Articles | Volume 10, issue 4
https://doi.org/10.5194/cp-10-1291-2014
© Author(s) 2014. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/cp-10-1291-2014
© Author(s) 2014. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
04 Jul 2014
Research article |
| 04 Jul 2014
New online method for water isotope analysis of speleothem fluid inclusions using laser absorption spectroscopy (WS-CRDS)
S. Affolter
Climate and Environmental Physics, Physics Institute, University of Bern, 3012 Bern, Switzerland
Oeschger Centre for Climate Change Research, University of Bern, 3012 Bern, Switzerland
D. Fleitmann
Oeschger Centre for Climate Change Research, University of Bern, 3012 Bern, Switzerland
now at: Department of Archaeology, School of Archaeology, Geography and Environmental Sciences and Centre for Past Climate Change, University of Reading, Whiteknights, P.O. Box 227, Reading RG6 6AB, UK
M. Leuenberger
Climate and Environmental Physics, Physics Institute, University of Bern, 3012 Bern, Switzerland
Oeschger Centre for Climate Change Research, University of Bern, 3012 Bern, Switzerland
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Clim. Past, 19, 1847–1862, https://doi.org/10.5194/cp-19-1847-2023, https://doi.org/10.5194/cp-19-1847-2023, 2023
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Clumped-isotope signals obtained through gas-source mass spectrometry are typically small and require pressure baseline corrections. While such corrections have been developed for square-shaped peaks, we present an approach for correcting peaks with complex shapes. Our method is demonstrated using oxygen clumped isotopes measured in pure oxygen, where the peak tops are linearly increasing and/or negatively curved.
Marie Bouchet, Amaëlle Landais, Antoine Grisart, Frédéric Parrenin, Frédéric Prié, Roxanne Jacob, Elise Fourré, Emilie Capron, Dominique Raynaud, Vladimir Ya Lipenkov, Marie-France Loutre, Thomas Extier, Anders Svensson, Etienne Legrain, Patricia Martinerie, Markus Leuenberger, Wei Jiang, Florian Ritterbusch, Zheng-Tian Lu, and Guo-Min Yang
Clim. Past, 19, 2257–2286, https://doi.org/10.5194/cp-19-2257-2023, https://doi.org/10.5194/cp-19-2257-2023, 2023
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A new federative chronology for five deep polar ice cores retrieves 800 000 years of past climate variations with improved accuracy. Precise ice core timescales are key to studying the mechanisms linking changes in the Earth’s orbit to the diverse climatic responses (temperature and atmospheric greenhouse gas concentrations). To construct the chronology, new measurements from the oldest continuous ice core as well as glaciological modeling estimates were combined in a statistical model.
Stephan Räss, Peter Nyfeler, Paul Wheeler, Will Price, and Markus Christian Leuenberger
Atmos. Meas. Tech., 16, 4489–4505, https://doi.org/10.5194/amt-16-4489-2023, https://doi.org/10.5194/amt-16-4489-2023, 2023
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Due to technological advances clumped-isotope studies have gained importance in recent years. Typically, these studies are performed with high-resolution isotope ratio mass spectrometers (IRMSs) along with a changeover-valve-based dual-inlet system (DIS). We are taking a different approach, namely performing clumped-isotope measurements with a compact low-resolution IRMS with an open-split-based DIS. Currently, we are working with pure-oxygen gas for which we are providing a proof of concept.
Jenny Maccali, Anna Nele Meckler, Stein-Erik Lauritzen, Torill Brekken, Helen Aase Rokkan, Alvaro Fernandez, Yves Krüger, Jane Adigun, Stéphane Affolter, and Markus Leuenberger
Clim. Past, 19, 1847–1862, https://doi.org/10.5194/cp-19-1847-2023, https://doi.org/10.5194/cp-19-1847-2023, 2023
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The southern coast of South Africa hosts some key archeological sites for the study of early human evolution. Here we present a short but high-resolution record of past changes in the hydroclimate and temperature on the southern coast of South Africa based on the study of a speleothem collected from Bloukrantz Cave. Overall, the paleoclimate indicators suggest stable temperature from 48.3 to 45.2 ka, whereas precipitation was variable, with marked short drier episodes.
Andreas Plach, Rolf Rüfenacht, Simone Kotthaus, and Markus Leuenberger
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Greenhouse gases emissions are contributing to global warming and it is essential to better understand where they originate from and how they are transported. In this study we analyze greenhouse gas observations at a Swiss tall tower where measurements are taken more than 200 m above ground and investigate their origin by looking at the condition of the atmosphere at the time of the observations. We find that most pollution at this site is caused from emissions transported from further away.
Peter Bergamaschi, Arjo Segers, Dominik Brunner, Jean-Matthieu Haussaire, Stephan Henne, Michel Ramonet, Tim Arnold, Tobias Biermann, Huilin Chen, Sebastien Conil, Marc Delmotte, Grant Forster, Arnoud Frumau, Dagmar Kubistin, Xin Lan, Markus Leuenberger, Matthias Lindauer, Morgan Lopez, Giovanni Manca, Jennifer Müller-Williams, Simon O'Doherty, Bert Scheeren, Martin Steinbacher, Pamela Trisolino, Gabriela Vítková, and Camille Yver Kwok
Atmos. Chem. Phys., 22, 13243–13268, https://doi.org/10.5194/acp-22-13243-2022, https://doi.org/10.5194/acp-22-13243-2022, 2022
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We present a novel high-resolution inverse modelling system, "FLEXVAR", and its application for the inverse modelling of European CH4 emissions in 2018. The new system combines a high spatial resolution of 7 km x 7 km with a variational data assimilation technique, which allows CH4 emissions to be optimized from individual model grid cells. The high resolution allows the observations to be better reproduced, while the derived emissions show overall good consistency with two existing models.
Tito Arosio, Malin M. Ziehmer-Wenz, Kurt Nicolussi, Christian Schlüchter, and Markus Leuenberger
Biogeosciences Discuss., https://doi.org/10.5194/bg-2020-406, https://doi.org/10.5194/bg-2020-406, 2020
Revised manuscript not accepted
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A recent analysis of stable isotopes of samples from larch and cembran trees, revealed that δD and δ18O exhibit no trends in adult trees, but trends in the juvenile period. In this work we applied a correlation analysis on different cambial age to verify if these changes were correlated with tree-ring width values. The results prove a significant correlation between tree-ring-width and both hydrogen and oxygen stable isotopes before 100 year of cambial age, but not afterwards, in both species.
