Articles | Volume 17, issue 5
https://doi.org/10.5194/cp-17-2119-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/cp-17-2119-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| Highlight paper
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18 Oct 2021
Research article | Highlight paper |
| 18 Oct 2021
| 18 Oct 2021
New insights into the ∼ 74 ka Toba eruption from sulfur isotopes of polar ice cores
School Of Earth And Environmental Sciences, University Of St Andrews, St Andrews, United Kingdom
Andrea Burke
School Of Earth And Environmental Sciences, University Of St Andrews, St Andrews, United Kingdom
William Hutchison
School Of Earth And Environmental Sciences, University Of St Andrews, St Andrews, United Kingdom
Mika Kohno
Geoscience Center (GZG), Department of Geochemistry, Georg August Universität Göttingen, Göttingen, Germany
Kathryn A. Moore
Department Of Atmospheric Science, Colorado State University, Fort Collins, Colorado, USA
Joel Savarino
Institut Des Géosciences De L'environnement, Grenoble, France
Emily A. Doyle
Department Of Earth Sciences, University Of Cambridge, Cambridge, United Kingdom
Sue Mahony
School Of Earth Sciences, University Of Bristol, Bristol, United Kingdom
Sepp Kipfstuhl
Alfred Wegener Institute, Bremerhaven, Germany
James W. B. Rae
School Of Earth And Environmental Sciences, University Of St Andrews, St Andrews, United Kingdom
Robert C. J. Steele
School Of Earth And Environmental Sciences, University Of St Andrews, St Andrews, United Kingdom
R. Stephen J. Sparks
School Of Earth Sciences, University Of Bristol, Bristol, United Kingdom
Eric W. Wolff
Department Of Earth Sciences, University Of Cambridge, Cambridge, United Kingdom
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Eric W. Wolff, Andrea Burke, Laura Crick, Emily A. Doyle, Helen M. Innes, Sue H. Mahony, James W. B. Rae, Mirko Severi, and R. Stephen J. Sparks
Clim. Past, 19, 23–33, https://doi.org/10.5194/cp-19-23-2023, https://doi.org/10.5194/cp-19-23-2023, 2023
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Large volcanic eruptions leave an imprint of a spike of sulfate deposition that can be measured in ice cores. Here we use a method that logs the number and size of large eruptions recorded in an Antarctic core in a consistent way through the last 200 000 years. The rate of recorded eruptions is variable but shows no trends. In particular, there is no increase in recorded eruptions during deglaciation periods. This is consistent with most recorded eruptions being from lower latitudes.
Helene Hoffmann, Jason Day, Rachael H. Rhodes, Mackenzie Grieman, Jack Humby, Isobel Rowell, Christoph Nehrbass-Ahles, Robert Mulvaney, Sally Gibson, and Eric Wolff
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Ice cores are archives of past atmospheric conditions. In deep and old ice, the layers containing this information get thinned to the millimetre scale or below. We installed a setup for high-resolution (182 μm) chemical impurity measurements in ice cores using the laser ablation technique at the University of Cambridge. In a first application to the Skytrain ice core from Antarctica, we discuss the potential to detect fine-layered structures in ice up to an age of 26 000 years.
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A better understanding of ice flow requires more observational data. The EastGRIP core is the first ice core through an active ice stream. We discuss crystal orientation data to determine the present deformation regimes. A comparison with other deep ice cores shows the unique properties of EastGRIP and that deep ice originates from the Eemian. We further show that the overall plug flow of NEGIS is characterised by many small-scale variations, which remain to be considered in ice-flow models.
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Clim. Past, 20, 2031–2043, https://doi.org/10.5194/cp-20-2031-2024, https://doi.org/10.5194/cp-20-2031-2024, 2024
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Kathryn A. Moore, Thomas C. J. Hill, Samantha Greeney, Chamika K. Madawala, Raymond J. Leibensperger III, Christopher D. Cappa, M. Dale Stokes, Grant B. Deane, Christopher Lee, Alexei V. Tivanski, Kimberly A. Prather, and Paul J. DeMott
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This article presents results from the first study in a new wind-wave channel at the Scripps Institution of Oceanography. The experiment tested how wind speed over the ocean surface influences production of sea spray particles, which are important for radiative forcing and cloud formation in the atmosphere. We found that particle concentration and chemical composition varied with winds speed, and the changes were driven by changes in wind and wave-breaking rather seawater biology or chemistry.
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The Cryosphere, 18, 2691–2718, https://doi.org/10.5194/tc-18-2691-2024, https://doi.org/10.5194/tc-18-2691-2024, 2024
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Natalie Brett, Kathy S. Law, Steve R. Arnold, Javier G. Fochesatto, Jean-Christophe Raut, Tatsuo Onishi, Robert Gilliam, Kathleen Fahey, Deanna Huff, George Pouliot, Brice Barret, Elsa Dieudonne, Roman Pohorsky, Julia Schmale, Andrea Baccarini, Slimane Bekki, Gianluca Pappaccogli, Federico Scoto, Stefano Decesari, Antonio Donateo, Meeta Cesler-Maloney, William Simpson, Patrice Medina, Barbara D'Anna, Brice Temime-Roussel, Joel Savarino, Sarah Albertin, Jingqiu Mao, Becky Alexander, Allison Moon, Peter F. DeCarlo, Vanessa Selimovic, Robert Yokelson, and Ellis S. Robinson
EGUsphere, https://doi.org/10.5194/egusphere-2024-1450, https://doi.org/10.5194/egusphere-2024-1450, 2024
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Processes influencing dispersion of local anthropogenic emissions in Arctic wintertime are investigated with dispersion model simulations. Modelled power plant plume rise that considers surface and elevated temperature inversions improves results compared to observations. Modelled near-surface concentrations are improved by representation of vertical mixing and emission estimates. Large increases in diesel vehicle emissions at temperatures reaching -35 °C are required to reproduce observed NOx.
V. Holly L. Winton, Robert Mulvaney, Joel Savarino, Kyle R. Clem, and Markus M. Frey
Clim. Past, 20, 1213–1232, https://doi.org/10.5194/cp-20-1213-2024, https://doi.org/10.5194/cp-20-1213-2024, 2024
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In 2018, a new 120 m ice core was drilled in a region located under the Antarctic ozone hole. We present the first results including a 1300-year record of snow accumulation and aerosol chemistry. We investigate the aerosol and moisture source regions and atmospheric processes related to the ice core record and discuss what this means for developing a record of past ultraviolet radiation and ozone depletion using the stable isotopic composition of nitrate measured in the same ice core.
Zhuang Jiang, Becky Alexander, Joel Savarino, and Lei Geng
Atmos. Chem. Phys., 24, 4895–4914, https://doi.org/10.5194/acp-24-4895-2024, https://doi.org/10.5194/acp-24-4895-2024, 2024
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Larissa Lacher, Michael P. Adams, Kevin Barry, Barbara Bertozzi, Heinz Bingemer, Cristian Boffo, Yannick Bras, Nicole Büttner, Dimitri Castarede, Daniel J. Cziczo, Paul J. DeMott, Romy Fösig, Megan Goodell, Kristina Höhler, Thomas C. J. Hill, Conrad Jentzsch, Luis A. Ladino, Ezra J. T. Levin, Stephan Mertes, Ottmar Möhler, Kathryn A. Moore, Benjamin J. Murray, Jens Nadolny, Tatjana Pfeuffer, David Picard, Carolina Ramírez-Romero, Mickael Ribeiro, Sarah Richter, Jann Schrod, Karine Sellegri, Frank Stratmann, Benjamin E. Swanson, Erik S. Thomson, Heike Wex, Martin J. Wolf, and Evelyn Freney
Atmos. Chem. Phys., 24, 2651–2678, https://doi.org/10.5194/acp-24-2651-2024, https://doi.org/10.5194/acp-24-2651-2024, 2024
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Atmos. Chem. Phys., 24, 1361–1388, https://doi.org/10.5194/acp-24-1361-2024, https://doi.org/10.5194/acp-24-1361-2024, 2024
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Ryan J. Patnaude, Kathryn A. Moore, Russell J. Perkins, Thomas C. J. Hill, Paul J. DeMott, and Sonia M. Kreidenweis
Atmos. Chem. Phys., 24, 911–928, https://doi.org/10.5194/acp-24-911-2024, https://doi.org/10.5194/acp-24-911-2024, 2024
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In this study we examined the effect of atmospheric aging on sea spray aerosols (SSAs) to form ice and how newly formed secondary marine aerosols (SMAs) may freeze at cirrus temperatures (< −38 °C). Results show that SSAs freeze at different relative humidities (RHs) depending on the temperature and that the ice-nucleating ability of SSA was not hindered by atmospheric aging. SMAs are shown to freeze at high RHs and are likely inefficient at forming ice at cirrus temperatures.
Alexis Lamothe, Joel Savarino, Patrick Ginot, Lison Soussaintjean, Elsa Gautier, Pete D. Akers, Nicolas Caillon, and Joseph Erbland
Atmos. Meas. Tech., 16, 4015–4030, https://doi.org/10.5194/amt-16-4015-2023, https://doi.org/10.5194/amt-16-4015-2023, 2023
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Ammonia is a reactive gas in our atmosphere that is key in air quality issues. Assessing its emissions and how it reacts is a hot topic that can be addressed from the past. Stable isotopes (the mass of the molecule) measured in ice cores (glacial archives) can teach us a lot. However, the concentrations in ice cores are very small. We propose a protocol to limit the contamination and apply it to one ice core drilled in Mont Blanc, describing the opportunities our method brings.
