar Wagenbach
Atmos. Chem. Phys., 17, 14039–14054, https://doi.org/10.5194/acp-17-14039-2017, https://doi.org/10.5194/acp-17-14039-2017, 2017
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Multiple year-round records of bulk and size-segregated composition of sea-salt aerosol and acidic gases (HCl and HNO3) were obtained at inland Antarctica. Both acidic sulfur particles and nitric acid are involved in the observed sea-salt dechlorination in spring/summer. The observed sulfate to sodium mass ratio of sea-salt aerosol in winter (0.16 ± 0.05) suggests on average a similar contribution of sea-ice and open-ocean emissions to the sea-salt load over inland Antarctica at that season.
Rachael H. Rhodes, Xin Yang, Eric W. Wolff, Joseph R. McConnell, and Markus M. Frey
Atmos. Chem. Phys., 17, 9417–9433, https://doi.org/10.5194/acp-17-9417-2017, https://doi.org/10.5194/acp-17-9417-2017, 2017
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Sea salt aerosol comes from the open ocean or the sea ice surface. In the polar regions, this opens up the possibility of reconstructing sea ice history using sea salt recorded in ice cores. We use a chemical transport model to demonstrate that the sea ice source of aerosol is important in the Arctic. For the first time, we simulate realistic Greenland ice core sea salt in a process-based model. The importance of the sea ice source increases from south to north across the Greenland ice sheet.
Silvia Becagli, Fabrizio Anello, Carlo Bommarito, Federico Cassola, Giulia Calzolai, Tatiana Di Iorio, Alcide di Sarra, José-Luis Gómez-Amo, Franco Lucarelli, Miriam Marconi, Daniela Meloni, Francesco Monteleone, Silvia Nava, Giandomenico Pace, Mirko Severi, Damiano Massimiliano Sferlazzo, Rita Traversi, and Roberto Udisti
Atmos. Chem. Phys., 17, 2067–2084, https://doi.org/10.5194/acp-17-2067-2017, https://doi.org/10.5194/acp-17-2067-2017, 2017
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The paper aims to implement a specific strategy to target the aerosol due to ship emissions. PM10 is collected south and north of the main shipping route through the Mediterranean. Other than ions and metals the analysis is complemented with measurements of rare earth elements, trajectories from a high resolution regional model and actual observations of ship traffic. The combination of these approaches allows for unambiguous identification of the ship contribution (8–11 % of PM10) in this area.
Olivia J. Maselli, Nathan J. Chellman, Mackenzie Grieman, Lawrence Layman, Joseph R. McConnell, Daniel Pasteris, Rachael H. Rhodes, Eric Saltzman, and Michael Sigl
Clim. Past, 13, 39–59, https://doi.org/10.5194/cp-13-39-2017, https://doi.org/10.5194/cp-13-39-2017, 2017
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We analysed two Greenland ice cores for methanesulfonate (MSA) and bromine (Br) and concluded that both species are suitable proxies for local sea ice conditions. Interpretation of the records reveals that there have been sharp declines in sea ice in these areas in the past 250 years. However, at both sites the Br record deviates from MSA during the industrial period, raising questions about the value of Br as a sea ice proxy during recent periods of high, industrial, atmospheric acid pollution.
Michel Legrand, Joseph McConnell, Hubertus Fischer, Eric W. Wolff, Susanne Preunkert, Monica Arienzo, Nathan Chellman, Daiana Leuenberger, Olivia Maselli, Philip Place, Michael Sigl, Simon Schüpbach, and Mike Flannigan
Clim. Past, 12, 2033–2059, https://doi.org/10.5194/cp-12-2033-2016, https://doi.org/10.5194/cp-12-2033-2016, 2016
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Here, we review previous attempts made to reconstruct past forest fire using chemical signals recorded in Greenland ice. We showed that the Greenland ice records of ammonium, found to be a good fire proxy, consistently indicate changing fire activity in Canada in response to past climatic conditions that occurred since the last 15 000 years, including the Little Ice Age and the last large climatic transition.