Tito Arosio, Malin M. Ziehmer, Kurt Nicolussi, Christian Schlüchter, and Markus Leuenberger
Biogeosciences, 17, 4871–4882, https://doi.org/10.5194/bg-17-4871-2020, https://doi.org/10.5194/bg-17-4871-2020, 2020
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Stable isotopes in tree-ring cellulose are tools for climatic reconstructions, but interpretation is challenging due to nonclimate trends. We analyzed the tree-age trends in tree-ring isotopes of deciduous larch and evergreen cembran pine. Samples covering the whole Holocene were collected at the tree line in the Alps. For cambial ages over 100 years, we prove the absence of age trends in δD, δ18O, and δ13C for both species. For lower cambial ages, trends differ for each isotope and species.
Michael Döring and Markus Christian Leuenberger
Clim. Past Discuss., https://doi.org/10.5194/cp-2020-132, https://doi.org/10.5194/cp-2020-132, 2020
Manuscript not accepted for further review
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We analyze Holocene temperatures reconstructed from gas-stable-isotope species measured on ancient air extracted from a Greenland ice core. Also, we compare two state of the art firn-models which are needed for the inversion of the gas-isotope data to paleo-temperature and provide detailed uncertainty estimations for the reconstructed temperature estimates. Finally, we compare our reconstructed temperatures to two recent reconstructions based on the same gas-isotope data as used here.
Steffen Therre, Jens Fohlmeister, Dominik Fleitmann, Albert Matter, Stephen J. Burns, Jennifer Arps, Andrea Schröder-Ritzrau, Ronny Friedrich, and Norbert Frank
Clim. Past, 16, 409–421, https://doi.org/10.5194/cp-16-409-2020, https://doi.org/10.5194/cp-16-409-2020, 2020
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The radiocarbon (14C) levels of a stalagmite (grown 27–11 kyr before today) from Socotra Island (Arabian Sea) show drastic changes across the last termination. Our study highlights the influence of a warming climate with increasing precipitation towards the ending glacial on stalagmite 14C. High-resolution measurements suggest 14C is linked to a denser vegetation coverage on the island. Therefore, stalagmite 14C can be used as a climate tracer on millennial to sub-centennial timescales.
Ece Satar, Peter Nyfeler, Céline Pascale, Bernhard Niederhauser, and Markus Leuenberger
Atmos. Meas. Tech., 13, 119–130, https://doi.org/10.5194/amt-13-119-2020, https://doi.org/10.5194/amt-13-119-2020, 2020
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To ensure the best preparation and measurement conditions for trace gases, usage of coated materials is in demand in gas metrology and atmospheric measurement communities. In this article, the previously introduced aluminum measurement chamber is used to investigate materials such as glass, aluminum, copper, brass, steel and three different commercially available coatings. Our measurements focus on temperature and pressure dependencies for the species CO2, CO, CH4 and H2O using a CRDS analyzer.
Ece Satar, Peter Nyfeler, Bernhard Bereiter, Céline Pascale, Bernhard Niederhauser, and Markus Leuenberger
Atmos. Meas. Tech., 13, 101–117, https://doi.org/10.5194/amt-13-101-2020, https://doi.org/10.5194/amt-13-101-2020, 2020
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Good-quality measurements of atmospheric trace gases are only possible with regular calibrations and stable measurements from the standard cylinders. This study investigates instabilities due to surface effects on newly built aluminum and steel cylinders. We present measurements over a set of temperature and pressure ranges for the amount fractions of CO2, CO, CH4 and H2O using a commercial and a novel laser spectroscopic analyzer.
Tesfaye A. Berhanu, John Hoffnagle, Chris Rella, David Kimhak, Peter Nyfeler, and Markus Leuenberger
Atmos. Meas. Tech., 12, 6803–6826, https://doi.org/10.5194/amt-12-6803-2019, https://doi.org/10.5194/amt-12-6803-2019, 2019
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Accurate measurement of variations in atmospheric O2 can provide useful information about atmospheric, biospheric, and oceanic processes, which is a challenge for existing measurement techniques. Here, we introduce a newly built high-precision, stable CRDS analyzer (Picarro G2207) that can measure O2 mixing ratios with a short-term precision of < 1 ppm and only requires calibration every 12 h. Measurements from tower and mountain sites are also presented.
Michael Döring and Markus Christian Leuenberger
Clim. Past Discuss., https://doi.org/10.5194/cp-2019-132, https://doi.org/10.5194/cp-2019-132, 2019
Manuscript not accepted for further review
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We analyse Holocen temperatures reconstructed from gas-stable-isotope species measured on ancient air extracted from a Greenland ice core. Also, we compare two state of the art firn-models which are needed for the inversion of the gas-isotope data to paleo-temperature and provide detailed uncertainty estimations for the reconstructed temperature estimates. Finally, we compare our reconstructed temperatures to two recent reconstructions based on the same gas-isotope data as used here.
Michael Döring and Markus C. Leuenberger
Clim. Past, 14, 763–788, https://doi.org/10.5194/cp-14-763-2018, https://doi.org/10.5194/cp-14-763-2018, 2018
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We present a novel approach for ice-core-based temperature reconstructions, which is based on gas-isotope data measured on enclosed air bubbles in ice cores. The processes of air movement and enclosure are highly temperature dependent due to heat diffusion in and densification of the snow and ice. Our method inverts a model, which describes these processes, to desired temperature histories. This paper examines the performance of our novel approach on different synthetic isotope-data scenarios.
Ye Yuan, Ludwig Ries, Hannes Petermeier, Martin Steinbacher, Angel J. Gómez-Peláez, Markus C. Leuenberger, Marcus Schumacher, Thomas Trickl, Cedric Couret, Frank Meinhardt, and Annette Menzel
Atmos. Meas. Tech., 11, 1501–1514, https://doi.org/10.5194/amt-11-1501-2018, https://doi.org/10.5194/amt-11-1501-2018, 2018
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This paper presents a novel statistical method, ADVS, for baseline selection of representative CO2 data at elevated mountain measurement stations. It provides insights on how data processing techniques are critical for measurements and data analyses. Compared with other statistical methods, our method appears to be a good option as a generalized approach with improved comparability, which is important for research on measurement site characteristics and comparisons between stations.