Isobel Rowell, Carlos Martin, Robert Mulvaney, Helena Pryer, Dieter Tetzner, Emily Doyle, Hara Madhav Talasila, Jilu Li, and Eric Wolff
Clim. Past, 19, 1699–1714, https://doi.org/10.5194/cp-19-1699-2023, https://doi.org/10.5194/cp-19-1699-2023, 2023
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We present an age scale for a new type of ice core from a vulnerable region in West Antarctic, which is lacking in longer-term (greater than a few centuries) ice core records. The Sherman Island core extends to greater than 1 kyr. We provide modelling evidence for the potential of a 10 kyr long core. We show that this new type of ice core can be robustly dated and that climate records from this core will be a significant addition to existing regional climate records.
Sune Olander Rasmussen, Dorthe Dahl-Jensen, Hubertus Fischer, Katrin Fuhrer, Steffen Bo Hansen, Margareta Hansson, Christine S. Hvidberg, Ulf Jonsell, Sepp Kipfstuhl, Urs Ruth, Jakob Schwander, Marie-Louise Siggaard-Andersen, Giulia Sinnl, Jørgen Peder Steffensen, Anders M. Svensson, and Bo M. Vinther
Earth Syst. Sci. Data, 15, 3351–3364, https://doi.org/10.5194/essd-15-3351-2023, https://doi.org/10.5194/essd-15-3351-2023, 2023
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Timescales are essential for interpreting palaeoclimate data. The data series presented here were used for annual-layer identification when constructing the timescales named the Greenland Ice-Core Chronology 2005 (GICC05) and the revised version GICC21. Hopefully, these high-resolution data sets will be useful also for other purposes.
Robert Mulvaney, Eric W. Wolff, Mackenzie M. Grieman, Helene H. Hoffmann, Jack D. Humby, Christoph Nehrbass-Ahles, Rachael H. Rhodes, Isobel F. Rowell, Frédéric Parrenin, Loïc Schmidely, Hubertus Fischer, Thomas F. Stocker, Marcus Christl, Raimund Muscheler, Amaelle Landais, and Frédéric Prié
Clim. Past, 19, 851–864, https://doi.org/10.5194/cp-19-851-2023, https://doi.org/10.5194/cp-19-851-2023, 2023
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We present an age scale for a new ice core drilled at Skytrain Ice Rise, an ice rise facing the Ronne Ice Shelf in Antarctica. Various measurements in the ice and air phases are used to match the ice core to other Antarctic cores that have already been dated, and a new age scale is constructed. The 651 m ice core includes ice that is confidently dated to 117 000–126 000 years ago, in the last interglacial. Older ice is found deeper down, but there are flow disturbances in the deeper ice.
Simone Ventisette, Samuele Baldini, Claudio Artoni, Silvia Becagli, Laura Caiazzo, Barbara Delmonte, Massimo Frezzotti, Raffaello Nardin, Joel Savarino, Mirko Severi, Andrea Spolaor, Barbara Stenni, and Rita Traversi
EGUsphere, https://doi.org/10.5194/egusphere-2023-393, https://doi.org/10.5194/egusphere-2023-393, 2023
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The paper reports the spatial variability of concentration and fluxes of chemical impurities in superficial snow over unexplored area of the East Antarctic ice sheet. Pinatubo and Puyehue-Cordón Caulle volcanic eruptions in non-sea salt sulfate and dust snow pits record were used to achieve the accumulation rates. Deposition (wet, dry and uptake from snow surface) and post deposition processes are constrained. These knowledges are fundamental in Antarctic ice cores stratigraphies interpretation.
David A. Hodell, Simon J. Crowhurst, Lucas Lourens, Vasiliki Margari, John Nicolson, James E. Rolfe, Luke C. Skinner, Nicola C. Thomas, Polychronis C. Tzedakis, Maryline J. Mleneck-Vautravers, and Eric W. Wolff
Clim. Past, 19, 607–636, https://doi.org/10.5194/cp-19-607-2023, https://doi.org/10.5194/cp-19-607-2023, 2023
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We produced a 1.5-million-year-long history of climate change at International Ocean Discovery Program Site U1385 of the Iberian margin, a well-known location for rapidly accumulating sediments on the seafloor. Our record demonstrates that longer-term orbital changes in Earth's climate were persistently overprinted by abrupt millennial-to-centennial climate variability. The occurrence of abrupt climate change is modulated by the slower variations in Earth's orbit and climate background state.
Romilly Harris Stuart, Anne-Katrine Faber, Sonja Wahl, Maria Hörhold, Sepp Kipfstuhl, Kristian Vasskog, Melanie Behrens, Alexandra M. Zuhr, and Hans Christian Steen-Larsen
The Cryosphere, 17, 1185–1204, https://doi.org/10.5194/tc-17-1185-2023, https://doi.org/10.5194/tc-17-1185-2023, 2023
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This empirical study uses continuous daily measurements from the Greenland Ice Sheet to document changes in surface snow properties. Consistent changes in snow isotopic composition are observed in the absence of deposition due to surface processes, indicating the isotopic signal of deposited precipitation is not always preserved. Our observations have potential implications for the interpretation of water isotopes in ice cores – historically assumed to reflect isotopic composition at deposition.
Eric W. Wolff, Andrea Burke, Laura Crick, Emily A. Doyle, Helen M. Innes, Sue H. Mahony, James W. B. Rae, Mirko Severi, and R. Stephen J. Sparks
Clim. Past, 19, 23–33, https://doi.org/10.5194/cp-19-23-2023, https://doi.org/10.5194/cp-19-23-2023, 2023
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Large volcanic eruptions leave an imprint of a spike of sulfate deposition that can be measured in ice cores. Here we use a method that logs the number and size of large eruptions recorded in an Antarctic core in a consistent way through the last 200 000 years. The rate of recorded eruptions is variable but shows no trends. In particular, there is no increase in recorded eruptions during deglaciation periods. This is consistent with most recorded eruptions being from lower latitudes.
Pete D. Akers, Joël Savarino, Nicolas Caillon, Olivier Magand, and Emmanuel Le Meur
Atmos. Chem. Phys., 22, 15637–15657, https://doi.org/10.5194/acp-22-15637-2022, https://doi.org/10.5194/acp-22-15637-2022, 2022
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Nitrate isotopes in Antarctic ice do not preserve the seasonal isotopic cycles of the atmosphere, which limits their use to study the past. We studied nitrate along an 850 km Antarctic transect to learn how these cycles are changed by sunlight-driven chemistry in the snow. Our findings suggest that the snow accumulation rate and other environmental signals can be extracted from nitrate with the right sampling and analytical approaches.
Jessica G. M. Crumpton-Banks, Thomas Tanner, Ivan Hernández Almeida, James W. B. Rae, and Heather Stoll
Biogeosciences, 19, 5633–5644, https://doi.org/10.5194/bg-19-5633-2022, https://doi.org/10.5194/bg-19-5633-2022, 2022
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Past ocean carbon is reconstructed using proxies, but it is unknown whether preparing ocean sediment for one proxy might damage the data given by another. We have tested whether the extraction of an organic proxy archive from sediment samples impacts the geochemistry of tiny shells also within the sediment. We find no difference in shell geochemistry between samples which come from treated and untreated sediment. This will help us to maximize scientific return from valuable sediment samples.
Yanzhi Cao, Zhuang Jiang, Becky Alexander, Jihong Cole-Dai, Joel Savarino, Joseph Erbland, and Lei Geng
Atmos. Chem. Phys., 22, 13407–13422, https://doi.org/10.5194/acp-22-13407-2022, https://doi.org/10.5194/acp-22-13407-2022, 2022
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We investigate the potential of ice-core preserved nitrate isotopes as proxies of stratospheric ozone variability by measuring nitrate isotopes in a shallow ice core from the South Pole. The large variability in the snow accumulation rate and its slight increase after the 1970s masked any signals caused by the ozone hole. Moreover, the nitrate oxygen isotope decrease may reflect changes in the atmospheric oxidation environment in the Southern Ocean.
Andrea Bevilacqua, Alvaro Aravena, Willy Aspinall, Antonio Costa, Sue Mahony, Augusto Neri, Stephen Sparks, and Brittain Hill
Nat. Hazards Earth Syst. Sci., 22, 3329–3348, https://doi.org/10.5194/nhess-22-3329-2022, https://doi.org/10.5194/nhess-22-3329-2022, 2022
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We evaluate through first-order kinetic energy models, the minimum volume and mass of a pyroclastic density current generated at the Aso caldera that might affect any of five distal infrastructure sites. These target sites are all located 115–145 km from the caldera, but in well-separated directions. Our constraints of volume and mass are then compared with the scale of Aso-4, the largest caldera-forming eruption of Aso.
