Articles | Volume 19, issue 12
https://doi.org/10.5194/cp-19-2423-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/cp-19-2423-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
04 Dec 2023
Research article |
| 04 Dec 2023
| 04 Dec 2023
Distinguishing the combined vegetation and soil component of δ13C variation in speleothem records from subsequent degassing and prior calcite precipitation effects
Heather M. Stoll
CORRESPONDING AUTHOR
Department of Earth Sciences, ETH Zurich, Sonneggstrasse 5, 8006 Zurich, Switzerland
Chris Day
Department of Earth Sciences, University of Oxford, South Parks Road, OX1 3AN, Oxford, UK
Franziska Lechleitner
Department of Chemistry and Biochemistry and Oeschger Centre for Climate Change Research, University of Bern, Freiestrasse 3, 3012 Bern, Switzerland
Oliver Kost
Department of Earth Sciences, ETH Zurich, Sonneggstrasse 5, 8006 Zurich, Switzerland
Laura Endres
Department of Earth Sciences, ETH Zurich, Sonneggstrasse 5, 8006 Zurich, Switzerland
Jakub Sliwinski
Department of Earth Sciences, ETH Zurich, Sonneggstrasse 5, 8006 Zurich, Switzerland
Carlos Pérez-Mejías
Institute of Global Environmental Change, Xi'an Jiaotong University, Xi'an, China
Hai Cheng
Institute of Global Environmental Change, Xi'an Jiaotong University, Xi'an, China
Denis Scholz
Institute of Geosciences, University of Mainz, Mainz, Germany
Related authors
Alexander J. Clark, Ismael Torres-Romero, Madalina Jaggi, Stefano M. Bernasconi, and Heather M. Stoll
Clim. Past, 20, 2081–2101, https://doi.org/10.5194/cp-20-2081-2024, https://doi.org/10.5194/cp-20-2081-2024, 2024
Short summary
Short summary
Coccoliths are abundant in sediments across the world’s oceans, yet it is difficult to apply traditional carbon or oxygen isotope methodologies for temperature reconstructions. We show that our coccolith clumped isotope temperature calibration with well-constrained temperatures systematically differs from inorganic carbonate calibrations. We suggest the use of our well-constrained calibration for future coccolith carbonate temperature reconstructions.
Judit Torner, Isabel Cacho, Heather Stoll, Ana Moreno, Joan O. Grimalt, Francisco J. Sierro, Hai Cheng, and R. Lawrence Edwards
Clim. Past Discuss., https://doi.org/10.5194/cp-2024-54, https://doi.org/10.5194/cp-2024-54, 2024
Preprint under review for CP
Short summary
Short summary
This study presents a new speleothem record of the western Mediterranean region that offers new insights into the timeline of glacial terminations TIV, TIII, and TIII.a. The comparison among the studied deglaciations reveals differences in terms of intensity and duration and opens the opportunity to evaluate marine sediment chronologies based on orbital tuning from the North Atlantic and the Western Mediterranean.
Nikita Kaushal, Carlos Perez-Mejias, and Heather M. Stoll
Clim. Past Discuss., https://doi.org/10.5194/cp-2024-37, https://doi.org/10.5194/cp-2024-37, 2024
Revised manuscript under review for CP
Short summary
Short summary
Terminations are large magnitude rapid events triggered in the North Atlantic region that manifest across the global climate system. They provide key examples of climatic teleconnections and dynamics. In this study, we use the SISAL global speleothem database and find that there are sufficient climatic records from key locations to make speleothems a valuable archive for studying Terminations and provide instances for more targeted work on speleothem research.
Nikita Kaushal, Franziska A. Lechleitner, Micah Wilhelm, Khalil Azennoud, Janica C. Bühler, Kerstin Braun, Yassine Ait Brahim, Andy Baker, Yuval Burstyn, Laia Comas-Bru, Jens Fohlmeister, Yonaton Goldsmith, Sandy P. Harrison, István G. Hatvani, Kira Rehfeld, Magdalena Ritzau, Vanessa Skiba, Heather M. Stoll, József G. Szűcs, Péter Tanos, Pauline C. Treble, Vitor Azevedo, Jonathan L. Baker, Andrea Borsato, Sakonvan Chawchai, Andrea Columbu, Laura Endres, Jun Hu, Zoltán Kern, Alena Kimbrough, Koray Koç, Monika Markowska, Belen Martrat, Syed Masood Ahmad, Carole Nehme, Valdir Felipe Novello, Carlos Pérez-Mejías, Jiaoyang Ruan, Natasha Sekhon, Nitesh Sinha, Carol V. Tadros, Benjamin H. Tiger, Sophie Warken, Annabel Wolf, Haiwei Zhang, and SISAL Working Group members
Earth Syst. Sci. Data, 16, 1933–1963, https://doi.org/10.5194/essd-16-1933-2024, https://doi.org/10.5194/essd-16-1933-2024, 2024
Short summary
Short summary
Speleothems are a popular, multi-proxy climate archive that provide regional to global insights into past hydroclimate trends with precise chronologies. We present an update to the SISAL (Speleothem Isotopes
Synthesis and AnaLysis) database, SISALv3, which, for the first time, contains speleothem trace element records, in addition to an update to the stable isotope records available in previous versions of the database, cumulatively providing data from 365 globally distributed sites.
Synthesis and AnaLysis) database, SISALv3, which, for the first time, contains speleothem trace element records, in addition to an update to the stable isotope records available in previous versions of the database, cumulatively providing data from 365 globally distributed sites.
Miguel Bartolomé, Ana Moreno, Carlos Sancho, Isabel Cacho, Heather Stoll, Negar Haghipour, Ánchel Belmonte, Christoph Spötl, John Hellstrom, R. Lawrence Edwards, and Hai Cheng
Clim. Past, 20, 467–494, https://doi.org/10.5194/cp-20-467-2024, https://doi.org/10.5194/cp-20-467-2024, 2024
Short summary
Short summary
Reconstructing past temperatures at regional scales during the Common Era is necessary to place the current warming in the context of natural climate variability. We present a climate reconstruction based on eight stalagmites from four caves in the Pyrenees, NE Spain. These stalagmites were dated precisely and analysed for their oxygen isotopes, which appear dominated by temperature changes. Solar variability and major volcanic eruptions are the two main drivers of observed climate variability.
Heather M. Stoll, Leopoldo D. Pena, Ivan Hernandez-Almeida, José Guitián, Thomas Tanner, and Heiko Pälike
Clim. Past, 20, 25–36, https://doi.org/10.5194/cp-20-25-2024, https://doi.org/10.5194/cp-20-25-2024, 2024
Short summary
Short summary
The Oligocene and early Miocene periods featured dynamic glacial cycles on Antarctica. In this paper, we use Sr isotopes in marine carbonate sediments to document a change in the location and intensity of continental weathering during short periods of very intense Antarctic glaciation. Potentially, the weathering intensity of old continental rocks on Antarctica was reduced during glaciation. We also show improved age models for correlation of Southern Ocean and North Atlantic sediments.
Oliver Kost, Saúl González-Lemos, Laura Rodríguez-Rodríguez, Jakub Sliwinski, Laura Endres, Negar Haghipour, and Heather Stoll
Hydrol. Earth Syst. Sci., 27, 2227–2255, https://doi.org/10.5194/hess-27-2227-2023, https://doi.org/10.5194/hess-27-2227-2023, 2023
Short summary
Short summary
Cave monitoring studies including cave drip water are unique opportunities to sample water which has percolated through the soil and rock. The change in drip water chemistry is resolved over the course of 16 months, inferring seasonal and hydrological variations in soil and karst processes at the water–air and water–rock interface. Such data sets improve the understanding of hydrological and hydrochemical processes and ultimately advance the interpretation of geochemical stalagmite records.
Amanda Gerotto, Hongrui Zhang, Renata Hanae Nagai, Heather M. Stoll, Rubens César Lopes Figueira, Chuanlian Liu, and Iván Hernández-Almeida
Biogeosciences, 20, 1725–1739, https://doi.org/10.5194/bg-20-1725-2023, https://doi.org/10.5194/bg-20-1725-2023, 2023
Short summary
Short summary
Based on the analysis of the response of coccolithophores’ morphological attributes in a laboratory dissolution experiment and surface sediment samples from the South China Sea, we proposed that the thickness shape (ks) factor of fossil coccoliths together with the normalized ks variation, which is the ratio of the standard deviation of ks (σ) over the mean ks (σ/ks), is a robust and novel proxy to reconstruct past changes in deep ocean carbon chemistry.
Jessica G. M. Crumpton-Banks, Thomas Tanner, Ivan Hernández Almeida, James W. B. Rae, and Heather Stoll
Biogeosciences, 19, 5633–5644, https://doi.org/10.5194/bg-19-5633-2022, https://doi.org/10.5194/bg-19-5633-2022, 2022
Short summary
Short summary
Past ocean carbon is reconstructed using proxies, but it is unknown whether preparing ocean sediment for one proxy might damage the data given by another. We have tested whether the extraction of an organic proxy archive from sediment samples impacts the geochemistry of tiny shells also within the sediment. We find no difference in shell geochemistry between samples which come from treated and untreated sediment. This will help us to maximize scientific return from valuable sediment samples.
José Guitián, Miguel Ángel Fuertes, José-Abel Flores, Iván Hernández-Almeida, and Heather Stoll
Biogeosciences, 19, 5007–5019, https://doi.org/10.5194/bg-19-5007-2022, https://doi.org/10.5194/bg-19-5007-2022, 2022
Short summary
Short summary
The effect of environmental conditions on the degree of calcification of marine phytoplankton remains unclear. This study implements a new microscopic approach to quantify the calcification of ancient coccolithophores, using North Atlantic sediments. Results show significant differences in the thickness and shape factor of coccoliths for samples with minimum dissolution, providing the first evaluation of phytoplankton physiology adaptation to million-year-scale variable environmental conditions.
Franziska A. Lechleitner, Christopher C. Day, Oliver Kost, Micah Wilhelm, Negar Haghipour, Gideon M. Henderson, and Heather M. Stoll
Clim. Past, 17, 1903–1918, https://doi.org/10.5194/cp-17-1903-2021, https://doi.org/10.5194/cp-17-1903-2021, 2021
Short summary
Short summary
Soil respiration is a critical but poorly constrained component of the global carbon cycle. We analyse the effect of changing soil respiration rates on the stable carbon isotope ratio of speleothems from northern Spain covering the last deglaciation. Using geochemical analysis and forward modelling we quantify the processes affecting speleothem stable carbon isotope ratios and extract a signature of increasing soil respiration synchronous with deglacial warming.
