Articles | Volume 20, issue 5
https://doi.org/10.5194/cp-20-1213-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Special issue:
https://doi.org/10.5194/cp-20-1213-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
28 May 2024
Research article |
| 28 May 2024
| 28 May 2024
Drivers of late Holocene ice core chemistry in Dronning Maud Land: the context for the ISOL-ICE project
V. Holly L. Winton
CORRESPONDING AUTHOR
British Antarctica Survey, Cambridge, CB3 0ET, United Kingdom
Te Puna Pātiotio–Antarctic Research Centre, Te Herenga Waka–Victoria University of Wellington, Te Whanganui a Tara/Wellington 6102, Aotearoa/New Zealand
Robert Mulvaney
British Antarctica Survey, Cambridge, CB3 0ET, United Kingdom
Joel Savarino
University of Grenoble Alpes, CNRS, IRD, Grenoble INP, INRAE, IGE, 38000 Grenoble, France
Kyle R. Clem
Te Kura Tātai Aro Whenua–School of Geography, Environment and Earth Sciences, Te Herenga Waka–Victoria University of Wellington, Te Whanganui a Tara/Wellington 6102, Aotearoa/New Zealand
British Antarctica Survey, Cambridge, CB3 0ET, United Kingdom
Related authors
Elizabeth R. Thomas, Diana O. Vladimirova, Dieter R. Tetzner, B. Daniel Emanuelsson, Nathan Chellman, Daniel A. Dixon, Hugues Goosse, Mackenzie M. Grieman, Amy C. F. King, Michael Sigl, Danielle G. Udy, Tessa R. Vance, Dominic A. Winski, V. Holly L. Winton, Nancy A. N. Bertler, Akira Hori, Chavarukonam M. Laluraj, Joseph R. McConnell, Yuko Motizuki, Kazuya Takahashi, Hideaki Motoyama, Yoichi Nakai, Franciéle Schwanck, Jefferson Cardia Simões, Filipe Gaudie Ley Lindau, Mirko Severi, Rita Traversi, Sarah Wauthy, Cunde Xiao, Jiao Yang, Ellen Mosely-Thompson, Tamara V. Khodzher, Ludmila P. Golobokova, and Alexey A. Ekaykin
Earth Syst. Sci. Data, 15, 2517–2532, https://doi.org/10.5194/essd-15-2517-2023, https://doi.org/10.5194/essd-15-2517-2023, 2023
Short summary
Short summary
The concentration of sodium and sulfate measured in Antarctic ice cores is related to changes in both sea ice and winds. Here we have compiled a database of sodium and sulfate records from 105 ice core sites in Antarctica. The records span all, or part, of the past 2000 years. The records will improve our understanding of how winds and sea ice have changed in the past and how they have influenced the climate of Antarctica over the past 2000 years.
Abhijith U. Venugopal, Nancy A. N. Bertler, Rebecca L. Pyne, Helle A. Kjær, V. Holly L. Winton, Paul A. Mayewski, and Giuseppe Cortese
Clim. Past Discuss., https://doi.org/10.5194/cp-2020-151, https://doi.org/10.5194/cp-2020-151, 2020
Manuscript not accepted for further review
Short summary
Short summary
We present a new and highly resolved glacial record of nitrate and calcium from a deep ice core obtained from Roosevelt Island, West Antarctica. Our data show a dependent association among nitrate and non-sea salt calcium (mineral dust) as observed previously in East Antarctica. The spatial pattern indicates that mineral dust is scavenging nitrate from the atmosphere and the westerlies are dispersing the dust-bound nitrate across Antarctica, making nitrate a potential paleo-westerly wind proxy.
V. Holly L. Winton, Alison Ming, Nicolas Caillon, Lisa Hauge, Anna E. Jones, Joel Savarino, Xin Yang, and Markus M. Frey
Atmos. Chem. Phys., 20, 5861–5885, https://doi.org/10.5194/acp-20-5861-2020, https://doi.org/10.5194/acp-20-5861-2020, 2020
Short summary
Short summary
The transfer of the nitrogen stable isotopic composition in nitrate between the air and snow at low accumulation sites in Antarctica leaves an UV imprint in the snow. Quantifying how nitrate isotope values change allows us to interpret longer ice core records. Based on nitrate observations and modelling at Kohnen, East Antarctica, the dominant factors controlling the nitrate isotope signature in deep snow layers are the depth of light penetration into the snowpack and the snow accumulation rate.
Pascal Bohleber, Mathieu Casado, Kirsti Ashworth, Chelsey A. Baker, Anna Belcher, Jilda Alicia Caccavo, Holly E. Jenkins, Erin Satterthwaite, Andrea Spolaor, and V. Holly L. Winton
Adv. Geosci., 53, 1–14, https://doi.org/10.5194/adgeo-53-1-2020, https://doi.org/10.5194/adgeo-53-1-2020, 2020
Short summary
Short summary
International Early Career Networks (ECN) are global voluntary communities of Early Career Scientists (ECS) aiming to advance the careers of ECS and to improve their inclusion into the international scientific community. We use member surveys alongside with case studies from well-established and long-term networks to elucidate the attributes that make a successful, sustainable ECN, and propose best practices for developing ECN successfully.
Nancy A. N. Bertler, Howard Conway, Dorthe Dahl-Jensen, Daniel B. Emanuelsson, Mai Winstrup, Paul T. Vallelonga, James E. Lee, Ed J. Brook, Jeffrey P. Severinghaus, Taylor J. Fudge, Elizabeth D. Keller, W. Troy Baisden, Richard C. A. Hindmarsh, Peter D. Neff, Thomas Blunier, Ross Edwards, Paul A. Mayewski, Sepp Kipfstuhl, Christo Buizert, Silvia Canessa, Ruzica Dadic, Helle A. Kjær, Andrei Kurbatov, Dongqi Zhang, Edwin D. Waddington, Giovanni Baccolo, Thomas Beers, Hannah J. Brightley, Lionel Carter, David Clemens-Sewall, Viorela G. Ciobanu, Barbara Delmonte, Lukas Eling, Aja Ellis, Shruthi Ganesh, Nicholas R. Golledge, Skylar Haines, Michael Handley, Robert L. Hawley, Chad M. Hogan, Katelyn M. Johnson, Elena Korotkikh, Daniel P. Lowry, Darcy Mandeno, Robert M. McKay, James A. Menking, Timothy R. Naish, Caroline Noerling, Agathe Ollive, Anaïs Orsi, Bernadette C. Proemse, Alexander R. Pyne, Rebecca L. Pyne, James Renwick, Reed P. Scherer, Stefanie Semper, Marius Simonsen, Sharon B. Sneed, Eric J. Steig, Andrea Tuohy, Abhijith Ulayottil Venugopal, Fernando Valero-Delgado, Janani Venkatesh, Feitang Wang, Shimeng Wang, Dominic A. Winski, V. Holly L. Winton, Arran Whiteford, Cunde Xiao, Jiao Yang, and Xin Zhang
Clim. Past, 14, 193–214, https://doi.org/10.5194/cp-14-193-2018, https://doi.org/10.5194/cp-14-193-2018, 2018
Short summary
Short summary
Temperature and snow accumulation records from the annually dated Roosevelt Island Climate Evolution (RICE) ice core show that for the past 2 700 years, the eastern Ross Sea warmed, while the western Ross Sea showed no trend and West Antarctica cooled. From the 17th century onwards, this dipole relationship changed. Now all three regions show concurrent warming, with snow accumulation declining in West Antarctica and the eastern Ross Sea.
Marc D. Mallet, Maximilien J. Desservettaz, Branka Miljevic, Andelija Milic, Zoran D. Ristovski, Joel Alroe, Luke T. Cravigan, E. Rohan Jayaratne, Clare Paton-Walsh, David W. T. Griffith, Stephen R. Wilson, Graham Kettlewell, Marcel V. van der Schoot, Paul Selleck, Fabienne Reisen, Sarah J. Lawson, Jason Ward, James Harnwell, Min Cheng, Rob W. Gillett, Suzie B. Molloy, Dean Howard, Peter F. Nelson, Anthony L. Morrison, Grant C. Edwards, Alastair G. Williams, Scott D. Chambers, Sylvester Werczynski, Leah R. Williams, V. Holly L. Winton, Brad Atkinson, Xianyu Wang, and Melita D. Keywood
Atmos. Chem. Phys., 17, 13681–13697, https://doi.org/10.5194/acp-17-13681-2017, https://doi.org/10.5194/acp-17-13681-2017, 2017
Short summary
Short summary
Fires play an important role within atmosphere. Gaseous and aerosol emissions influence Earth's temperature but these emissions can vary drastically across region and season. The SAFIRED (Savannah Fires in the Early Dry Season) campaign was undertaken at the Australian Tropical Research Station in north Australia during the 2014 early dry season. This paper presents an overview of the fires in this region, the measurements of their emissions and the implications of these fires on the atmosphere.
V. Holly L. Winton, Ross Edwards, Andrew R. Bowie, Melita Keywood, Alistair G. Williams, Scott D. Chambers, Paul W. Selleck, Maximilien Desservettaz, Marc D. Mallet, and Clare Paton-Walsh
Atmos. Chem. Phys., 16, 12829–12848, https://doi.org/10.5194/acp-16-12829-2016, https://doi.org/10.5194/acp-16-12829-2016, 2016
Short summary
Short summary
The deposition of soluble aerosol iron (Fe) can initiate nitrogen fixation and trigger toxic algal blooms in nitrate-poor tropical waters. We present dry season soluble Fe data from northern Australia that reflect coincident dust and biomass burning sources of soluble Fe. Our results show that while biomass burning species are not a direct source of soluble Fe, biomass burning may substantially enhance the solubility of mineral dust with fractional Fe solubility up to 12 % in mixed aerosols.
Holly Winton, Andrew Bowie, Melita Keywood, Pier van der Merwe, and Ross Edwards
Atmos. Meas. Tech. Discuss., https://doi.org/10.5194/amt-2016-12, https://doi.org/10.5194/amt-2016-12, 2016
Revised manuscript not accepted
Short summary
Short summary
Aerosols containing iron have been investigated over the remote Southern Ocean to constrain iron budgets in surface waters and related biological production. Protocols for the sampling of ambient air were used to assess the suitability of high-volume aerosol samplers for aerosol iron studies in pristine air masses. Significant evidence of airborne insect and local soil contamination was detected in exposure blank filters. Suggestions for future aerosol iron sampling in clean air are provided.
Lison Soussaintjean, Jochen Schmitt, Joël Savarino, J. Andy Menking, Edward J. Brook, Barbara Seth, Vladimir Lipenkov, Thomas Röckmann, and Hubertus Fischer
EGUsphere, https://doi.org/10.5194/egusphere-2025-3108, https://doi.org/10.5194/egusphere-2025-3108, 2025
This preprint is open for discussion and under review for Biogeosciences (BG).
Short summary
Short summary
Nitrous oxide (N2O) produced in dust-rich Antarctic ice complicates the reconstruction of past atmospheric levels from ice core records. Using isotope analysis, we show that N2O forms from two nitrogen precursors, one being nitrate. For the first time, we demonstrate that the site preference (SP) of N2O reflects the isotopic difference between these precursors, not the production pathway, which challenges the common interpretation of SP.
Filip Pastierovic, Roberto Grilli, Nicolas Caillon, and Joel Savarino
EGUsphere, https://doi.org/10.5194/egusphere-2025-3115, https://doi.org/10.5194/egusphere-2025-3115, 2025
This preprint is open for discussion and under review for Atmospheric Measurement Techniques (AMT).
Short summary
Short summary
The development of an open detector based on absorption spectroscopy, enhanced by high-reflectivity mirrors, for the simultaneous measurement of NO2, IO, and CHOCHO is reported. The instrument shows good correlation with a closed system during both indoor and outdoor measurements. An open system is able to measure NO2, IO, and CHOCHO with high precision.