Albane Barbero, Roberto Grilli, Markus M. Frey, Camille Blouzon, Detlev Helmig, Nicolas Caillon, and Joël Savarino
Atmos. Chem. Phys., 22, 12025–12054, https://doi.org/10.5194/acp-22-12025-2022, https://doi.org/10.5194/acp-22-12025-2022, 2022
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The high reactivity of the summer Antarctic boundary layer results in part from the emissions of nitrogen oxides produced during photo-denitrification of the snowpack, but its underlying mechanisms are not yet fully understood. The results of this study suggest that more NO2 is produced from the snowpack early in the photolytic season, possibly due to stronger UV irradiance caused by a smaller solar zenith angle near the solstice.
Takahito Mitsui, Polychronis C. Tzedakis, and Eric W. Wolff
Clim. Past, 18, 1983–1996, https://doi.org/10.5194/cp-18-1983-2022, https://doi.org/10.5194/cp-18-1983-2022, 2022
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We provide simple quantitative models for the interglacial and glacial intensities over the last 800 000 years. Our results suggest that the memory of previous climate states and the time course of the insolation in both hemispheres are crucial for understanding interglacial and glacial intensities. In our model, the shift in interglacial intensities at the Mid-Brunhes Event (~430 ka) is ultimately attributed to the amplitude modulation of obliquity.
Helene M. Hoffmann, Mackenzie M. Grieman, Amy C. F. King, Jenna A. Epifanio, Kaden Martin, Diana Vladimirova, Helena V. Pryer, Emily Doyle, Axel Schmidt, Jack D. Humby, Isobel F. Rowell, Christoph Nehrbass-Ahles, Elizabeth R. Thomas, Robert Mulvaney, and Eric W. Wolff
Clim. Past, 18, 1831–1847, https://doi.org/10.5194/cp-18-1831-2022, https://doi.org/10.5194/cp-18-1831-2022, 2022
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The WACSWAIN project (WArm Climate Stability of the West Antarctic ice sheet in the last INterglacial) investigates the fate of the West Antarctic Ice Sheet during the last warm period on Earth (115 000–130 000 years before present). Within this framework an ice core was recently drilled at Skytrain Ice Rise. In this study we present a stratigraphic chronology of that ice core based on absolute age markers and annual layer counting for the last 2000 years.
Zhuang Jiang, Joel Savarino, Becky Alexander, Joseph Erbland, Jean-Luc Jaffrezo, and Lei Geng
The Cryosphere, 16, 2709–2724, https://doi.org/10.5194/tc-16-2709-2022, https://doi.org/10.5194/tc-16-2709-2022, 2022
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A record of year-round atmospheric nitrate isotopic composition along with snow nitrate isotopic data from Summit, Greenland, revealed apparent enrichments in nitrogen isotopes in snow nitrate compared to atmospheric nitrate, in addition to a relatively smaller degree of changes in oxygen isotopes. The results suggest that at this site post-depositional processing takes effect, which should be taken into account when interpreting ice-core nitrate isotope records.
Eric W. Wolff, Hubertus Fischer, Tas van Ommen, and David A. Hodell
Clim. Past, 18, 1563–1577, https://doi.org/10.5194/cp-18-1563-2022, https://doi.org/10.5194/cp-18-1563-2022, 2022
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Projects are underway to drill ice cores in Antarctica reaching 1.5 Myr back in time. Dating such cores will be challenging. One method is to match records from the new core against datasets from existing marine sediment cores. Here we explore the options for doing this and assess how well the ice and marine records match over the existing 800 000-year time period. We are able to recommend a strategy for using marine data to place an age scale on the new ice cores.
Julien Westhoff, Giulia Sinnl, Anders Svensson, Johannes Freitag, Helle Astrid Kjær, Paul Vallelonga, Bo Vinther, Sepp Kipfstuhl, Dorthe Dahl-Jensen, and Ilka Weikusat
Clim. Past, 18, 1011–1034, https://doi.org/10.5194/cp-18-1011-2022, https://doi.org/10.5194/cp-18-1011-2022, 2022
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We present a melt event record from an ice core from central Greenland, which covers the past 10 000 years. Our record displays warm summer events, which can be used to enhance our understanding of the past climate. We compare our data to anomalies in tree ring width, which also represents summer temperatures, and find a good correlation. Furthermore, we investigate an outstandingly warm event in the year 986 AD or 991 AD, which has not been analyzed before.
Saehee Lim, Meehye Lee, Joel Savarino, and Paolo Laj
Atmos. Chem. Phys., 22, 5099–5115, https://doi.org/10.5194/acp-22-5099-2022, https://doi.org/10.5194/acp-22-5099-2022, 2022
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We determined δ15N(NO3−) and Δ17O(NO3−) of PM2.5 in Seoul during 2018–2019 and estimated quantitatively the contribution of oxidation pathways to NO3− formation and NOx emission sources. The nighttime pathway played a significant role in NO3− formation during the winter, and its contribution further increased up to 70 % on haze days when PM2.5 was greater than 75 µg m−3. Vehicle emissions were confirmed as a main NO3− source with an increasing contribution from coal combustion in winter.
Zhuang Jiang, Becky Alexander, Joel Savarino, Joseph Erbland, and Lei Geng
The Cryosphere, 15, 4207–4220, https://doi.org/10.5194/tc-15-4207-2021, https://doi.org/10.5194/tc-15-4207-2021, 2021
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We used a snow photochemistry model (TRANSITS) to simulate the seasonal nitrate snow profile at Summit, Greenland. Comparisons between model outputs and observations suggest that at Summit post-depositional processing is active and probably dominates the snowpack δ15N seasonality. We also used the model to assess the degree of snow nitrate loss and the consequences in its isotopes at present and in the past, which helps for quantitative interpretations of ice-core nitrate records.
Helle Astrid Kjær, Lisa Lolk Hauge, Marius Simonsen, Zurine Yoldi, Iben Koldtoft, Maria Hörhold, Johannes Freitag, Sepp Kipfstuhl, Anders Svensson, and Paul Vallelonga
The Cryosphere, 15, 3719–3730, https://doi.org/10.5194/tc-15-3719-2021, https://doi.org/10.5194/tc-15-3719-2021, 2021
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Ice core analyses are often done in home laboratories after costly transport of samples from the field. This limits the amount of sample that can be analysed.
Here, we present the first truly field-portable continuous flow analysis (CFA) system for the analysis of impurities in snow, firn and ice cores while still in the field: the lightweight in situ analysis (LISA) box.
LISA is demonstrated in Greenland to reconstruct accumulation, conductivity and peroxide in snow cores.
Sarah Albertin, Joël Savarino, Slimane Bekki, Albane Barbero, and Nicolas Caillon
Atmos. Chem. Phys., 21, 10477–10497, https://doi.org/10.5194/acp-21-10477-2021, https://doi.org/10.5194/acp-21-10477-2021, 2021
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We report an efficient method to collect atmospheric NO2 adapted for multi-isotopic analysis and present the first NO2 triple oxygen and double nitrogen isotope measurements. Atmospheric samplings carried out in Grenoble, France, highlight the NO2 isotopic signature sensitivity to the local NOx emissions and chemical regimes. These preliminary results are very promising for using the combination of Δ17O and δ15N of NO2 as a probe of the atmospheric NOx emissions and chemistry.
Bette L. Otto-Bliesner, Esther C. Brady, Anni Zhao, Chris M. Brierley, Yarrow Axford, Emilie Capron, Aline Govin, Jeremy S. Hoffman, Elizabeth Isaacs, Masa Kageyama, Paolo Scussolini, Polychronis C. Tzedakis, Charles J. R. Williams, Eric Wolff, Ayako Abe-Ouchi, Pascale Braconnot, Silvana Ramos Buarque, Jian Cao, Anne de Vernal, Maria Vittoria Guarino, Chuncheng Guo, Allegra N. LeGrande, Gerrit Lohmann, Katrin J. Meissner, Laurie Menviel, Polina A. Morozova, Kerim H. Nisancioglu, Ryouta O'ishi, David Salas y Mélia, Xiaoxu Shi, Marie Sicard, Louise Sime, Christian Stepanek, Robert Tomas, Evgeny Volodin, Nicholas K. H. Yeung, Qiong Zhang, Zhongshi Zhang, and Weipeng Zheng
Clim. Past, 17, 63–94, https://doi.org/10.5194/cp-17-63-2021, https://doi.org/10.5194/cp-17-63-2021, 2021
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The CMIP6–PMIP4 Tier 1 lig127k experiment was designed to address the climate responses to strong orbital forcing. We present a multi-model ensemble of 17 climate models, most of which have also completed the CMIP6 DECK experiments and are thus important for assessing future projections. The lig127ksimulations show strong summer warming over the NH continents. More than half of the models simulate a retreat of the Arctic minimum summer ice edge similar to the average for 2000–2018.
Helle Astrid Kjær, Patrick Zens, Ross Edwards, Martin Olesen, Ruth Mottram, Gabriel Lewis, Christian Terkelsen Holme, Samuel Black, Kasper Holst Lund, Mikkel Schmidt, Dorthe Dahl-Jensen, Bo Vinther, Anders Svensson, Nanna Karlsson, Jason E. Box, Sepp Kipfstuhl, and Paul Vallelonga
The Cryosphere Discuss., https://doi.org/10.5194/tc-2020-337, https://doi.org/10.5194/tc-2020-337, 2021
Manuscript not accepted for further review
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We have reconstructed accumulation in 6 firn cores and 8 snow cores in Northern Greenland and compared with a regional Climate model over Greenland. We find the model underestimate precipitation especially in north-eastern part of the ice cap- an important finding if aiming to reconstruct surface mass balance.
