Articles | Volume 20, issue 2
https://doi.org/10.5194/cp-20-297-2024
https://doi.org/10.5194/cp-20-297-2024
Research article
 | 
08 Feb 2024
Research article |  | 08 Feb 2024

Effective diffusivity of sulfuric acid in Antarctic ice cores

Tyler J. Fudge, Raphael Sauvage, Linh Vu, Benjamin H. Hills, Mirko Severi, and Edwin D. Waddington

Related authors

Ice core site considerations from modeling CO2 and O2/N2 ratio diffusion in interior East Antarctica
Marc J. Sailer, Tyler J. Fudge, John D. Patterson, Shuai Yan, Duncan A. Young, Shivangini Singh, Don Blankenship, and Megan Kerr
EGUsphere, https://doi.org/10.5194/egusphere-2025-2104,https://doi.org/10.5194/egusphere-2025-2104, 2025
This preprint is open for discussion and under review for Climate of the Past (CP).
Short summary
Doomed descent? How fast sulphate signals diffuse in the EPICA Dome C ice column
Felix S. L. Ng, Rachael H. Rhodes, Tyler J. Fudge, and Eric W. Wolff
EGUsphere, https://doi.org/10.5194/egusphere-2025-1566,https://doi.org/10.5194/egusphere-2025-1566, 2025
This preprint is open for discussion and under review for The Cryosphere (TC).
Short summary
Review Article: Antarctica’s internal architecture: Towards a radiostratigraphically-informed age–depth model of the Antarctic ice sheets
Robert G. Bingham, Julien A. Bodart, Marie G. P. Cavitte, Ailsa Chung, Rebecca J. Sanderson, Johannes C. R. Sutter, Olaf Eisen, Nanna B. Karlsson, Joseph A. MacGregor, Neil Ross, Duncan A. Young, David W. Ashmore, Andreas Born, Winnie Chu, Xiangbin Cui, Reinhard Drews, Steven Franke, Vikram Goel, John W. Goodge, A. Clara J. Henry, Antoine Hermant, Benjamin H. Hills, Nicholas Holschuh, Michelle R. Koutnik, Gwendolyn J.-M. C. Leysinger Vieli, Emma J. Mackie, Elisa Mantelli, Carlos Martín, Felix S. L. Ng, Falk M. Oraschewski, Felipe Napoleoni, Frédéric Parrenin, Sergey V. Popov, Therese Rieckh, Rebecca Schlegel, Dustin M. Schroeder, Martin J. Siegert, Xueyuan Tang, Thomas O. Teisberg, Kate Winter, Shuai Yan, Harry Davis, Christine F. Dow, Tyler J. Fudge, Tom A. Jordan, Bernd Kulessa, Kenichi Matsuoka, Clara J. Nyqvist, Maryam Rahnemoonfar, Matthew R. Siegfried, Shivangini Singh, Verjan Višnjević, Rodrigo Zamora, and Alexandra Zuhr
EGUsphere, https://doi.org/10.5194/egusphere-2024-2593,https://doi.org/10.5194/egusphere-2024-2593, 2024
Short summary
Gas isotope thermometry in the South Pole and Dome Fuji ice cores provides evidence for seasonal rectification of ice core gas records
Jacob D. Morgan, Christo Buizert, Tyler J. Fudge, Kenji Kawamura, Jeffrey P. Severinghaus, and Cathy M. Trudinger
The Cryosphere, 16, 2947–2966, https://doi.org/10.5194/tc-16-2947-2022,https://doi.org/10.5194/tc-16-2947-2022, 2022
Short summary
The SP19 chronology for the South Pole Ice Core – Part 2: gas chronology, Δage, and smoothing of atmospheric records
Jenna A. Epifanio, Edward J. Brook, Christo Buizert, Jon S. Edwards, Todd A. Sowers, Emma C. Kahle, Jeffrey P. Severinghaus, Eric J. Steig, Dominic A. Winski, Erich C. Osterberg, Tyler J. Fudge, Murat Aydin, Ekaterina Hood, Michael Kalk, Karl J. Kreutz, David G. Ferris, and Joshua A. Kennedy
Clim. Past, 16, 2431–2444, https://doi.org/10.5194/cp-16-2431-2020,https://doi.org/10.5194/cp-16-2431-2020, 2020
Short summary