Ana Moreno, Miguel Iglesias, Cesar Azorin-Molina, Carlos Pérez-Mejías, Miguel Bartolomé, Carlos Sancho, Heather Stoll, Isabel Cacho, Jaime Frigola, Cinta Osácar, Arsenio Muñoz, Antonio Delgado-Huertas, Ileana Bladé, and Françoise Vimeux
Atmos. Chem. Phys., 21, 10159–10177, https://doi.org/10.5194/acp-21-10159-2021, https://doi.org/10.5194/acp-21-10159-2021, 2021
Short summary
Short summary
We present a large and unique dataset of the rainfall isotopic composition at seven sites from northern Iberia to characterize their variability at daily and monthly timescales and to assess the role of climate and geographic factors in the modulation of δ18O values. We found that the origin, moisture uptake along the trajectory and type of precipitation play a key role. These results will help to improve the interpretation of δ18O paleorecords from lacustrine carbonates or speleothems.
Hongrui Zhang, Chuanlian Liu, Luz María Mejía, and Heather Stoll
Biogeosciences, 18, 1909–1916, https://doi.org/10.5194/bg-18-1909-2021, https://doi.org/10.5194/bg-18-1909-2021, 2021
Catarina Cavaleiro, Antje H. L. Voelker, Heather Stoll, Karl-Heinz Baumann, and Michal Kucera
Clim. Past, 16, 2017–2037, https://doi.org/10.5194/cp-16-2017-2020, https://doi.org/10.5194/cp-16-2017-2020, 2020
Hongrui Zhang, Heather Stoll, Clara Bolton, Xiaobo Jin, and Chuanlian Liu
Biogeosciences, 15, 4759–4775, https://doi.org/10.5194/bg-15-4759-2018, https://doi.org/10.5194/bg-15-4759-2018, 2018
Short summary
Short summary
The sinking speeds of coccoliths are relevant for laboratory methods to separate coccoliths for geochemical analysis. However, in the absence of estimates of coccolith settling velocity, previous implementations have depended mainly on time-consuming method development by trial and error. In this study, the sinking velocities of cocooliths were carefully measured for the first time. We also provide an estimation of coccolith sinking velocity by shape, which will make coccolith separation easier.
Saúl González-Lemos, José Guitián, Miguel-Ángel Fuertes, José-Abel Flores, and Heather M. Stoll
Biogeosciences, 15, 1079–1091, https://doi.org/10.5194/bg-15-1079-2018, https://doi.org/10.5194/bg-15-1079-2018, 2018
Short summary
Short summary
Changes in atmospheric carbon dioxide affect ocean chemistry and the ability of marine organisms to manufacture shells from calcium carbonate. We describe a technique to obtain more reproducible measurements of the thickness of calcium carbonate shells made by microscopic marine algae called coccolithophores, which will allow researchers to compare how the shell thickness responds to variations in ocean chemistry in the past and present.
M. N. Müller, M. Lebrato, U. Riebesell, J. Barcelos e Ramos, K. G. Schulz, S. Blanco-Ameijeiras, S. Sett, A. Eisenhauer, and H. M. Stoll
Biogeosciences, 11, 1065–1075, https://doi.org/10.5194/bg-11-1065-2014, https://doi.org/10.5194/bg-11-1065-2014, 2014
Juan Luis Bernal-Wormull, Ana Moreno, Yuri Dublyansky, Christoph Spötl, Reyes Giménez, Carlos Pérez-Mejías, Miguel Bartolomé, Martin Arriolabengoa, Eneko Iriarte, Isabel Cacho, Richard Lawrence Edwards, and Hai Cheng
EGUsphere, https://doi.org/10.5194/egusphere-2024-3612, https://doi.org/10.5194/egusphere-2024-3612, 2024
This preprint is open for discussion and under review for Climate of the Past (CP).
Short summary
Short summary
We present in this manuscript a record of temperature changes during the last deglaciation and the Holocene using isotopes of fluid inclusions in stalagmites from the northeastern region of the Iberian Peninsula. This innovative climate proxy for this study region provides a quantitative understanding of the abrupt temperature changes in southern Europe of the last 16500 years before present.
Timothy J. Pollard, Jon D. Woodhead, Russell N. Drysdale, R. Lawrence Edwards, Xianglei Li, Ashlea N. Wainwright, Mathieu Pythoud, Hai Cheng, John C. Hellstrom, Ilaria Isola, Eleonora Regattieri, Giovanni Zanchetta, and Dylan S. Parmenter
EGUsphere, https://doi.org/10.5194/egusphere-2024-3594, https://doi.org/10.5194/egusphere-2024-3594, 2024
Short summary
Short summary
The uranium-thorium and uranium-lead radiometric dating methods are both capable of dating carbonate samples ranging in age from about 400,000 to 650,000 years. Here we test agreement between the two methods by 'double dating' speleothems (i.e. secondary cave mineral deposits) that grew within this age range. We demonstrate excellent agreement between the two dating methods and discuss their relative strengths and weaknesses.
Hu Yang, Xiaoxu Shi, Xulong Wang, Qingsong Liu, Yi Zhong, Xiaodong Liu, Youbin Sun, Yanjun Cai, Fei Liu, Gerrit Lohmann, Martin Werner, Zhimin Jian, Tainã M. L. Pinho, Hai Cheng, Lijuan Lu, Jiping Liu, Chao-Yuan Yang, Qinghua Yang, Yongyun Hu, Xing Cheng, Jingyu Zhang, and Dake Chen
EGUsphere, https://doi.org/10.5194/egusphere-2024-2778, https://doi.org/10.5194/egusphere-2024-2778, 2024
This preprint is open for discussion and under review for Climate of the Past (CP).
Short summary
Short summary
The precession driven low-latitude hydrological cycle is not paced by hemispheric summer insolation, but shifting perihelion.
Alexander J. Clark, Ismael Torres-Romero, Madalina Jaggi, Stefano M. Bernasconi, and Heather M. Stoll
Clim. Past, 20, 2081–2101, https://doi.org/10.5194/cp-20-2081-2024, https://doi.org/10.5194/cp-20-2081-2024, 2024
Short summary
Short summary
Coccoliths are abundant in sediments across the world’s oceans, yet it is difficult to apply traditional carbon or oxygen isotope methodologies for temperature reconstructions. We show that our coccolith clumped isotope temperature calibration with well-constrained temperatures systematically differs from inorganic carbonate calibrations. We suggest the use of our well-constrained calibration for future coccolith carbonate temperature reconstructions.
Judit Torner, Isabel Cacho, Heather Stoll, Ana Moreno, Joan O. Grimalt, Francisco J. Sierro, Hai Cheng, and R. Lawrence Edwards
Clim. Past Discuss., https://doi.org/10.5194/cp-2024-54, https://doi.org/10.5194/cp-2024-54, 2024
Preprint under review for CP
Short summary
Short summary
This study presents a new speleothem record of the western Mediterranean region that offers new insights into the timeline of glacial terminations TIV, TIII, and TIII.a. The comparison among the studied deglaciations reveals differences in terms of intensity and duration and opens the opportunity to evaluate marine sediment chronologies based on orbital tuning from the North Atlantic and the Western Mediterranean.
Pengzhen Duan, Hanying Li, Zhibang Ma, Jingyao Zhao, Xiyu Dong, Ashish Sinha, Peng Hu, Haiwei Zhang, Youfeng Ning, Guangyou Zhu, and Hai Cheng
Clim. Past, 20, 1401–1414, https://doi.org/10.5194/cp-20-1401-2024, https://doi.org/10.5194/cp-20-1401-2024, 2024
Short summary
Short summary
We use multi-proxy speleothem records to reveal a two droughts–one pluvial pattern during 8.5–8.0 ka. The different rebounded rainfall quantity after two droughts causes different behavior of δ13C, suggesting the dominant role of rainfall threshold on the ecosystem. A comparison of different records suggests the prolonged 8.2 ka event is a globally common phenomenon rather than a regional signal. The variability of the AMOC strength is mainly responsible for these climate changes.
Stuart Umbo, Franziska Lechleitner, Thomas Opel, Sevasti Modestou, Tobias Braun, Anton Vaks, Gideon Henderson, Pete Scott, Alexander Osintzev, Alexandr Kononov, Irina Adrian, Yuri Dublyansky, Alena Giesche, and Sebastian Breitenbach
EGUsphere, https://doi.org/10.5194/egusphere-2024-1691, https://doi.org/10.5194/egusphere-2024-1691, 2024
Short summary
Short summary
We use cave rocks to reconstruct northern Siberian climate 8.68 ± 0.09 million years ago. We show that when global average temperature was about 4.5 °C warmer than today (similar to what’s expected in the coming decades should carbon emissions continue unabated), Arctic temperature increased by more than 18 °C. Similar levels of Arctic warming in the future would see huge areas of permafrost (permanently frozen ground) thaw and release greenhouse gases to the atmosphere.
Jade Margerum, Julia Homann, Stuart Umbo, Gernot Nehrke, Thorsten Hoffmann, Anton Vaks, Aleksandr Kononov, Alexander Osintsev, Alena Giesche, Andrew Mason, Franziska A. Lechleitner, Gideon M. Henderson, Ola Kwiecien, and Sebastian F. M. Breitenbach
EGUsphere, https://doi.org/10.5194/egusphere-2024-1707, https://doi.org/10.5194/egusphere-2024-1707, 2024
Short summary
Short summary
We analyse a southern Siberian stalagmite to reconstruct soil respiration, wildfire, and vegetation trends, during the last interglacial (LIG) (124.1 – 118.8 ka BP) and Holocene (10 – 0 ka BP). We show that wildfires were greater during the LIG than the Holocene and were supported by fire prone-species, low soil respiration, and a greater difference between summer and winter temperature. We show that vegetation type and summer/winter temperature contrast are strong drivers of Siberian wildfires.
Nikita Kaushal, Carlos Perez-Mejias, and Heather M. Stoll
Clim. Past Discuss., https://doi.org/10.5194/cp-2024-37, https://doi.org/10.5194/cp-2024-37, 2024
Revised manuscript under review for CP
Short summary
Short summary
Terminations are large magnitude rapid events triggered in the North Atlantic region that manifest across the global climate system. They provide key examples of climatic teleconnections and dynamics. In this study, we use the SISAL global speleothem database and find that there are sufficient climatic records from key locations to make speleothems a valuable archive for studying Terminations and provide instances for more targeted work on speleothem research.