Temperatures at 10 meters depth at 6 sites in Greenland were also determined and show a significant warming since the 1990's of 0.9 to 2.5 °C.
Seyedhamidreza Mojtabavi, Frank Wilhelms, Eliza Cook, Siwan M. Davies, Giulia Sinnl, Mathias Skov Jensen, Dorthe Dahl-Jensen, Anders Svensson, Bo M. Vinther, Sepp Kipfstuhl, Gwydion Jones, Nanna B. Karlsson, Sergio Henrique Faria, Vasileios Gkinis, Helle Astrid Kjær, Tobias Erhardt, Sarah M. P. Berben, Kerim H. Nisancioglu, Iben Koldtoft, and Sune Olander Rasmussen
Clim. Past, 16, 2359–2380, https://doi.org/10.5194/cp-16-2359-2020, https://doi.org/10.5194/cp-16-2359-2020, 2020
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We present a first chronology for the East Greenland Ice-core Project (EGRIP) over the Holocene and last glacial termination. After field measurements and processing of the ice-core data, the GICC05 timescale is transferred from the NGRIP core to the EGRIP core by means of matching volcanic events and common patterns (381 match points) in the ECM and DEP records. The new timescale is named GICC05-EGRIP-1 and extends back to around 15 kyr b2k.
Alexander H. Weinhart, Johannes Freitag, Maria Hörhold, Sepp Kipfstuhl, and Olaf Eisen
The Cryosphere, 14, 3663–3685, https://doi.org/10.5194/tc-14-3663-2020, https://doi.org/10.5194/tc-14-3663-2020, 2020
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From 1 m snow profiles along a traverse on the East Antarctic Plateau, we calculated a representative surface snow density of 355 kg m−3 for this region with an error less than 1.5 %.
This density is 10 % higher and density fluctuations seem to happen on smaller scales than climate model outputs suggest. Our study can help improve the parameterization of surface snow density in climate models to reduce the error in future sea level predictions.
Jean-Louis Bonne, Hanno Meyer, Melanie Behrens, Julia Boike, Sepp Kipfstuhl, Benjamin Rabe, Toni Schmidt, Lutz Schönicke, Hans Christian Steen-Larsen, and Martin Werner
Atmos. Chem. Phys., 20, 10493–10511, https://doi.org/10.5194/acp-20-10493-2020, https://doi.org/10.5194/acp-20-10493-2020, 2020
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This study introduces 2 years of continuous near-surface in situ observations of the stable isotopic composition of water vapour in parallel with precipitation in north-eastern Siberia. We evaluate the atmospheric transport of moisture towards the region of our observations with simulations constrained by meteorological reanalyses and use this information to interpret the temporal variations of the vapour isotopic composition from seasonal to synoptic timescales.
Anders Svensson, Dorthe Dahl-Jensen, Jørgen Peder Steffensen, Thomas Blunier, Sune O. Rasmussen, Bo M. Vinther, Paul Vallelonga, Emilie Capron, Vasileios Gkinis, Eliza Cook, Helle Astrid Kjær, Raimund Muscheler, Sepp Kipfstuhl, Frank Wilhelms, Thomas F. Stocker, Hubertus Fischer, Florian Adolphi, Tobias Erhardt, Michael Sigl, Amaelle Landais, Frédéric Parrenin, Christo Buizert, Joseph R. McConnell, Mirko Severi, Robert Mulvaney, and Matthias Bigler
Clim. Past, 16, 1565–1580, https://doi.org/10.5194/cp-16-1565-2020, https://doi.org/10.5194/cp-16-1565-2020, 2020
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We identify signatures of large bipolar volcanic eruptions in Greenland and Antarctic ice cores during the last glacial period, which allows for a precise temporal alignment of the ice cores. Thereby the exact timing of unexplained, abrupt climatic changes occurring during the last glacial period can be determined in a global context. The study thus provides a step towards a full understanding of elements of the climate system that may also play an important role in the future.
Albane Barbero, Camille Blouzon, Joël Savarino, Nicolas Caillon, Aurélien Dommergue, and Roberto Grilli
Atmos. Meas. Tech., 13, 4317–4331, https://doi.org/10.5194/amt-13-4317-2020, https://doi.org/10.5194/amt-13-4317-2020, 2020
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In this paper, we present a compact, affordable and robust instrument for in situ measurements of different trace gases: NOx, IO, CHOCHO and O3 with very low detection limits. The device weighs 15 kg and has a total electrical power consumption of < 300 W. Its very low detection limits and its design make it suitable for field applications to address different questions such as how to better constrain the oxidative capacity of the atmosphere and study the chemistry of highly reactive species.
V. Holly L. Winton, Alison Ming, Nicolas Caillon, Lisa Hauge, Anna E. Jones, Joel Savarino, Xin Yang, and Markus M. Frey
Atmos. Chem. Phys., 20, 5861–5885, https://doi.org/10.5194/acp-20-5861-2020, https://doi.org/10.5194/acp-20-5861-2020, 2020
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The transfer of the nitrogen stable isotopic composition in nitrate between the air and snow at low accumulation sites in Antarctica leaves an UV imprint in the snow. Quantifying how nitrate isotope values change allows us to interpret longer ice core records. Based on nitrate observations and modelling at Kohnen, East Antarctica, the dominant factors controlling the nitrate isotope signature in deep snow layers are the depth of light penetration into the snowpack and the snow accumulation rate.
Markus M. Frey, Sarah J. Norris, Ian M. Brooks, Philip S. Anderson, Kouichi Nishimura, Xin Yang, Anna E. Jones, Michelle G. Nerentorp Mastromonaco, David H. Jones, and Eric W. Wolff
Atmos. Chem. Phys., 20, 2549–2578, https://doi.org/10.5194/acp-20-2549-2020, https://doi.org/10.5194/acp-20-2549-2020, 2020
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A winter sea ice expedition to Antarctica provided the first direct observations of sea salt aerosol (SSA) production during snow storms above sea ice, thereby validating a model hypothesis to account for winter time SSA maxima in Antarctica not explained otherwise. Defining SSA sources is important given the critical roles that aerosol plays for climate, for air quality and as a potential ice core proxy for sea ice conditions in the past.
Detlev Helmig, Daniel Liptzin, Jacques Hueber, and Joel Savarino
The Cryosphere, 14, 199–209, https://doi.org/10.5194/tc-14-199-2020, https://doi.org/10.5194/tc-14-199-2020, 2020
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We present 15 months of trace gas observations from air withdrawn within the snowpack and from above the snow at Concordia Station in Antarctica. The data show occasional positive spikes, indicative of pollution from the station generator. The pollution signal can be seen in snowpack air shortly after it is observed above the snow surface, and lasting for up to several days, much longer than above the surface.
Laurie Menviel, Emilie Capron, Aline Govin, Andrea Dutton, Lev Tarasov, Ayako Abe-Ouchi, Russell N. Drysdale, Philip L. Gibbard, Lauren Gregoire, Feng He, Ruza F. Ivanovic, Masa Kageyama, Kenji Kawamura, Amaelle Landais, Bette L. Otto-Bliesner, Ikumi Oyabu, Polychronis C. Tzedakis, Eric Wolff, and Xu Zhang
Geosci. Model Dev., 12, 3649–3685, https://doi.org/10.5194/gmd-12-3649-2019, https://doi.org/10.5194/gmd-12-3649-2019, 2019
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As part of the Past Global Changes (PAGES) working group on Quaternary Interglacials, we propose a protocol to perform transient simulations of the penultimate deglaciation for the Paleoclimate Modelling Intercomparison Project (PMIP4). This design includes time-varying changes in orbital forcing, greenhouse gas concentrations, continental ice sheets as well as freshwater input from the disintegration of continental ice sheets. Key paleo-records for model-data comparison are also included.
Xin Yang, Markus M. Frey, Rachael H. Rhodes, Sarah J. Norris, Ian M. Brooks, Philip S. Anderson, Kouichi Nishimura, Anna E. Jones, and Eric W. Wolff
Atmos. Chem. Phys., 19, 8407–8424, https://doi.org/10.5194/acp-19-8407-2019, https://doi.org/10.5194/acp-19-8407-2019, 2019
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This is a comprehensive model–data comparison aiming to evaluate the proposed mechanism of sea salt aerosol (SSA) production from blowing snow on sea ice. Some key parameters such as snow salinity and blowing-snow size distribution were constrained by data collected in the Weddell Sea. The good agreement between modelled SSA and the cruise data strongly indicates that sea ice surface is a large SSA source in polar regions, a process which has not been considered in current climate models.
Samuel A. Atwood, Sonia M. Kreidenweis, Paul J. DeMott, Markus D. Petters, Gavin C. Cornwell, Andrew C. Martin, and Kathryn A. Moore
Atmos. Chem. Phys., 19, 6931–6947, https://doi.org/10.5194/acp-19-6931-2019, https://doi.org/10.5194/acp-19-6931-2019, 2019
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This paper presents measurements of aerosol particles at a coastal location. The particles were classified into distinct aerosol types using both microphysical measurements and meteorological information, allowing rapid changes between the aerosol types to be reliably identified. These particles can alter cloud and precipitation processes, and inclusion of the differences between types can improve atmospheric models and remote sensing retrievals in littoral zones.