Emma J. Stone, Emilie Capron, Daniel J. Lunt, Antony J. Payne, Joy S. Singarayer, Paul J. Valdes, and Eric W. Wolff
Clim. Past, 12, 1919–1932, https://doi.org/10.5194/cp-12-1919-2016, https://doi.org/10.5194/cp-12-1919-2016, 2016
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Climate models forced only with greenhouse gas concentrations and orbital parameters representative of the early Last Interglacial are unable to reproduce the observed colder-than-present temperatures in the North Atlantic and the warmer-than-present temperatures in the Southern Hemisphere. Using a climate model forced also with a freshwater amount derived from data representing melting from the remnant Northern Hemisphere ice sheets accounts for this response via the bipolar seesaw mechanism.
Rachael H. Rhodes, Xavier Faïn, Edward J. Brook, Joseph R. McConnell, Olivia J. Maselli, Michael Sigl, Jon Edwards, Christo Buizert, Thomas Blunier, Jérôme Chappellaz, and Johannes Freitag
Clim. Past, 12, 1061–1077, https://doi.org/10.5194/cp-12-1061-2016, https://doi.org/10.5194/cp-12-1061-2016, 2016
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Local artifacts in ice core methane data are superimposed on consistent records of past atmospheric variability. These artifacts are not related to past atmospheric history and care should be taken to avoid interpreting them as such. By investigating five polar ice cores from sites with different conditions, we relate isolated methane spikes to melt layers and decimetre-scale variations as "trapping signal" associated with a difference in timing of air bubble closure in adjacent firn layers.
Ikumi Oyabu, Yoshinori Iizuka, Eric Wolff, and Margareta Hansson
Clim. Past Discuss., https://doi.org/10.5194/cp-2016-42, https://doi.org/10.5194/cp-2016-42, 2016
Manuscript not accepted for further review
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This study presented the chemical compositions of non-volatile particles around the last termination in the Dome C ice core by using the sublimation-EDS method. The major soluble salt particles are CaSO4, Na2SO4, and NaCl, and time-series changes in the composition of these salts are similar to those for the Dome Fuji ice core. However, some differences occurred. The sulfatization rate of NaCl at Dome C is higher than that at Dome Fuji.
Michael Sigl, Tyler J. Fudge, Mai Winstrup, Jihong Cole-Dai, David Ferris, Joseph R. McConnell, Ken C. Taylor, Kees C. Welten, Thomas E. Woodruff, Florian Adolphi, Marion Bisiaux, Edward J. Brook, Christo Buizert, Marc W. Caffee, Nelia W. Dunbar, Ross Edwards, Lei Geng, Nels Iverson, Bess Koffman, Lawrence Layman, Olivia J. Maselli, Kenneth McGwire, Raimund Muscheler, Kunihiko Nishiizumi, Daniel R. Pasteris, Rachael H. Rhodes, and Todd A. Sowers
Clim. Past, 12, 769–786, https://doi.org/10.5194/cp-12-769-2016, https://doi.org/10.5194/cp-12-769-2016, 2016
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Here we present a chronology (WD2014) for the upper part (0–2850 m; 31.2 ka BP) of the West Antarctic Ice Sheet (WAIS) Divide ice core, which is based on layer counting of distinctive annual cycles preserved in the elemental, chemical and electrical conductivity records. We validated the chronology by comparing it to independent high-accuracy, absolutely dated chronologies. Given its demonstrated high accuracy, WD2014 can become a reference chronology for the Southern Hemisphere.
Fulvio Amato, Andrés Alastuey, Angeliki Karanasiou, Franco Lucarelli, Silvia Nava, Giulia Calzolai, Mirko Severi, Silvia Becagli, Vorne L. Gianelle, Cristina Colombi, Celia Alves, Danilo Custódio, Teresa Nunes, Mario Cerqueira, Casimiro Pio, Konstantinos Eleftheriadis, Evangelia Diapouli, Cristina Reche, María Cruz Minguillón, Manousos-Ioannis Manousakas, Thomas Maggos, Stergios Vratolis, Roy M. Harrison, and Xavier Querol
Atmos. Chem. Phys., 16, 3289–3309, https://doi.org/10.5194/acp-16-3289-2016, https://doi.org/10.5194/acp-16-3289-2016, 2016
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Harmonized source apportionment of atmospheric particulate matter (PM10 and PM2.5) at 5 EU cities (Barcelona, Florence, Milan, Athens and Porto) reveals that vehicle exhaust (excluding nitrate) plus non-exhaust contributes 16–32 % to PM10 and 15–36 % to PM2.5. Secondary PM represents 37–82 % of PM2.5. Biomass burning varies from < 2 to 24 % of PM10, depending on the residential heating fuel. Other sources are local dust (7–19 % of PM10), industries (4–11 % of PM10), shipping, sea salt and Saharan dust.