Nikita Kaushal, Franziska A. Lechleitner, Micah Wilhelm, Khalil Azennoud, Janica C. Bühler, Kerstin Braun, Yassine Ait Brahim, Andy Baker, Yuval Burstyn, Laia Comas-Bru, Jens Fohlmeister, Yonaton Goldsmith, Sandy P. Harrison, István G. Hatvani, Kira Rehfeld, Magdalena Ritzau, Vanessa Skiba, Heather M. Stoll, József G. Szűcs, Péter Tanos, Pauline C. Treble, Vitor Azevedo, Jonathan L. Baker, Andrea Borsato, Sakonvan Chawchai, Andrea Columbu, Laura Endres, Jun Hu, Zoltán Kern, Alena Kimbrough, Koray Koç, Monika Markowska, Belen Martrat, Syed Masood Ahmad, Carole Nehme, Valdir Felipe Novello, Carlos Pérez-Mejías, Jiaoyang Ruan, Natasha Sekhon, Nitesh Sinha, Carol V. Tadros, Benjamin H. Tiger, Sophie Warken, Annabel Wolf, Haiwei Zhang, and SISAL Working Group members
Earth Syst. Sci. Data, 16, 1933–1963, https://doi.org/10.5194/essd-16-1933-2024, https://doi.org/10.5194/essd-16-1933-2024, 2024
Short summary
Short summary
Speleothems are a popular, multi-proxy climate archive that provide regional to global insights into past hydroclimate trends with precise chronologies. We present an update to the SISAL (Speleothem Isotopes
Synthesis and AnaLysis) database, SISALv3, which, for the first time, contains speleothem trace element records, in addition to an update to the stable isotope records available in previous versions of the database, cumulatively providing data from 365 globally distributed sites.
Synthesis and AnaLysis) database, SISALv3, which, for the first time, contains speleothem trace element records, in addition to an update to the stable isotope records available in previous versions of the database, cumulatively providing data from 365 globally distributed sites.
Hubert Vonhof, Sophie Verheyden, Dominique Bonjean, Stéphane Pirson, Michael Weber, Denis Scholz, John Hellstrom, Hai Cheng, Xue Jia, Kevin Di Modica, Gregory Abrams, Marjan van Nunen, Joost Ruiter, Michèlle van der Does, Daniel Böhl, and Jeroen van der Lubbe
Clim. Past Discuss., https://doi.org/10.5194/cp-2024-27, https://doi.org/10.5194/cp-2024-27, 2024
Revised manuscript accepted for CP
Short summary
Short summary
The sedimentary sequence in Scladina Cave (Belgium) is well-known for its rich archeological assemblages and its numerous faunal remains. Of particular interest is the presence of a nearly complete jaw bone of a Neandertal child. In this study, we present new Uranium-series ages of stalagmites from the archeological sequence which allow more precise dating of the archeological finds. One key result is that the Neandertal child may be slightly older than previously thought.
Miguel Bartolomé, Ana Moreno, Carlos Sancho, Isabel Cacho, Heather Stoll, Negar Haghipour, Ánchel Belmonte, Christoph Spötl, John Hellstrom, R. Lawrence Edwards, and Hai Cheng
Clim. Past, 20, 467–494, https://doi.org/10.5194/cp-20-467-2024, https://doi.org/10.5194/cp-20-467-2024, 2024
Short summary
Short summary
Reconstructing past temperatures at regional scales during the Common Era is necessary to place the current warming in the context of natural climate variability. We present a climate reconstruction based on eight stalagmites from four caves in the Pyrenees, NE Spain. These stalagmites were dated precisely and analysed for their oxygen isotopes, which appear dominated by temperature changes. Solar variability and major volcanic eruptions are the two main drivers of observed climate variability.
Heather M. Stoll, Leopoldo D. Pena, Ivan Hernandez-Almeida, José Guitián, Thomas Tanner, and Heiko Pälike
Clim. Past, 20, 25–36, https://doi.org/10.5194/cp-20-25-2024, https://doi.org/10.5194/cp-20-25-2024, 2024
Short summary
Short summary
The Oligocene and early Miocene periods featured dynamic glacial cycles on Antarctica. In this paper, we use Sr isotopes in marine carbonate sediments to document a change in the location and intensity of continental weathering during short periods of very intense Antarctic glaciation. Potentially, the weathering intensity of old continental rocks on Antarctica was reduced during glaciation. We also show improved age models for correlation of Southern Ocean and North Atlantic sediments.
Giselle Utida, Francisco W. Cruz, Mathias Vuille, Angela Ampuero, Valdir F. Novello, Jelena Maksic, Gilvan Sampaio, Hai Cheng, Haiwei Zhang, Fabio Ramos Dias de Andrade, and R. Lawrence Edwards
Clim. Past, 19, 1975–1992, https://doi.org/10.5194/cp-19-1975-2023, https://doi.org/10.5194/cp-19-1975-2023, 2023
Short summary
Short summary
We reconstruct the Intertropical Convergence Zone (ITCZ) behavior during the past 3000 years over northeastern Brazil based on oxygen stable isotopes of stalagmites. Paleoclimate changes were mainly forced by the tropical South Atlantic and tropical Pacific sea surface temperature variability. We describe an ITCZ zonal behavior active around 1100 CE and the period from 1500 to 1750 CE. The dataset also records historical droughts that affected modern human population in this area of Brazil.
Charlotte Honiat, Gabriella Koltai, Yuri Dublyansky, R. Lawrence Edwards, Haiwei Zhang, Hai Cheng, and Christoph Spötl
Clim. Past, 19, 1177–1199, https://doi.org/10.5194/cp-19-1177-2023, https://doi.org/10.5194/cp-19-1177-2023, 2023
Short summary
Short summary
A look at the climate evolution during the last warm period may allow us to test ground for future climate conditions. We quantified the temperature evolution during the Last Interglacial using a tiny amount of water trapped in the crystals of precisely dated stalagmites in caves from the southeastern European Alps. Our record indicates temperatures up to 2 °C warmer than today and an unstable climate during the first half of the Last Interglacial.
Oliver Kost, Saúl González-Lemos, Laura Rodríguez-Rodríguez, Jakub Sliwinski, Laura Endres, Negar Haghipour, and Heather Stoll
Hydrol. Earth Syst. Sci., 27, 2227–2255, https://doi.org/10.5194/hess-27-2227-2023, https://doi.org/10.5194/hess-27-2227-2023, 2023
Short summary
Short summary
Cave monitoring studies including cave drip water are unique opportunities to sample water which has percolated through the soil and rock. The change in drip water chemistry is resolved over the course of 16 months, inferring seasonal and hydrological variations in soil and karst processes at the water–air and water–rock interface. Such data sets improve the understanding of hydrological and hydrochemical processes and ultimately advance the interpretation of geochemical stalagmite records.
Amanda Gerotto, Hongrui Zhang, Renata Hanae Nagai, Heather M. Stoll, Rubens César Lopes Figueira, Chuanlian Liu, and Iván Hernández-Almeida
Biogeosciences, 20, 1725–1739, https://doi.org/10.5194/bg-20-1725-2023, https://doi.org/10.5194/bg-20-1725-2023, 2023
Short summary
Short summary
Based on the analysis of the response of coccolithophores’ morphological attributes in a laboratory dissolution experiment and surface sediment samples from the South China Sea, we proposed that the thickness shape (ks) factor of fossil coccoliths together with the normalized ks variation, which is the ratio of the standard deviation of ks (σ) over the mean ks (σ/ks), is a robust and novel proxy to reconstruct past changes in deep ocean carbon chemistry.
Jessica G. M. Crumpton-Banks, Thomas Tanner, Ivan Hernández Almeida, James W. B. Rae, and Heather Stoll
Biogeosciences, 19, 5633–5644, https://doi.org/10.5194/bg-19-5633-2022, https://doi.org/10.5194/bg-19-5633-2022, 2022
Short summary
Short summary
Past ocean carbon is reconstructed using proxies, but it is unknown whether preparing ocean sediment for one proxy might damage the data given by another. We have tested whether the extraction of an organic proxy archive from sediment samples impacts the geochemistry of tiny shells also within the sediment. We find no difference in shell geochemistry between samples which come from treated and untreated sediment. This will help us to maximize scientific return from valuable sediment samples.
José Guitián, Miguel Ángel Fuertes, José-Abel Flores, Iván Hernández-Almeida, and Heather Stoll
Biogeosciences, 19, 5007–5019, https://doi.org/10.5194/bg-19-5007-2022, https://doi.org/10.5194/bg-19-5007-2022, 2022
Short summary
Short summary
The effect of environmental conditions on the degree of calcification of marine phytoplankton remains unclear. This study implements a new microscopic approach to quantify the calcification of ancient coccolithophores, using North Atlantic sediments. Results show significant differences in the thickness and shape factor of coccoliths for samples with minimum dissolution, providing the first evaluation of phytoplankton physiology adaptation to million-year-scale variable environmental conditions.
Janica C. Bühler, Josefine Axelsson, Franziska A. Lechleitner, Jens Fohlmeister, Allegra N. LeGrande, Madhavan Midhun, Jesper Sjolte, Martin Werner, Kei Yoshimura, and Kira Rehfeld
Clim. Past, 18, 1625–1654, https://doi.org/10.5194/cp-18-1625-2022, https://doi.org/10.5194/cp-18-1625-2022, 2022
Short summary
Short summary
We collected and standardized the output of five isotope-enabled simulations for the last millennium and assess differences and similarities to records from a global speleothem database. Modeled isotope variations mostly arise from temperature differences. While lower-resolution speleothems do not capture extreme changes to the extent of models, they show higher variability on multi-decadal timescales. As no model excels in all comparisons, we advise a multi-model approach where possible.
Sophie F. Warken, Therese Weißbach, Tobias Kluge, Hubert Vonhof, Denis Scholz, Rolf Vieten, Martina Schmidt, Amos Winter, and Norbert Frank
Clim. Past, 18, 167–181, https://doi.org/10.5194/cp-18-167-2022, https://doi.org/10.5194/cp-18-167-2022, 2022
Short summary
Short summary
The analysis of fluid inclusions from a Puerto Rican speleothem provides quantitative information about past rainfall conditions and temperatures during the Last Glacial Period, when the climate was extremely variable. Our data show that the region experienced a climate that was generally colder and drier. However, we also reconstruct intervals when temperatures reached nearly modern values, and convective activity was comparable to or only slightly weaker than the present day.
