Articles | Volume 15, issue 2
https://doi.org/10.5194/cp-15-539-2019
https://doi.org/10.5194/cp-15-539-2019
Research article
 | 
27 Mar 2019
Research article |  | 27 Mar 2019

Insensitivity of alkenone carbon isotopes to atmospheric CO2 at low to moderate CO2 levels

Marcus P. S. Badger, Thomas B. Chalk, Gavin L. Foster, Paul R. Bown, Samantha J. Gibbs, Philip F. Sexton, Daniela N. Schmidt, Heiko Pälike, Andreas Mackensen, and Richard D. Pancost

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Cited articles

Ahn, J. and Brook, E. J.: Siple Dome ice reveals two modes of millennial CO2 change during the last ice age, Nat. Commun., 5, 3723, https://doi.org/10.1038/ncomms4723, 2014. 
Ahn, J., Brook, E. J., Mitchell, L., Rosen, J., McConnell, J. R., Taylor, K., Etheridge, D., and Rubino, M.: Atmospheric CO2 over the last 1000 years: A high-resolution record from the West Antarctic Ice Sheet (WAIS) Divide ice core, Global Biogeochem. Cy., 26, GB2027, https://doi.org/10.1029/2011GB004247, 2012. 
Anagnostou, E., John, E. H., Edgar, K. M., Foster, G. L., Ridgwell, A., Inglis, G. N., Pancost, R. D., Lunt, D. J., and Pearson, P. N.: Changing atmospheric CO2 concentration was the primary driver of early Cenozoic climate, Nature, 533, 380–384, https://doi.org/10.1038/nature17423, 2016. 
Andersen, N., Miiller, P. J., Kirsf, G., and Schneider, R. R.: Alkenone δ13C as a proxy for past pCO2 in surface waters: Results from the Late Quarternary Angola Current, 1999. 
Bach, L. T., Mackinder, L. C. M., Schulz, K. G., Wheeler, G., Schroeder, D. C., Brownlee, C., and Riebesell, U.: Dissecting the impact of CO2 and pH on the mechanisms of photosynthesis and calcification in the coccolithophore Emiliania huxleyi., New Phytol., 199, 121–34, https://doi.org/10.1111/nph.12225, 2013. 
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Understanding how atmospheric CO2 has affected the climate of the past is an important way of furthering our understanding of how CO2 may affect our climate in the future. There are several ways of determining CO2 in the past; in this paper, we ground-truth one method (based on preserved organic matter from alga) against the record of CO2 preserved as bubbles in ice cores over a glacial–interglacial cycle. We find that there is a discrepancy between the two.