Zhao Wei, Shohei Hattori, Asuka Tsuruta, Zhuang Jiang, Sakiko Ishino, Koji Fujita, Sumito Matoba, Lei Geng, Alexis Lamothe, Ryu Uemura, Naohiro Yoshida, Joel Savarino, and Yoshinori Iizuka
Atmos. Chem. Phys., 25, 5727–5742, https://doi.org/10.5194/acp-25-5727-2025, https://doi.org/10.5194/acp-25-5727-2025, 2025
Short summary
Short summary
Nitrate isotope records in ice cores reveal changes in NOₓ emissions and atmospheric oxidation chemistry driven by human activity. However, UV-driven postdepositional processes can alter nitrate in snow, making snow accumulation rates critical for preserving these records. This study examines nitrate isotopes in a southeastern Greenland ice core, where high snow accumulation minimizes these effects, providing a reliable archive of atmospheric nitrogen cycling.
Brice Barret, Patrice Medina, Natalie Brett, Roman Pohorsky, Kathy S. Law, Slimane Bekki, Gilberto J. Fochesatto, Julia Schmale, Steve R. Arnold, Andrea Baccarini, Maurizio Busetto, Meeta Cesler-Maloney, Barbara D'Anna, Stefano Decesari, Jingqiu Mao, Gianluca Pappaccogli, Joel Savarino, Federico Scoto, and William R. Simpson
Atmos. Meas. Tech., 18, 1163–1184, https://doi.org/10.5194/amt-18-1163-2025, https://doi.org/10.5194/amt-18-1163-2025, 2025
Short summary
Short summary
The Fairbanks area experiences severe pollution episodes in winter because of enhanced emissions of pollutants trapped near the surface by strong temperature inversions. Low-cost sensors were deployed on board a car and a tethered balloon to measure the concentrations of gaseous pollutants (CO, O3, and NOx) in Fairbanks during winter 2022. Data calibration with reference measurements and machine learning methods enabled us to document pollution at the surface and power plant plumes aloft.
Benjamin Heutte, Nora Bergner, Hélène Angot, Jakob B. Pernov, Lubna Dada, Jessica A. Mirrielees, Ivo Beck, Andrea Baccarini, Matthew Boyer, Jessie M. Creamean, Kaspar R. Daellenbach, Imad El Haddad, Markus M. Frey, Silvia Henning, Tiia Laurila, Vaios Moschos, Tuukka Petäjä, Kerri A. Pratt, Lauriane L. J. Quéléver, Matthew D. Shupe, Paul Zieger, Tuija Jokinen, and Julia Schmale
Atmos. Chem. Phys., 25, 2207–2241, https://doi.org/10.5194/acp-25-2207-2025, https://doi.org/10.5194/acp-25-2207-2025, 2025
Short summary
Short summary
Limited aerosol measurements in the central Arctic hinder our understanding of aerosol–climate interactions in the region. Our year-long observations of aerosol physicochemical properties during the MOSAiC expedition reveal strong seasonal variations in aerosol chemical composition, where the short-term variability is heavily affected by storms in the Arctic. Local wind-generated particles are shown to be an important source of cloud seeds, especially in autumn.
James Brean, David C. S. Beddows, Eija Asmi, Aki Virkkula, Lauriane L. J. Quéléver, Mikko Sipilä, Floortje Van Den Heuvel, Thomas Lachlan-Cope, Anna Jones, Markus Frey, Angelo Lupi, Jiyeon Park, Young Jun Yoon, Rolf Weller, Giselle L. Marincovich, Gabriela C. Mulena, Roy M. Harrison, and Manuel Dall'Osto
Atmos. Chem. Phys., 25, 1145–1162, https://doi.org/10.5194/acp-25-1145-2025, https://doi.org/10.5194/acp-25-1145-2025, 2025
Short summary
Short summary
Our results emphasise how understanding the geographical variation in surface types across the Antarctic is key to understanding secondary aerosol sources.
Natalie Brett, Kathy S. Law, Steve R. Arnold, Javier G. Fochesatto, Jean-Christophe Raut, Tatsuo Onishi, Robert Gilliam, Kathleen Fahey, Deanna Huff, George Pouliot, Brice Barret, Elsa Dieudonné, Roman Pohorsky, Julia Schmale, Andrea Baccarini, Slimane Bekki, Gianluca Pappaccogli, Federico Scoto, Stefano Decesari, Antonio Donateo, Meeta Cesler-Maloney, William Simpson, Patrice Medina, Barbara D'Anna, Brice Temime-Roussel, Joel Savarino, Sarah Albertin, Jingqiu Mao, Becky Alexander, Allison Moon, Peter F. DeCarlo, Vanessa Selimovic, Robert Yokelson, and Ellis S. Robinson
Atmos. Chem. Phys., 25, 1063–1104, https://doi.org/10.5194/acp-25-1063-2025, https://doi.org/10.5194/acp-25-1063-2025, 2025
Short summary
Short summary
Processes influencing dispersion of local anthropogenic pollution in Arctic wintertime are investigated with Lagrangian dispersion modelling. Simulated power plant plume rise that considers temperature inversion layers improves results compared to observations (interior Alaska). Modelled surface concentrations are improved by representation of vertical mixing and emission estimates. Large increases in diesel vehicle emissions at temperatures reaching −35°C are required to reproduce observed NOx.
Agnese Petteni, Elise Fourré, Elsa Gautier, Azzurra Spagnesi, Roxanne Jacob, Pete D. Akers, Daniele Zannoni, Jacopo Gabrieli, Olivier Jossoud, Frédéric Prié, Amaëlle Landais, Titouan Tcheng, Barbara Stenni, Joel Savarino, Patrick Ginot, and Mathieu Casado
EGUsphere, https://doi.org/10.5194/egusphere-2024-3335, https://doi.org/10.5194/egusphere-2024-3335, 2025
Short summary
Short summary
Our research compares three CFA-CRDS systems from Venice, Paris, and Grenoble for measuring water isotopes in ice cores, crucial for reconstructing past climate. We quantify each system’s mixing and measurement noise effects, which impact the achievable resolution of isotope continuous records. Our findings reveal specific configurations and procedures to enhance measurement accuracy, providing a framework to optimise water isotope analysis.
Amna Ijaz, Brice Temime-Roussel, Benjamin Chazeau, Sarah Albertin, Stephen R. Arnold, Brice Barrett, Slimane Bekki, Natalie Brett, Meeta Cesler-Maloney, Elsa Dieudonne, Kayane K. Dingilian, Javier G. Fochesatto, Jingqiu Mao, Allison Moon, Joel Savarino, William Simpson, Rodney J. Weber, Kathy S. Law, and Barbara D'Anna
EGUsphere, https://doi.org/10.5194/egusphere-2024-3789, https://doi.org/10.5194/egusphere-2024-3789, 2024
Short summary
Short summary
Fairbanks is among the most polluted cities with the highest particulate matter (PM) levels in the US during winters. Highly time-resolved measurements of the sub-micron PM elucidated residential heating with wood and oil and hydrocarbon-like organics from traffic, as well as sulphur-containing organic aerosol, to be the key pollution sources. Remarkable differences existed between complementary instruments, warranting the deployment of multiple tools at sites with wide-ranging influences.
Frédéric Parrenin, Marie Bouchet, Christo Buizert, Emilie Capron, Ellen Corrick, Russell Drysdale, Kenji Kawamura, Amaëlle Landais, Robert Mulvaney, Ikumi Oyabu, and Sune Olander Rasmussen
Geosci. Model Dev., 17, 8735–8750, https://doi.org/10.5194/gmd-17-8735-2024, https://doi.org/10.5194/gmd-17-8735-2024, 2024
Short summary
Short summary
The Paleochrono-1.1 probabilistic dating model allows users to derive a common and optimized chronology for several paleoclimatic sites from various archives (ice cores, speleothems, marine cores, lake cores, etc.). It combines prior sedimentation scenarios with chronological information such as dated horizons, dated intervals, stratigraphic links and (for ice cores) Δdepth observations. Paleochrono-1.1 is available under an open-source license.
Helene Hoffmann, Jason Day, Rachael H. Rhodes, Mackenzie Grieman, Jack Humby, Isobel Rowell, Christoph Nehrbass-Ahles, Robert Mulvaney, Sally Gibson, and Eric Wolff
The Cryosphere, 18, 4993–5013, https://doi.org/10.5194/tc-18-4993-2024, https://doi.org/10.5194/tc-18-4993-2024, 2024
Short summary
Short summary
Ice cores are archives of past atmospheric conditions. In deep and old ice, the layers containing this information get thinned to the millimetre scale or below. We installed a setup for high-resolution (182 μm) chemical impurity measurements in ice cores using the laser ablation technique at the University of Cambridge. In a first application to the Skytrain ice core from Antarctica, we discuss the potential to detect fine-layered structures in ice up to an age of 26 000 years.
Romilly Harris Stuart, Amaëlle Landais, Laurent Arnaud, Christo Buizert, Emilie Capron, Marie Dumont, Quentin Libois, Robert Mulvaney, Anaïs Orsi, Ghislain Picard, Frédéric Prié, Jeffrey Severinghaus, Barbara Stenni, and Patricia Martinerie
The Cryosphere, 18, 3741–3763, https://doi.org/10.5194/tc-18-3741-2024, https://doi.org/10.5194/tc-18-3741-2024, 2024
Short summary
Short summary
Ice core δO2/N2 records are useful dating tools due to their local insolation pacing. A precise understanding of the physical mechanism driving this relationship, however, remain ambiguous. By compiling data from 15 polar sites, we find a strong dependence of mean δO2/N2 on accumulation rate and temperature in addition to the well-documented insolation dependence. Snowpack modelling is used to investigate which physical properties drive the mechanistic dependence on these local parameters.
Ailsa Chung, Frédéric Parrenin, Robert Mulvaney, Luca Vittuari, Massimo Frezzotti, Antonio Zanutta, David A. Lilien, Marie G. P. Cavitte, and Olaf Eisen
EGUsphere, https://doi.org/10.5194/egusphere-2024-1650, https://doi.org/10.5194/egusphere-2024-1650, 2024
Short summary
Short summary
We applied an ice flow model to a flow line from the summit of Dome C to the Beyond EPICA ice core drill site on Little Dome C in Antarctica. Results show that the oldest ice at the drill site may be 1.12 Ma (at age density of 20 kyr/m) and originate from around 15 km upstream. We also discuss the nature of the 200–250 m thick basal layer which could be composed of accreted ice, stagnant ice, or even disturbed ice containing debris.
Zhuang Jiang, Becky Alexander, Joel Savarino, and Lei Geng
Atmos. Chem. Phys., 24, 4895–4914, https://doi.org/10.5194/acp-24-4895-2024, https://doi.org/10.5194/acp-24-4895-2024, 2024
Short summary
Short summary
Ice-core nitrate could track the past atmospheric NOx and oxidant level, but its interpretation is hampered by the post-depositional processing. In this work, an inverse model was developed and tested against two polar sites and was shown to well reproduce the observed nitrate signals in snow and atmosphere, suggesting that the model can properly correct for the effect of post-depositional processing. This model offers a very useful tool for future studies on ice-core nitrate records.
Sarah Albertin, Joël Savarino, Slimane Bekki, Albane Barbero, Roberto Grilli, Quentin Fournier, Irène Ventrillard, Nicolas Caillon, and Kathy Law
Atmos. Chem. Phys., 24, 1361–1388, https://doi.org/10.5194/acp-24-1361-2024, https://doi.org/10.5194/acp-24-1361-2024, 2024
Short summary
Short summary
This study reports the first simultaneous records of oxygen (Δ17O) and nitrogen (δ15N) isotopes in nitrogen dioxide (NO2) and nitrate (NO3−). These data are combined with atmospheric observations to explore sub-daily N reactive chemistry and quantify N fractionation effects in an Alpine winter city. The results highlight the necessity of using Δ17O and δ15N in both NO2 and NO3− to avoid biased estimations of NOx sources and fates from NO3− isotopic records in urban winter environments.
