Articles | Volume 11, issue 2
https://doi.org/10.5194/cp-11-227-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/cp-11-227-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
11 Feb 2015
Research article |
| 11 Feb 2015
A method for analysis of vanillic acid in polar ice cores
Department of Earth System Science, University of California, Irvine, USA
J. Greaves
Department of Chemistry, University of California, Irvine, USA
E. S. Saltzman
Department of Earth System Science, University of California, Irvine, USA
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Elizabeth R. Thomas, Diana O. Vladimirova, Dieter R. Tetzner, B. Daniel Emanuelsson, Nathan Chellman, Daniel A. Dixon, Hugues Goosse, Mackenzie M. Grieman, Amy C. F. King, Michael Sigl, Danielle G. Udy, Tessa R. Vance, Dominic A. Winski, V. Holly L. Winton, Nancy A. N. Bertler, Akira Hori, Chavarukonam M. Laluraj, Joseph R. McConnell, Yuko Motizuki, Kazuya Takahashi, Hideaki Motoyama, Yoichi Nakai, Franciéle Schwanck, Jefferson Cardia Simões, Filipe Gaudie Ley Lindau, Mirko Severi, Rita Traversi, Sarah Wauthy, Cunde Xiao, Jiao Yang, Ellen Mosely-Thompson, Tamara V. Khodzher, Ludmila P. Golobokova, and Alexey A. Ekaykin
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The concentration of sodium and sulfate measured in Antarctic ice cores is related to changes in both sea ice and winds. Here we have compiled a database of sodium and sulfate records from 105 ice core sites in Antarctica. The records span all, or part, of the past 2000 years. The records will improve our understanding of how winds and sea ice have changed in the past and how they have influenced the climate of Antarctica over the past 2000 years.
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Helene M. Hoffmann, Mackenzie M. Grieman, Amy C. F. King, Jenna A. Epifanio, Kaden Martin, Diana Vladimirova, Helena V. Pryer, Emily Doyle, Axel Schmidt, Jack D. Humby, Isobel F. Rowell, Christoph Nehrbass-Ahles, Elizabeth R. Thomas, Robert Mulvaney, and Eric W. Wolff
Clim. Past, 18, 1831–1847, https://doi.org/10.5194/cp-18-1831-2022, https://doi.org/10.5194/cp-18-1831-2022, 2022
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The WACSWAIN project (WArm Climate Stability of the West Antarctic ice sheet in the last INterglacial) investigates the fate of the West Antarctic Ice Sheet during the last warm period on Earth (115 000–130 000 years before present). Within this framework an ice core was recently drilled at Skytrain Ice Rise. In this study we present a stratigraphic chronology of that ice core based on absolute age markers and annual layer counting for the last 2000 years.
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Changes in the Southern Hemisphere westerly winds are drivers of recent environmental changes in West Antarctica. However, our understanding of this relationship is limited by short and sparse observational records. Here we present the first regional wind study based on the novel use of diatoms preserved in Antarctic ice cores. Our results demonstrate that diatom abundance is the optimal record for reconstructing wind strength variability over the Southern Hemisphere westerly wind belt.
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Vanillic acid is reported in the Tunu ice core from northeastern Greenland. It is an aerosol-borne acid produced by biomass burning. North American boreal forests are likely the source regions of the vanillic acid deposited at the ice core site. Vanillic acid levels were elevated during warm climate periods and lower during cooler climate periods. There is a positive correlation between the vanillic acid ice core record and ammonium and black carbon in the NEEM ice core from northern Greenland.
Mackenzie M. Grieman, Murat Aydin, Elisabeth Isaksson, Margit Schwikowski, and Eric S. Saltzman
Clim. Past, 14, 637–651, https://doi.org/10.5194/cp-14-637-2018, https://doi.org/10.5194/cp-14-637-2018, 2018
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This study presents organic acid levels in an ice core from Svalbard over the past 800 years. These acids are produced from wildfire emissions and transported as aerosol. Organic acid levels are high early in the record and decline until the 20th century. Siberia and Europe are likely the primary source regions of the fire emissions. The data are similar to those from a Siberian ice core prior to 1400 CE. The timing of the divergence after 1400 CE is similar to a shift in North Atlantic climate.