G. Calzolai, S. Nava, F. Lucarelli, M. Chiari, M. Giannoni, S. Becagli, R. Traversi, M. Marconi, D. Frosini, M. Severi, R. Udisti, A. di Sarra, G. Pace, D. Meloni, C. Bommarito, F. Monteleone, F. Anello, and D. M. Sferlazzo
Atmos. Chem. Phys., 15, 13939–13955, https://doi.org/10.5194/acp-15-13939-2015, https://doi.org/10.5194/acp-15-13939-2015, 2015
S. Fujita, F. Parrenin, M. Severi, H. Motoyama, and E. W. Wolff
Clim. Past, 11, 1395–1416, https://doi.org/10.5194/cp-11-1395-2015, https://doi.org/10.5194/cp-11-1395-2015, 2015
F. Parrenin, S. Fujita, A. Abe-Ouchi, K. Kawamura, V. Masson-Delmotte, H. Motoyama, F. Saito, M. Severi, B. Stenni, R. Uemura, and E. Wolff
Clim. Past Discuss., https://doi.org/10.5194/cpd-11-377-2015, https://doi.org/10.5194/cpd-11-377-2015, 2015
Revised manuscript has not been submitted
C. Buizert, K. M. Cuffey, J. P. Severinghaus, D. Baggenstos, T. J. Fudge, E. J. Steig, B. R. Markle, M. Winstrup, R. H. Rhodes, E. J. Brook, T. A. Sowers, G. D. Clow, H. Cheng, R. L. Edwards, M. Sigl, J. R. McConnell, and K. C. Taylor
Clim. Past, 11, 153–173, https://doi.org/10.5194/cp-11-153-2015, https://doi.org/10.5194/cp-11-153-2015, 2015
A. E. Jones, N. Brough, P. S. Anderson, and E. W. Wolff
Atmos. Chem. Phys., 14, 11843–11851, https://doi.org/10.5194/acp-14-11843-2014, https://doi.org/10.5194/acp-14-11843-2014, 2014
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We report observations of nitric acid and peroxynitric acid, in coastal Antarctica during winter. During winter, it is dark 24h per day, so there is no influence of sunlight on atmospheric composition. We show that observed variability in concentrations is highly correlated with changes in temperature. We derive enthalpies of adsorption and show they are consistent with those derived in laboratory studies. The Antarctic, during winter, is an ideal natural laboratory to study air-snow exchange.
X. Faïn, J. Chappellaz, R. H. Rhodes, C. Stowasser, T. Blunier, J. R. McConnell, E. J. Brook, S. Preunkert, M. Legrand, T. Debois, and D. Romanini
Clim. Past, 10, 987–1000, https://doi.org/10.5194/cp-10-987-2014, https://doi.org/10.5194/cp-10-987-2014, 2014
M. Marconi, D. M. Sferlazzo, S. Becagli, C. Bommarito, G. Calzolai, M. Chiari, A. di Sarra, C. Ghedini, J. L. Gómez-Amo, F. Lucarelli, D. Meloni, F. Monteleone, S. Nava, G. Pace, S. Piacentino, F. Rugi, M. Severi, R. Traversi, and R. Udisti
Atmos. Chem. Phys., 14, 2039–2054, https://doi.org/10.5194/acp-14-2039-2014, https://doi.org/10.5194/acp-14-2039-2014, 2014
A. M. Foley, D. Dalmonech, A. D. Friend, F. Aires, A. T. Archibald, P. Bartlein, L. Bopp, J. Chappellaz, P. Cox, N. R. Edwards, G. Feulner, P. Friedlingstein, S. P. Harrison, P. O. Hopcroft, C. D. Jones, J. Kolassa, J. G. Levine, I. C. Prentice, J. Pyle, N. Vázquez Riveiros, E. W. Wolff, and S. Zaehle
Biogeosciences, 10, 8305–8328, https://doi.org/10.5194/bg-10-8305-2013, https://doi.org/10.5194/bg-10-8305-2013, 2013
H. Fischer, J. Severinghaus, E. Brook, E. Wolff, M. Albert, O. Alemany, R. Arthern, C. Bentley, D. Blankenship, J. Chappellaz, T. Creyts, D. Dahl-Jensen, M. Dinn, M. Frezzotti, S. Fujita, H. Gallee, R. Hindmarsh, D. Hudspeth, G. Jugie, K. Kawamura, V. Lipenkov, H. Miller, R. Mulvaney, F. Parrenin, F. Pattyn, C. Ritz, J. Schwander, D. Steinhage, T. van Ommen, and F. Wilhelms