Malin M. Ziehmer, Kurt Nicolussi, Christian Schlüchter, and Markus Leuenberger
Biogeosciences, 15, 1047–1064, https://doi.org/10.5194/bg-15-1047-2018, https://doi.org/10.5194/bg-15-1047-2018, 2018
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Cellulose content (CC (%)) series from two high-Alpine species, Larix decidua Mill. (European larch, LADE) and Pinus cembra L. (Swiss stone pine, PICE) are investigated in modern wood samples and Holocene wood remains from the Early and mid-Holocene. Trends in modern and Holocene time series as well as climate–cellulose relationships for modern trees in the Alps show high potential for CC (%) to be established as novel supplementary proxy in dendroclimatology.
Tesfaye A. Berhanu, Sönke Szidat, Dominik Brunner, Ece Satar, Rüdiger Schanda, Peter Nyfeler, Michael Battaglia, Martin Steinbacher, Samuel Hammer, and Markus Leuenberger
Atmos. Chem. Phys., 17, 10753–10766, https://doi.org/10.5194/acp-17-10753-2017, https://doi.org/10.5194/acp-17-10753-2017, 2017
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Fossil fuel CO2 is the major contributor of anthropogenic CO2 in the atmosphere, and accurate quantification is essential to better understand the carbon cycle. Such accurate quantification can be conducted based on radiocarbon measurements. In this study, we present radiocarbon measurements from a tall tower site in Switzerland. From these measurements, we have observed seasonally varying fossil fuel CO2 contributions and a biospheric CO2 component that varies diurnally and seasonally.
Kathrin M. Keller, Sebastian Lienert, Anil Bozbiyik, Thomas F. Stocker, Olga V. Churakova (Sidorova), David C. Frank, Stefan Klesse, Charles D. Koven, Markus Leuenberger, William J. Riley, Matthias Saurer, Rolf Siegwolf, Rosemarie B. Weigt, and Fortunat Joos
Biogeosciences, 14, 2641–2673, https://doi.org/10.5194/bg-14-2641-2017, https://doi.org/10.5194/bg-14-2641-2017, 2017
Chantal Camenisch, Kathrin M. Keller, Melanie Salvisberg, Benjamin Amann, Martin Bauch, Sandro Blumer, Rudolf Brázdil, Stefan Brönnimann, Ulf Büntgen, Bruce M. S. Campbell, Laura Fernández-Donado, Dominik Fleitmann, Rüdiger Glaser, Fidel González-Rouco, Martin Grosjean, Richard C. Hoffmann, Heli Huhtamaa, Fortunat Joos, Andrea Kiss, Oldřich Kotyza, Flavio Lehner, Jürg Luterbacher, Nicolas Maughan, Raphael Neukom, Theresa Novy, Kathleen Pribyl, Christoph C. Raible, Dirk Riemann, Maximilian Schuh, Philip Slavin, Johannes P. Werner, and Oliver Wetter
Clim. Past, 12, 2107–2126, https://doi.org/10.5194/cp-12-2107-2016, https://doi.org/10.5194/cp-12-2107-2016, 2016
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Throughout the last millennium, several cold periods occurred which affected humanity. Here, we investigate an exceptionally cold decade during the 15th century. The cold conditions challenged the food production and led to increasing food prices and a famine in parts of Europe. In contrast to periods such as the “Year Without Summer” after the eruption of Tambora, these extreme climatic conditions seem to have occurred by chance and in relation to the internal variability of the climate system.
Michael F. Schibig, Emmanuel Mahieu, Stephan Henne, Bernard Lejeune, and Markus C. Leuenberger
Atmos. Chem. Phys., 16, 9935–9949, https://doi.org/10.5194/acp-16-9935-2016, https://doi.org/10.5194/acp-16-9935-2016, 2016
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Two CO2 time series measured at the High Alpine Research Station Jungfraujoch, Switzerland (3580 m a.s.l.), in the period from 2005 to 2013 were compared. One data set was measured in situ whereas the other data set was measured in the column above Jungfraujoch. The trends of the column integrated and the in situ data set are in good agreement, the amplitude of the in situ data set is ca. two times the amplitude of the column integrated data set, because it is closer to the sources and sinks.
Tesfaye Ayalneh Berhanu, Ece Satar, Rudiger Schanda, Peter Nyfeler, Hanspeter Moret, Dominik Brunner, Brian Oney, and Markus Leuenberger
Atmos. Meas. Tech., 9, 2603–2614, https://doi.org/10.5194/amt-9-2603-2016, https://doi.org/10.5194/amt-9-2603-2016, 2016
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In this manuscript, we have presented Co, CO2 and CH4 measurement data from an old radio tower tower (217.5 m) at Beromunster, Switzerland. From about 2 years of continuous CO, CO2 and CH4 measurement at five different heights, we have determined a long-term reproducibility of 2.79 ppb, 0.05 ppm and 0.29 ppb for CO, CO2 and CH4, respectively, compliant with the GAW requirements. We have also observed seasonal and diurnal variation of these species.
Ece Satar, Tesfaye A. Berhanu, Dominik Brunner, Stephan Henne, and Markus Leuenberger
Biogeosciences, 13, 2623–2635, https://doi.org/10.5194/bg-13-2623-2016, https://doi.org/10.5194/bg-13-2623-2016, 2016
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Beromünster tall tower is the flagship of the densely placed Swiss greenhouse gas observation network (CarboCount CH). In this research article we report the first 2 years of the continuous greenhouse gas measurements using cavity ring down spectroscopy analyzer from this tall tower. We have adopted a purely observation based, multi-species and multi-level approach to characterize the site with respect to sources and sinks of natural and anthropogenic origin at diurnal to annual timescales.