Mackenzie M. Grieman, Murat Aydin, Diedrich Fritzsche, Joseph R. McConnell, Thomas Opel, Michael Sigl, and Eric S. Saltzman
Clim. Past, 13, 395–410, https://doi.org/10.5194/cp-13-395-2017, https://doi.org/10.5194/cp-13-395-2017, 2017
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Wildfires impact ecosystems, climate, and atmospheric chemistry. Records that predate instrumental records and industrialization are needed to study the climatic controls on biomass burning. In this study, we analyzed organic chemicals produced from burning of plant matter that were preserved in an ice core from the Eurasian Arctic. These chemicals are elevated during three periods that have similar timing to climate variability. This is the first millennial-scale record of these chemicals.
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We analysed two Greenland ice cores for methanesulfonate (MSA) and bromine (Br) and concluded that both species are suitable proxies for local sea ice conditions. Interpretation of the records reveals that there have been sharp declines in sea ice in these areas in the past 250 years. However, at both sites the Br record deviates from MSA during the industrial period, raising questions about the value of Br as a sea ice proxy during recent periods of high, industrial, atmospheric acid pollution.
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The concentration of sodium and sulfate measured in Antarctic ice cores is related to changes in both sea ice and winds. Here we have compiled a database of sodium and sulfate records from 105 ice core sites in Antarctica. The records span all, or part, of the past 2000 years. The records will improve our understanding of how winds and sea ice have changed in the past and how they have influenced the climate of Antarctica over the past 2000 years.
Robert Mulvaney, Eric W. Wolff, Mackenzie M. Grieman, Helene H. Hoffmann, Jack D. Humby, Christoph Nehrbass-Ahles, Rachael H. Rhodes, Isobel F. Rowell, Frédéric Parrenin, Loïc Schmidely, Hubertus Fischer, Thomas F. Stocker, Marcus Christl, Raimund Muscheler, Amaelle Landais, and Frédéric Prié
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The WACSWAIN project (WArm Climate Stability of the West Antarctic ice sheet in the last INterglacial) investigates the fate of the West Antarctic Ice Sheet during the last warm period on Earth (115 000–130 000 years before present). Within this framework an ice core was recently drilled at Skytrain Ice Rise. In this study we present a stratigraphic chronology of that ice core based on absolute age markers and annual layer counting for the last 2000 years.
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Changes in the Southern Hemisphere westerly winds are drivers of recent environmental changes in West Antarctica. However, our understanding of this relationship is limited by short and sparse observational records. Here we present the first regional wind study based on the novel use of diatoms preserved in Antarctic ice cores. Our results demonstrate that diatom abundance is the optimal record for reconstructing wind strength variability over the Southern Hemisphere westerly wind belt.
Mackenzie M. Grieman, Murat Aydin, Joseph R. McConnell, and Eric S. Saltzman
Clim. Past, 14, 1625–1637, https://doi.org/10.5194/cp-14-1625-2018, https://doi.org/10.5194/cp-14-1625-2018, 2018
Short summary
Short summary
Vanillic acid is reported in the Tunu ice core from northeastern Greenland. It is an aerosol-borne acid produced by biomass burning. North American boreal forests are likely the source regions of the vanillic acid deposited at the ice core site. Vanillic acid levels were elevated during warm climate periods and lower during cooler climate periods. There is a positive correlation between the vanillic acid ice core record and ammonium and black carbon in the NEEM ice core from northern Greenland.
Mackenzie M. Grieman, Murat Aydin, Elisabeth Isaksson, Margit Schwikowski, and Eric S. Saltzman
Clim. Past, 14, 637–651, https://doi.org/10.5194/cp-14-637-2018, https://doi.org/10.5194/cp-14-637-2018, 2018
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This study presents organic acid levels in an ice core from Svalbard over the past 800 years. These acids are produced from wildfire emissions and transported as aerosol. Organic acid levels are high early in the record and decline until the 20th century. Siberia and Europe are likely the primary source regions of the fire emissions. The data are similar to those from a Siberian ice core prior to 1400 CE. The timing of the divergence after 1400 CE is similar to a shift in North Atlantic climate.
Mackenzie M. Grieman, Murat Aydin, Diedrich Fritzsche, Joseph R. McConnell, Thomas Opel, Michael Sigl, and Eric S. Saltzman
Clim. Past, 13, 395–410, https://doi.org/10.5194/cp-13-395-2017, https://doi.org/10.5194/cp-13-395-2017, 2017
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Wildfires impact ecosystems, climate, and atmospheric chemistry. Records that predate instrumental records and industrialization are needed to study the climatic controls on biomass burning. In this study, we analyzed organic chemicals produced from burning of plant matter that were preserved in an ice core from the Eurasian Arctic. These chemicals are elevated during three periods that have similar timing to climate variability. This is the first millennial-scale record of these chemicals.