Tetsuro Taranczewski, Johannes Freitag, Olaf Eisen, Bo Vinther, Sonja Wahl, and Sepp Kipfstuhl
The Cryosphere Discuss., https://doi.org/10.5194/tc-2018-280, https://doi.org/10.5194/tc-2018-280, 2019
Preprint withdrawn
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We used melt layers detected in ice cores from the Renland ice cap in East Greenland to find evidence of past climate trends in this region. Our record provides such information for the past 10,000 years. We developed an attempt to increase the reliability of such a record by correcting deformation-induced biases. It proves that such simple to obtain melt records can be used to gather information about paleoclimate especially for regions where climate records are sparse.
Tommaso Galeazzo, Slimane Bekki, Erwan Martin, Joël Savarino, and Stephen R. Arnold
Atmos. Chem. Phys., 18, 17909–17931, https://doi.org/10.5194/acp-18-17909-2018, https://doi.org/10.5194/acp-18-17909-2018, 2018
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Volcanic sulfur can have climatic impacts for the planet via sulfate aerosol formation, leading also to pollution events. We provide model constraints on tropospheric volcanic sulfate formation, with implications for its lifetime and impacts on regional air quality. Oxygen isotope investigations from our model suggest that in the poor tropospheric plumes of halogens, the O2/TMI sulfur oxidation pathway might significantly control sulfate production. The produced sulfate has no isotopic anomaly.
Shaojie Song, Hélène Angot, Noelle E. Selin, Hubert Gallée, Francesca Sprovieri, Nicola Pirrone, Detlev Helmig, Joël Savarino, Olivier Magand, and Aurélien Dommergue
Atmos. Chem. Phys., 18, 15825–15840, https://doi.org/10.5194/acp-18-15825-2018, https://doi.org/10.5194/acp-18-15825-2018, 2018
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Mercury is a trace metal with adverse health effects on human and wildlife. Its unique property makes it undergo long-range transport, and even remote Antarctica receives significant inputs. This paper presents the first model that aims to understand mercury behavior over the Antarctic Plateau. We find that mercury is quickly cycled between snow and air in the sunlit period, likely driven by bromine chemistry, and that several uncertain processes contribute to its behavior in the dark period.
Laurie Menviel, Emilie Capron, Aline Govin, Andrea Dutton, Lev Tarasov, Ayako Abe-Ouchi, Russell Drysdale, Philip Gibbard, Lauren Gregoire, Feng He, Ruza Ivanovic, Masa Kageyama, Kenji Kawamura, Amaelle Landais, Bette L. Otto-Bliesner, Ikumi Oyabu, Polychronis Tzedakis, Eric Wolff, and Xu Zhang
Clim. Past Discuss., https://doi.org/10.5194/cp-2018-106, https://doi.org/10.5194/cp-2018-106, 2018
Preprint withdrawn
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The penultimate deglaciation (~ 138–128 ka), which represents the transition into the Last Interglacial period, provides a framework to investigate the climate and environmental response to large changes in boundary conditions. Here, as part of the PAGES-PMIP working group on Quaternary Interglacials, we propose a protocol to perform transient simulations of the penultimate deglaciation as well as a selection of paleo records for upcoming model-data comparisons.
James W. B. Rae and Wally Broecker
Biogeosciences, 15, 3779–3794, https://doi.org/10.5194/bg-15-3779-2018, https://doi.org/10.5194/bg-15-3779-2018, 2018
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The deep ocean is the major store of heat and carbon in Earth's surface environment and thus has a major impact on climate. Waters that fill the deep ocean come from the North Atlantic and the Southern Ocean, but there is debate on their relative importance. Here we reconcile previous estimates using deep sea phosphate and oxygen data. We show that although a large volume of deep water comes from the south, this does not spend enough time in the southern surface to fully exchange heat and CO2.
Nancy A. N. Bertler, Howard Conway, Dorthe Dahl-Jensen, Daniel B. Emanuelsson, Mai Winstrup, Paul T. Vallelonga, James E. Lee, Ed J. Brook, Jeffrey P. Severinghaus, Taylor J. Fudge, Elizabeth D. Keller, W. Troy Baisden, Richard C. A. Hindmarsh, Peter D. Neff, Thomas Blunier, Ross Edwards, Paul A. Mayewski, Sepp Kipfstuhl, Christo Buizert, Silvia Canessa, Ruzica Dadic, Helle A. Kjær, Andrei Kurbatov, Dongqi Zhang, Edwin D. Waddington, Giovanni Baccolo, Thomas Beers, Hannah J. Brightley, Lionel Carter, David Clemens-Sewall, Viorela G. Ciobanu, Barbara Delmonte, Lukas Eling, Aja Ellis, Shruthi Ganesh, Nicholas R. Golledge, Skylar Haines, Michael Handley, Robert L. Hawley, Chad M. Hogan, Katelyn M. Johnson, Elena Korotkikh, Daniel P. Lowry, Darcy Mandeno, Robert M. McKay, James A. Menking, Timothy R. Naish, Caroline Noerling, Agathe Ollive, Anaïs Orsi, Bernadette C. Proemse, Alexander R. Pyne, Rebecca L. Pyne, James Renwick, Reed P. Scherer, Stefanie Semper, Marius Simonsen, Sharon B. Sneed, Eric J. Steig, Andrea Tuohy, Abhijith Ulayottil Venugopal, Fernando Valero-Delgado, Janani Venkatesh, Feitang Wang, Shimeng Wang, Dominic A. Winski, V. Holly L. Winton, Arran Whiteford, Cunde Xiao, Jiao Yang, and Xin Zhang
Clim. Past, 14, 193–214, https://doi.org/10.5194/cp-14-193-2018, https://doi.org/10.5194/cp-14-193-2018, 2018
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Temperature and snow accumulation records from the annually dated Roosevelt Island Climate Evolution (RICE) ice core show that for the past 2 700 years, the eastern Ross Sea warmed, while the western Ross Sea showed no trend and West Antarctica cooled. From the 17th century onwards, this dipole relationship changed. Now all three regions show concurrent warming, with snow accumulation declining in West Antarctica and the eastern Ross Sea.
Thomas Laepple, Thomas Münch, Mathieu Casado, Maria Hoerhold, Amaelle Landais, and Sepp Kipfstuhl
The Cryosphere, 12, 169–187, https://doi.org/10.5194/tc-12-169-2018, https://doi.org/10.5194/tc-12-169-2018, 2018
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We explain why snow pits across different sites in East Antarctica show visually similar isotopic variations. We argue that the similarity and the apparent cycles of around 20 cm in the δD and δ18O variations are the result of a seasonal cycle in isotopes, noise, for example from precipitation intermittency, and diffusion. The near constancy of the diffusion length across many ice-coring sites explains why the structure and cycle length is largely independent of the accumulation conditions.
Tim Carlsen, Gerit Birnbaum, André Ehrlich, Johannes Freitag, Georg Heygster, Larysa Istomina, Sepp Kipfstuhl, Anaïs Orsi, Michael Schäfer, and Manfred Wendisch
The Cryosphere, 11, 2727–2741, https://doi.org/10.5194/tc-11-2727-2017, https://doi.org/10.5194/tc-11-2727-2017, 2017
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The optical size of snow grains (ropt) affects the reflectivity of snow surfaces and thus the local surface energy budget in particular in polar regions. The temporal evolution of ropt retrieved from ground-based, airborne, and spaceborne remote sensing could reproduce optical in situ measurements for a 2-month period in central Antarctica (2013/14). The presented validation study provided a unique testbed for retrievals of ropt under Antarctic conditions where in situ data are scarce.
Michel Legrand, Susanne Preunkert, Eric Wolff, Rolf Weller, Bruno Jourdain, and Dietmar Wagenbach
Atmos. Chem. Phys., 17, 14039–14054, https://doi.org/10.5194/acp-17-14039-2017, https://doi.org/10.5194/acp-17-14039-2017, 2017
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Multiple year-round records of bulk and size-segregated composition of sea-salt aerosol and acidic gases (HCl and HNO3) were obtained at inland Antarctica. Both acidic sulfur particles and nitric acid are involved in the observed sea-salt dechlorination in spring/summer. The observed sulfate to sodium mass ratio of sea-salt aerosol in winter (0.16 ± 0.05) suggests on average a similar contribution of sea-ice and open-ocean emissions to the sea-salt load over inland Antarctica at that season.
Thomas Münch, Sepp Kipfstuhl, Johannes Freitag, Hanno Meyer, and Thomas Laepple
The Cryosphere, 11, 2175–2188, https://doi.org/10.5194/tc-11-2175-2017, https://doi.org/10.5194/tc-11-2175-2017, 2017
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The importance of post-depositional changes for the temperature interpretation of water isotopes is poorly constrained by observations. Here, for the first time, temporal isotope changes in the open-porous firn are directly analysed using a large array of shallow isotope profiles. By this, we can reject the possibility of post-depositional change beyond diffusion and densification as the cause of the discrepancy between isotope and local temperature variations at Kohnen Station, East Antarctica.