Franziska A. Lechleitner, Christopher C. Day, Oliver Kost, Micah Wilhelm, Negar Haghipour, Gideon M. Henderson, and Heather M. Stoll
Clim. Past, 17, 1903–1918, https://doi.org/10.5194/cp-17-1903-2021, https://doi.org/10.5194/cp-17-1903-2021, 2021
Short summary
Short summary
Soil respiration is a critical but poorly constrained component of the global carbon cycle. We analyse the effect of changing soil respiration rates on the stable carbon isotope ratio of speleothems from northern Spain covering the last deglaciation. Using geochemical analysis and forward modelling we quantify the processes affecting speleothem stable carbon isotope ratios and extract a signature of increasing soil respiration synchronous with deglacial warming.
Ana Moreno, Miguel Iglesias, Cesar Azorin-Molina, Carlos Pérez-Mejías, Miguel Bartolomé, Carlos Sancho, Heather Stoll, Isabel Cacho, Jaime Frigola, Cinta Osácar, Arsenio Muñoz, Antonio Delgado-Huertas, Ileana Bladé, and Françoise Vimeux
Atmos. Chem. Phys., 21, 10159–10177, https://doi.org/10.5194/acp-21-10159-2021, https://doi.org/10.5194/acp-21-10159-2021, 2021
Short summary
Short summary
We present a large and unique dataset of the rainfall isotopic composition at seven sites from northern Iberia to characterize their variability at daily and monthly timescales and to assess the role of climate and geographic factors in the modulation of δ18O values. We found that the origin, moisture uptake along the trajectory and type of precipitation play a key role. These results will help to improve the interpretation of δ18O paleorecords from lacustrine carbonates or speleothems.
Inken Heidke, Adam Hartland, Denis Scholz, Andrew Pearson, John Hellstrom, Sebastian F. M. Breitenbach, and Thorsten Hoffmann
Biogeosciences, 18, 2289–2300, https://doi.org/10.5194/bg-18-2289-2021, https://doi.org/10.5194/bg-18-2289-2021, 2021
Short summary
Short summary
We analyzed lignin oxidation products (LOPs) in leaf litter and different soil horizons as well as dripwater and flowstone samples from four different cave sites from different vegetation zones in New Zealand using liquid chromatography coupled to mass spectrometry. We test whether the original source-dependent LOP signal of the overlying vegetation is preserved and can be recovered from flowstone samples and investigate how the signal is altered by the transport from the soil to the cave.
Gabriella Koltai, Christoph Spötl, Alexander H. Jarosch, and Hai Cheng
Clim. Past, 17, 775–789, https://doi.org/10.5194/cp-17-775-2021, https://doi.org/10.5194/cp-17-775-2021, 2021
Short summary
Short summary
This paper utilises a novel palaeoclimate archive from caves, cryogenic cave carbonates, which allow for precisely constraining permafrost thawing events in the past. Our study provides new insights into the climate of the Younger Dryas (12 800 to 11 700 years BP) in mid-Europe from the perspective of a high-elevation cave sensitive to permafrost development. We quantify seasonal temperature and precipitation changes by using a heat conduction model.
Hongrui Zhang, Chuanlian Liu, Luz María Mejía, and Heather Stoll
Biogeosciences, 18, 1909–1916, https://doi.org/10.5194/bg-18-1909-2021, https://doi.org/10.5194/bg-18-1909-2021, 2021
Chao-Jun Chen, Dao-Xian Yuan, Jun-Yun Li, Xian-Feng Wang, Hai Cheng, You-Feng Ning, R. Lawrence Edwards, Yao Wu, Si-Ya Xiao, Yu-Zhen Xu, Yang-Yang Huang, Hai-Ying Qiu, Jian Zhang, Ming-Qiang Liang, and Ting-Yong Li
Clim. Past Discuss., https://doi.org/10.5194/cp-2021-20, https://doi.org/10.5194/cp-2021-20, 2021
Manuscript not accepted for further review
Ana Moreno, Miguel Bartolomé, Juan Ignacio López-Moreno, Jorge Pey, Juan Pablo Corella, Jordi García-Orellana, Carlos Sancho, María Leunda, Graciela Gil-Romera, Penélope González-Sampériz, Carlos Pérez-Mejías, Francisco Navarro, Jaime Otero-García, Javier Lapazaran, Esteban Alonso-González, Cristina Cid, Jerónimo López-Martínez, Belén Oliva-Urcia, Sérgio Henrique Faria, María José Sierra, Rocío Millán, Xavier Querol, Andrés Alastuey, and José M. García-Ruíz
The Cryosphere, 15, 1157–1172, https://doi.org/10.5194/tc-15-1157-2021, https://doi.org/10.5194/tc-15-1157-2021, 2021
Short summary
Short summary
Our study of the chronological sequence of Monte Perdido Glacier in the Central Pyrenees (Spain) reveals that, although the intense warming associated with the Roman period or Medieval Climate Anomaly produced important ice mass losses, it was insufficient to make this glacier disappear. By contrast, recent global warming has melted away almost 600 years of ice accumulated since the Little Ice Age, jeopardising the survival of this and other southern European glaciers over the next few decades.
Catarina Cavaleiro, Antje H. L. Voelker, Heather Stoll, Karl-Heinz Baumann, and Michal Kucera
Clim. Past, 16, 2017–2037, https://doi.org/10.5194/cp-16-2017-2020, https://doi.org/10.5194/cp-16-2017-2020, 2020
Laia Comas-Bru, Kira Rehfeld, Carla Roesch, Sahar Amirnezhad-Mozhdehi, Sandy P. Harrison, Kamolphat Atsawawaranunt, Syed Masood Ahmad, Yassine Ait Brahim, Andy Baker, Matthew Bosomworth, Sebastian F. M. Breitenbach, Yuval Burstyn, Andrea Columbu, Michael Deininger, Attila Demény, Bronwyn Dixon, Jens Fohlmeister, István Gábor Hatvani, Jun Hu, Nikita Kaushal, Zoltán Kern, Inga Labuhn, Franziska A. Lechleitner, Andrew Lorrey, Belen Martrat, Valdir Felipe Novello, Jessica Oster, Carlos Pérez-Mejías, Denis Scholz, Nick Scroxton, Nitesh Sinha, Brittany Marie Ward, Sophie Warken, Haiwei Zhang, and SISAL Working Group members
Earth Syst. Sci. Data, 12, 2579–2606, https://doi.org/10.5194/essd-12-2579-2020, https://doi.org/10.5194/essd-12-2579-2020, 2020
Short summary
Short summary
This paper presents an updated version of the SISAL (Speleothem Isotope Synthesis and Analysis) database. This new version contains isotopic data from 691 speleothem records from 294 cave sites and new age–depth models, including their uncertainties, for 512 speleothems.
Tobias Kluge, Tatjana S. Münster, Norbert Frank, Elisabeth Eiche, Regina Mertz-Kraus, Denis Scholz, Martin Finné, and Ingmar Unkel
Clim. Past Discuss., https://doi.org/10.5194/cp-2020-47, https://doi.org/10.5194/cp-2020-47, 2020
Revised manuscript not accepted
Short summary
Short summary
A stalagmite from Hermes Cave (Greece) provides new insights into the climate evolution from 5.3−0.8 ka. Its close proximity to Mycenae and Corinth allows for a future comparative assessment of societal changes in a climatic context. Proxy data suggest significant centennial scale climate variability (i.e., wet vs. dry) with a long-term trend towards drier conditions from ca 3.7 to ~ 2.0 ka. The largest proxy variation of the whole record is found around the 4.2 ka event.
Yue Hu, Xiaoming Sun, Hai Cheng, and Hong Yan
Clim. Past, 16, 597–610, https://doi.org/10.5194/cp-16-597-2020, https://doi.org/10.5194/cp-16-597-2020, 2020
Short summary
Short summary
Tridacna, as the largest marine bivalves, can be used for high-resolution paleoclimate reconstruction in its carbonate skeleton. In this contribution, the modern δ18O shell is suggested to be a proxy for sea surface temperature in the Xisha Islands, South China Sea. Data from a fossil Tridacna (3673 ± 28 BP) indicate a warmer climate and intense ENSO-related variability but reduced ENSO frequency and more extreme El Niño winters compared to modern Tridacna.
Haiwei Zhang, Hai Cheng, Yanjun Cai, Christoph Spötl, Ashish Sinha, Gayatri Kathayat, and Hanying Li
Clim. Past, 16, 211–225, https://doi.org/10.5194/cp-16-211-2020, https://doi.org/10.5194/cp-16-211-2020, 2020
Short summary
Short summary
Few studies have paid attention to the important effect of nonsummer monsoon (NSM) precipitation on the speleothem δ18O in SE China. We find the summer monsoon precipitation is equivalent to NSM precipitation amount in the area of spring persistent rain in SE China, and we discuss the relationships between seasonal precipitation amount, moisture source, δ18O, and ENSO. Characterizing the spatial differences in seasonal precipitation is key to interpreting the speleothem δ18O record.
Inken Heidke, Denis Scholz, and Thorsten Hoffmann
Clim. Past, 15, 1025–1037, https://doi.org/10.5194/cp-15-1025-2019, https://doi.org/10.5194/cp-15-1025-2019, 2019
Short summary
Short summary
This is the first quantitative study of lignin biomarkers in stalagmites and cave drip water. Lignin is only produced by higher plants; therefore, its analysis can be used to reconstruct the vegetation of the past. We compared our lignin results with stable isotope and trace element records from the same samples and found correlations or similarities with P, Ba, U and Mg concentrations as well as δ13C values. These results can help to better interpret other vegetation proxies.
Tobias Anhäuser, Birgit Sehls, Werner Thomas, Claudia Hartl, Markus Greule, Denis Scholz, Jan Esper, and Frank Keppler
Clim. Past Discuss., https://doi.org/10.5194/cp-2019-8, https://doi.org/10.5194/cp-2019-8, 2019
Revised manuscript not accepted
Hanying Li, Hai Cheng, Ashish Sinha, Gayatri Kathayat, Christoph Spötl, Aurèle Anquetil André, Arnaud Meunier, Jayant Biswas, Pengzhen Duan, Youfeng Ning, and Richard Lawrence Edwards
Clim. Past, 14, 1881–1891, https://doi.org/10.5194/cp-14-1881-2018, https://doi.org/10.5194/cp-14-1881-2018, 2018
Short summary
Short summary
The
4.2 ka eventbetween 4.2 and 3.9 ka has been widely discussed in the Northern Hemsiphere but less reported in the Southern Hemisphere. Here, we use speleothem records from Rodrigues in the southwestern Indian Ocean spanning from 6000 to 3000 years ago to investigate the regional hydro-climatic variability. Our records show no evidence for an unusual climate anomaly between 4.2 and 3.9 ka. Instead, it shows a multi-centennial drought between 3.9 and 3.5 ka.