Emma Nilsson, Carmen Paulina Vega, Dmitry Divine, Anja Eichler, Tonu Martma, Robert Mulvaney, Elisabeth Schlosser, Margit Schwikowski, and Elisabeth Isaksson
EGUsphere, https://doi.org/10.5194/egusphere-2023-3156, https://doi.org/10.5194/egusphere-2023-3156, 2024
Preprint withdrawn
Short summary
Short summary
To project future climate change it is necessary to understand paleoclimate including past sea ice conditions. We have investigated methane sulphonic acid (MSA) in Antarctic firn and ice cores to reconstruct sea ice extent (SIE) and found that the MSA – SIE as well as the MSA – phytoplankton biomass relationship varies across the different firn and ice cores. These inconsistencies in correlations across records suggest that MSA in Fimbul Ice Shelf cores does not reliably indicate regional SIE.
Alexis Lamothe, Joel Savarino, Patrick Ginot, Lison Soussaintjean, Elsa Gautier, Pete D. Akers, Nicolas Caillon, and Joseph Erbland
Atmos. Meas. Tech., 16, 4015–4030, https://doi.org/10.5194/amt-16-4015-2023, https://doi.org/10.5194/amt-16-4015-2023, 2023
Short summary
Short summary
Ammonia is a reactive gas in our atmosphere that is key in air quality issues. Assessing its emissions and how it reacts is a hot topic that can be addressed from the past. Stable isotopes (the mass of the molecule) measured in ice cores (glacial archives) can teach us a lot. However, the concentrations in ice cores are very small. We propose a protocol to limit the contamination and apply it to one ice core drilled in Mont Blanc, describing the opportunities our method brings.
Ailsa Chung, Frédéric Parrenin, Daniel Steinhage, Robert Mulvaney, Carlos Martín, Marie G. P. Cavitte, David A. Lilien, Veit Helm, Drew Taylor, Prasad Gogineni, Catherine Ritz, Massimo Frezzotti, Charles O'Neill, Heinrich Miller, Dorthe Dahl-Jensen, and Olaf Eisen
The Cryosphere, 17, 3461–3483, https://doi.org/10.5194/tc-17-3461-2023, https://doi.org/10.5194/tc-17-3461-2023, 2023
Short summary
Short summary
We combined a numerical model with radar measurements in order to determine the age of ice in the Dome C region of Antarctica. Our results show that at the current ice core drilling sites on Little Dome C, the maximum age of the ice is almost 1.5 Ma. We also highlight a new potential drill site called North Patch with ice up to 2 Ma. Finally, we explore the nature of a stagnant ice layer at the base of the ice sheet which has been independently observed and modelled but is not well understood.
Isobel Rowell, Carlos Martin, Robert Mulvaney, Helena Pryer, Dieter Tetzner, Emily Doyle, Hara Madhav Talasila, Jilu Li, and Eric Wolff
Clim. Past, 19, 1699–1714, https://doi.org/10.5194/cp-19-1699-2023, https://doi.org/10.5194/cp-19-1699-2023, 2023
Short summary
Short summary
We present an age scale for a new type of ice core from a vulnerable region in West Antarctic, which is lacking in longer-term (greater than a few centuries) ice core records. The Sherman Island core extends to greater than 1 kyr. We provide modelling evidence for the potential of a 10 kyr long core. We show that this new type of ice core can be robustly dated and that climate records from this core will be a significant addition to existing regional climate records.
Benoit S. Lecavalier, Lev Tarasov, Greg Balco, Perry Spector, Claus-Dieter Hillenbrand, Christo Buizert, Catherine Ritz, Marion Leduc-Leballeur, Robert Mulvaney, Pippa L. Whitehouse, Michael J. Bentley, and Jonathan Bamber
Earth Syst. Sci. Data, 15, 3573–3596, https://doi.org/10.5194/essd-15-3573-2023, https://doi.org/10.5194/essd-15-3573-2023, 2023
Short summary
Short summary
The Antarctic Ice Sheet Evolution constraint database version 2 (AntICE2) consists of a large variety of observations that constrain the evolution of the Antarctic Ice Sheet over the last glacial cycle. This includes observations of past ice sheet extent, past ice thickness, past relative sea level, borehole temperature profiles, and present-day bedrock displacement rates. The database is intended to improve our understanding of past Antarctic changes and for ice sheet model calibrations.
Elizabeth R. Thomas, Diana O. Vladimirova, Dieter R. Tetzner, B. Daniel Emanuelsson, Nathan Chellman, Daniel A. Dixon, Hugues Goosse, Mackenzie M. Grieman, Amy C. F. King, Michael Sigl, Danielle G. Udy, Tessa R. Vance, Dominic A. Winski, V. Holly L. Winton, Nancy A. N. Bertler, Akira Hori, Chavarukonam M. Laluraj, Joseph R. McConnell, Yuko Motizuki, Kazuya Takahashi, Hideaki Motoyama, Yoichi Nakai, Franciéle Schwanck, Jefferson Cardia Simões, Filipe Gaudie Ley Lindau, Mirko Severi, Rita Traversi, Sarah Wauthy, Cunde Xiao, Jiao Yang, Ellen Mosely-Thompson, Tamara V. Khodzher, Ludmila P. Golobokova, and Alexey A. Ekaykin
Earth Syst. Sci. Data, 15, 2517–2532, https://doi.org/10.5194/essd-15-2517-2023, https://doi.org/10.5194/essd-15-2517-2023, 2023
Short summary
Short summary
The concentration of sodium and sulfate measured in Antarctic ice cores is related to changes in both sea ice and winds. Here we have compiled a database of sodium and sulfate records from 105 ice core sites in Antarctica. The records span all, or part, of the past 2000 years. The records will improve our understanding of how winds and sea ice have changed in the past and how they have influenced the climate of Antarctica over the past 2000 years.
Amelia M. H. Bond, Markus M. Frey, Jan Kaiser, Jörg Kleffmann, Anna E. Jones, and Freya A. Squires
Atmos. Chem. Phys., 23, 5533–5550, https://doi.org/10.5194/acp-23-5533-2023, https://doi.org/10.5194/acp-23-5533-2023, 2023
Short summary
Short summary
Atmospheric nitrous acid (HONO) amount fractions measured at Halley Research Station, Antarctica, were found to be low. Vertical fluxes of HONO from the snow were also measured and agree with the estimated HONO production rate from photolysis of snow nitrate. In a simple box model of HONO sources and sinks, there was good agreement between the measured flux and amount fraction. HONO was found to be an important OH radical source at Halley.
Robert Mulvaney, Eric W. Wolff, Mackenzie M. Grieman, Helene H. Hoffmann, Jack D. Humby, Christoph Nehrbass-Ahles, Rachael H. Rhodes, Isobel F. Rowell, Frédéric Parrenin, Loïc Schmidely, Hubertus Fischer, Thomas F. Stocker, Marcus Christl, Raimund Muscheler, Amaelle Landais, and Frédéric Prié
Clim. Past, 19, 851–864, https://doi.org/10.5194/cp-19-851-2023, https://doi.org/10.5194/cp-19-851-2023, 2023
Short summary
Short summary
We present an age scale for a new ice core drilled at Skytrain Ice Rise, an ice rise facing the Ronne Ice Shelf in Antarctica. Various measurements in the ice and air phases are used to match the ice core to other Antarctic cores that have already been dated, and a new age scale is constructed. The 651 m ice core includes ice that is confidently dated to 117 000–126 000 years ago, in the last interglacial. Older ice is found deeper down, but there are flow disturbances in the deeper ice.
Simone Ventisette, Samuele Baldini, Claudio Artoni, Silvia Becagli, Laura Caiazzo, Barbara Delmonte, Massimo Frezzotti, Raffaello Nardin, Joel Savarino, Mirko Severi, Andrea Spolaor, Barbara Stenni, and Rita Traversi
EGUsphere, https://doi.org/10.5194/egusphere-2023-393, https://doi.org/10.5194/egusphere-2023-393, 2023
Preprint archived
Short summary
Short summary
The paper reports the spatial variability of concentration and fluxes of chemical impurities in superficial snow over unexplored area of the East Antarctic ice sheet. Pinatubo and Puyehue-Cordón Caulle volcanic eruptions in non-sea salt sulfate and dust snow pits record were used to achieve the accumulation rates. Deposition (wet, dry and uptake from snow surface) and post deposition processes are constrained. These knowledges are fundamental in Antarctic ice cores stratigraphies interpretation.
Christo Buizert, Sarah Shackleton, Jeffrey P. Severinghaus, William H. G. Roberts, Alan Seltzer, Bernhard Bereiter, Kenji Kawamura, Daniel Baggenstos, Anaïs J. Orsi, Ikumi Oyabu, Benjamin Birner, Jacob D. Morgan, Edward J. Brook, David M. Etheridge, David Thornton, Nancy Bertler, Rebecca L. Pyne, Robert Mulvaney, Ellen Mosley-Thompson, Peter D. Neff, and Vasilii V. Petrenko
Clim. Past, 19, 579–606, https://doi.org/10.5194/cp-19-579-2023, https://doi.org/10.5194/cp-19-579-2023, 2023
Short summary
Short summary
It is unclear how different components of the global atmospheric circulation, such as the El Niño effect, respond to large-scale climate change. We present a new ice core gas proxy, called krypton-86 excess, that reflects past storminess in Antarctica. We present data from 11 ice cores that suggest the new proxy works. We present a reconstruction of changes in West Antarctic storminess over the last 24 000 years and suggest these are caused by north–south movement of the tropical rain belt.
Pete D. Akers, Joël Savarino, Nicolas Caillon, Olivier Magand, and Emmanuel Le Meur
Atmos. Chem. Phys., 22, 15637–15657, https://doi.org/10.5194/acp-22-15637-2022, https://doi.org/10.5194/acp-22-15637-2022, 2022
Short summary
Short summary
Nitrate isotopes in Antarctic ice do not preserve the seasonal isotopic cycles of the atmosphere, which limits their use to study the past. We studied nitrate along an 850 km Antarctic transect to learn how these cycles are changed by sunlight-driven chemistry in the snow. Our findings suggest that the snow accumulation rate and other environmental signals can be extracted from nitrate with the right sampling and analytical approaches.
Yanzhi Cao, Zhuang Jiang, Becky Alexander, Jihong Cole-Dai, Joel Savarino, Joseph Erbland, and Lei Geng
Atmos. Chem. Phys., 22, 13407–13422, https://doi.org/10.5194/acp-22-13407-2022, https://doi.org/10.5194/acp-22-13407-2022, 2022
Short summary
Short summary
We investigate the potential of ice-core preserved nitrate isotopes as proxies of stratospheric ozone variability by measuring nitrate isotopes in a shallow ice core from the South Pole. The large variability in the snow accumulation rate and its slight increase after the 1970s masked any signals caused by the ozone hole. Moreover, the nitrate oxygen isotope decrease may reflect changes in the atmospheric oxidation environment in the Southern Ocean.
Albane Barbero, Roberto Grilli, Markus M. Frey, Camille Blouzon, Detlev Helmig, Nicolas Caillon, and Joël Savarino
Atmos. Chem. Phys., 22, 12025–12054, https://doi.org/10.5194/acp-22-12025-2022, https://doi.org/10.5194/acp-22-12025-2022, 2022
Short summary
Short summary
The high reactivity of the summer Antarctic boundary layer results in part from the emissions of nitrogen oxides produced during photo-denitrification of the snowpack, but its underlying mechanisms are not yet fully understood. The results of this study suggest that more NO2 is produced from the snowpack early in the photolytic season, possibly due to stronger UV irradiance caused by a smaller solar zenith angle near the solstice.
Franz Lutz, David J. Prior, Holly Still, M. Hamish Bowman, Bia Boucinhas, Lisa Craw, Sheng Fan, Daeyeong Kim, Robert Mulvaney, Rilee E. Thomas, and Christina L. Hulbe
The Cryosphere, 16, 3313–3329, https://doi.org/10.5194/tc-16-3313-2022, https://doi.org/10.5194/tc-16-3313-2022, 2022
Short summary
Short summary
Ice crystal alignment in the sheared margins of fast-flowing polar ice is important as it may control the ice sheet flow rate, from land to the ocean. Sampling shear margins is difficult because of logistical and safety considerations. We show that crystal alignments in a glacier shear margin in Antarctica can be measured using sound waves. Results from a seismic experiment on the 50 m scale and from ultrasonic experiments on the decimetre scale match ice crystal measurements from an ice core.