Lucie Bazin, Amaelle Landais, Emilie Capron, Valérie Masson-Delmotte, Catherine Ritz, Ghislain Picard, Jean Jouzel, Marie Dumont, Markus Leuenberger, and Frédéric Prié
Clim. Past, 12, 729–748, https://doi.org/10.5194/cp-12-729-2016, https://doi.org/10.5194/cp-12-729-2016, 2016
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We present new measurements of δO2⁄N2 and δ18Oatm performed on well-conserved ice from EDC covering MIS5 and between 380 and 800 ka. The combination of the observation of a 100 ka periodicity in the new δO2⁄N2 record with a MIS5 multi-site multi-proxy study has revealed a potential influence of local climatic parameters on δO2⁄N2. Moreover, we propose that the varying delay between d18Oatm and precession for the last 800 ka is affected by the occurrence of ice sheet discharge events.
Stephan Henne, Dominik Brunner, Brian Oney, Markus Leuenberger, Werner Eugster, Ines Bamberger, Frank Meinhardt, Martin Steinbacher, and Lukas Emmenegger
Atmos. Chem. Phys., 16, 3683–3710, https://doi.org/10.5194/acp-16-3683-2016, https://doi.org/10.5194/acp-16-3683-2016, 2016
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Greenhouse gas emissions can be assessed by "top-down" methods that combine atmospheric observations, a transport model and a mathematical optimisation framework. Here, we apply such a top-down method to the methane emissions of Switzerland, utilising observations from the recently installed CarboCount-CH network. Our Swiss total emissions largely agree with those of the national "bottom-up" inventory, whereas regional differences suggest lower than reported emissions from manure handling.
M. C. Leuenberger, M. F. Schibig, and P. Nyfeler
Atmos. Meas. Tech., 8, 5289–5299, https://doi.org/10.5194/amt-8-5289-2015, https://doi.org/10.5194/amt-8-5289-2015, 2015
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Adsorption/desorption effects of trace gases in gas cylinders were investigated. Our measurements indicate a rather strong effect on steel cylinders for CO2 that becomes easily visible through enhanced concentrations for low (<20 bars) gas pressure. Much smaller effects are observed for CO and CH4. Significantly smaller effects are measured for all gas species investigated on aluminium cylinders. Careful selection of gas cylinders for high-precision calibration purposes is recommended.
T. Kobashi, T. Ikeda-Fukazawa, M. Suwa, J. Schwander, T. Kameda, J. Lundin, A. Hori, H. Motoyama, M. Döring, and M. Leuenberger
Atmos. Chem. Phys., 15, 13895–13914, https://doi.org/10.5194/acp-15-13895-2015, https://doi.org/10.5194/acp-15-13895-2015, 2015
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We find that argon/nitrogen ratios of trapped air in the GISP2 ice core on “gas ages” are significantly negatively correlated with accumulation rate changes over the past 6000 years. Lines of evidence indicate that changes in overloading pressure at bubble closeoff depths induced the gas fractionation in closed bubbles. Further understanding of the fractionation processes may lead to a new proxy for the past temperature and accumulation rate.
B. Oney, S. Henne, N. Gruber, M. Leuenberger, I. Bamberger, W. Eugster, and D. Brunner
Atmos. Chem. Phys., 15, 11147–11164, https://doi.org/10.5194/acp-15-11147-2015, https://doi.org/10.5194/acp-15-11147-2015, 2015
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We present a detailed analysis of a new greenhouse gas measurement network
in the Swiss Plateau, situated between the Jura mountains and the Alps. We
find the network's measurements to be information rich and suitable
for studying surface carbon fluxes of the study region. However, we are
limited by the high-resolution (2km) atmospheric transport model's ability
to simulate meteorology at the individual measurement stations, especially
at those situated in rough terrain.
F. Spadin, D. Marti, R. Hidalgo-Staub, J. Rička, D. Fleitmann, and M. Frenz
Clim. Past, 11, 905–913, https://doi.org/10.5194/cp-11-905-2015, https://doi.org/10.5194/cp-11-905-2015, 2015
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Fluid inclusions inside stalagmites retain information on the cave temperature at the time they formed and thus can be used to reconstruct the continental climate of the past. A method for extracting this information based on a thermodynamic model and size measurements of femtosecond-laser-induced vapour bubbles is presented. Applying our method to stalagmites taken from the Milandre cave in the Swiss Jura Mountains demonstrate that palaeotemperatures can be determined with an accuracy of ±1°C.
M. S. Studer, R. T. W. Siegwolf, M. Leuenberger, and S. Abiven
Biogeosciences, 12, 1865–1879, https://doi.org/10.5194/bg-12-1865-2015, https://doi.org/10.5194/bg-12-1865-2015, 2015
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We present a new technique to label organic matter (OM) at its place of formation by the application of 13C, 18O and 2H through the gaseous phase. The label diffused into leaves was incorporated into assimilates and was detected in plant tissues. This technique can be applied in soil sciences, e.g. to trace the decomposition pathways of soil OM inputs, or in plant physiology and palaeoclimatic reconstruction, e.g. to further investigate the origin of the 18O and 2H signal in tree ring cellulose.