Gayatri Kathayat, Hai Cheng, Ashish Sinha, Max Berkelhammer, Haiwei Zhang, Pengzhen Duan, Hanying Li, Xianglei Li, Youfeng Ning, and R. Lawrence Edwards
Clim. Past, 14, 1869–1879, https://doi.org/10.5194/cp-14-1869-2018, https://doi.org/10.5194/cp-14-1869-2018, 2018
Short summary
Short summary
The 4.2 ka event is generally characterized as an approximately 300-year period of major global climate anomaly. However, the climatic manifestation of this event remains unclear in the Indian monsoon domain. Our high-resolution and precisely dated speleothem record from Meghalaya, India, characterizes the event as consisting of a series of multi-decadal droughts between 3.9 and 4.0 ka rather than a singular pulse of multi-centennial drought as previously thought.
Haiwei Zhang, Hai Cheng, Yanjun Cai, Christoph Spötl, Gayatri Kathayat, Ashish Sinha, R. Lawrence Edwards, and Liangcheng Tan
Clim. Past, 14, 1805–1817, https://doi.org/10.5194/cp-14-1805-2018, https://doi.org/10.5194/cp-14-1805-2018, 2018
Short summary
Short summary
The collapses of several Neolithic cultures in China are considered to have been associated with abrupt climate change during the 4.2 ka BP event; however, the hydroclimate of this event in China is still poorly known. Based on stalagmite records from monsoonal China, we found that north China was dry but south China was wet during this event. We propose that the rain belt remained longer at its southern position, giving rise to a pronounced humidity gradient between north and south China.
Florian Adolphi, Christopher Bronk Ramsey, Tobias Erhardt, R. Lawrence Edwards, Hai Cheng, Chris S. M. Turney, Alan Cooper, Anders Svensson, Sune O. Rasmussen, Hubertus Fischer, and Raimund Muscheler
Clim. Past, 14, 1755–1781, https://doi.org/10.5194/cp-14-1755-2018, https://doi.org/10.5194/cp-14-1755-2018, 2018
Short summary
Short summary
The last glacial period was characterized by a number of rapid climate changes seen, for example, as abrupt warmings in Greenland and changes in monsoon rainfall intensity. However, due to chronological uncertainties it is challenging to know how tightly coupled these changes were. Here we exploit cosmogenic signals caused by changes in the Sun and Earth magnetic fields to link different climate archives and improve our understanding of the dynamics of abrupt climate change.
Inken Heidke, Denis Scholz, and Thorsten Hoffmann
Biogeosciences, 15, 5831–5845, https://doi.org/10.5194/bg-15-5831-2018, https://doi.org/10.5194/bg-15-5831-2018, 2018
Short summary
Short summary
We developed a sensitive method to analyze the lignin composition of organic traces contained in speleothems. Lignin is a main constituent of woody plants and its composition contains information about the type of vegetation. This method offers new possibilities to reconstruct the vegetation of past millennia since it combines the advantages of lignin analysis as a highly specific vegetation biomarker with the benefits of speleothems as unique terrestrial climate archives.
Kamolphat Atsawawaranunt, Laia Comas-Bru, Sahar Amirnezhad Mozhdehi, Michael Deininger, Sandy P. Harrison, Andy Baker, Meighan Boyd, Nikita Kaushal, Syed Masood Ahmad, Yassine Ait Brahim, Monica Arienzo, Petra Bajo, Kerstin Braun, Yuval Burstyn, Sakonvan Chawchai, Wuhui Duan, István Gábor Hatvani, Jun Hu, Zoltán Kern, Inga Labuhn, Matthew Lachniet, Franziska A. Lechleitner, Andrew Lorrey, Carlos Pérez-Mejías, Robyn Pickering, Nick Scroxton, and SISAL Working Group Members
Earth Syst. Sci. Data, 10, 1687–1713, https://doi.org/10.5194/essd-10-1687-2018, https://doi.org/10.5194/essd-10-1687-2018, 2018
Short summary
Short summary
This paper is an overview of the contents of the SISAL database and its structure. The database contains oxygen and carbon isotope measurements from 371 individual speleothem records and 10 composite records from 174 cave systems from around the world. The SISAL database is created by a collective effort of the members of the Past Global Changes SISAL working group, which aims to provide a comprehensive compilation of speleothem isotope records for climate reconstruction and model evaluation.
Hongrui Zhang, Heather Stoll, Clara Bolton, Xiaobo Jin, and Chuanlian Liu
Biogeosciences, 15, 4759–4775, https://doi.org/10.5194/bg-15-4759-2018, https://doi.org/10.5194/bg-15-4759-2018, 2018
Short summary
Short summary
The sinking speeds of coccoliths are relevant for laboratory methods to separate coccoliths for geochemical analysis. However, in the absence of estimates of coccolith settling velocity, previous implementations have depended mainly on time-consuming method development by trial and error. In this study, the sinking velocities of cocooliths were carefully measured for the first time. We also provide an estimation of coccolith sinking velocity by shape, which will make coccolith separation easier.
Gabriella Koltai, Hai Cheng, and Christoph Spötl
Clim. Past, 14, 369–381, https://doi.org/10.5194/cp-14-369-2018, https://doi.org/10.5194/cp-14-369-2018, 2018
Short summary
Short summary
Here we present a multi-proxy study of flowstones in fractures of crystalline rocks with the aim of assessing the palaeoclimate significance of this new type of speleothem archive. Our results indicate a high degree of spatial heterogeneity, whereby changes in speleothem mineralogy and carbon isotope composition are likely governed by aquifer-internal processes. In contrast, the oxygen isotope composition reflects first-order climate variability.
Saúl González-Lemos, José Guitián, Miguel-Ángel Fuertes, José-Abel Flores, and Heather M. Stoll
Biogeosciences, 15, 1079–1091, https://doi.org/10.5194/bg-15-1079-2018, https://doi.org/10.5194/bg-15-1079-2018, 2018
Short summary
Short summary
Changes in atmospheric carbon dioxide affect ocean chemistry and the ability of marine organisms to manufacture shells from calcium carbonate. We describe a technique to obtain more reproducible measurements of the thickness of calcium carbonate shells made by microscopic marine algae called coccolithophores, which will allow researchers to compare how the shell thickness responds to variations in ocean chemistry in the past and present.
Ny Riavo Gilbertinie Voarintsoa, Loren Bruce Railsback, George Albert Brook, Lixin Wang, Gayatri Kathayat, Hai Cheng, Xianglei Li, Richard Lawrence Edwards, Amos Fety Michel Rakotondrazafy, and Marie Olga Madison Razanatseheno
Clim. Past, 13, 1771–1790, https://doi.org/10.5194/cp-13-1771-2017, https://doi.org/10.5194/cp-13-1771-2017, 2017
Short summary
Short summary
This research has been an investigation of two stalagmites from two caves in NW Madagascar to reconstruct the region's paleoenvironmental changes, and to understand the linkage of such changes to the dynamics of the ITCZ. Stable isotopes, mineralogy, and petrography suggest wetter climate conditions than today during the early and late Holocene, when the mean ITCZ was south, and drier during the mid-Holocene when the ITCZ was north.
Stef Vansteenberge, Sophie Verheyden, Hai Cheng, R. Lawrence Edwards, Eddy Keppens, and Philippe Claeys
Clim. Past, 12, 1445–1458, https://doi.org/10.5194/cp-12-1445-2016, https://doi.org/10.5194/cp-12-1445-2016, 2016
Short summary
Short summary
The use of stalagmites for last interglacial continental climate reconstructions in Europe has been successful in the past; however to expand the geographical coverage, additional data from Belgium is presented. It has been shown that stalagmite growth, morphology and stable isotope content reflect regional and local climate conditions, with Eemian optimum climate occurring between 125.3 and 117.3 ka. The start the Weichselian is expressed by a stop of growth caused by a drying climate.
M. N. Müller, M. Lebrato, U. Riebesell, J. Barcelos e Ramos, K. G. Schulz, S. Blanco-Ameijeiras, S. Sett, A. Eisenhauer, and H. M. Stoll
Biogeosciences, 11, 1065–1075, https://doi.org/10.5194/bg-11-1065-2014, https://doi.org/10.5194/bg-11-1065-2014, 2014
M. Pacton, S. F. M. Breitenbach, F. A. Lechleitner, A. Vaks, C. Rollion-Bard, O. S. Gutareva, A. V. Osintcev, and C. Vasconcelos
Biogeosciences, 10, 6115–6130, https://doi.org/10.5194/bg-10-6115-2013, https://doi.org/10.5194/bg-10-6115-2013, 2013
G. Lohmann, A. Wackerbarth, P. M. Langebroek, M. Werner, J. Fohlmeister, D. Scholz, and A. Mangini
Clim. Past, 9, 89–98, https://doi.org/10.5194/cp-9-89-2013, https://doi.org/10.5194/cp-9-89-2013, 2013
Related subject area
Subject: Proxy Use-Development-Validation | Archive: Terrestrial Archives | Timescale: Pleistocene
The Indo–Pacific Pollen Database – a Neotoma constituent database
Can machine-learning algorithms improve upon classical palaeoenvironmental reconstruction models?