Clim. Past, 9, 2489–2505, https://doi.org/10.5194/cp-9-2489-2013, https://doi.org/10.5194/cp-9-2489-2013, 2013
L. Bazin, A. Landais, B. Lemieux-Dudon, H. Toyé Mahamadou Kele, D. Veres, F. Parrenin, P. Martinerie, C. Ritz, E. Capron, V. Lipenkov, M.-F. Loutre, D. Raynaud, B. Vinther, A. Svensson, S. O. Rasmussen, M. Severi, T. Blunier, M. Leuenberger, H. Fischer, V. Masson-Delmotte, J. Chappellaz, and E. Wolff
Clim. Past, 9, 1715–1731, https://doi.org/10.5194/cp-9-1715-2013, https://doi.org/10.5194/cp-9-1715-2013, 2013
D. Veres, L. Bazin, A. Landais, H. Toyé Mahamadou Kele, B. Lemieux-Dudon, F. Parrenin, P. Martinerie, E. Blayo, T. Blunier, E. Capron, J. Chappellaz, S. O. Rasmussen, M. Severi, A. Svensson, B. Vinther, and E. W. Wolff
Clim. Past, 9, 1733–1748, https://doi.org/10.5194/cp-9-1733-2013, https://doi.org/10.5194/cp-9-1733-2013, 2013
A. Svensson, M. Bigler, T. Blunier, H. B. Clausen, D. Dahl-Jensen, H. Fischer, S. Fujita, K. Goto-Azuma, S. J. Johnsen, K. Kawamura, S. Kipfstuhl, M. Kohno, F. Parrenin, T. Popp, S. O. Rasmussen, J. Schwander, I. Seierstad, M. Severi, J. P. Steffensen, R. Udisti, R. Uemura, P. Vallelonga, B. M. Vinther, A. Wegner, F. Wilhelms, and M. Winstrup
Clim. Past, 9, 749–766, https://doi.org/10.5194/cp-9-749-2013, https://doi.org/10.5194/cp-9-749-2013, 2013
M. M. Frey, N. Brough, J. L. France, P. S. Anderson, O. Traulle, M. D. King, A. E. Jones, E. W. Wolff, and J. Savarino
Atmos. Chem. Phys., 13, 3045–3062, https://doi.org/10.5194/acp-13-3045-2013, https://doi.org/10.5194/acp-13-3045-2013, 2013
A. E. Jones, E. W. Wolff, N. Brough, S. J.-B. Bauguitte, R. Weller, M. Yela, M. Navarro-Comas, H. A. Ochoa, and N. Theys
Atmos. Chem. Phys., 13, 1457–1467, https://doi.org/10.5194/acp-13-1457-2013, https://doi.org/10.5194/acp-13-1457-2013, 2013
Related subject area
Subject: Proxy Use-Development-Validation | Archive: Ice Cores | Timescale: Pleistocene
Evaluating marine dust records as templates for optical dating of Oldest Ice
Total Air Content measurements from the RECAP ice core
Effective diffusivity of sulfuric acid in Antarctic ice cores
The WAIS Divide deep ice core WD2014 chronology – Part 2: Annual-layer counting (0–31 ka BP)
Comparing past accumulation rate reconstructions in East Antarctic ice cores using 10Be, water isotopes and CMIP5-PMIP3 models
The WAIS Divide deep ice core WD2014 chronology – Part 1: Methane synchronization (68–31 ka BP) and the gas age–ice age difference
On the gas-ice depth difference (Δdepth) along the EPICA Dome C ice core
Centennial mineral dust variability in high-resolution ice core data from Dome C, Antarctica
Jessica Ng, Jeffrey Severinghaus, Ryan Bay, and Delia Tosi
Clim. Past, 20, 1437–1449, https://doi.org/10.5194/cp-20-1437-2024, https://doi.org/10.5194/cp-20-1437-2024, 2024
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The pattern of Earth’s ice age cycles shifted around a million years ago, becoming more extreme and longer in duration. Multiple projects are underway to obtain an Antarctic ice core that covers this time period, as ice cores contain important clues to why the transition happened. To make sure the ice is old enough at the bottom, we demonstrate how to use new technology to quickly measure dust patterns in the ice and compare them to dust in deep-ocean sediments whose ages are known.