M. F. Schibig, M. Steinbacher, B. Buchmann, I. T. van der Laan-Luijkx, S. van der Laan, S. Ranjan, and M. C. Leuenberger
Atmos. Meas. Tech., 8, 57–68, https://doi.org/10.5194/amt-8-57-2015, https://doi.org/10.5194/amt-8-57-2015, 2015
M. C. Leuenberger, M. F. Schibig, and P. Nyfeler
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acpd-14-19293-2014, https://doi.org/10.5194/acpd-14-19293-2014, 2014
Revised manuscript not accepted
I. Mariani, A. Eichler, T. M. Jenk, S. Brönnimann, R. Auchmann, M. C. Leuenberger, and M. Schwikowski
Clim. Past, 10, 1093–1108, https://doi.org/10.5194/cp-10-1093-2014, https://doi.org/10.5194/cp-10-1093-2014, 2014
L. S. Shumilovskikh, D. Fleitmann, N. R. Nowaczyk, H. Behling, F. Marret, A. Wegwerth, and H. W. Arz
Clim. Past, 10, 939–954, https://doi.org/10.5194/cp-10-939-2014, https://doi.org/10.5194/cp-10-939-2014, 2014
P. Kindler, M. Guillevic, M. Baumgartner, J. Schwander, A. Landais, and M. Leuenberger
Clim. Past, 10, 887–902, https://doi.org/10.5194/cp-10-887-2014, https://doi.org/10.5194/cp-10-887-2014, 2014
M. Baumgartner, P. Kindler, O. Eicher, G. Floch, A. Schilt, J. Schwander, R. Spahni, E. Capron, J. Chappellaz, M. Leuenberger, H. Fischer, and T. F. Stocker
Clim. Past, 10, 903–920, https://doi.org/10.5194/cp-10-903-2014, https://doi.org/10.5194/cp-10-903-2014, 2014
Z. Kern, B. Kohán, and M. Leuenberger
Atmos. Chem. Phys., 14, 1897–1907, https://doi.org/10.5194/acp-14-1897-2014, https://doi.org/10.5194/acp-14-1897-2014, 2014
L. Bazin, A. Landais, B. Lemieux-Dudon, H. Toyé Mahamadou Kele, D. Veres, F. Parrenin, P. Martinerie, C. Ritz, E. Capron, V. Lipenkov, M.-F. Loutre, D. Raynaud, B. Vinther, A. Svensson, S. O. Rasmussen, M. Severi, T. Blunier, M. Leuenberger, H. Fischer, V. Masson-Delmotte, J. Chappellaz, and E. Wolff
Clim. Past, 9, 1715–1731, https://doi.org/10.5194/cp-9-1715-2013, https://doi.org/10.5194/cp-9-1715-2013, 2013
I. T. van der Laan-Luijkx, S. van der Laan, C. Uglietti, M. F. Schibig, R. E. M. Neubert, H. A. J. Meijer, W. A. Brand, A. Jordan, J. M. Richter, M. Rothe, and M. C. Leuenberger
Atmos. Meas. Tech., 6, 1805–1815, https://doi.org/10.5194/amt-6-1805-2013, https://doi.org/10.5194/amt-6-1805-2013, 2013
M. Guillevic, L. Bazin, A. Landais, P. Kindler, A. Orsi, V. Masson-Delmotte, T. Blunier, S. L. Buchardt, E. Capron, M. Leuenberger, P. Martinerie, F. Prié, and B. M. Vinther
Clim. Past, 9, 1029–1051, https://doi.org/10.5194/cp-9-1029-2013, https://doi.org/10.5194/cp-9-1029-2013, 2013
E. Capron, A. Landais, D. Buiron, A. Cauquoin, J. Chappellaz, M. Debret, J. Jouzel, M. Leuenberger, P. Martinerie, V. Masson-Delmotte, R. Mulvaney, F. Parrenin, and F. Prié
Clim. Past, 9, 983–999, https://doi.org/10.5194/cp-9-983-2013, https://doi.org/10.5194/cp-9-983-2013, 2013
N. Vogel, Y. Scheidegger, M. S. Brennwald, D. Fleitmann, S. Figura, R. Wieler, and R. Kipfer
Clim. Past, 9, 1–12, https://doi.org/10.5194/cp-9-1-2013, https://doi.org/10.5194/cp-9-1-2013, 2013
Related subject area
Subject: Proxy Use-Development-Validation | Archive: Terrestrial Archives | Timescale: Pleistocene
The Indo–Pacific Pollen Database – a Neotoma constituent database
Can machine-learning algorithms improve upon classical palaeoenvironmental reconstruction models?
Quantitative reconstruction of past monsoon precipitation based on tetraether membrane lipids in Chinese loess
Distinguishing the combined vegetation and soil component of δ13C variation in speleothem records from subsequent degassing and prior calcite precipitation effects
Multi-proxy speleothem-based reconstruction of mid-MIS 3 climate in South Africa
Biomarker proxy records of Arctic climate change during the Mid-Pleistocene transition from Lake El'gygytgyn (Far East Russia)
Hydroclimatic variability of opposing Late Pleistocene climates in the Levant revealed by deep Dead Sea sediments
Different facets of dry–wet patterns in south-western China over the past 27 000 years
The triple oxygen isotope composition of phytoliths, a new proxy of atmospheric relative humidity: controls of soil water isotope composition, temperature, CO2 concentration and relative humidity
The speleothem oxygen record as a proxy for thermal or moisture changes: a case study of multiproxy records from MIS 5–MIS 6 speleothems from the Demänová Cave system
A new multivariable benchmark for Last Glacial Maximum climate simulations
The Last Glacial Maximum in the central North Island, New Zealand: palaeoclimate inferences from glacier modelling
Late-glacial to late-Holocene shifts in global precipitation δ18O
Climate history of the Southern Hemisphere Westerlies belt during the last glacial–interglacial transition revealed from lake water oxygen isotope reconstruction of Laguna Potrok Aike (52° S, Argentina)
Inorganic geochemistry data from Lake El'gygytgyn sediments: marine isotope stages 6–11
A 350 ka record of climate change from Lake El'gygytgyn, Far East Russian Arctic: refining the pattern of climate modes by means of cluster analysis
Dynamic diatom response to changing climate 0–1.2 Ma at Lake El'gygytgyn, Far East Russian Arctic
Amplified bioproductivity during Transition IV (332 000–342 000 yr ago): evidence from the geochemical record of Lake El'gygytgyn
Potential and limits of OSL, TT-OSL, IRSL and pIRIR290 dating methods applied on a Middle Pleistocene sediment record of Lake El'gygytgyn, Russia
Rock magnetic properties, magnetic susceptibility, and organic geochemistry comparison in core LZ1029-7 Lake El'gygytgyn, Russia Far East
High-temperature thermomagnetic properties of vivianite nodules, Lake El'gygytgyn, Northeast Russia
Reconstruction of drip-water δ18O based on calcite oxygen and clumped isotopes of speleothems from Bunker Cave (Germany)
A biomarker record of Lake El'gygytgyn, Far East Russian Arctic: investigating sources of organic matter and carbon cycling during marine isotope stages 1–3
Climate warming and vegetation response after Heinrich event 1 (16 700–16 000 cal yr BP) in Europe south of the Alps
A 250 ka oxygen isotope record from diatoms at Lake El'gygytgyn, far east Russian Arctic
The oxygen isotopic composition of phytolith assemblages from tropical rainforest soil tops (Queensland, Australia): validation of a new paleoenvironmental tool
Terrestrial mollusc records from Xifeng and Luochuan L9 loess strata and their implications for paleoclimatic evolution in the Chinese Loess Plateau during marine Oxygen Isotope Stages 24-22
Annika V. Herbert, Simon G. Haberle, Suzette G. A. Flantua, Ondrej Mottl, Jessica L. Blois, John W. Williams, Adrian George, and Geoff S. Hope
Clim. Past, 20, 2473–2485, https://doi.org/10.5194/cp-20-2473-2024, https://doi.org/10.5194/cp-20-2473-2024, 2024
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The Indo-Pacific Pollen Database is a large collection of pollen samples from across the Indo-Pacific region, with most samples coming from Australia. This is a valuable collection that can be used to analyse vegetation dynamics going back thousands of years. It is now being fully shared via Neotoma for the first time, opening up many exciting new avenues of research. This paper presents key aspects of this database, including geographical distribution, age control and deposition times.