Multi-proxy speleothem-based reconstruction of mid-MIS 3 climate in South Africa
Biomarker proxy records of Arctic climate change during the Mid-Pleistocene transition from Lake El'gygytgyn (Far East Russia)
Hydroclimatic variability of opposing Late Pleistocene climates in the Levant revealed by deep Dead Sea sediments
Different facets of dry–wet patterns in south-western China over the past 27 000 years
The triple oxygen isotope composition of phytoliths, a new proxy of atmospheric relative humidity: controls of soil water isotope composition, temperature, CO2 concentration and relative humidity
The speleothem oxygen record as a proxy for thermal or moisture changes: a case study of multiproxy records from MIS 5–MIS 6 speleothems from the Demänová Cave system
A new multivariable benchmark for Last Glacial Maximum climate simulations
The Last Glacial Maximum in the central North Island, New Zealand: palaeoclimate inferences from glacier modelling
Late-glacial to late-Holocene shifts in global precipitation δ18O
Climate history of the Southern Hemisphere Westerlies belt during the last glacial–interglacial transition revealed from lake water oxygen isotope reconstruction of Laguna Potrok Aike (52° S, Argentina)
New online method for water isotope analysis of speleothem fluid inclusions using laser absorption spectroscopy (WS-CRDS)
Inorganic geochemistry data from Lake El'gygytgyn sediments: marine isotope stages 6–11
A 350 ka record of climate change from Lake El'gygytgyn, Far East Russian Arctic: refining the pattern of climate modes by means of cluster analysis
Dynamic diatom response to changing climate 0–1.2 Ma at Lake El'gygytgyn, Far East Russian Arctic
Amplified bioproductivity during Transition IV (332 000–342 000 yr ago): evidence from the geochemical record of Lake El'gygytgyn
Potential and limits of OSL, TT-OSL, IRSL and pIRIR290 dating methods applied on a Middle Pleistocene sediment record of Lake El'gygytgyn, Russia
Rock magnetic properties, magnetic susceptibility, and organic geochemistry comparison in core LZ1029-7 Lake El'gygytgyn, Russia Far East
High-temperature thermomagnetic properties of vivianite nodules, Lake El'gygytgyn, Northeast Russia
Reconstruction of drip-water δ18O based on calcite oxygen and clumped isotopes of speleothems from Bunker Cave (Germany)
A biomarker record of Lake El'gygytgyn, Far East Russian Arctic: investigating sources of organic matter and carbon cycling during marine isotope stages 1–3
Climate warming and vegetation response after Heinrich event 1 (16 700–16 000 cal yr BP) in Europe south of the Alps
A 250 ka oxygen isotope record from diatoms at Lake El'gygytgyn, far east Russian Arctic
The oxygen isotopic composition of phytolith assemblages from tropical rainforest soil tops (Queensland, Australia): validation of a new paleoenvironmental tool
Terrestrial mollusc records from Xifeng and Luochuan L9 loess strata and their implications for paleoclimatic evolution in the Chinese Loess Plateau during marine Oxygen Isotope Stages 24-22
Annika V. Herbert, Simon G. Haberle, Suzette G. A. Flantua, Ondrej Mottl, Jessica L. Blois, John W. Williams, Adrian George, and Geoff S. Hope
Clim. Past, 20, 2473–2485, https://doi.org/10.5194/cp-20-2473-2024, https://doi.org/10.5194/cp-20-2473-2024, 2024
Short summary
Short summary
The Indo-Pacific Pollen Database is a large collection of pollen samples from across the Indo-Pacific region, with most samples coming from Australia. This is a valuable collection that can be used to analyse vegetation dynamics going back thousands of years. It is now being fully shared via Neotoma for the first time, opening up many exciting new avenues of research. This paper presents key aspects of this database, including geographical distribution, age control and deposition times.
Peng Sun, Philip B. Holden, and H. John B. Birks
Clim. Past, 20, 2373–2398, https://doi.org/10.5194/cp-20-2373-2024, https://doi.org/10.5194/cp-20-2373-2024, 2024
Short summary
Short summary
We develop the Multi Ensemble Machine Learning Model (MEMLM) for reconstructing palaeoenvironments from microfossil assemblages. The machine-learning approaches, which include random tree and natural language processing techniques, substantially outperform classical approaches under cross-validation, but they can fail when applied to reconstruct past environments. Statistical significance testing is found sufficient to identify these unreliable reconstructions.
Jenny Maccali, Anna Nele Meckler, Stein-Erik Lauritzen, Torill Brekken, Helen Aase Rokkan, Alvaro Fernandez, Yves Krüger, Jane Adigun, Stéphane Affolter, and Markus Leuenberger
Clim. Past, 19, 1847–1862, https://doi.org/10.5194/cp-19-1847-2023, https://doi.org/10.5194/cp-19-1847-2023, 2023
Short summary
Short summary
The southern coast of South Africa hosts some key archeological sites for the study of early human evolution. Here we present a short but high-resolution record of past changes in the hydroclimate and temperature on the southern coast of South Africa based on the study of a speleothem collected from Bloukrantz Cave. Overall, the paleoclimate indicators suggest stable temperature from 48.3 to 45.2 ka, whereas precipitation was variable, with marked short drier episodes.
Kurt R. Lindberg, William C. Daniels, Isla S. Castañeda, and Julie Brigham-Grette
Clim. Past, 18, 559–577, https://doi.org/10.5194/cp-18-559-2022, https://doi.org/10.5194/cp-18-559-2022, 2022
Short summary
Short summary
Earth experiences regular ice ages resulting in shifts between cooler and warmer climates. Around 1 million years ago, the ice age cycles grew longer and stronger. We used bacterial and plant lipids preserved in an Arctic lake to reconstruct temperature and vegetation during this climate transition. We find that Arctic land temperatures did not cool much compared to ocean records from this period, and that vegetation shifts correspond with a long-term drying previously reported in the region.
Yoav Ben Dor, Francesco Marra, Moshe Armon, Yehouda Enzel, Achim Brauer, Markus Julius Schwab, and Efrat Morin
Clim. Past, 17, 2653–2677, https://doi.org/10.5194/cp-17-2653-2021, https://doi.org/10.5194/cp-17-2653-2021, 2021
Short summary
Short summary
Laminated sediments from the deepest part of the Dead Sea unravel the hydrological response of the eastern Mediterranean to past climate changes. This study demonstrates the importance of geological archives in complementing modern hydrological measurements that do not fully capture natural hydroclimatic variability, which is crucial to configure for understanding the impact of climate change on the hydrological cycle in subtropical regions.
Mengna Liao, Kai Li, Weiwei Sun, and Jian Ni
Clim. Past, 17, 2291–2303, https://doi.org/10.5194/cp-17-2291-2021, https://doi.org/10.5194/cp-17-2291-2021, 2021
Short summary
Short summary
The long-term trajectories of precipitation, hydrological balance and soil moisture are not completely consistent in southwest China. Hydrological balance was more sensitive to temperature change on a millennial scale. For soil moisture, plant processes also played a big role in addition to precipitation and temperature. Under future climate warming, surface water shortage in southwest China can be even more serious and efforts at reforestation may bring some relief to the soil moisture deficit.
Clément Outrequin, Anne Alexandre, Christine Vallet-Coulomb, Clément Piel, Sébastien Devidal, Amaelle Landais, Martine Couapel, Jean-Charles Mazur, Christophe Peugeot, Monique Pierre, Frédéric Prié, Jacques Roy, Corinne Sonzogni, and Claudia Voigt
Clim. Past, 17, 1881–1902, https://doi.org/10.5194/cp-17-1881-2021, https://doi.org/10.5194/cp-17-1881-2021, 2021
Short summary
Short summary
Continental atmospheric humidity is a key climate parameter poorly captured by global climate models. Model–data comparison approaches that are applicable beyond the instrumental period are essential to progress on this issue but face a lack of quantitative relative humidity proxies. Here, we calibrate the triple oxygen isotope composition of phytoliths as a new quantitative proxy of continental relative humidity suitable for past climate reconstructions.
Jacek Pawlak
Clim. Past, 17, 1051–1064, https://doi.org/10.5194/cp-17-1051-2021, https://doi.org/10.5194/cp-17-1051-2021, 2021
Short summary
Short summary
Presently, central Europe is under the influence of two types of climate, transitional and continental. The 60 ka long multiproxy speleothem dataset from Slovakia records the climate of the Last Interglacial cycle and its transition to the Last Glacial. The interpretation of stable isotopic composition and trace element content proxies helps to distinguish which factor had the strongest influence on the δ18O record shape: the local temperature, the humidity or the source effect.
Sean F. Cleator, Sandy P. Harrison, Nancy K. Nichols, I. Colin Prentice, and Ian Roulstone
Clim. Past, 16, 699–712, https://doi.org/10.5194/cp-16-699-2020, https://doi.org/10.5194/cp-16-699-2020, 2020
Short summary
Short summary
We present geographically explicit reconstructions of seasonal temperature and annual moisture variables at the Last Glacial Maximum (LGM), 21 000 years ago. The reconstructions use existing site-based estimates of climate, interpolated in space and time in a physically consistent way using climate model simulations. The reconstructions give a much better picture of the LGM climate and will provide a robust evaluation of how well state-of-the-art climate models simulate large climate changes.
Shaun R. Eaves, Andrew N. Mackintosh, Brian M. Anderson, Alice M. Doughty, Dougal B. Townsend, Chris E. Conway, Gisela Winckler, Joerg M. Schaefer, Graham S. Leonard, and Andrew T. Calvert
Clim. Past, 12, 943–960, https://doi.org/10.5194/cp-12-943-2016, https://doi.org/10.5194/cp-12-943-2016, 2016
Short summary
Short summary
Geological evidence for past changes in glacier length provides a useful source of information about pre-historic climate change. We have used glacier modelling to show that air temperature reductions of −5 to −7 °C, relative to present, are required to simulate the glacial extent in the North Island, New Zealand, during the last ice age (approx. 20000 years ago). Our results provide data to assess climate model simulations, with the aim of determining the drivers of past natural climate change.
S. Jasechko, A. Lechler, F. S. R. Pausata, P. J. Fawcett, T. Gleeson, D. I. Cendón, J. Galewsky, A. N. LeGrande, C. Risi, Z. D. Sharp, J. M. Welker, M. Werner, and K. Yoshimura
Clim. Past, 11, 1375–1393, https://doi.org/10.5194/cp-11-1375-2015, https://doi.org/10.5194/cp-11-1375-2015, 2015
Short summary
Short summary
In this study we compile global isotope proxy records of climate changes from the last ice age to the late-Holocene preserved in cave calcite, glacial ice and groundwater aquifers. We show that global patterns of late-Pleistocene to late-Holocene precipitation isotope shifts are consistent with stronger-than-modern isotopic distillation of air masses during the last ice age, likely impacted by larger global temperature differences between the tropics and the poles.