Sindhu Vudayagiri, Bo Vinther, Johannes Freitag, Peter L. Langen, and Thomas Blunier
EGUsphere, https://doi.org/10.5194/egusphere-2024-237, https://doi.org/10.5194/egusphere-2024-237, 2024
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During the formation of ice from natural snowfall air is occluded in polar ice. The amount of air occluded (total air content) mainly reflects air pressure when the air is occluded and is therefore a proxy for elevation. However, there are several complications, such as melt, changes in firn structure and air pressure variability. We measured total air content in the RECAP ice core on the Renland Icecap in East Greenland. The core covers the period back to 121 thousand years before present.
Tyler J. Fudge, Raphael Sauvage, Linh Vu, Benjamin H. Hills, Mirko Severi, and Edwin D. Waddington
Clim. Past, 20, 297–312, https://doi.org/10.5194/cp-20-297-2024, https://doi.org/10.5194/cp-20-297-2024, 2024
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We use the oldest Antarctic ice core to estimate the rate of diffusion of sulfuric acid. Sulfuric acid is a marker of past volcanic activity and is critical in developing ice core timescales. The rate of diffusion is uncertain and is important to know, both for selecting future ice core locations and interpreting ice core records. We find the effective diffusivity of sulfate is 10 times smaller than previously estimated, indicating that the sulfuric acid signals will persist for longer.
Michael Sigl, Tyler J. Fudge, Mai Winstrup, Jihong Cole-Dai, David Ferris, Joseph R. McConnell, Ken C. Taylor, Kees C. Welten, Thomas E. Woodruff, Florian Adolphi, Marion Bisiaux, Edward J. Brook, Christo Buizert, Marc W. Caffee, Nelia W. Dunbar, Ross Edwards, Lei Geng, Nels Iverson, Bess Koffman, Lawrence Layman, Olivia J. Maselli, Kenneth McGwire, Raimund Muscheler, Kunihiko Nishiizumi, Daniel R. Pasteris, Rachael H. Rhodes, and Todd A. Sowers
Clim. Past, 12, 769–786, https://doi.org/10.5194/cp-12-769-2016, https://doi.org/10.5194/cp-12-769-2016, 2016
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Here we present a chronology (WD2014) for the upper part (0–2850 m; 31.2 ka BP) of the West Antarctic Ice Sheet (WAIS) Divide ice core, which is based on layer counting of distinctive annual cycles preserved in the elemental, chemical and electrical conductivity records. We validated the chronology by comparing it to independent high-accuracy, absolutely dated chronologies. Given its demonstrated high accuracy, WD2014 can become a reference chronology for the Southern Hemisphere.
A. Cauquoin, A. Landais, G. M. Raisbeck, J. Jouzel, L. Bazin, M. Kageyama, J.-Y. Peterschmitt, M. Werner, E. Bard, and ASTER Team
Clim. Past, 11, 355–367, https://doi.org/10.5194/cp-11-355-2015, https://doi.org/10.5194/cp-11-355-2015, 2015
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We present a new 10Be record at EDC between 269 and 355ka. Our 10Be-based accumulation rate is in good agreement with the one associated with the EDC3 timescale except for the warm MIS 9.3 optimum. This suggests that temperature reconstruction from water isotopes may be underestimated by 2.4K for the difference between the MIS 9.3 and present day. The CMIP5-PMIP3 models do not quantitatively reproduce changes in precipitation vs. temperature increase during glacial–interglacial transitions.
C. Buizert, K. M. Cuffey, J. P. Severinghaus, D. Baggenstos, T. J. Fudge, E. J. Steig, B. R. Markle, M. Winstrup, R. H. Rhodes, E. J. Brook, T. A. Sowers, G. D. Clow, H. Cheng, R. L. Edwards, M. Sigl, J. R. McConnell, and K. C. Taylor
Clim. Past, 11, 153–173, https://doi.org/10.5194/cp-11-153-2015, https://doi.org/10.5194/cp-11-153-2015, 2015
F. Parrenin, S. Barker, T. Blunier, J. Chappellaz, J. Jouzel, A. Landais, V. Masson-Delmotte, J. Schwander, and D. Veres
Clim. Past, 8, 1239–1255, https://doi.org/10.5194/cp-8-1239-2012, https://doi.org/10.5194/cp-8-1239-2012, 2012
F. Lambert, M. Bigler, J. P. Steffensen, M. Hutterli, and H. Fischer
Clim. Past, 8, 609–623, https://doi.org/10.5194/cp-8-609-2012, https://doi.org/10.5194/cp-8-609-2012, 2012
Cited articles
Barnes, P. R. F., Wolff, E. W., Mader, H. M., Udisti, R., Castellano, E., and Röthlisberger, R.: Evolution of chemical peak shapes in the Dome C, Antarctica, ice core, J. Geophys. Res.-Atmos., 108, 4126, https://doi.org/10.1029/2002JD002538, 2003a.