Peng Sun, Philip B. Holden, and H. John B. Birks
Clim. Past, 20, 2373–2398, https://doi.org/10.5194/cp-20-2373-2024, https://doi.org/10.5194/cp-20-2373-2024, 2024
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We develop the Multi Ensemble Machine Learning Model (MEMLM) for reconstructing palaeoenvironments from microfossil assemblages. The machine-learning approaches, which include random tree and natural language processing techniques, substantially outperform classical approaches under cross-validation, but they can fail when applied to reconstruct past environments. Statistical significance testing is found sufficient to identify these unreliable reconstructions.
Jingjing Guo, Martin Ziegler, Louise Fuchs, Youbin Sun, and Francien Peterse
EGUsphere, https://doi.org/10.5194/egusphere-2024-1648, https://doi.org/10.5194/egusphere-2024-1648, 2024
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In this study, we use the distribution of soil bacterial membrane lipids stored on the Chinese Loess Plateau (CLP) to quantitatively reconstruct variations in precipitation amount over the past 130 kyr. The precipitation record shows orbital- and millennial-scale variations and varies at precession and obliquity scale. The application of this precipitation proxy across the CLP indicates a more pronounced spatial gradient during glacials, when the western CLP experiences more arid conditions.
Heather M. Stoll, Chris Day, Franziska Lechleitner, Oliver Kost, Laura Endres, Jakub Sliwinski, Carlos Pérez-Mejías, Hai Cheng, and Denis Scholz
Clim. Past, 19, 2423–2444, https://doi.org/10.5194/cp-19-2423-2023, https://doi.org/10.5194/cp-19-2423-2023, 2023
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Stalagmites formed in caves provide valuable information about past changes in climate and vegetation conditions. In this contribution, we present a new method to better estimate past changes in soil and vegetation productivity using carbon isotopes and trace elements measured in stalagmites. Applying this method to other stalagmites should provide a better indication of past vegetation feedbacks to climate change.
Jenny Maccali, Anna Nele Meckler, Stein-Erik Lauritzen, Torill Brekken, Helen Aase Rokkan, Alvaro Fernandez, Yves Krüger, Jane Adigun, Stéphane Affolter, and Markus Leuenberger
Clim. Past, 19, 1847–1862, https://doi.org/10.5194/cp-19-1847-2023, https://doi.org/10.5194/cp-19-1847-2023, 2023
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The southern coast of South Africa hosts some key archeological sites for the study of early human evolution. Here we present a short but high-resolution record of past changes in the hydroclimate and temperature on the southern coast of South Africa based on the study of a speleothem collected from Bloukrantz Cave. Overall, the paleoclimate indicators suggest stable temperature from 48.3 to 45.2 ka, whereas precipitation was variable, with marked short drier episodes.
Kurt R. Lindberg, William C. Daniels, Isla S. Castañeda, and Julie Brigham-Grette
Clim. Past, 18, 559–577, https://doi.org/10.5194/cp-18-559-2022, https://doi.org/10.5194/cp-18-559-2022, 2022
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Earth experiences regular ice ages resulting in shifts between cooler and warmer climates. Around 1 million years ago, the ice age cycles grew longer and stronger. We used bacterial and plant lipids preserved in an Arctic lake to reconstruct temperature and vegetation during this climate transition. We find that Arctic land temperatures did not cool much compared to ocean records from this period, and that vegetation shifts correspond with a long-term drying previously reported in the region.
Yoav Ben Dor, Francesco Marra, Moshe Armon, Yehouda Enzel, Achim Brauer, Markus Julius Schwab, and Efrat Morin
Clim. Past, 17, 2653–2677, https://doi.org/10.5194/cp-17-2653-2021, https://doi.org/10.5194/cp-17-2653-2021, 2021
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Laminated sediments from the deepest part of the Dead Sea unravel the hydrological response of the eastern Mediterranean to past climate changes. This study demonstrates the importance of geological archives in complementing modern hydrological measurements that do not fully capture natural hydroclimatic variability, which is crucial to configure for understanding the impact of climate change on the hydrological cycle in subtropical regions.
Mengna Liao, Kai Li, Weiwei Sun, and Jian Ni
Clim. Past, 17, 2291–2303, https://doi.org/10.5194/cp-17-2291-2021, https://doi.org/10.5194/cp-17-2291-2021, 2021
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The long-term trajectories of precipitation, hydrological balance and soil moisture are not completely consistent in southwest China. Hydrological balance was more sensitive to temperature change on a millennial scale. For soil moisture, plant processes also played a big role in addition to precipitation and temperature. Under future climate warming, surface water shortage in southwest China can be even more serious and efforts at reforestation may bring some relief to the soil moisture deficit.
Clément Outrequin, Anne Alexandre, Christine Vallet-Coulomb, Clément Piel, Sébastien Devidal, Amaelle Landais, Martine Couapel, Jean-Charles Mazur, Christophe Peugeot, Monique Pierre, Frédéric Prié, Jacques Roy, Corinne Sonzogni, and Claudia Voigt
Clim. Past, 17, 1881–1902, https://doi.org/10.5194/cp-17-1881-2021, https://doi.org/10.5194/cp-17-1881-2021, 2021
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Continental atmospheric humidity is a key climate parameter poorly captured by global climate models. Model–data comparison approaches that are applicable beyond the instrumental period are essential to progress on this issue but face a lack of quantitative relative humidity proxies. Here, we calibrate the triple oxygen isotope composition of phytoliths as a new quantitative proxy of continental relative humidity suitable for past climate reconstructions.