Ilka Weikusat, Ernst-Jan N. Kuiper, Gill M. Pennock, Sepp Kipfstuhl, and Martyn R. Drury
Solid Earth, 8, 883–898, https://doi.org/10.5194/se-8-883-2017, https://doi.org/10.5194/se-8-883-2017, 2017
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Understanding the flow of large ice masses on Earth is a major challenge in our changing climate. Deformation mechanisms are governed by the strong anisotropy of ice. As anisotropy is currently moving into the focus of ice sheet flow studies, we provide a detailed analysis of microstructure data from natural ice core samples which directly relate to anisotropic plasticity. Our findings reveal surprising dislocation activity which seems to contradict the concept of macroscopic ice anisotropy.
Rachael H. Rhodes, Xin Yang, Eric W. Wolff, Joseph R. McConnell, and Markus M. Frey
Atmos. Chem. Phys., 17, 9417–9433, https://doi.org/10.5194/acp-17-9417-2017, https://doi.org/10.5194/acp-17-9417-2017, 2017
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Sea salt aerosol comes from the open ocean or the sea ice surface. In the polar regions, this opens up the possibility of reconstructing sea ice history using sea salt recorded in ice cores. We use a chemical transport model to demonstrate that the sea ice source of aerosol is important in the Arctic. For the first time, we simulate realistic Greenland ice core sea salt in a process-based model. The importance of the sea ice source increases from south to north across the Greenland ice sheet.
Jan Eichler, Ina Kleitz, Maddalena Bayer-Giraldi, Daniela Jansen, Sepp Kipfstuhl, Wataru Shigeyama, Christian Weikusat, and Ilka Weikusat
The Cryosphere, 11, 1075–1090, https://doi.org/10.5194/tc-11-1075-2017, https://doi.org/10.5194/tc-11-1075-2017, 2017
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This study contributes to investigations of the effect of impurities on ice microstructure and flow properties. For the first time we mapped over 5000 micro-inclusions in four samples from the EDML and NEEM polar ice cores. The particle distributions show no correlation with grain boundaries and thus we conclude that particle pinning plays only a secondary role for the microstructure evolution. Alternative mechanisms are discussed.
Sakiko Ishino, Shohei Hattori, Joel Savarino, Bruno Jourdain, Susanne Preunkert, Michel Legrand, Nicolas Caillon, Albane Barbero, Kota Kuribayashi, and Naohiro Yoshida
Atmos. Chem. Phys., 17, 3713–3727, https://doi.org/10.5194/acp-17-3713-2017, https://doi.org/10.5194/acp-17-3713-2017, 2017
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We show the first simultaneous observations of triple oxygen isotopic compositions of atmospheric sulfate, nitrate, and ozone at Dumont d'Urville, coastal Antarctica. The contrasting seasonal trends between oxygen isotopes of ozone and those of sulfate and nitrate indicate that these signatures in sulfate and nitrate are mainly controlled by changes in oxidation chemistry. We also discuss the specific oxidation chemistry induced by the unique phenomena at the site.
Andrew C. Martin, Gavin C. Cornwell, Samuel A. Atwood, Kathryn A. Moore, Nicholas E. Rothfuss, Hans Taylor, Paul J. DeMott, Sonia M. Kreidenweis, Markus D. Petters, and Kimberly A. Prather
Atmos. Chem. Phys., 17, 1491–1509, https://doi.org/10.5194/acp-17-1491-2017, https://doi.org/10.5194/acp-17-1491-2017, 2017
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Anthropogenic influence on air quality, aerosol properties, and cloud activity was observed at Bodega Bay, CA, during periods when air from California's interior was transported to the coast. The sudden change in aerosol properties can impact atmospheric radiative balance and cloud formation in ways that must be accounted for in regional climate simulations.
Michel Legrand, Joseph McConnell, Hubertus Fischer, Eric W. Wolff, Susanne Preunkert, Monica Arienzo, Nathan Chellman, Daiana Leuenberger, Olivia Maselli, Philip Place, Michael Sigl, Simon Schüpbach, and Mike Flannigan
Clim. Past, 12, 2033–2059, https://doi.org/10.5194/cp-12-2033-2016, https://doi.org/10.5194/cp-12-2033-2016, 2016
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Here, we review previous attempts made to reconstruct past forest fire using chemical signals recorded in Greenland ice. We showed that the Greenland ice records of ammonium, found to be a good fire proxy, consistently indicate changing fire activity in Canada in response to past climatic conditions that occurred since the last 15 000 years, including the Little Ice Age and the last large climatic transition.
Josué Bock, Joël Savarino, and Ghislain Picard
Atmos. Chem. Phys., 16, 12531–12550, https://doi.org/10.5194/acp-16-12531-2016, https://doi.org/10.5194/acp-16-12531-2016, 2016
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We develop a physically based parameterisation of the co-condensation process. Our model includes solid-state diffusion within a snow grain. It reproduces with good agreement the nitrate measurement in surface snow. Winter and summer concentrations are driven respectively by thermodynamic equilibrium and co-condensation. Adsorbed nitrate likely accounts for a minor part. This work shows that co-condensation is required to explain the chemical composition of snow undergoing temperature gradient.
Emma J. Stone, Emilie Capron, Daniel J. Lunt, Antony J. Payne, Joy S. Singarayer, Paul J. Valdes, and Eric W. Wolff
Clim. Past, 12, 1919–1932, https://doi.org/10.5194/cp-12-1919-2016, https://doi.org/10.5194/cp-12-1919-2016, 2016
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Climate models forced only with greenhouse gas concentrations and orbital parameters representative of the early Last Interglacial are unable to reproduce the observed colder-than-present temperatures in the North Atlantic and the warmer-than-present temperatures in the Southern Hemisphere. Using a climate model forced also with a freshwater amount derived from data representing melting from the remnant Northern Hemisphere ice sheets accounts for this response via the bipolar seesaw mechanism.
Christoph Florian Schaller, Johannes Freitag, Sepp Kipfstuhl, Thomas Laepple, Hans Christian Steen-Larsen, and Olaf Eisen
The Cryosphere, 10, 1991–2002, https://doi.org/10.5194/tc-10-1991-2016, https://doi.org/10.5194/tc-10-1991-2016, 2016
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Along a traverse through North Greenland in May 2015 we collected snow cores up to 2 m in depth and analyzed their properties (e.g., density). A new technique for this sampling and an adapted algorithm for comparing data sets from different positions and aligning stratigraphic features are presented. We find good agreement of the density layering in the snowpack over hundreds of kilometers. This allows the construction of a representative density profile that is statistically validated.
Ruza F. Ivanovic, Lauren J. Gregoire, Masa Kageyama, Didier M. Roche, Paul J. Valdes, Andrea Burke, Rosemarie Drummond, W. Richard Peltier, and Lev Tarasov
Geosci. Model Dev., 9, 2563–2587, https://doi.org/10.5194/gmd-9-2563-2016, https://doi.org/10.5194/gmd-9-2563-2016, 2016
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This manuscript presents the experiment design for the PMIP4 Last Deglaciation Core experiment: a transient simulation of the last deglaciation, 21–9 ka. Specified model boundary conditions include time-varying orbital parameters, greenhouse gases, ice sheets, ice meltwater fluxes and other geographical changes (provided for 26–0 ka). The context of the experiment and the choices for the boundary conditions are explained, along with the future direction of the working group.
François Ritter, Hans Christian Steen-Larsen, Martin Werner, Valérie Masson-Delmotte, Anais Orsi, Melanie Behrens, Gerit Birnbaum, Johannes Freitag, Camille Risi, and Sepp Kipfstuhl
The Cryosphere, 10, 1647–1663, https://doi.org/10.5194/tc-10-1647-2016, https://doi.org/10.5194/tc-10-1647-2016, 2016
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We present successful continuous measurements of water vapor isotopes performed in Antarctica in January 2013. The interest is to understand the impact of the water vapor isotopic composition on the near-surface snow isotopes. Our study reveals a diurnal cycle in the snow isotopic composition in phase with the vapor. This finding suggests fractionation during the sublimation of the ice, which has an important consequence on the interpretation of water isotope variations in ice cores.
Thomas Münch, Sepp Kipfstuhl, Johannes Freitag, Hanno Meyer, and Thomas Laepple
Clim. Past, 12, 1565–1581, https://doi.org/10.5194/cp-12-1565-2016, https://doi.org/10.5194/cp-12-1565-2016, 2016
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Ice-core oxygen isotope ratios are a key climate archive to infer past temperatures, an interpretation however complicated by non-climatic noise. Based on 50 m firn trenches, we present for the first time a two-dimensional view (vertical × horizontal) of how oxygen isotopes are stored in Antarctic firn. A statistical noise model allows inferences for the validity of ice coring efforts to reconstruct past temperatures, highlighting the need of replicate cores for Holocene climate reconstructions.