Helene M. Hoffmann, Mackenzie M. Grieman, Amy C. F. King, Jenna A. Epifanio, Kaden Martin, Diana Vladimirova, Helena V. Pryer, Emily Doyle, Axel Schmidt, Jack D. Humby, Isobel F. Rowell, Christoph Nehrbass-Ahles, Elizabeth R. Thomas, Robert Mulvaney, and Eric W. Wolff
Clim. Past, 18, 1831–1847, https://doi.org/10.5194/cp-18-1831-2022, https://doi.org/10.5194/cp-18-1831-2022, 2022
Short summary
Short summary
The WACSWAIN project (WArm Climate Stability of the West Antarctic ice sheet in the last INterglacial) investigates the fate of the West Antarctic Ice Sheet during the last warm period on Earth (115 000–130 000 years before present). Within this framework an ice core was recently drilled at Skytrain Ice Rise. In this study we present a stratigraphic chronology of that ice core based on absolute age markers and annual layer counting for the last 2000 years.
Zhuang Jiang, Joel Savarino, Becky Alexander, Joseph Erbland, Jean-Luc Jaffrezo, and Lei Geng
The Cryosphere, 16, 2709–2724, https://doi.org/10.5194/tc-16-2709-2022, https://doi.org/10.5194/tc-16-2709-2022, 2022
Short summary
Short summary
A record of year-round atmospheric nitrate isotopic composition along with snow nitrate isotopic data from Summit, Greenland, revealed apparent enrichments in nitrogen isotopes in snow nitrate compared to atmospheric nitrate, in addition to a relatively smaller degree of changes in oxygen isotopes. The results suggest that at this site post-depositional processing takes effect, which should be taken into account when interpreting ice-core nitrate isotope records.
David N. Wagner, Matthew D. Shupe, Christopher Cox, Ola G. Persson, Taneil Uttal, Markus M. Frey, Amélie Kirchgaessner, Martin Schneebeli, Matthias Jaggi, Amy R. Macfarlane, Polona Itkin, Stefanie Arndt, Stefan Hendricks, Daniela Krampe, Marcel Nicolaus, Robert Ricker, Julia Regnery, Nikolai Kolabutin, Egor Shimanshuck, Marc Oggier, Ian Raphael, Julienne Stroeve, and Michael Lehning
The Cryosphere, 16, 2373–2402, https://doi.org/10.5194/tc-16-2373-2022, https://doi.org/10.5194/tc-16-2373-2022, 2022
Short summary
Short summary
Based on measurements of the snow cover over sea ice and atmospheric measurements, we estimate snowfall and snow accumulation for the MOSAiC ice floe, between November 2019 and May 2020. For this period, we estimate 98–114 mm of precipitation. We suggest that about 34 mm of snow water equivalent accumulated until the end of April 2020 and that at least about 50 % of the precipitated snow was eroded or sublimated. Further, we suggest explanations for potential snowfall overestimation.
M. Reza Ershadi, Reinhard Drews, Carlos Martín, Olaf Eisen, Catherine Ritz, Hugh Corr, Julia Christmann, Ole Zeising, Angelika Humbert, and Robert Mulvaney
The Cryosphere, 16, 1719–1739, https://doi.org/10.5194/tc-16-1719-2022, https://doi.org/10.5194/tc-16-1719-2022, 2022
Short summary
Short summary
Radio waves transmitted through ice split up and inform us about the ice sheet interior and orientation of single ice crystals. This can be used to infer how ice flows and improve projections on how it will evolve in the future. Here we used an inverse approach and developed a new algorithm to infer ice properties from observed radar data. We applied this technique to the radar data obtained at two EPICA drilling sites, where ice cores were used to validate our results.
Saehee Lim, Meehye Lee, Joel Savarino, and Paolo Laj
Atmos. Chem. Phys., 22, 5099–5115, https://doi.org/10.5194/acp-22-5099-2022, https://doi.org/10.5194/acp-22-5099-2022, 2022
Short summary
Short summary
We determined δ15N(NO3−) and Δ17O(NO3−) of PM2.5 in Seoul during 2018–2019 and estimated quantitatively the contribution of oxidation pathways to NO3− formation and NOx emission sources. The nighttime pathway played a significant role in NO3− formation during the winter, and its contribution further increased up to 70 % on haze days when PM2.5 was greater than 75 µg m−3. Vehicle emissions were confirmed as a main NO3− source with an increasing contribution from coal combustion in winter.
Tobias Erhardt, Matthias Bigler, Urs Federer, Gideon Gfeller, Daiana Leuenberger, Olivia Stowasser, Regine Röthlisberger, Simon Schüpbach, Urs Ruth, Birthe Twarloh, Anna Wegner, Kumiko Goto-Azuma, Takayuki Kuramoto, Helle A. Kjær, Paul T. Vallelonga, Marie-Louise Siggaard-Andersen, Margareta E. Hansson, Ailsa K. Benton, Louise G. Fleet, Rob Mulvaney, Elizabeth R. Thomas, Nerilie Abram, Thomas F. Stocker, and Hubertus Fischer
Earth Syst. Sci. Data, 14, 1215–1231, https://doi.org/10.5194/essd-14-1215-2022, https://doi.org/10.5194/essd-14-1215-2022, 2022
Short summary
Short summary
The datasets presented alongside this manuscript contain high-resolution concentration measurements of chemical impurities in deep ice cores, NGRIP and NEEM, from the Greenland ice sheet. The impurities originate from the deposition of aerosols to the surface of the ice sheet and are influenced by source, transport and deposition processes. Together, these records contain detailed, multi-parameter records of past climate variability over the last glacial period.
Marie G. P. Cavitte, Duncan A. Young, Robert Mulvaney, Catherine Ritz, Jamin S. Greenbaum, Gregory Ng, Scott D. Kempf, Enrica Quartini, Gail R. Muldoon, John Paden, Massimo Frezzotti, Jason L. Roberts, Carly R. Tozer, Dustin M. Schroeder, and Donald D. Blankenship
Earth Syst. Sci. Data, 13, 4759–4777, https://doi.org/10.5194/essd-13-4759-2021, https://doi.org/10.5194/essd-13-4759-2021, 2021
Short summary
Short summary
We present a data set consisting of ice-penetrating-radar internal stratigraphy: 26 internal reflecting horizons that cover the greater Dome C area, East Antarctica, the most extensive IRH data set to date in the region. This data set uses radar surveys collected over the span of 10 years, starting with an airborne international collaboration in 2008 to explore the region, up to the detailed ground-based surveys in support of the European Beyond EPICA – Oldest Ice (BE-OI) project.
Laura Crick, Andrea Burke, William Hutchison, Mika Kohno, Kathryn A. Moore, Joel Savarino, Emily A. Doyle, Sue Mahony, Sepp Kipfstuhl, James W. B. Rae, Robert C. J. Steele, R. Stephen J. Sparks, and Eric W. Wolff
Clim. Past, 17, 2119–2137, https://doi.org/10.5194/cp-17-2119-2021, https://doi.org/10.5194/cp-17-2119-2021, 2021
Short summary
Short summary
The ~ 74 ka eruption of Toba was one of the largest eruptions of the last 100 ka. We have measured the sulfur isotopic composition for 11 Toba eruption candidates in two Antarctic ice cores. Sulfur isotopes allow us to distinguish between large eruptions that have erupted material into the stratosphere and smaller ones that reach lower altitudes. Using this we have identified the events most likely to be Toba and place the eruption on the transition into a cold period in the Northern Hemisphere.
Zhuang Jiang, Becky Alexander, Joel Savarino, Joseph Erbland, and Lei Geng
The Cryosphere, 15, 4207–4220, https://doi.org/10.5194/tc-15-4207-2021, https://doi.org/10.5194/tc-15-4207-2021, 2021
Short summary
Short summary
We used a snow photochemistry model (TRANSITS) to simulate the seasonal nitrate snow profile at Summit, Greenland. Comparisons between model outputs and observations suggest that at Summit post-depositional processing is active and probably dominates the snowpack δ15N seasonality. We also used the model to assess the degree of snow nitrate loss and the consequences in its isotopes at present and in the past, which helps for quantitative interpretations of ice-core nitrate records.
Sarah Albertin, Joël Savarino, Slimane Bekki, Albane Barbero, and Nicolas Caillon
Atmos. Chem. Phys., 21, 10477–10497, https://doi.org/10.5194/acp-21-10477-2021, https://doi.org/10.5194/acp-21-10477-2021, 2021
Short summary
Short summary
We report an efficient method to collect atmospheric NO2 adapted for multi-isotopic analysis and present the first NO2 triple oxygen and double nitrogen isotope measurements. Atmospheric samplings carried out in Grenoble, France, highlight the NO2 isotopic signature sensitivity to the local NOx emissions and chemical regimes. These preliminary results are very promising for using the combination of Δ17O and δ15N of NO2 as a probe of the atmospheric NOx emissions and chemistry.
Max Thomas, Johannes C. Laube, Jan Kaiser, Samuel Allin, Patricia Martinerie, Robert Mulvaney, Anna Ridley, Thomas Röckmann, William T. Sturges, and Emmanuel Witrant
Atmos. Chem. Phys., 21, 6857–6873, https://doi.org/10.5194/acp-21-6857-2021, https://doi.org/10.5194/acp-21-6857-2021, 2021
Short summary
Short summary
CFC gases are destroying the Earth's life-protecting ozone layer. We improve understanding of CFC destruction by measuring the isotopic fingerprint of the carbon in the three most abundant CFCs. These are the first such measurements in the main region where CFCs are destroyed – the stratosphere. We reconstruct the atmospheric isotope histories of these CFCs back to the 1950s by measuring air extracted from deep snow and using a model. The model and the measurements are generally consistent.
David A. Lilien, Daniel Steinhage, Drew Taylor, Frédéric Parrenin, Catherine Ritz, Robert Mulvaney, Carlos Martín, Jie-Bang Yan, Charles O'Neill, Massimo Frezzotti, Heinrich Miller, Prasad Gogineni, Dorthe Dahl-Jensen, and Olaf Eisen
The Cryosphere, 15, 1881–1888, https://doi.org/10.5194/tc-15-1881-2021, https://doi.org/10.5194/tc-15-1881-2021, 2021
Short summary
Short summary
We collected radar data between EDC, an ice core spanning ~800 000 years, and BELDC, the site chosen for a new
oldest icecore at nearby Little Dome C. These data allow us to identify 50 % older internal horizons than previously traced in the area. We fit a model to the ages of those horizons at BELDC to determine the age of deep ice there. We find that there is likely to be 1.5 Myr old ice ~265 m above the bed, with sufficient resolution to preserve desired climatic information.
Abhijith U. Venugopal, Nancy A. N. Bertler, Rebecca L. Pyne, Helle A. Kjær, V. Holly L. Winton, Paul A. Mayewski, and Giuseppe Cortese
Clim. Past Discuss., https://doi.org/10.5194/cp-2020-151, https://doi.org/10.5194/cp-2020-151, 2020
Manuscript not accepted for further review
Short summary
Short summary
We present a new and highly resolved glacial record of nitrate and calcium from a deep ice core obtained from Roosevelt Island, West Antarctica. Our data show a dependent association among nitrate and non-sea salt calcium (mineral dust) as observed previously in East Antarctica. The spatial pattern indicates that mineral dust is scavenging nitrate from the atmosphere and the westerlies are dispersing the dust-bound nitrate across Antarctica, making nitrate a potential paleo-westerly wind proxy.