Olivia J. Maselli, Nathan J. Chellman, Mackenzie Grieman, Lawrence Layman, Joseph R. McConnell, Daniel Pasteris, Rachael H. Rhodes, Eric Saltzman, and Michael Sigl
Clim. Past, 13, 39–59, https://doi.org/10.5194/cp-13-39-2017, https://doi.org/10.5194/cp-13-39-2017, 2017
Short summary
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We analysed two Greenland ice cores for methanesulfonate (MSA) and bromine (Br) and concluded that both species are suitable proxies for local sea ice conditions. Interpretation of the records reveals that there have been sharp declines in sea ice in these areas in the past 250 years. However, at both sites the Br record deviates from MSA during the industrial period, raising questions about the value of Br as a sea ice proxy during recent periods of high, industrial, atmospheric acid pollution.
T. G. Bell, W. De Bruyn, C. A. Marandino, S. D. Miller, C. S. Law, M. J. Smith, and E. S. Saltzman
Atmos. Chem. Phys., 15, 1783–1794, https://doi.org/10.5194/acp-15-1783-2015, https://doi.org/10.5194/acp-15-1783-2015, 2015
S. Landwehr, S. D. Miller, M. J. Smith, E. S. Saltzman, and B. Ward
Atmos. Chem. Phys., 14, 3361–3372, https://doi.org/10.5194/acp-14-3361-2014, https://doi.org/10.5194/acp-14-3361-2014, 2014
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Tessa R. Vance, Nerilie J. Abram, Alison S. Criscitiello, Camilla K. Crockart, Aylin DeCampo, Vincent Favier, Vasileios Gkinis, Margaret Harlan, Sarah L. Jackson, Helle A. Kjær, Chelsea A. Long, Meredith K. Nation, Christopher T. Plummer, Delia Segato, Andrea Spolaor, and Paul T. Vallelonga
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Abigail G. Hughes, Tyler R. Jones, Bo M. Vinther, Vasileios Gkinis, C. Max Stevens, Valerie Morris, Bruce H. Vaughn, Christian Holme, Bradley R. Markle, and James W. C. White
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Jessica A. Badgeley, Eric J. Steig, Gregory J. Hakim, and Tyler J. Fudge
Clim. Past, 16, 1325–1346, https://doi.org/10.5194/cp-16-1325-2020, https://doi.org/10.5194/cp-16-1325-2020, 2020
Juan Pablo Corella, Niccolo Maffezzoli, Carlos Alberto Cuevas, Paul Vallelonga, Andrea Spolaor, Giulio Cozzi, Juliane Müller, Bo Vinther, Carlo Barbante, Helle Astrid Kjær, Ross Edwards, and Alfonso Saiz-Lopez
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Dominic A. Winski, Tyler J. Fudge, David G. Ferris, Erich C. Osterberg, John M. Fegyveresi, Jihong Cole-Dai, Zayta Thundercloud, Thomas S. Cox, Karl J. Kreutz, Nikolas Ortman, Christo Buizert, Jenna Epifanio, Edward J. Brook, Ross Beaudette, Jeffrey Severinghaus, Todd Sowers, Eric J. Steig, Emma C. Kahle, Tyler R. Jones, Valerie Morris, Murat Aydin, Melinda R. Nicewonger, Kimberly A. Casey, Richard B. Alley, Edwin D. Waddington, Nels A. Iverson, Nelia W. Dunbar, Ryan C. Bay, Joseph M. Souney, Michael Sigl, and Joseph R. McConnell
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A deep ice core was recently drilled at the South Pole to understand past variations in the Earth's climate. To understand the information contained within the ice, we present the relationship between the depth and age of the ice in the South Pole Ice Core. We found that the oldest ice in our record is from 54 302 ± 519 years ago. Our results show that, on average, 7.4 cm of snow falls at the South Pole each year.
Michael Döring and Markus C. Leuenberger
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We present a novel approach for ice-core-based temperature reconstructions, which is based on gas-isotope data measured on enclosed air bubbles in ice cores. The processes of air movement and enclosure are highly temperature dependent due to heat diffusion in and densification of the snow and ice. Our method inverts a model, which describes these processes, to desired temperature histories. This paper examines the performance of our novel approach on different synthetic isotope-data scenarios.