Sara D. Forestieri, Gavin C. Cornwell, Taylor M. Helgestad, Kathryn A. Moore, Christopher Lee, Gordon A. Novak, Camille M. Sultana, Xiaofei Wang, Timothy H. Bertram, Kimberly A. Prather, and Christopher D. Cappa
Atmos. Chem. Phys., 16, 9003–9018, https://doi.org/10.5194/acp-16-9003-2016, https://doi.org/10.5194/acp-16-9003-2016, 2016
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Hygroscopic growth factors at 85 % relative humidity (GF(85 %)) were quantified along with particle composition for primary sea spray aerosol (SSA) particles generated in marine aerosol reference tanks (MARTs) from seawater in which two independent phytoplankton blooms were induced. The observed 5 to 15 % depression in the GF(85 %) values (relative to pure sea salt) is consistent with the large observed volume fractions of non-refractory organic matter (NR-OM) comprising the SSA.
Michel Legrand, Susanne Preunkert, Joël Savarino, Markus M. Frey, Alexandre Kukui, Detlev Helmig, Bruno Jourdain, Anna E. Jones, Rolf Weller, Neil Brough, and Hubert Gallée
Atmos. Chem. Phys., 16, 8053–8069, https://doi.org/10.5194/acp-16-8053-2016, https://doi.org/10.5194/acp-16-8053-2016, 2016
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Surface ozone, the most abundant atmospheric oxidant, has been measured since 2004 at the coastal East Antarctic site of Dumont d’Urville, and since 2007 at the Concordia station located on the high East Antarctic plateau. Long-term changes, seasonal and diurnal cycles, as well as inter-annual summer variability observed at these two East Antarctic sites are discussed. Influences like sea ice extent and outflow from inland Antarctica are discussed.
Alexandra Touzeau, Amaëlle Landais, Barbara Stenni, Ryu Uemura, Kotaro Fukui, Shuji Fujita, Sarah Guilbaud, Alexey Ekaykin, Mathieu Casado, Eugeni Barkan, Boaz Luz, Olivier Magand, Grégory Teste, Emmanuel Le Meur, Mélanie Baroni, Joël Savarino, Ilann Bourgeois, and Camille Risi
The Cryosphere, 10, 837–852, https://doi.org/10.5194/tc-10-837-2016, https://doi.org/10.5194/tc-10-837-2016, 2016
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The relationship between water isotope ratios and temperature is investigated in precipitation snow at Vostok and Dome C, as well as in surface snow along traverses. The temporal slope of the linear regression for the precipitation is smaller than the geographical slope. Thus, using the latter could lead to an underestimation of past temperature changes. The processes active at remote sites (best glacial analogs) are explored through a combination of water isotopes in short snow pits.
Ikumi Oyabu, Yoshinori Iizuka, Eric Wolff, and Margareta Hansson
Clim. Past Discuss., https://doi.org/10.5194/cp-2016-42, https://doi.org/10.5194/cp-2016-42, 2016
Manuscript not accepted for further review
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This study presented the chemical compositions of non-volatile particles around the last termination in the Dome C ice core by using the sublimation-EDS method. The major soluble salt particles are CaSO4, Na2SO4, and NaCl, and time-series changes in the composition of these salts are similar to those for the Dome Fuji ice core. However, some differences occurred. The sulfatization rate of NaCl at Dome C is higher than that at Dome Fuji.
Joël Savarino, William C. Vicars, Michel Legrand, Suzanne Preunkert, Bruno Jourdain, Markus M. Frey, Alexandre Kukui, Nicolas Caillon, and Jaime Gil Roca
Atmos. Chem. Phys., 16, 2659–2673, https://doi.org/10.5194/acp-16-2659-2016, https://doi.org/10.5194/acp-16-2659-2016, 2016
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Atmospheric nitrate is collected on the East Antarctic ice sheet. Nitrogen and oxygen stable isotopes and concentrations of nitrate are measured. Using a box model, we show that there is s systematic discrepancy between observations and model results. We suggest that this discrepancy probably results from unknown NOx chemistry above the Antarctic ice sheet. However, possible misconception in the stable isotope mass balance is not completely excluded.
D. Jansen, M.-G. Llorens, J. Westhoff, F. Steinbach, S. Kipfstuhl, P. D. Bons, A. Griera, and I. Weikusat
The Cryosphere, 10, 359–370, https://doi.org/10.5194/tc-10-359-2016, https://doi.org/10.5194/tc-10-359-2016, 2016
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In this study we present examples of typical small-scale folds observed in the NEEM ice core, North Greenland, and discuss their characteristics. Numerical modelling of viscoplastic deformation and dynamic recrystallisation was used to improve the understanding of the formation of the observed structures under simple shear boundary conditions. We conclude that the folds originate from bands of grains with a tilted lattice relative to the strong lattice preferred orientation below 1500 m depth.
S. Weißbach, A. Wegner, T. Opel, H. Oerter, B. M. Vinther, and S. Kipfstuhl
Clim. Past, 12, 171–188, https://doi.org/10.5194/cp-12-171-2016, https://doi.org/10.5194/cp-12-171-2016, 2016
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Based on a set of 12 intermediate deep ice cores, covering an area of about 200 000 km2, we studied the spatial and temporal d18O patterns of northern Greenland over the past millennium and found a strong east-west gradient related to the main ice divide. A stacked record with significantly reduced noise revealed distinct climate variations with a pronounced Little Ice Age and distinct warm events such as the Medieval Climate Anomaly, around AD 1420 and in the 20th century.
E. Gautier, J. Savarino, J. Erbland, A. Lanciki, and P. Possenti
Clim. Past, 12, 103–113, https://doi.org/10.5194/cp-12-103-2016, https://doi.org/10.5194/cp-12-103-2016, 2016
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We evaluate the local-scale variability of a sulfate profile at a low-accumulation site (Dome C, Antarctica) to assess the representativeness of one ice core for volcanic reconstructions. Peak statistical occurrence, depth and flux variability are evaluated from five cores. Due to local-scale variability, 64 volcanic peaks can be identified by a five-cores analysis, while only half of them can be assessed from two cores. Using five cores, the uncertainty of the mean flux is reduced to 29 %.
J. Erbland, J. Savarino, S. Morin, J. L. France, M. M. Frey, and M. D. King
Atmos. Chem. Phys., 15, 12079–12113, https://doi.org/10.5194/acp-15-12079-2015, https://doi.org/10.5194/acp-15-12079-2015, 2015
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In this paper, we describe the development of a numerical model which aims at representing nitrate recycling at the air-snow interface on the East Antarctic Plateau. Stable isotopes are used as diagnostic and evaluation tools by comparing the model's results to recent field measurements of nitrate and key atmospheric species at Dome C, Antarctica. From sensitivity tests conducted with the model, we propose a framework for the interpretation of the nitrate isotope record in deep ice cores.
S. Fujita, F. Parrenin, M. Severi, H. Motoyama, and E. W. Wolff
Clim. Past, 11, 1395–1416, https://doi.org/10.5194/cp-11-1395-2015, https://doi.org/10.5194/cp-11-1395-2015, 2015
T. A. Berhanu, J. Savarino, J. Erbland, W. C. Vicars, S. Preunkert, J. F. Martins, and M. S. Johnson
Atmos. Chem. Phys., 15, 11243–11256, https://doi.org/10.5194/acp-15-11243-2015, https://doi.org/10.5194/acp-15-11243-2015, 2015
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In this field study at Dome C, Antarctica, we investigated the effect of solar UV photolysis on the stable isotopes of nitrate in snow via comparison of two identical snow pits while exposing only one to solar UV. From the difference between the average isotopic fractionations calculated for each pit, we determined a purely photolytic nitrogen isotopic fractionation of -55.8‰, in good agreement with what has been recently determined in a laboratory study.
A. Svensson, S. Fujita, M. Bigler, M. Braun, R. Dallmayr, V. Gkinis, K. Goto-Azuma, M. Hirabayashi, K. Kawamura, S. Kipfstuhl, H. A. Kjær, T. Popp, M. Simonsen, J. P. Steffensen, P. Vallelonga, and B. M. Vinther
Clim. Past, 11, 1127–1137, https://doi.org/10.5194/cp-11-1127-2015, https://doi.org/10.5194/cp-11-1127-2015, 2015
S. Preunkert, M. Legrand, M. M. Frey, A. Kukui, J. Savarino, H. Gallée, M. King, B. Jourdain, W. Vicars, and D. Helmig
Atmos. Chem. Phys., 15, 6689–6705, https://doi.org/10.5194/acp-15-6689-2015, https://doi.org/10.5194/acp-15-6689-2015, 2015
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During two austral summers HCHO was investigated in air, snow, and interstitial air at the Concordia site located on the East Antarctic Plateau. Snow emission fluxes were estimated to be around 1 to 2 and 3 to 5 x 10^12 molecules m-2 s-1 at night and at noon, respectively. Shading experiments suggest that the photochemical HCHO production in the snowpack at Concordia remains negligible. The mean HCHO level of 130pptv observed at 1m above the surface is quite well reproduced by 1-D simulations.