Jacek Pawlak
Clim. Past, 17, 1051–1064, https://doi.org/10.5194/cp-17-1051-2021, https://doi.org/10.5194/cp-17-1051-2021, 2021
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Presently, central Europe is under the influence of two types of climate, transitional and continental. The 60 ka long multiproxy speleothem dataset from Slovakia records the climate of the Last Interglacial cycle and its transition to the Last Glacial. The interpretation of stable isotopic composition and trace element content proxies helps to distinguish which factor had the strongest influence on the δ18O record shape: the local temperature, the humidity or the source effect.
Sean F. Cleator, Sandy P. Harrison, Nancy K. Nichols, I. Colin Prentice, and Ian Roulstone
Clim. Past, 16, 699–712, https://doi.org/10.5194/cp-16-699-2020, https://doi.org/10.5194/cp-16-699-2020, 2020
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We present geographically explicit reconstructions of seasonal temperature and annual moisture variables at the Last Glacial Maximum (LGM), 21 000 years ago. The reconstructions use existing site-based estimates of climate, interpolated in space and time in a physically consistent way using climate model simulations. The reconstructions give a much better picture of the LGM climate and will provide a robust evaluation of how well state-of-the-art climate models simulate large climate changes.
Shaun R. Eaves, Andrew N. Mackintosh, Brian M. Anderson, Alice M. Doughty, Dougal B. Townsend, Chris E. Conway, Gisela Winckler, Joerg M. Schaefer, Graham S. Leonard, and Andrew T. Calvert
Clim. Past, 12, 943–960, https://doi.org/10.5194/cp-12-943-2016, https://doi.org/10.5194/cp-12-943-2016, 2016
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Geological evidence for past changes in glacier length provides a useful source of information about pre-historic climate change. We have used glacier modelling to show that air temperature reductions of −5 to −7 °C, relative to present, are required to simulate the glacial extent in the North Island, New Zealand, during the last ice age (approx. 20000 years ago). Our results provide data to assess climate model simulations, with the aim of determining the drivers of past natural climate change.
S. Jasechko, A. Lechler, F. S. R. Pausata, P. J. Fawcett, T. Gleeson, D. I. Cendón, J. Galewsky, A. N. LeGrande, C. Risi, Z. D. Sharp, J. M. Welker, M. Werner, and K. Yoshimura
Clim. Past, 11, 1375–1393, https://doi.org/10.5194/cp-11-1375-2015, https://doi.org/10.5194/cp-11-1375-2015, 2015
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In this study we compile global isotope proxy records of climate changes from the last ice age to the late-Holocene preserved in cave calcite, glacial ice and groundwater aquifers. We show that global patterns of late-Pleistocene to late-Holocene precipitation isotope shifts are consistent with stronger-than-modern isotopic distillation of air masses during the last ice age, likely impacted by larger global temperature differences between the tropics and the poles.
J. Zhu, A. Lücke, H. Wissel, C. Mayr, D. Enters, K. Ja Kim, C. Ohlendorf, F. Schäbitz, and B. Zolitschka
Clim. Past, 10, 2153–2169, https://doi.org/10.5194/cp-10-2153-2014, https://doi.org/10.5194/cp-10-2153-2014, 2014
P. S. Minyuk, V. Y. Borkhodoev, and V. Wennrich
Clim. Past, 10, 467–485, https://doi.org/10.5194/cp-10-467-2014, https://doi.org/10.5194/cp-10-467-2014, 2014
U. Frank, N. R. Nowaczyk, P. Minyuk, H. Vogel, P. Rosén, and M. Melles
Clim. Past, 9, 1559–1569, https://doi.org/10.5194/cp-9-1559-2013, https://doi.org/10.5194/cp-9-1559-2013, 2013
J. A. Snyder, M. V. Cherepanova, and A. Bryan
Clim. Past, 9, 1309–1319, https://doi.org/10.5194/cp-9-1309-2013, https://doi.org/10.5194/cp-9-1309-2013, 2013
L. Cunningham, H. Vogel, V. Wennrich, O. Juschus, N. Nowaczyk, and P. Rosén
Clim. Past, 9, 679–686, https://doi.org/10.5194/cp-9-679-2013, https://doi.org/10.5194/cp-9-679-2013, 2013
A. Zander and A. Hilgers
Clim. Past, 9, 719–733, https://doi.org/10.5194/cp-9-719-2013, https://doi.org/10.5194/cp-9-719-2013, 2013
K. J. Murdock, K. Wilkie, and L. L. Brown
Clim. Past, 9, 467–479, https://doi.org/10.5194/cp-9-467-2013, https://doi.org/10.5194/cp-9-467-2013, 2013
P. S. Minyuk, T. V. Subbotnikova, L. L. Brown, and K. J. Murdock
Clim. Past, 9, 433–446, https://doi.org/10.5194/cp-9-433-2013, https://doi.org/10.5194/cp-9-433-2013, 2013
T. Kluge, H. P. Affek, T. Marx, W. Aeschbach-Hertig, D. F. C. Riechelmann, D. Scholz, S. Riechelmann, A. Immenhauser, D. K. Richter, J. Fohlmeister, A. Wackerbarth, A. Mangini, and C. Spötl
Clim. Past, 9, 377–391, https://doi.org/10.5194/cp-9-377-2013, https://doi.org/10.5194/cp-9-377-2013, 2013
A. R. Holland, S. T. Petsch, I. S. Castañeda, K. M. Wilkie, S. J. Burns, and J. Brigham-Grette
Clim. Past, 9, 243–260, https://doi.org/10.5194/cp-9-243-2013, https://doi.org/10.5194/cp-9-243-2013, 2013
S. Samartin, O. Heiri, A. F. Lotter, and W. Tinner
Clim. Past, 8, 1913–1927, https://doi.org/10.5194/cp-8-1913-2012, https://doi.org/10.5194/cp-8-1913-2012, 2012
B. Chapligin, H. Meyer, G. E. A. Swann, C. Meyer-Jacob, and H.-W. Hubberten
Clim. Past, 8, 1621–1636, https://doi.org/10.5194/cp-8-1621-2012, https://doi.org/10.5194/cp-8-1621-2012, 2012
A. Alexandre, J. Crespin, F. Sylvestre, C. Sonzogni, and D. W. Hilbert
Clim. Past, 8, 307–324, https://doi.org/10.5194/cp-8-307-2012, https://doi.org/10.5194/cp-8-307-2012, 2012
B. Wu and N. Q. Wu
Clim. Past, 7, 349–359, https://doi.org/10.5194/cp-7-349-2011, https://doi.org/10.5194/cp-7-349-2011, 2011
Cited articles
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Arienzo, M. M., Swart, P. K., and Vonhof, H. B.: Measurement of δ18O and \delta2H values of fluid inclusion water in speleothems using cavity ring-down spectroscopy compared with isotope ratio mass spectrometry, Rapid Commun. Mass Sp., 27, 2616–2624, https://doi.org/10.1002/rcm.6723, 2013.