Anders Svensson, Dorthe Dahl-Jensen, Jørgen Peder Steffensen, Thomas Blunier, Sune O. Rasmussen, Bo M. Vinther, Paul Vallelonga, Emilie Capron, Vasileios Gkinis, Eliza Cook, Helle Astrid Kjær, Raimund Muscheler, Sepp Kipfstuhl, Frank Wilhelms, Thomas F. Stocker, Hubertus Fischer, Florian Adolphi, Tobias Erhardt, Michael Sigl, Amaelle Landais, Frédéric Parrenin, Christo Buizert, Joseph R. McConnell, Mirko Severi, Robert Mulvaney, and Matthias Bigler
Clim. Past, 16, 1565–1580, https://doi.org/10.5194/cp-16-1565-2020, https://doi.org/10.5194/cp-16-1565-2020, 2020
Short summary
Short summary
We identify signatures of large bipolar volcanic eruptions in Greenland and Antarctic ice cores during the last glacial period, which allows for a precise temporal alignment of the ice cores. Thereby the exact timing of unexplained, abrupt climatic changes occurring during the last glacial period can be determined in a global context. The study thus provides a step towards a full understanding of elements of the climate system that may also play an important role in the future.
Albane Barbero, Camille Blouzon, Joël Savarino, Nicolas Caillon, Aurélien Dommergue, and Roberto Grilli
Atmos. Meas. Tech., 13, 4317–4331, https://doi.org/10.5194/amt-13-4317-2020, https://doi.org/10.5194/amt-13-4317-2020, 2020
Short summary
Short summary
In this paper, we present a compact, affordable and robust instrument for in situ measurements of different trace gases: NOx, IO, CHOCHO and O3 with very low detection limits. The device weighs 15 kg and has a total electrical power consumption of < 300 W. Its very low detection limits and its design make it suitable for field applications to address different questions such as how to better constrain the oxidative capacity of the atmosphere and study the chemistry of highly reactive species.
V. Holly L. Winton, Alison Ming, Nicolas Caillon, Lisa Hauge, Anna E. Jones, Joel Savarino, Xin Yang, and Markus M. Frey
Atmos. Chem. Phys., 20, 5861–5885, https://doi.org/10.5194/acp-20-5861-2020, https://doi.org/10.5194/acp-20-5861-2020, 2020
Short summary
Short summary
The transfer of the nitrogen stable isotopic composition in nitrate between the air and snow at low accumulation sites in Antarctica leaves an UV imprint in the snow. Quantifying how nitrate isotope values change allows us to interpret longer ice core records. Based on nitrate observations and modelling at Kohnen, East Antarctica, the dominant factors controlling the nitrate isotope signature in deep snow layers are the depth of light penetration into the snowpack and the snow accumulation rate.
Pascal Bohleber, Mathieu Casado, Kirsti Ashworth, Chelsey A. Baker, Anna Belcher, Jilda Alicia Caccavo, Holly E. Jenkins, Erin Satterthwaite, Andrea Spolaor, and V. Holly L. Winton
Adv. Geosci., 53, 1–14, https://doi.org/10.5194/adgeo-53-1-2020, https://doi.org/10.5194/adgeo-53-1-2020, 2020
Short summary
Short summary
International Early Career Networks (ECN) are global voluntary communities of Early Career Scientists (ECS) aiming to advance the careers of ECS and to improve their inclusion into the international scientific community. We use member surveys alongside with case studies from well-established and long-term networks to elucidate the attributes that make a successful, sustainable ECN, and propose best practices for developing ECN successfully.
Markus M. Frey, Sarah J. Norris, Ian M. Brooks, Philip S. Anderson, Kouichi Nishimura, Xin Yang, Anna E. Jones, Michelle G. Nerentorp Mastromonaco, David H. Jones, and Eric W. Wolff
Atmos. Chem. Phys., 20, 2549–2578, https://doi.org/10.5194/acp-20-2549-2020, https://doi.org/10.5194/acp-20-2549-2020, 2020
Short summary
Short summary
A winter sea ice expedition to Antarctica provided the first direct observations of sea salt aerosol (SSA) production during snow storms above sea ice, thereby validating a model hypothesis to account for winter time SSA maxima in Antarctica not explained otherwise. Defining SSA sources is important given the critical roles that aerosol plays for climate, for air quality and as a potential ice core proxy for sea ice conditions in the past.
Detlev Helmig, Daniel Liptzin, Jacques Hueber, and Joel Savarino
The Cryosphere, 14, 199–209, https://doi.org/10.5194/tc-14-199-2020, https://doi.org/10.5194/tc-14-199-2020, 2020
Short summary
Short summary
We present 15 months of trace gas observations from air withdrawn within the snowpack and from above the snow at Concordia Station in Antarctica. The data show occasional positive spikes, indicative of pollution from the station generator. The pollution signal can be seen in snowpack air shortly after it is observed above the snow surface, and lasting for up to several days, much longer than above the surface.
Kévin Fourteau, Patricia Martinerie, Xavier Faïn, Christoph F. Schaller, Rebecca J. Tuckwell, Henning Löwe, Laurent Arnaud, Olivier Magand, Elizabeth R. Thomas, Johannes Freitag, Robert Mulvaney, Martin Schneebeli, and Vladimir Ya. Lipenkov
The Cryosphere, 13, 3383–3403, https://doi.org/10.5194/tc-13-3383-2019, https://doi.org/10.5194/tc-13-3383-2019, 2019
Short summary
Short summary
Understanding gas trapping in polar ice is essential to study the relationship between greenhouse gases and past climates. New data of bubble closure, used in a simple gas-trapping model, show inconsistency with the final air content in ice. This suggests gas trapping is not fully understood. We also use a combination of high-resolution measurements to investigate the effect of polar snow stratification on gas trapping and find that all strata have similar pores, but that some close in advance.
Xin Yang, Markus M. Frey, Rachael H. Rhodes, Sarah J. Norris, Ian M. Brooks, Philip S. Anderson, Kouichi Nishimura, Anna E. Jones, and Eric W. Wolff
Atmos. Chem. Phys., 19, 8407–8424, https://doi.org/10.5194/acp-19-8407-2019, https://doi.org/10.5194/acp-19-8407-2019, 2019
Short summary
Short summary
This is a comprehensive model–data comparison aiming to evaluate the proposed mechanism of sea salt aerosol (SSA) production from blowing snow on sea ice. Some key parameters such as snow salinity and blowing-snow size distribution were constrained by data collected in the Weddell Sea. The good agreement between modelled SSA and the cruise data strongly indicates that sea ice surface is a large SSA source in polar regions, a process which has not been considered in current climate models.
Tommaso Galeazzo, Slimane Bekki, Erwan Martin, Joël Savarino, and Stephen R. Arnold
Atmos. Chem. Phys., 18, 17909–17931, https://doi.org/10.5194/acp-18-17909-2018, https://doi.org/10.5194/acp-18-17909-2018, 2018
Short summary
Short summary
Volcanic sulfur can have climatic impacts for the planet via sulfate aerosol formation, leading also to pollution events. We provide model constraints on tropospheric volcanic sulfate formation, with implications for its lifetime and impacts on regional air quality. Oxygen isotope investigations from our model suggest that in the poor tropospheric plumes of halogens, the O2/TMI sulfur oxidation pathway might significantly control sulfate production. The produced sulfate has no isotopic anomaly.
Shaojie Song, Hélène Angot, Noelle E. Selin, Hubert Gallée, Francesca Sprovieri, Nicola Pirrone, Detlev Helmig, Joël Savarino, Olivier Magand, and Aurélien Dommergue
Atmos. Chem. Phys., 18, 15825–15840, https://doi.org/10.5194/acp-18-15825-2018, https://doi.org/10.5194/acp-18-15825-2018, 2018
Short summary
Short summary
Mercury is a trace metal with adverse health effects on human and wildlife. Its unique property makes it undergo long-range transport, and even remote Antarctica receives significant inputs. This paper presents the first model that aims to understand mercury behavior over the Antarctic Plateau. We find that mercury is quickly cycled between snow and air in the sunlit period, likely driven by bromine chemistry, and that several uncertain processes contribute to its behavior in the dark period.
Emmanuel Le Meur, Olivier Magand, Laurent Arnaud, Michel Fily, Massimo Frezzotti, Marie Cavitte, Robert Mulvaney, and Stefano Urbini
The Cryosphere, 12, 1831–1850, https://doi.org/10.5194/tc-12-1831-2018, https://doi.org/10.5194/tc-12-1831-2018, 2018
Short summary
Short summary
This paper presents surface mass balance measurements from both GPR and ice core data collected during a traverse in a so-far-unexplored area between the DC and Vostok stations. Results presented here will contribute to a better knowledge of the global mass balance of the Antarctic ice sheet and thus help in constraining its contribution to sea level rise. Another novelty of the paper resides in the comprehensive error budget proposed for the method used for inferring accumulation rates.
Carmen Paulina Vega, Elisabeth Isaksson, Elisabeth Schlosser, Dmitry Divine, Tõnu Martma, Robert Mulvaney, Anja Eichler, and Margit Schwikowski-Gigar
The Cryosphere, 12, 1681–1697, https://doi.org/10.5194/tc-12-1681-2018, https://doi.org/10.5194/tc-12-1681-2018, 2018
Short summary
Short summary
Ions were measured in firn and ice cores from Fimbul Ice Shelf, Antarctica, to evaluate sea-salt loads. A significant sixfold increase in sea salts was found in the S100 core after 1950s which suggests that it contains a more local sea-salt signal, dominated by processes during sea-ice formation in the neighbouring waters. In contrast, firn cores from three ice rises register the larger-scale signal of atmospheric flow conditions and transport of sea-salt aerosols produced over open water.
Nancy A. N. Bertler, Howard Conway, Dorthe Dahl-Jensen, Daniel B. Emanuelsson, Mai Winstrup, Paul T. Vallelonga, James E. Lee, Ed J. Brook, Jeffrey P. Severinghaus, Taylor J. Fudge, Elizabeth D. Keller, W. Troy Baisden, Richard C. A. Hindmarsh, Peter D. Neff, Thomas Blunier, Ross Edwards, Paul A. Mayewski, Sepp Kipfstuhl, Christo Buizert, Silvia Canessa, Ruzica Dadic, Helle A. Kjær, Andrei Kurbatov, Dongqi Zhang, Edwin D. Waddington, Giovanni Baccolo, Thomas Beers, Hannah J. Brightley, Lionel Carter, David Clemens-Sewall, Viorela G. Ciobanu, Barbara Delmonte, Lukas Eling, Aja Ellis, Shruthi Ganesh, Nicholas R. Golledge, Skylar Haines, Michael Handley, Robert L. Hawley, Chad M. Hogan, Katelyn M. Johnson, Elena Korotkikh, Daniel P. Lowry, Darcy Mandeno, Robert M. McKay, James A. Menking, Timothy R. Naish, Caroline Noerling, Agathe Ollive, Anaïs Orsi, Bernadette C. Proemse, Alexander R. Pyne, Rebecca L. Pyne, James Renwick, Reed P. Scherer, Stefanie Semper, Marius Simonsen, Sharon B. Sneed, Eric J. Steig, Andrea Tuohy, Abhijith Ulayottil Venugopal, Fernando Valero-Delgado, Janani Venkatesh, Feitang Wang, Shimeng Wang, Dominic A. Winski, V. Holly L. Winton, Arran Whiteford, Cunde Xiao, Jiao Yang, and Xin Zhang
Clim. Past, 14, 193–214, https://doi.org/10.5194/cp-14-193-2018, https://doi.org/10.5194/cp-14-193-2018, 2018
Short summary
Short summary
Temperature and snow accumulation records from the annually dated Roosevelt Island Climate Evolution (RICE) ice core show that for the past 2 700 years, the eastern Ross Sea warmed, while the western Ross Sea showed no trend and West Antarctica cooled. From the 17th century onwards, this dipole relationship changed. Now all three regions show concurrent warming, with snow accumulation declining in West Antarctica and the eastern Ross Sea.
Hoi Ga Chan, Markus M. Frey, and Martin D. King
Atmos. Chem. Phys., 18, 1507–1534, https://doi.org/10.5194/acp-18-1507-2018, https://doi.org/10.5194/acp-18-1507-2018, 2018
Short summary
Short summary
Emissions of reactive nitrogen from snowpacks influence remote air quality. Two physical air–snow models for nitrate were developed. One assumes that below a threshold temperature the air–snow grain interface is pure ice and above it a disordered interface emerges. The other assumes an air–ice interface below melting and that any liquid present is concentrated in micropockets. Only the latter matches observations at two Antarctic lcoations covering a wide range of environmental conditions.