Barnes, P. R. F., Wolff, E. W., Mallard, D. C., and Mader, H. M.: SEM studies of the morphology and chemistry of polar ice, Microsc. Res. Tech., 62, 62–69, https://doi.org/10.1002/jemt.10385, 2003b.
Bazin, L., Landais, A., Lemieux-Dudon, B., Toyé Mahamadou Kele, H., Veres, D., Parrenin, F., Martinerie, P., Ritz, C., Capron, E., Lipenkov, V., Loutre, M.-F., Raynaud, D., Vinther, B., Svensson, A., Rasmussen, S. O., Severi, M., Blunier, T., Leuenberger, M., Fischer, H., Masson-Delmotte, V., Chappellaz, J., and Wolff, E.: An optimized multi-proxy, multi-site Antarctic ice and gas orbital chronology (AICC2012): 120–800 ka, Clim. Past, 9, 1715–1731, https://doi.org/10.5194/cp-9-1715-2013, 2013.
Bohleber, P., Roman, M., Šala, M., Delmonte, B., Stenni, B., and Barbante, C.: Two-dimensional impurity imaging in deep Antarctic ice cores: snapshots of three climatic periods and implications for high-resolution signal interpretation, The Cryosphere, 15, 3523–3538, https://doi.org/10.5194/tc-15-3523-2021, 2021.
Buizert, C., Fudge, T. J., Roberts, W. H. G., Steig, E. J., Sherriff-Tadano, S., Ritz, C., Lefebvre, E., Edwards, J., Kawamura, K., Oyabu, I., Motoyama, H., Kahle, E. C., Jones, T. R., Abe-Ouchi, A., Obase, T., Martin, C., Corr, H., Severinghaus, J. P., Beaudette, R., Epifanio, J. A., Brook, E. J., Martin, K., Chappellaz, J., Aoki, S., Nakazawa, T., Sowers, T. A., Alley, R. B., Ahn, J., Sigl, M., Severi, M., Dunbar, N. W., Svensson, A., Fegyveresi, J. M., He, C., Liu, Z., Zhu, J., Otto-Bliesner, B. L., Lipenkov, V. Y., Kageyama, M., and Schwander, J.: Antarctic surface temperature and elevation during the Last Glacial Maximum, Science, 372, 1097–1101, https://doi.org/10.1126/science.abd2897, 2021.
Durand, G., Weiss, J., Lipenkov, V., Barnola, J. M., Krinner, G., Parrenin, F., Delmonte, B., Ritz, C., Duval, P., Röthlisberger, R., and Bigler, M.: Effect of impurities on grain growth in cold ice sheets, J. Geophys. Res.-Earth Surf., 111, F01015, https://doi.org/10.1029/2005JF000320, 2006.
Durand, G., Svensson, A., Persson, A., Gillet-Chaulet, F., Montagnat, M., and Dahl-Jensen, D.: Evolution of the Texture along the EPICA Dome C Ice Core, in: Low Temperature Science Supplement Issue: Physics of Ice Core Records II, Institute of Low Temperature Science, Hokkaido Univ., Sapporo, Japan, edited by: Hondoh, T., 68, 91–106, http://hdl.handle.net/2115/45436 (last access: 12 September 2024), 2009.
EPICA community members: Eight glacial cycles from an Antarctic ice core, Nature, 429, 623–628, https://doi.org/10.1038/nature02599, 2004.
Fudge, T. J. and Severi, M.: EPICA Dome C Sulfate Data 7–3190 m, U.S. Antarctic Program (USAP) Data Center [data set], https://doi.org/10.15784/601759, 2023.