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Brand, W. A., Geilmann, H., Crosson, E. R., and Rella, C. W.: Cavity ring-down spectroscopy versus high-temperature conversion isotope ratio mass spectrometry; a case study on delta H-2 and delta O-18 of pure water samples and alcohol/water mixtures, Rapid Commun. Mass Sp., 23, 1879–1884, https://doi.org/10.1002/Rcm.4083, 2009.
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Dublyansky, Y. V. and Spötl, C.: Hydrogen and oxygen isotopes of water from inclusions in minerals: design of a new crushing system and on-line continuous-flow isotope ratio mass spectrometric analysis, Rapid Commun. Mass Sp., 23, 2605–2613, https://doi.org/10.1002/Rcm.4155, 2009.
Fairchild, I. J., Smith, C. L., Baker, A., Fuller, L., Spötl, C., Mattey, D., McDermott, F., and E. I. M. F.: Modification and preservation of environmental signals in speleothems, Earth-Sci. Rev., 75, 105–153, https://doi.org/10.1016/j.earscirev.2005.08.003, 2006.
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Harmon, R. S., Schwarcz, H. P., and Oneil, J. R.: D-H ratios in speleothem fluid inclusions – guide to variations in the isotopic composition of meteoric precipitation, Earth Planet. Sc. Lett., 42, 254–266, https://doi.org/10.1016/0012-821x(79)90033-5, 1979.
Hodell, D. A., Turchyn, A. V., Wiseman, C. J., Escobar, J., Curtis, J. H., Brenner, M., Gilli, A., Mueller, A. D., Anselmetti, F., Ariztegui, D., and Brown, E. T.: Late Glacial temperature and precipitation changes in the lowland Neotropics by tandem measurement of delta O-18 in biogenic carbonate and gypsum hydration water, Geochim. Cosmochim. Ac., 77, 352–368, https://doi.org/10.1016/j.gca.2011.11.026, 2012.
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McGarry, S., Bar-Matthews, M., Matthews, A., Vaks, A., Schilman, B., and Ayalon, A.: Constraints on hydrological and paleotemperature variations in the Eastern Mediterranean region in the last 140 ka given by the delta D values of speleothem fluid inclusions, Quaternary Sci. Rev., 23, 919–934, https://doi.org/10.1016/j.quascirev.2003.06.020, 2004.
Meckler, A. N., Clarkson, M. O., Cobb, K. M., Sodemann, H., and Adkins, J. F.: Interglacial hydroclimate in the tropical west Pacific through the late pleistocene, Science, 336, 1301–1304, https://doi.org/10.1126/science.1218340, 2012.
Mickler, P. J., Stern, L. A., and Banner, J. L.: Large kinetic isotope effects in modern speleothems, Geol. Soc. Am. Bull., 118, 65–81, https://doi.org/10.1130/B25698.1, 2006.
Moerman, J. W., Cobb, K. M., Adkins, J. F., Sodemann, H., Clark, B., and Tuen, A. A.: Diurnal to interannual rainfall delta O-18 variations in northern Borneo driven by regional hydrology, Earth Planet Sc. Lett., 369, 108–119, https://doi.org/10.1016/j.epsl.2013.03.014, 2013.
Morrison, J., Brockwell, T., Merren, T., Fourel, F., and Phillips, A. M.: On-Line High-Precision Stable Hydrogen Isotopic Analyses on Nanoliter Water Samples, Anal. Chem., 73, 3570–3575, https://doi.org/10.1021/ac001447t, 2001.
Scheidegger, Y., Baur, H., Brennwald, M. S., Fleitmann, D., Wieler, R., and Kipfer, R.: Accurate analysis of noble gas concentrations in small water samples and its application to fluid inclusions in stalagmites, Chem. Geol., 272, 31–39, https://doi.org/10.1016/j.chemgeo.2010.01.010, 2010.
Schwarcz, H. P., Harmon, R. S., Thompson, P., and Ford, D. C.: Stable isotope studies of fluid inclusions in speleothems and their paleoclimatic significance, Geochim. Cosmochim. Acta, 40, 657–665, https://doi.org/10.1016/0016-7037(76)90111-3, 1976.
Sharp, Z. D., Atudorei, V., and Durakiewicz, T.: Arapid method for determination of hydrogen and oxygen isotope ratios from water and hydrous minerals, Chem. Geol., 178, 197–210, https://doi.org/10.1016/S0009-2541(01)00262-5, 2001.
Smalley, P. C., Stijfhoorn, D. E., Raheim, A., Johansen, H., and Dickson, J. A. D.: The laser microprobe and its application to the study of C and O isotopes in calcite and aragonite, Sediment. Geol., 65, 211–221, https://doi.org/10.1016/0037-0738(89)90023-7, 1989.
Sturm, P. and Knohl, A.: Water vapor \delta2H and \delta18O measurements using off-axis integrated cavity output spectroscopy, Atmos. Meas. Tech., 3, 67–77, https://doi.org/10.5194/amt-3-67-2010, 2010.
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