Marc D. Mallet, Maximilien J. Desservettaz, Branka Miljevic, Andelija Milic, Zoran D. Ristovski, Joel Alroe, Luke T. Cravigan, E. Rohan Jayaratne, Clare Paton-Walsh, David W. T. Griffith, Stephen R. Wilson, Graham Kettlewell, Marcel V. van der Schoot, Paul Selleck, Fabienne Reisen, Sarah J. Lawson, Jason Ward, James Harnwell, Min Cheng, Rob W. Gillett, Suzie B. Molloy, Dean Howard, Peter F. Nelson, Anthony L. Morrison, Grant C. Edwards, Alastair G. Williams, Scott D. Chambers, Sylvester Werczynski, Leah R. Williams, V. Holly L. Winton, Brad Atkinson, Xianyu Wang, and Melita D. Keywood
Atmos. Chem. Phys., 17, 13681–13697, https://doi.org/10.5194/acp-17-13681-2017, https://doi.org/10.5194/acp-17-13681-2017, 2017
Short summary
Short summary
Fires play an important role within atmosphere. Gaseous and aerosol emissions influence Earth's temperature but these emissions can vary drastically across region and season. The SAFIRED (Savannah Fires in the Early Dry Season) campaign was undertaken at the Australian Tropical Research Station in north Australia during the 2014 early dry season. This paper presents an overview of the fires in this region, the measurements of their emissions and the implications of these fires on the atmosphere.
Rachael H. Rhodes, Xin Yang, Eric W. Wolff, Joseph R. McConnell, and Markus M. Frey
Atmos. Chem. Phys., 17, 9417–9433, https://doi.org/10.5194/acp-17-9417-2017, https://doi.org/10.5194/acp-17-9417-2017, 2017
Short summary
Short summary
Sea salt aerosol comes from the open ocean or the sea ice surface. In the polar regions, this opens up the possibility of reconstructing sea ice history using sea salt recorded in ice cores. We use a chemical transport model to demonstrate that the sea ice source of aerosol is important in the Arctic. For the first time, we simulate realistic Greenland ice core sea salt in a process-based model. The importance of the sea ice source increases from south to north across the Greenland ice sheet.
Sakiko Ishino, Shohei Hattori, Joel Savarino, Bruno Jourdain, Susanne Preunkert, Michel Legrand, Nicolas Caillon, Albane Barbero, Kota Kuribayashi, and Naohiro Yoshida
Atmos. Chem. Phys., 17, 3713–3727, https://doi.org/10.5194/acp-17-3713-2017, https://doi.org/10.5194/acp-17-3713-2017, 2017
Short summary
Short summary
We show the first simultaneous observations of triple oxygen isotopic compositions of atmospheric sulfate, nitrate, and ozone at Dumont d'Urville, coastal Antarctica. The contrasting seasonal trends between oxygen isotopes of ozone and those of sulfate and nitrate indicate that these signatures in sulfate and nitrate are mainly controlled by changes in oxidation chemistry. We also discuss the specific oxidation chemistry induced by the unique phenomena at the site.
V. Holly L. Winton, Ross Edwards, Andrew R. Bowie, Melita Keywood, Alistair G. Williams, Scott D. Chambers, Paul W. Selleck, Maximilien Desservettaz, Marc D. Mallet, and Clare Paton-Walsh
Atmos. Chem. Phys., 16, 12829–12848, https://doi.org/10.5194/acp-16-12829-2016, https://doi.org/10.5194/acp-16-12829-2016, 2016
Short summary
Short summary
The deposition of soluble aerosol iron (Fe) can initiate nitrogen fixation and trigger toxic algal blooms in nitrate-poor tropical waters. We present dry season soluble Fe data from northern Australia that reflect coincident dust and biomass burning sources of soluble Fe. Our results show that while biomass burning species are not a direct source of soluble Fe, biomass burning may substantially enhance the solubility of mineral dust with fractional Fe solubility up to 12 % in mixed aerosols.
Josué Bock, Joël Savarino, and Ghislain Picard
Atmos. Chem. Phys., 16, 12531–12550, https://doi.org/10.5194/acp-16-12531-2016, https://doi.org/10.5194/acp-16-12531-2016, 2016
Short summary
Short summary
We develop a physically based parameterisation of the co-condensation process. Our model includes solid-state diffusion within a snow grain. It reproduces with good agreement the nitrate measurement in surface snow. Winter and summer concentrations are driven respectively by thermodynamic equilibrium and co-condensation. Adsorbed nitrate likely accounts for a minor part. This work shows that co-condensation is required to explain the chemical composition of snow undergoing temperature gradient.
Michel Legrand, Susanne Preunkert, Joël Savarino, Markus M. Frey, Alexandre Kukui, Detlev Helmig, Bruno Jourdain, Anna E. Jones, Rolf Weller, Neil Brough, and Hubert Gallée
Atmos. Chem. Phys., 16, 8053–8069, https://doi.org/10.5194/acp-16-8053-2016, https://doi.org/10.5194/acp-16-8053-2016, 2016
Short summary
Short summary
Surface ozone, the most abundant atmospheric oxidant, has been measured since 2004 at the coastal East Antarctic site of Dumont d’Urville, and since 2007 at the Concordia station located on the high East Antarctic plateau. Long-term changes, seasonal and diurnal cycles, as well as inter-annual summer variability observed at these two East Antarctic sites are discussed. Influences like sea ice extent and outflow from inland Antarctica are discussed.
Alexandra Touzeau, Amaëlle Landais, Barbara Stenni, Ryu Uemura, Kotaro Fukui, Shuji Fujita, Sarah Guilbaud, Alexey Ekaykin, Mathieu Casado, Eugeni Barkan, Boaz Luz, Olivier Magand, Grégory Teste, Emmanuel Le Meur, Mélanie Baroni, Joël Savarino, Ilann Bourgeois, and Camille Risi
The Cryosphere, 10, 837–852, https://doi.org/10.5194/tc-10-837-2016, https://doi.org/10.5194/tc-10-837-2016, 2016
Short summary
Short summary
The relationship between water isotope ratios and temperature is investigated in precipitation snow at Vostok and Dome C, as well as in surface snow along traverses. The temporal slope of the linear regression for the precipitation is smaller than the geographical slope. Thus, using the latter could lead to an underestimation of past temperature changes. The processes active at remote sites (best glacial analogs) are explored through a combination of water isotopes in short snow pits.
Holly Winton, Andrew Bowie, Melita Keywood, Pier van der Merwe, and Ross Edwards
Atmos. Meas. Tech. Discuss., https://doi.org/10.5194/amt-2016-12, https://doi.org/10.5194/amt-2016-12, 2016
Revised manuscript not accepted
Short summary
Short summary
Aerosols containing iron have been investigated over the remote Southern Ocean to constrain iron budgets in surface waters and related biological production. Protocols for the sampling of ambient air were used to assess the suitability of high-volume aerosol samplers for aerosol iron studies in pristine air masses. Significant evidence of airborne insect and local soil contamination was detected in exposure blank filters. Suggestions for future aerosol iron sampling in clean air are provided.
Joël Savarino, William C. Vicars, Michel Legrand, Suzanne Preunkert, Bruno Jourdain, Markus M. Frey, Alexandre Kukui, Nicolas Caillon, and Jaime Gil Roca
Atmos. Chem. Phys., 16, 2659–2673, https://doi.org/10.5194/acp-16-2659-2016, https://doi.org/10.5194/acp-16-2659-2016, 2016
Short summary
Short summary
Atmospheric nitrate is collected on the East Antarctic ice sheet. Nitrogen and oxygen stable isotopes and concentrations of nitrate are measured. Using a box model, we show that there is s systematic discrepancy between observations and model results. We suggest that this discrepancy probably results from unknown NOx chemistry above the Antarctic ice sheet. However, possible misconception in the stable isotope mass balance is not completely excluded.
E. Gautier, J. Savarino, J. Erbland, A. Lanciki, and P. Possenti
Clim. Past, 12, 103–113, https://doi.org/10.5194/cp-12-103-2016, https://doi.org/10.5194/cp-12-103-2016, 2016
Short summary
Short summary
We evaluate the local-scale variability of a sulfate profile at a low-accumulation site (Dome C, Antarctica) to assess the representativeness of one ice core for volcanic reconstructions. Peak statistical occurrence, depth and flux variability are evaluated from five cores. Due to local-scale variability, 64 volcanic peaks can be identified by a five-cores analysis, while only half of them can be assessed from two cores. Using five cores, the uncertainty of the mean flux is reduced to 29 %.
J. Erbland, J. Savarino, S. Morin, J. L. France, M. M. Frey, and M. D. King
Atmos. Chem. Phys., 15, 12079–12113, https://doi.org/10.5194/acp-15-12079-2015, https://doi.org/10.5194/acp-15-12079-2015, 2015
Short summary
Short summary
In this paper, we describe the development of a numerical model which aims at representing nitrate recycling at the air-snow interface on the East Antarctic Plateau. Stable isotopes are used as diagnostic and evaluation tools by comparing the model's results to recent field measurements of nitrate and key atmospheric species at Dome C, Antarctica. From sensitivity tests conducted with the model, we propose a framework for the interpretation of the nitrate isotope record in deep ice cores.
T. A. Berhanu, J. Savarino, J. Erbland, W. C. Vicars, S. Preunkert, J. F. Martins, and M. S. Johnson
Atmos. Chem. Phys., 15, 11243–11256, https://doi.org/10.5194/acp-15-11243-2015, https://doi.org/10.5194/acp-15-11243-2015, 2015
Short summary
Short summary
In this field study at Dome C, Antarctica, we investigated the effect of solar UV photolysis on the stable isotopes of nitrate in snow via comparison of two identical snow pits while exposing only one to solar UV. From the difference between the average isotopic fractionations calculated for each pit, we determined a purely photolytic nitrogen isotopic fractionation of -55.8‰, in good agreement with what has been recently determined in a laboratory study.
M. M. Frey, H. K. Roscoe, A. Kukui, J. Savarino, J. L. France, M. D. King, M. Legrand, and S. Preunkert
Atmos. Chem. Phys., 15, 7859–7875, https://doi.org/10.5194/acp-15-7859-2015, https://doi.org/10.5194/acp-15-7859-2015, 2015
Short summary
Short summary
Surprisingly large concentrations and flux of atmospheric nitrogen oxides were measured at Dome C, East Antarctica. It was found that the surface snow holds a significant reservoir of photochemically produced NOx and is a sink of gas-phase ozone. Main drivers of NOx snow emissions were large snow nitrate concentrations, with contributions of increased UV from decreases in stratospheric ozone. Observed halogen and hydroxyl radical concentrations were too low to explain large NO2:NO ratios.
H. G. Chan, M. D. King, and M. M. Frey
Atmos. Chem. Phys., 15, 7913–7927, https://doi.org/10.5194/acp-15-7913-2015, https://doi.org/10.5194/acp-15-7913-2015, 2015
S. Preunkert, M. Legrand, M. M. Frey, A. Kukui, J. Savarino, H. Gallée, M. King, B. Jourdain, W. Vicars, and D. Helmig
Atmos. Chem. Phys., 15, 6689–6705, https://doi.org/10.5194/acp-15-6689-2015, https://doi.org/10.5194/acp-15-6689-2015, 2015
Short summary
Short summary
During two austral summers HCHO was investigated in air, snow, and interstitial air at the Concordia site located on the East Antarctic Plateau. Snow emission fluxes were estimated to be around 1 to 2 and 3 to 5 x 10^12 molecules m-2 s-1 at night and at noon, respectively. Shading experiments suggest that the photochemical HCHO production in the snowpack at Concordia remains negligible. The mean HCHO level of 130pptv observed at 1m above the surface is quite well reproduced by 1-D simulations.