Marius Folden Simonsen, Llorenç Cremonesi, Giovanni Baccolo, Samuel Bosch, Barbara Delmonte, Tobias Erhardt, Helle Astrid Kjær, Marco Potenza, Anders Svensson, and Paul Vallelonga
Clim. Past, 14, 601–608, https://doi.org/10.5194/cp-14-601-2018, https://doi.org/10.5194/cp-14-601-2018, 2018
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Ice core dust size distributions are more often measured today by an Abakus laser sensor than by the more technically demanding but also very accurate Coulter counter. However, Abakus measurements consistently give larger particle sizes. We show here that this bias exists because the particles are flat and elongated. Correcting for this gives more accurate Abakus measurements. Furthermore, the shape of the particles can be extracted from a combination of Coulter counter and Abakus measurements.
Pascal Bohleber, Tobias Erhardt, Nicole Spaulding, Helene Hoffmann, Hubertus Fischer, and Paul Mayewski
Clim. Past, 14, 21–37, https://doi.org/10.5194/cp-14-21-2018, https://doi.org/10.5194/cp-14-21-2018, 2018
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The Colle Gnifetti (CG) glacier is the only drilling site in the European Alps offering ice core records back to some 1000 years. We aim to fully exploit these unique long-term records by establishing a reliable long-term age scale and an improved ice core proxy interpretation for reconstructing temperature. Our findings reveal a site-specific temperature-related signal in the trends of the mineral dust proxy Ca2+ that may supplement other proxy evidence over the last millennium.
Thomas Münch, Sepp Kipfstuhl, Johannes Freitag, Hanno Meyer, and Thomas Laepple
Clim. Past, 12, 1565–1581, https://doi.org/10.5194/cp-12-1565-2016, https://doi.org/10.5194/cp-12-1565-2016, 2016
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Ice-core oxygen isotope ratios are a key climate archive to infer past temperatures, an interpretation however complicated by non-climatic noise. Based on 50 m firn trenches, we present for the first time a two-dimensional view (vertical × horizontal) of how oxygen isotopes are stored in Antarctic firn. A statistical noise model allows inferences for the validity of ice coring efforts to reconstruct past temperatures, highlighting the need of replicate cores for Holocene climate reconstructions.
F. Adolphi and R. Muscheler
Clim. Past, 12, 15–30, https://doi.org/10.5194/cp-12-15-2016, https://doi.org/10.5194/cp-12-15-2016, 2016
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Here we employ common variations in tree-ring 14C and Greenland ice core 10Be records to synchronize the Greenland ice core (GICC05) and the radiocarbon (IntCal13) timescale over the Holocene. We propose a transfer function between both timescales that allows continuous comparisons between radiocarbon dated and ice core climate records at unprecedented chronological precision.
M. Gay, M. De Angelis, and J.-L. Lacoume
Clim. Past, 10, 1659–1672, https://doi.org/10.5194/cp-10-1659-2014, https://doi.org/10.5194/cp-10-1659-2014, 2014
S. Hou, J. Chappellaz, D. Raynaud, V. Masson-Delmotte, J. Jouzel, P. Bousquet, and D. Hauglustaine
Clim. Past, 9, 2549–2554, https://doi.org/10.5194/cp-9-2549-2013, https://doi.org/10.5194/cp-9-2549-2013, 2013
T. Kobashi, K. Goto-Azuma, J. E. Box, C.-C. Gao, and T. Nakaegawa
Clim. Past, 9, 2299–2317, https://doi.org/10.5194/cp-9-2299-2013, https://doi.org/10.5194/cp-9-2299-2013, 2013
C. Barbante, N. M. Kehrwald, P. Marianelli, B. M. Vinther, J. P. Steffensen, G. Cozzi, C. U. Hammer, H. B. Clausen, and M.-L. Siggaard-Andersen
Clim. Past, 9, 1221–1232, https://doi.org/10.5194/cp-9-1221-2013, https://doi.org/10.5194/cp-9-1221-2013, 2013
R. Winkler, A. Landais, H. Sodemann, L. Dümbgen, F. Prié, V. Masson-Delmotte, B. Stenni, and J. Jouzel
Clim. Past, 8, 1–16, https://doi.org/10.5194/cp-8-1-2012, https://doi.org/10.5194/cp-8-1-2012, 2012
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