J. Zhu, A. Lücke, H. Wissel, C. Mayr, D. Enters, K. Ja Kim, C. Ohlendorf, F. Schäbitz, and B. Zolitschka
Clim. Past, 10, 2153–2169, https://doi.org/10.5194/cp-10-2153-2014, https://doi.org/10.5194/cp-10-2153-2014, 2014
S. Affolter, D. Fleitmann, and M. Leuenberger
Clim. Past, 10, 1291–1304, https://doi.org/10.5194/cp-10-1291-2014, https://doi.org/10.5194/cp-10-1291-2014, 2014
P. S. Minyuk, V. Y. Borkhodoev, and V. Wennrich
Clim. Past, 10, 467–485, https://doi.org/10.5194/cp-10-467-2014, https://doi.org/10.5194/cp-10-467-2014, 2014
U. Frank, N. R. Nowaczyk, P. Minyuk, H. Vogel, P. Rosén, and M. Melles
Clim. Past, 9, 1559–1569, https://doi.org/10.5194/cp-9-1559-2013, https://doi.org/10.5194/cp-9-1559-2013, 2013
J. A. Snyder, M. V. Cherepanova, and A. Bryan
Clim. Past, 9, 1309–1319, https://doi.org/10.5194/cp-9-1309-2013, https://doi.org/10.5194/cp-9-1309-2013, 2013
L. Cunningham, H. Vogel, V. Wennrich, O. Juschus, N. Nowaczyk, and P. Rosén
Clim. Past, 9, 679–686, https://doi.org/10.5194/cp-9-679-2013, https://doi.org/10.5194/cp-9-679-2013, 2013
A. Zander and A. Hilgers
Clim. Past, 9, 719–733, https://doi.org/10.5194/cp-9-719-2013, https://doi.org/10.5194/cp-9-719-2013, 2013
K. J. Murdock, K. Wilkie, and L. L. Brown
Clim. Past, 9, 467–479, https://doi.org/10.5194/cp-9-467-2013, https://doi.org/10.5194/cp-9-467-2013, 2013
P. S. Minyuk, T. V. Subbotnikova, L. L. Brown, and K. J. Murdock
Clim. Past, 9, 433–446, https://doi.org/10.5194/cp-9-433-2013, https://doi.org/10.5194/cp-9-433-2013, 2013
T. Kluge, H. P. Affek, T. Marx, W. Aeschbach-Hertig, D. F. C. Riechelmann, D. Scholz, S. Riechelmann, A. Immenhauser, D. K. Richter, J. Fohlmeister, A. Wackerbarth, A. Mangini, and C. Spötl
Clim. Past, 9, 377–391, https://doi.org/10.5194/cp-9-377-2013, https://doi.org/10.5194/cp-9-377-2013, 2013
A. R. Holland, S. T. Petsch, I. S. Castañeda, K. M. Wilkie, S. J. Burns, and J. Brigham-Grette
Clim. Past, 9, 243–260, https://doi.org/10.5194/cp-9-243-2013, https://doi.org/10.5194/cp-9-243-2013, 2013
S. Samartin, O. Heiri, A. F. Lotter, and W. Tinner
Clim. Past, 8, 1913–1927, https://doi.org/10.5194/cp-8-1913-2012, https://doi.org/10.5194/cp-8-1913-2012, 2012
B. Chapligin, H. Meyer, G. E. A. Swann, C. Meyer-Jacob, and H.-W. Hubberten
Clim. Past, 8, 1621–1636, https://doi.org/10.5194/cp-8-1621-2012, https://doi.org/10.5194/cp-8-1621-2012, 2012
A. Alexandre, J. Crespin, F. Sylvestre, C. Sonzogni, and D. W. Hilbert
Clim. Past, 8, 307–324, https://doi.org/10.5194/cp-8-307-2012, https://doi.org/10.5194/cp-8-307-2012, 2012
B. Wu and N. Q. Wu
Clim. Past, 7, 349–359, https://doi.org/10.5194/cp-7-349-2011, https://doi.org/10.5194/cp-7-349-2011, 2011
Cited articles
Alkhatib, M., Qutob, M., Alkhatib, S., and Eisenhauer, A.: Influence of precipitation rate and temperature on the partitioning of magnesium and strontium in calcite overgrowths, Chem. Geol., 599, 120841, https://doi.org/10.1016/j.chemgeo.2022.120841, 2022.
Ausín, B., Magill, C., Haghipour, N., Fernández, Á., Wacker, L., Hodell, D., Baumann, K.-H., and Eglinton, T. I.: (In) coherent multiproxy signals in marine sediments: Implications for high-resolution paleoclimate reconstruction, Earth Planet. Sc. Lett., 515, 38–46, 2019.
Breitenbach, S. F. and Bernasconi, S. M.: Carbon and oxygen isotope analysis of small carbonate samples (20 to 100 µg) with a GasBench II preparation device, Rapid Commun. Mass Spectrom., 25, 1910–1914, 2011.
Cacho, I., Grimalt, J. O., Pelejero, C., Canals, M., Sierro, F. J., Flores, J. A., and Shackleton, N.: Dansgaard-Oeschger and Heinrich event imprints in Alboran Sea paleotemperatures, Paleoceanography, 14, 698–705, 1999.
Day, C. C. and Henderson, G. M.: Controls on trace-element partitioning in cave-analogue calcite, Geochim. Cosmochim. Ac., 120, 612–627, 2013.
DePaolo, D. J.: Surface kinetic model for isotopic and trace element fractionation during precipitation of calcite from aqueous solutions, Geochim. Cosmochim. Ac., 75, 1039–1056, https://doi.org/10.1016/j.gca.2010.11.020, 2011.
de Wet, C. B., Erhardt, A. M., Sharp, W. D., Marks, N. E., Bradbury, H. J., Turchyn, A. V., Xu, Y., and Oster, J. L.: Semiquantitative estimates of rainfall variability during the 8.2 kyr event in California using speleothem calcium isotope ratios, Geophys. Res. Lett., 48, e2020GL089154, https://doi.org/10.1029/2020GL089154, 2021.
Dorale, J. A. and Liu, Z.: Limitations of Hendy test criteria in judging the paleoclimatic suitability of speleothems and the need for replication, J. Cave Karst Stud., 71, 73–80, 2009.
Emrich, K., Ehhalt, D., and Vogel, J.: Carbon isotope fractionation during the precipitation of calcium carbonate, Earth Planet. Sc. Lett., 8, 363–371, 1970.
Fairchild, I. J. and Treble, P. C.: Trace elements in speleothems as recorders of environmental change, Quaternary Sci. Rev., 28, 449–468, 2009.
Frisia, S., Borsato, A., Hartland, A., Faraji, M., Demeny, A., Drysdale, R. N., and Marjo, C. E.: Crystallization pathways, fabrics and the capture of climate proxies in speleothems: Examples from the tropics, Quaternary Sci. Rev., 297, 107833, https://doi.org/10.1016/j.quascirev.2022.107833, 2022.
Genty, D., Blamart, D., Ouahdi, R., Gilmour, M., Baker, A., Jouzel, J., and Van-Exter, S.: Precise dating of Dansgaard–Oeschger climate oscillations in western Europe from stalagmite data, Nature, 421, 833–837, 2003.
Genty, D., Blamart, D., Ghaleb, B., Plagnes, V., Causse, C., Bakalowicz, M., Zouari, K., Chkir, N., Hellstrom, J., and Wainer, K.: Timing and dynamics of the last deglaciation from European and North African δ13C stalagmite profiles – comparison with Chinese and South Hemisphere stalagmites, Quaternary Sci. Rev., 25, 2118–2142, 2006.
Goni, M. F. S., Landais, A., Fletcher, W. J., Naughton, F., Desprat, S., and Duprat, J.: Contrasting impacts of Dansgaard–Oeschger events over a western European latitudinal transect modulated by orbital parameters, Quaternary Sci. Rev., 27, 1136–1151, 2008.
Hansen, M., Scholz, D., Froeschmann, M.-L., Schöne, B. R., and Spötl, C.: Carbon isotope exchange between gaseous CO2 and thin solution films: Artificial cave experiments and a complete diffusion-reaction model, Geochim. Cosmochim. Ac., 211, 28–47, 2017.
Hansen, M., Scholz, D., Schöne, B. R., and Spötl, C.: Simulating speleothem growth in the laboratory: Determination of the stable isotope fractionation (δ13C and δ18O) between H2O, DIC and CaCO3, Chem. Geol., 509, 20–44, 2019.
Hendy, C. H.: The isotopic geochemistry of speleothems – I. The calculation of the effects of different modes of formation on the isotopic composition of speleothems and their applicability as palaeoclimatic indicators, Geochim. Cosmochim. Ac., 35, 801–824, https://doi.org/10.1016/0016-7037(71)90127-X, 1971.
Hippler, D., Schmitt, A. D., Gussone, N., Heuser, A., Stille, P., Eisenhauer, A., and Nägler, T. F.: Calcium isotopic composition of various reference materials and seawater, Geostand. Newslett., 27, 13–19, 2003.
Hofmann, A. E., Bourg, I. C., and DePaolo, D. J.: Ion desolvation as a mechanism for kinetic isotope fractionation in aqueous systems, P. Natl. Acad. Sci. USA, 109, 18689–18694, 2012.
Kost, O., Sliwinski, J., Gies, N., Lueder, M., and Stoll, H. M.: The influence of fluid inclusions, organics, and calcite fabric on trace element distributions in stalagmites, Front. Earth Sci., 202311, 1240888, https://doi.org/10.3389/feart.2023.1240888, 2023a.
Kost, O., Gonzalez Lemos, S., Rodriguez-Rodriguez, L., Sliwinski, J., Endres, L., Haghipour, N., and Stoll, H. M.: Relationship of seasonal variations in drip water δ13CDIC, δ18O, and trace elements with surface and physical cave conditions of La Vallina cave, NW Spain, Hydrol. Earth Syst. Sci., 27, 2227–2255, https://doi.org/10.5194/hess-27-2227-2023, 2023b.
Lechleitner, F. A., Day, C. C., Kost, O., Wilhelm, M., Haghipour, N., Henderson, G. M., and Stoll, H. M.: Stalagmite carbon isotopes suggest deglacial increase in soil respiration in western Europe driven by temperature change, Clim. Past, 17, 1903–1918, https://doi.org/10.5194/cp-17-1903-2021, 2021.
Li, X., Hu, C., Huang, J., Xie, S., and Baker, A.: A 9000-year carbon isotopic record of acid-soluble organic matter in a stalagmite from Heshang Cave, central China: Paleoclimate implications, Chem. Geol., 388, 71–77, 2014.
Li, X., Cui, X., He, D., Liao, J., and Hu, C.: Evaluation of the Heshang Cave stalagmite calcium isotope composition as a paleohydrologic proxy by comparison with the instrumental precipitation record, Sci. Rep., 8, 1–7, 2018.
Lorens, R. B.: Sr, Cd, Mn and Co distribution coefficients in calcite as a function of calcite precipitation rate, Geochim. Cosmochim. Ac., 45, 553–561, 1981.
Magiera, M., Lechleitner, F. A., Erhardt, A. M., Hartland, A., Kwiecien, O., Cheng, H., Bradbury, H. J., Turchyn, A. V., Riechelmann, S., and Edwards, L.: Local and regional Indian summer monsoon precipitation dynamics during Termination II and the Last Interglacial, Geophys. Res. Lett., 46, 12454–12463, 2019.