H. Gallée, S. Preunkert, S. Argentini, M. M. Frey, C. Genthon, B. Jourdain, I. Pietroni, G. Casasanta, H. Barral, E. Vignon, C. Amory, and M. Legrand
Atmos. Chem. Phys., 15, 6225–6236, https://doi.org/10.5194/acp-15-6225-2015, https://doi.org/10.5194/acp-15-6225-2015, 2015
Short summary
Short summary
Regional climate model MAR was run for the region of Dome C located on the East Antarctic plateau, during summer 2011–2012, with a high vertical resolution in the lower troposphere. MAR is generally in very good agreement with the observations and provides sufficiently reliable information about surface turbulent fluxes and vertical profiles of vertical diffusion coefficients when discussing the representativeness of chemical measurements made nearby the ground surface at Dome C.
L. Geng, J. Cole-Dai, B. Alexander, J. Erbland, J. Savarino, A. J. Schauer, E. J. Steig, P. Lin, Q. Fu, and M. C. Zatko
Atmos. Chem. Phys., 14, 13361–13376, https://doi.org/10.5194/acp-14-13361-2014, https://doi.org/10.5194/acp-14-13361-2014, 2014
Short summary
Short summary
Examinations on snowpit and firn core results from Summit, Greenland suggest that there are two mechanisms leading to the observed double nitrate peaks in some years in the industrial era: 1) long-rang transport of nitrate and 2) enhanced local photochemical production of nitrate. Both of these mechanisms are related to pollution transport, as the additional nitrate from either direct transport or enhanced local photochemistry requires enhanced nitrogen sources from anthropogenic emissions.
A. Kukui, M. Legrand, S. Preunkert, M. M. Frey, R. Loisil, J. Gil Roca, B. Jourdain, M. D. King, J. L. France, and G. Ancellet
Atmos. Chem. Phys., 14, 12373–12392, https://doi.org/10.5194/acp-14-12373-2014, https://doi.org/10.5194/acp-14-12373-2014, 2014
Short summary
Short summary
Concentrations of OH radicals and the sum of peroxy radicals, RO2, were measured in the boundary layer for the first time on the East Antarctic Plateau at the Concordia Station during the austral summer 2011/2012. The concentrations of radicals were comparable to those observed at the South Pole, confirming that the elevated oxidative capacity of the Antarctic atmospheric boundary layer found at the South Pole is not restricted to the South Pole but common over the high Antarctic plateau.
M. Legrand, S. Preunkert, M. Frey, Th. Bartels-Rausch, A. Kukui, M. D. King, J. Savarino, M. Kerbrat, and B. Jourdain
Atmos. Chem. Phys., 14, 9963–9976, https://doi.org/10.5194/acp-14-9963-2014, https://doi.org/10.5194/acp-14-9963-2014, 2014
J.-C. Gallet, F. Domine, J. Savarino, M. Dumont, and E. Brun
The Cryosphere, 8, 1205–1215, https://doi.org/10.5194/tc-8-1205-2014, https://doi.org/10.5194/tc-8-1205-2014, 2014
S. Masclin, M. M. Frey, W. F. Rogge, and R. C. Bales
Atmos. Chem. Phys., 13, 8857–8877, https://doi.org/10.5194/acp-13-8857-2013, https://doi.org/10.5194/acp-13-8857-2013, 2013
J. Erbland, W. C. Vicars, J. Savarino, S. Morin, M. M. Frey, D. Frosini, E. Vince, and J. M. F. Martins
Atmos. Chem. Phys., 13, 6403–6419, https://doi.org/10.5194/acp-13-6403-2013, https://doi.org/10.5194/acp-13-6403-2013, 2013
M. M. Frey, N. Brough, J. L. France, P. S. Anderson, O. Traulle, M. D. King, A. E. Jones, E. W. Wolff, and J. Savarino
Atmos. Chem. Phys., 13, 3045–3062, https://doi.org/10.5194/acp-13-3045-2013, https://doi.org/10.5194/acp-13-3045-2013, 2013
Related subject area
Subject: Proxy Use-Development-Validation | Archive: Ice Cores | Timescale: Decadal-Seasonal
The first firn core from Peter I Island – capturing climate variability across the Bellingshausen Sea
Climatology of the Mount Brown South ice core site in East Antarctica: implications for the interpretation of a water isotope record
Canadian forest fires, Icelandic volcanoes and increased local dust observed in six shallow Greenland firn cores
Regional validation of the use of diatoms in ice cores from the Antarctic Peninsula as a Southern Hemisphere westerly wind proxy
Seasonal reconstructions coupling ice core data and an isotope-enabled climate model – methodological implications of seasonality, climate modes and selection of proxy data
Climate information preserved in seasonal water isotope at NEEM: relationships with temperature, circulation and sea ice
Sea-ice-related halogen enrichment at Law Dome, coastal East Antarctica
Local artifacts in ice core methane records caused by layered bubble trapping and in situ production: a multi-site investigation
What controls the isotopic composition of Greenland surface snow?
High-resolution records of the beryllium-10 solar activity proxy in ice from Law Dome, East Antarctica: measurement, reproducibility and principal trends
Elizabeth R. Thomas, Dieter Tetzner, Bradley Markle, Joel Pedro, Guisella Gacitúa, Dorothea Elisabeth Moser, and Sarah Jackson
Clim. Past, 20, 2525–2538, https://doi.org/10.5194/cp-20-2525-2024, https://doi.org/10.5194/cp-20-2525-2024, 2024
Short summary
Short summary
The chemical records contained in a 12 m firn (ice) core from Peter I Island, a remote sub-Antarctic island situated in the Pacific sector of the Southern Ocean (the Bellingshausen Sea), capture changes in snowfall and temperature (2002–2017 CE). This data-sparse region has experienced dramatic climate change in recent decades, including sea ice decline and ice loss from adjacent West Antarctic glaciers.
Sarah L. Jackson, Tessa R. Vance, Camilla Crockart, Andrew Moy, Christopher Plummer, and Nerilie J. Abram
Clim. Past, 19, 1653–1675, https://doi.org/10.5194/cp-19-1653-2023, https://doi.org/10.5194/cp-19-1653-2023, 2023
Short summary
Short summary
Ice core records are useful tools for reconstructing past climate. However, ice cores favour recording climate conditions at times when snowfall occurs. Large snowfall events in Antarctica are often associated with warmer-than-usual temperatures. We show that this results in a tendency for the Mount Brown South ice core record to preserve a temperature record biased to the climate conditions that exist during extreme events, rather than a temperature record that reflects the mean annual climate.
Helle Astrid Kjær, Patrick Zens, Samuel Black, Kasper Holst Lund, Anders Svensson, and Paul Vallelonga
Clim. Past, 18, 2211–2230, https://doi.org/10.5194/cp-18-2211-2022, https://doi.org/10.5194/cp-18-2211-2022, 2022
Short summary
Short summary
Six shallow cores from northern Greenland spanning a distance of 426 km were retrieved during a traversal in 2015. We identify several recent acid horizons associated with Icelandic eruptions and eruptions in the Barents Sea region and obtain a robust forest fire proxy associated primarily with Canadian forest fires. We also observe an increase in the large dust particle fluxes that we attribute to an activation of Greenland local sources in recent years (1998–2015).
Dieter R. Tetzner, Elizabeth R. Thomas, Claire S. Allen, and Mackenzie M. Grieman
Clim. Past, 18, 1709–1727, https://doi.org/10.5194/cp-18-1709-2022, https://doi.org/10.5194/cp-18-1709-2022, 2022
Short summary
Short summary
Changes in the Southern Hemisphere westerly winds are drivers of recent environmental changes in West Antarctica. However, our understanding of this relationship is limited by short and sparse observational records. Here we present the first regional wind study based on the novel use of diatoms preserved in Antarctic ice cores. Our results demonstrate that diatom abundance is the optimal record for reconstructing wind strength variability over the Southern Hemisphere westerly wind belt.
Jesper Sjolte, Florian Adolphi, Bo M. Vinther, Raimund Muscheler, Christophe Sturm, Martin Werner, and Gerrit Lohmann
Clim. Past, 16, 1737–1758, https://doi.org/10.5194/cp-16-1737-2020, https://doi.org/10.5194/cp-16-1737-2020, 2020
Short summary
Short summary
In this study we investigate seasonal climate reconstructions produced by matching climate model output to ice core and tree-ring data, and we evaluate the model–data reconstructions against meteorological observations. The reconstructions capture the main patterns of variability in sea level pressure and temperature in summer and winter. The performance of the reconstructions depends on seasonal climate variability itself, and definitions of seasons can be optimized to capture this variability.
Minjie Zheng, Jesper Sjolte, Florian Adolphi, Bo Møllesøe Vinther, Hans Christian Steen-Larsen, Trevor James Popp, and Raimund Muscheler
Clim. Past, 14, 1067–1078, https://doi.org/10.5194/cp-14-1067-2018, https://doi.org/10.5194/cp-14-1067-2018, 2018
Short summary
Short summary
We show the seasonal δ18O data from the NEEM site in northwestern Greenland over the last 150 years. We found that the NEEM summer δ18O signal correlates well with summer temperature in western coastal Greenland, while the NEEM winter δ18O signal correlates well with sea ice concentration in Baffin Bay. In contrast with the winter δ18O data from central/southern Greenland, we find no linkage of NEEM winter δ18O to winter NAO.
Paul Vallelonga, Niccolo Maffezzoli, Andrew D. Moy, Mark A. J. Curran, Tessa R. Vance, Ross Edwards, Gwyn Hughes, Emily Barker, Gunnar Spreen, Alfonso Saiz-Lopez, J. Pablo Corella, Carlos A. Cuevas, and Andrea Spolaor
Clim. Past, 13, 171–184, https://doi.org/10.5194/cp-13-171-2017, https://doi.org/10.5194/cp-13-171-2017, 2017
Short summary
Short summary
We present a study of bromine, iodine and sodium in an ice core from Law Dome, in coastal East Antarctica. We find that bromine and iodine variability at Law Dome is correlated to changes in the area of sea ice along the Law Dome coast as observed by satellite since the early 1970s. These findings are in agreement with a previous study based on MSA and confirm a long-term trend of sea ice decrease for this sector of Antarctica over the 20th century.
Rachael H. Rhodes, Xavier Faïn, Edward J. Brook, Joseph R. McConnell, Olivia J. Maselli, Michael Sigl, Jon Edwards, Christo Buizert, Thomas Blunier, Jérôme Chappellaz, and Johannes Freitag
Clim. Past, 12, 1061–1077, https://doi.org/10.5194/cp-12-1061-2016, https://doi.org/10.5194/cp-12-1061-2016, 2016
Short summary
Short summary
Local artifacts in ice core methane data are superimposed on consistent records of past atmospheric variability. These artifacts are not related to past atmospheric history and care should be taken to avoid interpreting them as such. By investigating five polar ice cores from sites with different conditions, we relate isolated methane spikes to melt layers and decimetre-scale variations as "trapping signal" associated with a difference in timing of air bubble closure in adjacent firn layers.
H. C. Steen-Larsen, V. Masson-Delmotte, M. Hirabayashi, R. Winkler, K. Satow, F. Prié, N. Bayou, E. Brun, K. M. Cuffey, D. Dahl-Jensen, M. Dumont, M. Guillevic, S. Kipfstuhl, A. Landais, T. Popp, C. Risi, K. Steffen, B. Stenni, and A. E. Sveinbjörnsdottír
Clim. Past, 10, 377–392, https://doi.org/10.5194/cp-10-377-2014, https://doi.org/10.5194/cp-10-377-2014, 2014
J. B. Pedro, A. M. Smith, K. J. Simon, T. D. van Ommen, and M. A. J. Curran
Clim. Past, 7, 707–721, https://doi.org/10.5194/cp-7-707-2011, https://doi.org/10.5194/cp-7-707-2011, 2011
Cited articles
Abram, N. J., Mulvaney, R., Wolff, E. W., and Mudelsee, M.: Ice core records as sea ice proxies: An evaluation from the Weddell Sea region of Antarctica, J. Geophys. Res., 112, D15101, https://doi.org/10.1029/2006jd008139, 2007.