J. Christmann, R. Müller, K. G. Webber, D. Isaia, F. H. Schader, S. Kipfstuhl, J. Freitag, and A. Humbert
Earth Syst. Sci. Data, 7, 87–92, https://doi.org/10.5194/essd-7-87-2015, https://doi.org/10.5194/essd-7-87-2015, 2015
F. Parrenin, S. Fujita, A. Abe-Ouchi, K. Kawamura, V. Masson-Delmotte, H. Motoyama, F. Saito, M. Severi, B. Stenni, R. Uemura, and E. Wolff
Clim. Past Discuss., https://doi.org/10.5194/cpd-11-377-2015, https://doi.org/10.5194/cpd-11-377-2015, 2015
Revised manuscript has not been submitted
C. Elsässer, D. Wagenbach, I. Levin, A. Stanzick, M. Christl, A. Wallner, S. Kipfstuhl, I. K. Seierstad, H. Wershofen, and J. Dibb
Clim. Past, 11, 115–133, https://doi.org/10.5194/cp-11-115-2015, https://doi.org/10.5194/cp-11-115-2015, 2015
L. Geng, J. Cole-Dai, B. Alexander, J. Erbland, J. Savarino, A. J. Schauer, E. J. Steig, P. Lin, Q. Fu, and M. C. Zatko
Atmos. Chem. Phys., 14, 13361–13376, https://doi.org/10.5194/acp-14-13361-2014, https://doi.org/10.5194/acp-14-13361-2014, 2014
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Examinations on snowpit and firn core results from Summit, Greenland suggest that there are two mechanisms leading to the observed double nitrate peaks in some years in the industrial era: 1) long-rang transport of nitrate and 2) enhanced local photochemical production of nitrate. Both of these mechanisms are related to pollution transport, as the additional nitrate from either direct transport or enhanced local photochemistry requires enhanced nitrogen sources from anthropogenic emissions.
A. E. Jones, N. Brough, P. S. Anderson, and E. W. Wolff
Atmos. Chem. Phys., 14, 11843–11851, https://doi.org/10.5194/acp-14-11843-2014, https://doi.org/10.5194/acp-14-11843-2014, 2014
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We report observations of nitric acid and peroxynitric acid, in coastal Antarctica during winter. During winter, it is dark 24h per day, so there is no influence of sunlight on atmospheric composition. We show that observed variability in concentrations is highly correlated with changes in temperature. We derive enthalpies of adsorption and show they are consistent with those derived in laboratory studies. The Antarctic, during winter, is an ideal natural laboratory to study air-snow exchange.
P. Vallelonga, K. Christianson, R. B. Alley, S. Anandakrishnan, J. E. M. Christian, D. Dahl-Jensen, V. Gkinis, C. Holme, R. W. Jacobel, N. B. Karlsson, B. A. Keisling, S. Kipfstuhl, H. A. Kjær, M. E. L. Kristensen, A. Muto, L. E. Peters, T. Popp, K. L. Riverman, A. M. Svensson, C. Tibuleac, B. M. Vinther, Y. Weng, and M. Winstrup
The Cryosphere, 8, 1275–1287, https://doi.org/10.5194/tc-8-1275-2014, https://doi.org/10.5194/tc-8-1275-2014, 2014
J.-C. Gallet, F. Domine, J. Savarino, M. Dumont, and E. Brun
The Cryosphere, 8, 1205–1215, https://doi.org/10.5194/tc-8-1205-2014, https://doi.org/10.5194/tc-8-1205-2014, 2014
H. C. Steen-Larsen, V. Masson-Delmotte, M. Hirabayashi, R. Winkler, K. Satow, F. Prié, N. Bayou, E. Brun, K. M. Cuffey, D. Dahl-Jensen, M. Dumont, M. Guillevic, S. Kipfstuhl, A. Landais, T. Popp, C. Risi, K. Steffen, B. Stenni, and A. E. Sveinbjörnsdottír
Clim. Past, 10, 377–392, https://doi.org/10.5194/cp-10-377-2014, https://doi.org/10.5194/cp-10-377-2014, 2014
A. M. Foley, D. Dalmonech, A. D. Friend, F. Aires, A. T. Archibald, P. Bartlein, L. Bopp, J. Chappellaz, P. Cox, N. R. Edwards, G. Feulner, P. Friedlingstein, S. P. Harrison, P. O. Hopcroft, C. D. Jones, J. Kolassa, J. G. Levine, I. C. Prentice, J. Pyle, N. Vázquez Riveiros, E. W. Wolff, and S. Zaehle
Biogeosciences, 10, 8305–8328, https://doi.org/10.5194/bg-10-8305-2013, https://doi.org/10.5194/bg-10-8305-2013, 2013
S. O. Rasmussen, P. M. Abbott, T. Blunier, A. J. Bourne, E. Brook, S. L. Buchardt, C. Buizert, J. Chappellaz, H. B. Clausen, E. Cook, D. Dahl-Jensen, S. M. Davies, M. Guillevic, S. Kipfstuhl, T. Laepple, I. K. Seierstad, J. P. Severinghaus, J. P. Steffensen, C. Stowasser, A. Svensson, P. Vallelonga, B. M. Vinther, F. Wilhelms, and M. Winstrup
Clim. Past, 9, 2713–2730, https://doi.org/10.5194/cp-9-2713-2013, https://doi.org/10.5194/cp-9-2713-2013, 2013
H. Fischer, J. Severinghaus, E. Brook, E. Wolff, M. Albert, O. Alemany, R. Arthern, C. Bentley, D. Blankenship, J. Chappellaz, T. Creyts, D. Dahl-Jensen, M. Dinn, M. Frezzotti, S. Fujita, H. Gallee, R. Hindmarsh, D. Hudspeth, G. Jugie, K. Kawamura, V. Lipenkov, H. Miller, R. Mulvaney, F. Parrenin, F. Pattyn, C. Ritz, J. Schwander, D. Steinhage, T. van Ommen, and F. Wilhelms
Clim. Past, 9, 2489–2505, https://doi.org/10.5194/cp-9-2489-2013, https://doi.org/10.5194/cp-9-2489-2013, 2013
L. Bazin, A. Landais, B. Lemieux-Dudon, H. Toyé Mahamadou Kele, D. Veres, F. Parrenin, P. Martinerie, C. Ritz, E. Capron, V. Lipenkov, M.-F. Loutre, D. Raynaud, B. Vinther, A. Svensson, S. O. Rasmussen, M. Severi, T. Blunier, M. Leuenberger, H. Fischer, V. Masson-Delmotte, J. Chappellaz, and E. Wolff
Clim. Past, 9, 1715–1731, https://doi.org/10.5194/cp-9-1715-2013, https://doi.org/10.5194/cp-9-1715-2013, 2013
D. Veres, L. Bazin, A. Landais, H. Toyé Mahamadou Kele, B. Lemieux-Dudon, F. Parrenin, P. Martinerie, E. Blayo, T. Blunier, E. Capron, J. Chappellaz, S. O. Rasmussen, M. Severi, A. Svensson, B. Vinther, and E. W. Wolff
Clim. Past, 9, 1733–1748, https://doi.org/10.5194/cp-9-1733-2013, https://doi.org/10.5194/cp-9-1733-2013, 2013
A. Svensson, M. Bigler, T. Blunier, H. B. Clausen, D. Dahl-Jensen, H. Fischer, S. Fujita, K. Goto-Azuma, S. J. Johnsen, K. Kawamura, S. Kipfstuhl, M. Kohno, F. Parrenin, T. Popp, S. O. Rasmussen, J. Schwander, I. Seierstad, M. Severi, J. P. Steffensen, R. Udisti, R. Uemura, P. Vallelonga, B. M. Vinther, A. Wegner, F. Wilhelms, and M. Winstrup
Clim. Past, 9, 749–766, https://doi.org/10.5194/cp-9-749-2013, https://doi.org/10.5194/cp-9-749-2013, 2013
M. M. Frey, N. Brough, J. L. France, P. S. Anderson, O. Traulle, M. D. King, A. E. Jones, E. W. Wolff, and J. Savarino
Atmos. Chem. Phys., 13, 3045–3062, https://doi.org/10.5194/acp-13-3045-2013, https://doi.org/10.5194/acp-13-3045-2013, 2013
A. E. Jones, E. W. Wolff, N. Brough, S. J.-B. Bauguitte, R. Weller, M. Yela, M. Navarro-Comas, H. A. Ochoa, and N. Theys
Atmos. Chem. Phys., 13, 1457–1467, https://doi.org/10.5194/acp-13-1457-2013, https://doi.org/10.5194/acp-13-1457-2013, 2013
Related subject area
Subject: Atmospheric Dynamics | Archive: Ice Cores | Timescale: Pleistocene
Interpreting last glacial to Holocene dust changes at Talos Dome (East Antarctica): implications for atmospheric variations from regional to hemispheric scales
S. Albani, B. Delmonte, V. Maggi, C. Baroni, J.-R. Petit, B. Stenni, C. Mazzola, and M. Frezzotti
Clim. Past, 8, 741–750, https://doi.org/10.5194/cp-8-741-2012, https://doi.org/10.5194/cp-8-741-2012, 2012
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The ~ 74 ka eruption of Toba was one of the largest eruptions of the last 100 ka. We have measured the sulfur isotopic composition for 11 Toba eruption candidates in two Antarctic ice cores. Sulfur isotopes allow us to distinguish between large eruptions that have erupted material into the stratosphere and smaller ones that reach lower altitudes. Using this we have identified the events most likely to be Toba and place the eruption on the transition into a cold period in the Northern Hemisphere.
The ~ 74 ka eruption of Toba was one of the largest eruptions of the last 100 ka. We have...