Martrat, B., Grimalt, J. O., Shackleton, N. J., de Abreu, L., Hutterli, M. A., and Stocker, T. F.: Four climate cycles of recurring deep and surface water destabilizations on the Iberian margin, Science, 317, 502–507, 2007.
Meyer, K. W., Feng, W., Breecker, D. O., Banner, J. L., and Guilfoyle, A.: Interpretation of speleothem calcite δ13C variations: Evidence from monitoring soil CO2, drip water, and modern speleothem calcite in central Texas, Geochim. Cosmochim. Ac., 142, 281–298, 2014.
Mickler, P. J., Banner, J. L., Stern, L., Asmerom, Y., Edwards, R. L., and Ito, E.: Stable isotope variations in modern tropical speleothems: evaluating equilibrium vs. kinetic isotope effects, Geochim. Cosmochim. Ac., 68, 4381–4393, 2004.
Mickler, P. J., Stern, L. A., and Banner, J. L.: Large kinetic isotope effects in modern speleothems, Geol. Soc. Am. Bull., 118, 65–81, 2006.
Mickler, P. J., Carlson, P., Banner, J. L., Breecker, D. O., Stern, L., and Guilfoyle, A.: Quantifying carbon isotope disequilibrium during in-cave evolution of drip water along discreet flow paths, Geochim. Cosmochim. Ac., 244, 182–196, 2019.
Mills, J. V., DePaolo, D. J., and Lammers, L. N.: The influence of Ca:CO3 stoichiometry on Ca isotope fractionation: Implications for process-based models of calcite growth, Geochim. Cosmochim. Ac., 298, 87–111, 2021.
Mucci, A. and Morse, J. W.: The incorporation of Mg2+ and Sr2+ into calcite overgrowths: influences of growth rate and solution composition, Geochim. Cosmochim. Ac., 47, 217–233, 1983.
Mühlinghaus, C., Scholz, D., and Mangini, A.: Modelling stalagmite growth and δ13C as a function of drip interval and temperature, Geochim. Cosmochim. Ac., 71, 2780–2790, 2007.
Mühlinghaus, C., Scholz, D., and Mangini, A.: Modelling fractionation of stable isotopes in stalagmites, Geochim. Cosmochim. Ac., 73, 7275–7289, 2009.
Nielsen, L. C., De Yoreo, J. J., and DePaolo, D. J.: General model for calcite growth kinetics in the presence of impurity ions, Geochim. Cosmochim. Ac., 115, 100–114, 2013.
Noronha, A. L., Johnson, K. R., Hu, C., Ruan, J., Southon, J. R., and Ferguson, J. E.: Assessing influences on speleothem dead carbon variability over the Holocene: implications for speleothem-based radiocarbon calibration, Earth Planet. Sc. Lett., 394, 20–29, 2014.
Owen, R., Day, C., Hu, C.-Y., Liu, Y.-H., Pointing, M., Blättler, C., and Henderson, G.: Calcium isotopes in caves as a proxy for aridity: Modern calibration and application to the 8.2 kyr event, Earth Planet. Sc. Lett., 443, 129–138, 2016.
Owen, R., Day, C. C., and Henderson, G. M.: CaveCalc: A new model for speleothem chemistry & isotopes, Comput. Geosci., 119, 115–122, 2018.
Pataki, D., Ehleringer, J., Flanagan, L., Yakir, D., Bowling, D., Still, C., Buchmann, N., Kaplan, J. O., and Berry, J.: The application and interpretation of Keeling plots in terrestrial carbon cycle research, Global Biogeochem. Cy., 17, 1022, https://doi.org/10.1029/2001GB001850, 2003.
Polag, D., Scholz, D., Mühlinghaus, C., Spötl, C., Schröder-Ritzrau, A., Segl, M., and Mangini, A.: Stable isotope fractionation in speleothems: Laboratory experiments, Chem. Geol., 279, 31–39, https://doi.org/10.1016/j.chemgeo.2010.09.016, 2010.
Reynard, L., Day, C., and Henderson, G.: Large fractionation of calcium isotopes during cave-analogue calcium carbonate growth, Geochim. Cosmochim. Ac., 75, 3726–3740, 2011.
Romanek, C. S., Grossman, E. L., and Morse, J. W.: Carbon isotopic fractionation in synthetic aragonite and calcite: effects of temperature and precipitation rate, Geochim. Cosmochim. Ac., 56, 419–430, 1992.
Romanov, D., Kaufmann, G., and Dreybrodt, W.: Modeling stalagmite growth by first principles of chemistry and physics of calcite precipitation, Geochim. Cosmochim. Ac., 72, 423–437, 2008.
Romero-Mujalli, G., Hartmann, J., Börker, J., Gaillardet, J., and Calmels, D.: Ecosystem controlled soil-rock pCO2 and carbonate weathering – Constraints by temperature and soil water content, Chem. Geol., 527, 118634, https://doi.org/10.1016/j.chemgeo.2018.01.030, 2019.
Rubinson, M. and Clayton, R. N.: Carbon-13 fractionation between aragonite and calcite, Geochim. Cosmochim. Ac., 33, 997–1002, 1969.
Sade, Z., Hegyi, S., Hansen, M., Scholz, D., and Halevy, I.: The effects of drip rate and geometry on the isotopic composition of speleothems: Evaluation with an advection-diffusion-reaction model, Geochim. Cosmochim. Ac., 317, 409–432, 2022.
Scholz, D., Mühlinghaus, C., and Mangini, A.: Modelling δ13C and δ18O in the solution layer on stalagmite surfaces, Geochim. Cosmochim. Ac., 73, 2592–2602, 2009.
Sinclair, D. J.: Two mathematical models of Mg and Sr partitioning into solution during incongruent calcite dissolution: implications for dripwater and speleothem studies, Chem. Geol., 283, 119–133, 2011.
Sinclair, D. J., Banner, J. L., Taylor, F. W., Partin, J., Jenson, J., Mylroie, J., Goddard, E., Quinn, T., Jocson, J., and Miklavič, B.: Magnesium and strontium systematics in tropical speleothems from the Western Pacific, Chem. Geol., 294, 1–17, 2012.
Sliwinski, J., Kost, O., Endres, L., Iglesias, M., Haghipour, N., González-Lemos, S., and Stoll, H.: Exploring soluble and colloidally transported trace elements in stalagmites: The strontium-yttrium connection, Geochim. Cosmochim. Ac., 343, 64–83, 2023.
Sliwinski, J. T. and Stoll, H. M.: Combined fluorescence imaging and LA-ICP-MS trace element mapping of stalagmites: Microfabric identification and interpretation, Chem. Geol., 581, 120397, https://doi.org/10.1016/j.chemgeo.2021.120397, 2021.
Stoll, H., Mendez-Vicente, A., Gonzalez-Lemos, S., Moreno, A., Cacho, I., Cheng, H., and Edwards, R. L.: Interpretation of orbital scale variability in mid-latitude speleothem δ18O: Significance of growth rate controlled kinetic fractionation effects, Quaternary Sci. Rev., 127, 215–228, 2015.
Stoll, H. M., Müller, W., and Prieto, M.: I-STAL, a model for interpretation of
Stoll, H. M., Moreno, A., Mendez-Vicente, A., Gonzalez-Lemos, S., Jimenez-Sanchez, M., Dominguez-Cuesta, M. J., Edwards, R. L., Cheng, H., and Wang, X.: Paleoclimate and growth rates of speleothems in the northwestern Iberian Peninsula over the last two glacial cycles, Quatern. Res., 80, 284–290, https://doi.org/10.1016/j.yqres.2013.05.002, 2013.
Stoll, H. M., Cacho, I., Gasson, E., Sliwinski, J., Kost, O., Moreno, A., Iglesias, M., Torner, J., Perez-Mejias, C., and Haghipour, N.: Rapid northern hemisphere ice sheet melting during the penultimate deglaciation, Nat. Commun., 13, 1–16, 2022.
Stoll, H. M., Day, C., Lechleitner, F., Kost, O., Endres, L., Sliwinski, J., Pérez-Mejías, C., Cheng, H., and Scholz, D.: Distinguishing the combined vegetation and soil component of δ13C variation in speleothem records from subsequent degassing and prior calcite precipitation effects, ETH Zürich [data set], https://doi.org/10.3929/ethz-b-000630754, 2023.
Tang, J., Köhler, S. J., and Dietzel, M.: Sr2+/Ca2+ and 44Ca/40Ca fractionation during inorganic calcite formation: I. Sr incorporation, Geochim. Cosmochim. Ac., 72, 3718–3732, 2008a.
Tang, J., Dietzel, M., Böhm, F., Köhler, S. J., and Eisenhauer, A.: Sr2+/Ca2+ and 44Ca/40Ca fractionation during inorganic calcite formation: II. Ca isotopes, Geochim. Cosmochim. Ac., 72, 3733–3745, 2008b.
Tesoriero, A. J. and Pankow, J. F.: Solid solution partitioning of Sr2+, Ba2+, and Cd2+ to calcite, Geochim. Cosmochim. Ac., 60, 1053–1063, 1996.
Tremaine, D. M. and Froelich, P. N.: Speleothem trace element signatures: a hydrologic geochemical study of modern cave dripwaters and farmed calcite, Geochim. Cosmochim. Ac., 121, 522–545, 2013.
Tzedakis, P., Drysdale, R. N., Margari, V., Skinner, L. C., Menviel, L., Rhodes, R. H., Taschetto, A. S., Hodell, D. A., Crowhurst, S. J., and Hellstrom, J. C.: Enhanced climate instability in the North Atlantic and southern Europe during the Last Interglacial, Nat. Commun., 9, 4235, https://doi.org/10.1038/s41467-018-06683-3, 2018.
Wassenburg, J. A., Riechelmann, S., Schröder-Ritzrau, A., Riechelmann, D. F., Richter, D. K., Immenhauser, A., Terente, M., Constantin, S., Hachenberg, A., and Hansen, M.: Calcite Mg and Sr partition coefficients in cave environments: Implications for interpreting prior calcite precipitation in speleothems, Geochim. Cosmochim. Ac., 269, 581–596, 2020.
Short summary
Stalagmites formed in caves provide valuable information about past changes in climate and vegetation conditions. In this contribution, we present a new method to better estimate past changes in soil and vegetation productivity using carbon isotopes and trace elements measured in stalagmites. Applying this method to other stalagmites should provide a better indication of past vegetation feedbacks to climate change.
Stalagmites formed in caves provide valuable information about past changes in climate and...