Related subject area

Subject: Proxy Use-Development-Validation | Archive: Ice Cores | Timescale: Pleistocene
Total air content measurements from the RECAP ice core
Sindhu Vudayagiri, Bo Vinther, Johannes Freitag, Peter L. Langen, and Thomas Blunier
Clim. Past, 21, 517–528, https://doi.org/10.5194/cp-21-517-2025,https://doi.org/10.5194/cp-21-517-2025, 2025
Short summary
New estimates of sulfate diffusion rates in the EPICA Dome C ice core
Rachael H. Rhodes, Yvan Bollet-Quivogne, Piers Barnes, Mirko Severi, and Eric W. Wolff
Clim. Past, 20, 2031–2043, https://doi.org/10.5194/cp-20-2031-2024,https://doi.org/10.5194/cp-20-2031-2024, 2024
Short summary
Evaluating marine dust records as templates for optical dating of Oldest Ice
Jessica Ng, Jeffrey Severinghaus, Ryan Bay, and Delia Tosi
Clim. Past, 20, 1437–1449, https://doi.org/10.5194/cp-20-1437-2024,https://doi.org/10.5194/cp-20-1437-2024, 2024
Short summary
The WAIS Divide deep ice core WD2014 chronology – Part 2: Annual-layer counting (0–31 ka BP)
Michael Sigl, Tyler J. Fudge, Mai Winstrup, Jihong Cole-Dai, David Ferris, Joseph R. McConnell, Ken C. Taylor, Kees C. Welten, Thomas E. Woodruff, Florian Adolphi, Marion Bisiaux, Edward J. Brook, Christo Buizert, Marc W. Caffee, Nelia W. Dunbar, Ross Edwards, Lei Geng, Nels Iverson, Bess Koffman, Lawrence Layman, Olivia J. Maselli, Kenneth McGwire, Raimund Muscheler, Kunihiko Nishiizumi, Daniel R. Pasteris, Rachael H. Rhodes, and Todd A. Sowers
Clim. Past, 12, 769–786, https://doi.org/10.5194/cp-12-769-2016,https://doi.org/10.5194/cp-12-769-2016, 2016
Short summary
Comparing past accumulation rate reconstructions in East Antarctic ice cores using 10Be, water isotopes and CMIP5-PMIP3 models
A. Cauquoin, A. Landais, G. M. Raisbeck, J. Jouzel, L. Bazin, M. Kageyama, J.-Y. Peterschmitt, M. Werner, E. Bard, and ASTER Team
Clim. Past, 11, 355–367, https://doi.org/10.5194/cp-11-355-2015,https://doi.org/10.5194/cp-11-355-2015, 2015
Short summary

Cited articles

Aydin, M., Fudge, T. J., Verhulst, K. R., Nicewonger, M. R., Waddington, E. D., and Saltzman, E. S.: Carbonyl sulfide hydrolysis in Antarctic ice cores and an atmospheric history for the last 8000 years, J. Geophys. Res.-Atmos., 119, 8500–8514, https://doi.org/10.1002/2014JD021618, 2014. 
Barnes, P. R. F. and Wolff, E. W.: Distribution of soluble impurities in cold glacial ice, J. Glaciol., 50, 311–324, 2004. 
Barnes, P. R. F., Wolff, E. W., Mader, H. M., Udisti, R., Castellano, E., and Rothlisberger, R.: Evolution of chemical peak shapes in the Dome C, Antarctica, ice core, J. Geophys. Res.-Atmos., 108, 4126, 2003. 
Bereiter, B., Fischer, H., Schwander, J., and Stocker, T. F.: Diffusive equilibration of N2, O2 and CO2 mixing ratios in a 1.5-million-years-old ice core, The Cryosphere, 8, 245–256, https://doi.org/10.5194/tc-8-245-2014, 2014. 
Download
Short summary
We use the oldest Antarctic ice core to estimate the rate of diffusion of sulfuric acid. Sulfuric acid is a marker of past volcanic activity and is critical in developing ice core timescales. The rate of diffusion is uncertain and is important to know, both for selecting future ice core locations and interpreting ice core records. We find the effective diffusivity of sulfate is 10 times smaller than previously estimated, indicating that the sulfuric acid signals will persist for longer.
Share