Fudge, T. J., Taylor, K. C., Waddington, E. D., Fitzpatrick, J. J., and Conway, H.: Electrical stratigraphy of the WAIS Divide ice core: Identification of centimeter-scale irregular layering, J. Geophys. Res.-Earth Surf., 121, 1218–1229, https://doi.org/10.1002/2016JF003845, 2016.
Fudge, T. J., Sauvage, R., Vu, L., Hills, B. H., Severi, M., and Waddington, E. D.: Effective diffusivity of sulfuric acid in Antarctic ice cores, Clim. Past, 20, 297–312, https://doi.org/10.5194/cp-20-297-2024, 2024.
Gable, C. M., Betz, H. F., and Maron, S. H.: Phase Equilibria of the System Sulfur Trioxide-Water, J. Am. Chem. Soc., 72, 1445–1448, https://doi.org/10.1021/ja01160a005, 1950.
Koffman, B. G., Kreutz, K. J., Kurbatov, A. V., and Dunbar, N. W.: Impact of known local and tropical volcanic eruptions of the past millennium on the WAIS divide microparticle record, Geophys. Res. Lett., 40, 4712–4716, https://doi.org/10.1002/grl.50822, 2013.
Lambert, F., Delmonte, B., Petit, J. R., Bigler, M., Kaufmann, P. R., Hutterli, M. A., Stocker, T. F., Ruth, U., Steffensen, J. P., and Maggi, V.: Dust-climate couplings over the past 800,000 years from the EPICA Dome C ice core, Nature, 452, 616–619, https://doi.org/10.1038/nature06763, 2008.
Legresy, B., Rignot, E., and Tabacco, I. E.: Constraining ice dynamics at Dome C, Antarctica, using remotely sensed measurements, Geophys. Res. Lett., 27, 3493–3496, https://doi.org/10.1029/2000GL011707, 2000.
Lilien, D. A., Steinhage, D., Taylor, D., Parrenin, F., Ritz, C., Mulvaney, R., Martín, C., Yan, J.-B., O'Neill, C., Frezzotti, M., Miller, H., Gogineni, P., Dahl-Jensen, D., and Eisen, O.: Brief communication: New radar constraints support presence of ice older than 1.5 Myr at Little Dome C, The Cryosphere, 15, 1881–1888, https://doi.org/10.5194/tc-15-1881-2021, 2021.
Marshall, L., Schmidt, A., Toohey, M., Carslaw, K. S., Mann, G. W., Sigl, M., Khodri, M., Timmreck, C., Zanchettin, D., Ball, W. T., Bekki, S., Brooke, J. S. A., Dhomse, S., Johnson, C., Lamarque, J.-F., LeGrande, A. N., Mills, M. J., Niemeier, U., Pope, J. O., Poulain, V., Robock, A., Rozanov, E., Stenke, A., Sukhodolov, T., Tilmes, S., Tsigaridis, K., and Tummon, F.: Multi-model comparison of the volcanic sulfate deposition from the 1815 eruption of Mt. Tambora, Atmos. Chem. Phys., 18, 2307–2328, https://doi.org/10.5194/acp-18-2307-2018, 2018.
Marshall, L., Johnson, J. S., Mann, G. W., Lee, L., Dhomse, S. S., Regayre, L., Yoshioka, M., Carslaw, K. S., and Schmidt, A.: Exploring How Eruption Source Parameters Affect Volcanic Radiative Forcing Using Statistical Emulation, J. Geophys. Res.-Atmos., 124, 964–985, https://doi.org/10.1029/2018JD028675, 2019.
Mulvaney, R., Wolff, E. W., and Oates, K.: Sulphuric acid at grain boundaries in Antarctic ice, Nature 331, 247–249, 1988.
Ng, F. S. L.: Pervasive diffusion of climate signals recorded in ice-vein ionic impurities, The Cryosphere, 15, 1787–1810, https://doi.org/10.5194/tc-15-1787-2021, 2021.
Nye, J. F.: Correction Factor for Accumulation Measured by the Thickness of the Annual Layers in an Ice Sheet, J. Glaciol., 4, 785–788, https://doi.org/10.3189/S0022143000028367, 1963.
Ohno, H., Igarashi, M., and Hondoh, T.: Salt inclusions in polar ice core: Location and chemical form of water-soluble impurities, Earth Planet. Sci. Lett. 232, 171–178, https://doi.org/10.1016/j.epsl.2005.01.001, 2005.
Parrenin, F., Dreyfus, G., Durand, G., Fujita, S., Gagliardini, O., Gillet, F., Jouzel, J., Kawamura, K., Lhomme, N., Masson-Delmotte, V., Ritz, C., Schwander, J., Shoji, H., Uemura, R., Watanabe, O., and Yoshida, N.: 1-D-ice flow modelling at EPICA Dome C and Dome Fuji, East Antarctica, Clim. Past, 3, 243–259, https://doi.org/10.5194/cp-3-243-2007, 2007.
Rempel, A. W., Waddington, E. D., Wettlaufer, J. S., and Worster, M. G.: Possible displacement of the climate signal in ancient ice by premelting and anomalous diffusion, Nature, 411, 568–571, https://doi.org/10.1038/35079043, 2001.
Severi, M., Becagli, S., Traversi, R., and Udisti, R.: Recovering Paleo-Records from Antarctic Ice-Cores by Coupling a Continuous Melting Device and Fast Ion Chromatography, Anal. Chem., 87, 11441–11447, https://doi.org/10.1021/acs.analchem.5b02961, 2015.
Sigl, M., McConnell, J. R., Layman, L., Maselli, O., McGwire, K., Pasteris, D., Dahl-Jensen, D., Steffensen, J. P., Vinther, B., Edwards, R., Mulvaney, R., and Kipfstuhl, S.: A new bipolar ice core record of volcanism from WAIS Divide and NEEM and implications for climate forcing of the last 2000 years, J. Geophys. Res.-Atmos., 118, 1151–1169, https://doi.org/10.1029/2012jd018603, 2013.
Sigl, M., Fudge, T. J., Winstrup, M., Cole-Dai, J., Ferris, D., McConnell, J. R., Taylor, K. C., Welten, K. C., Woodruff, T. E., Adolphi, F., Bisiaux, M., Brook, E. J., Buizert, C., Caffee, M. W., Dunbar, N. W., Edwards, R., Geng, L., Iverson, N., Koffman, B., Layman, L., Maselli, O. J., McGwire, K., Muscheler, R., Nishiizumi, K., Pasteris, D. R., Rhodes, R. H., and Sowers, T. A.: The WAIS Divide deep ice core WD2014 chronology – Part 2: Annual-layer counting (0–31 ka BP), Clim. Past, 12, 769–786, https://doi.org/10.5194/cp-12-769-2016, 2016.
Thomason, L. W., Ernest, N., Millán, L., Rieger, L., Bourassa, A., Vernier, J.-P., Manney, G., Luo, B., Arfeuille, F., and Peter, T.: A global space-based stratospheric aerosol climatology: 1979–2016, Earth Syst. Sci. Data, 10, 469–492, https://doi.org/10.5194/essd-10-469-2018, 2018.
Traversi, R., Becagli, S., Castellano, E., Marino, F., Rugi, F., Severi, M., Angelis, M. de, Fischer, H., Hansson, M., Stauffer, B., Steffensen, J. P., Bigler, M., and Udisti, R.: Sulfate Spikes in the Deep Layers of EPICA-Dome C Ice Core: Evidence of Glaciological Artifacts, Environ. Sci. Technol., 43, 8737–8743, https://doi.org/10.1021/es901426y, 2009.
Wolff, E. W., Chappellaz, J., Blunier, T., Rasmussen, S. O., and Svensson, A.: Millennial-scale variability during the last glacial: The ice core record, Quat. Sci. Rev., 29, 2828–2838, https://doi.org/10.1016/j.quascirev.2009.10.013, 2010.
Wolff, E. W., Burke, A., Crick, L., Doyle, E. A., Innes, H. M., Mahony, S. H., Rae, J. W. B., Severi, M., and Sparks, R. S. J.: Frequency of large volcanic eruptions over the past 200 000 years, Clim. Past, 19, 23–33, https://doi.org/10.5194/cp-19-23-2023, 2023.
Short summary
Some ionic components slowly move through glacier ice by diffusion, but the rate of this diffusion, its exact mechanism(s), and the factors that might influence it are poorly understood. In this study, we model how peaks in sulfate, deposited at Dome C on the Antarctic ice sheet after volcanic eruptions, change with depth and time. We find that the sulfate diffusion rate in ice is relatively fast in young ice near the surface, but the rate is markedly reduced over time.
Some ionic components slowly move through glacier ice by diffusion, but the rate of this...