Abram, N. J., Thomas, E. R., McConnell, J. R., Mulvaney, R., Bracegirdle, T. J., Sime, L. C., and Aristarain, A. J.: Ice core evidence for a 20th century decline of sea ice in the Bellingshausen Sea, Antarctica, J. Geophys. Res.-Atmos., 115, D23101, https://doi.org/10.1029/2010JD014644, 2010.
Abram, N. J., Mulvaney, R., and Arrowsmith, C.: Environmental signals in a highly resolved ice core from James Ross Island, Antarctica, J. Geophys. Res.-Atmos., 116, D20116, https://doi.org/10.1029/2011JD016147, 2011.
Abram, N. J., Wolff, E. W., and Curran, M. A.: A review of sea ice proxy information from polar ice cores, Quaternary Sci. Rev., 79, 168–183, 2013.
Akers, P. D., Savarino, J., Caillon, N., Servettaz, A. P., Le Meur, E., Magand, O., Martins, J., Agosta, C., Crockford, P., and Kobayashi, K.: Sunlight-driven nitrate loss records Antarctic surface mass balance, Nat. Commun., 13, 4274, https://doi.org/10.1038/s41467-022-31855-7, 2022.
Berhanu, T. A., Meusinger, C., Erbland, J., Jost, R., Bhattacharya, S., Johnson, M. S., and Savarino, J.: Laboratory study of nitrate photolysis in Antarctic snow. II. Isotopic effects and wavelength dependence, J. Chem. Phys., 140, 244306, https://doi.org/10.1063/1.4882899, 2014.
Beyersdorf, A. J., Blake, D. R., Swanson, A., Meinardi, S., Rowland, F., and Davis, D.: Abundances and variability of tropospheric volatile organic compounds at the South Pole and other Antarctic locations, Atmos. Environ., 44, 4565–4574, 2010.
Bodeker, G. E., Nitzbon, J., Tradowsky, J. S., Kremser, S., Schwertheim, A., and Lewis, J.: A global total column ozone climate data record, Earth Syst. Sci. Data, 13, 3885–3906, https://doi.org/10.5194/essd-13-3885-2021, 2021.
Brean, J., Dall'Osto, M., Simó, R., Shi, Z., Beddows, D. C. S., and Harrison, R. M.: Open ocean and coastal new particle formation from sulfuric acid and amines around the Antarctic Peninsula, Nat. Geosci., 14, 383–388, https://doi.org/10.1038/s41561-021-00751-y, 2021.
Brönnimann, S., Staehelin, J., Farmer, S., Cain, J., Svendby, T., and Svenøe, T.: Total ozone observations prior to the IGY. I: A history, Q. J. Roy. Meteorol. Soc., 129, 2797–2817, 2003.
Burger, J. M., Granger, J., Joyce, E., Hastings, M. G., Spence, K. A. M., and Altieri, K. E.: The importance of alkyl nitrates and sea ice emissions to atmospheric NOx sources and cycling in the summertime Southern Ocean marine boundary layer, Atmos. Chem. Phys., 22, 1081–1096, https://doi.org/10.5194/acp-22-1081-2022, 2022.
Burger, J. M., Joyce, E., Hastings, M. G., Spence, K. A. M., and Altieri, K. E.: A seasonal analysis of aerosol NO3− sources and NOx oxidation pathways in the Southern Ocean marine boundary layer, Atmos. Chem. Phys., 23, 5605–5622, https://doi.org/10.5194/acp-23-5605-2023, 2023.
Cao, Y., Jiang, Z., Alexander, B., Cole-Dai, J., Savarino, J., Erbland, J., and Geng, L.: On the potential fingerprint of the Antarctic ozone hole in ice-core nitrate isotopes: a case study based on a South Pole ice core, Atmos. Chem. Phys., 22, 13407–13422, https://doi.org/10.5194/acp-22-13407-2022, 2022.
Clem, K. R., Renwick, J. A., and McGregor, J.: Autumn cooling of western East Antarctica linked to the tropical Pacific, J. Geophys. Res.-Atmos., 123, 89–107, 2018.
Cleveland, W. S. and Devlin, S. J.: Locally weighted regression: an approach to regression analysis by local fitting, J. Am. Stat. Assoc., 83, 596–610, 1988.
Cole-Dai, J. and Mosley-Thompson, E.: The Pinatubo eruption in South Pole snow and its potential value to ice-core paleovolcanic records, Ann. Glaciol., 29, 99–105, 1999.
Cole-Dai, J., Ferris, D. G., Lanciki, A. L., Savarino, J., Thiemens, M. H., and McConnell, J. R.: Two likely stratospheric volcanic eruptions in the 1450s CE found in a bipolar, subannually dated 800 year ice core record, J. Geophys. Res.-Atmos., 118, 7459–7466, 2013.
Crockart, C. K., Vance, T. R., Fraser, A. D., Abram, N. J., Criscitiello, A. S., Curran, M. A. J., Favier, V., Gallant, A. J. E., Kittel, C., Kjær, H. A., Klekociuk, A. R., Jong, L. M., Moy, A. D., Plummer, C. T., Vallelonga, P. T., Wille, J., and Zhang, L.: El Niño–Southern Oscillation signal in a new East Antarctic ice core, Mount Brown South, Clim. Past, 17, 1795–1818, https://doi.org/10.5194/cp-17-1795-2021, 2021.
Dalaiden, Q., Goosse, H., Rezsöhazy, J., and Thomas, E. R.: Reconstructing atmospheric circulation and sea-ice extent in the West Antarctic over the past 200 years using data assimilation, Clim. Dynam., 57, 3479–3503, 2021.
Dall'Osto, M., Ovadnevaite, J., Paglione, M., Beddows, D. C., Ceburnis, D., Cree, C., Cortés, P., Zamanillo, M., Nunes, S. O., and Pérez, G. L.: Antarctic sea ice region as a source of biogenic organic nitrogen in aerosols, Sci. Rep., 7, 1–10, 2017.
Dall'Osto, M., Airs, R. L., Beale, R., Cree, C., Fitzsimons, M. F., Beddows, D., Harrison, R. M., Ceburnis, D., O'Dowd, C., and Rinaldi, M.: Simultaneous detection of alkylamines in the surface ocean and atmosphere of the Antarctic sympagic environment, ACS Earth Space Chem., 3, 854–862, 2019.
Erbland, J., Vicars, W. C., Savarino, J., Morin, S., Frey, M. M., Frosini, D., Vince, E., and Martins, J. M. F.: Air–snow transfer of nitrate on the East Antarctic Plateau – Part 1: Isotopic evidence for a photolytically driven dynamic equilibrium in summer, Atmos. Chem. Phys., 13, 6403–6419, https://doi.org/10.5194/acp-13-6403-2013, 2013.
Frey, M. M., Savarino, J., Morin, S., Erbland, J., and Martins, J. M. F.: Photolysis imprint in the nitrate stable isotope signal in snow and atmosphere of East Antarctica and implications for reactive nitrogen cycling, Atmos. Chem. Phys., 9, 8681–8696, https://doi.org/10.5194/acp-9-8681-2009, 2009.
Frey, M. M., Norris, S. J., Brooks, I. M., Anderson, P. S., Nishimura, K., Yang, X., Jones, A. E., Nerentorp Mastromonaco, M. G., Jones, D. H., and Wolff, E. W.: First direct observation of sea salt aerosol production from blowing snow above sea ice, Atmos. Chem. Phys., 20, 2549–2578, https://doi.org/10.5194/acp-20-2549-2020, 2020.
Fundel, F., Fischer, H., Weller, R., Traufetter, F., Oerter, H., and Miller, H.: Influence of large-scale teleconnection patterns on methane sulfonate ice core records in Dronning Maud Land, J. Geophys. Res.-Atmos., 111, D04103, https://doi.org/10.1029/2005JD005872, 2006.
Garnett, J., Halsall, C., Winton, H., Joerss, H., Mulvaney, R., Ebinghaus, R., Frey, M., Jones, A., Leeson, A., and Wynn, P.: Increasing Accumulation of Perfluorocarboxylate Contaminants Revealed in an Antarctic Firn Core (1958–2017), Environ. Sci. Technol., 56, 11246–11255, https://doi.org/10.1021/acs.est.2c02592, 2022.
Göktas, F., Fischer, H., Oerter, H., Weller, R., Sommer, S., and Miller, H.: A glacio-chemical characterization of the new EPICA deep-drilling site on Amundsenisen, Dronning Maud Land, Antarctica, Ann. Glaciol., 35, 347–354, 2002.
Goyal, R., Jucker, M., Gupta, A. S., and England, M. H.: A new zonal wave-3 index for the Southern Hemisphere, J. Climate, 35, 5137–5149, 2022.
Grieman, M. M., Hoffmann, H. M., Humby, J. D., Mulvaney, R., Nehrbass-Ahles, C., Rix, J., Thomas, E. R., Tuckwell, R., and Wolff, E. W.: Continuous flow analysis methods for sodium, magnesium and calcium detection in the Skytrain ice core, J. Glaciol., 68, 90–100, 2022.
Hersbach, H., Bell, B., Berrisford, P., Hirahara, S., Horányi, A., Muñoz-Sabater, J., Nicolas, J., Peubey, C., Radu, R., and Schepers, D.: The ERA5 global reanalysis, Q. J. Roy. Meteorol. Soc., 146, 1999–2049, 2020.
Hofstede, C. M., van de Wal Roderik, S., Kaspers, K. A., Van Den Broeke, M. R., Karlöf, L., Winther, J.-G., Isaksson, E., Lappegard, G., Mulvaney, R., and Oerter, H.: Firn accumulation records for the past 1000 years on the basis of dielectric profiling of six cores from Dronning Maud Land, Antarctica, J. Glaciol., 50, 279–291, 2004.
Isaacs, F. E., Renwick, J. A., Mackintosh, A. N., and Dadic, R.: ENSO modulates summer and autumn sea ice variability around Dronning Maud Land, Antarctica, J. Geophys. Res.-Atmos., 126, e2020JD033140, https://doi.org/10.1029/2020JD033140, 2021.
Jacobi, H.-W., Weller, R., Jones, A., Anderson, P., and Schrems, O.: Peroxyacetyl nitrate (PAN) concentrations in the Antarctic troposphere measured during the photochemical experiment at Neumayer (PEAN'99), Atmos. Environ., 34, 5235–5247, 2000.
Jiang, Z., Alexander, B., Savarino, J., and Geng, L.: An inverse model to correct for the effects of post-depositional processing on ice-core nitrate and its isotopes: model framework and applications at Summit, Greenland and Dome C, Antarctica, EGUsphere [preprint], https://doi.org/10.5194/egusphere-2023-1054, 2023.
Jones, A., Weller, R., Minikin, A., Wolff, E., Sturges, W., McIntyre, H., Leonard, S., Schrems, O., and Bauguitte, S.: Oxidized nitrogen chemistry and speciation in the Antarctic troposphere, J. Geophys. Res.-Atmos., 104, 21355–21366, 1999.
Jones, A. E., Wolff, E. W., Ames, D., Bauguitte, S. J.-B., Clemitshaw, K. C., Fleming, Z., Mills, G. P., Saiz-Lopez, A., Salmon, R. A., Sturges, W. T., and Worton, D. R.: The multi-seasonal NOy budget in coastal Antarctica and its link with surface snow and ice core nitrate: results from the CHABLIS campaign, Atmos. Chem. Phys., 11, 9271–9285, https://doi.org/10.5194/acp-11-9271-2011, 2011.
Landwehr, S., Volpi, M., Derkani, M. H., Nelli, F., Alberello, A., Toffoli, A., Gysel-Beer, M., Modini, R. L., and Schmale, J.: Sea state and boundary layer stability limit sea spray aerosol lifetime over the southern ocean, Authorea Preprints, https://d197for5662m48.cloudfront.net/documents/publicationstatus/104987/preprint_pdf/edcca28511b1750323e1d1113a0ce9f7.pdf (last access: 3 April 2024) 2022.
Langway, C., Osada, K., Clausen, H., Hammer, C., and Shoji, H.: A 10-century comparison of prominent bipolar volcanic events in ice cores, J. Geophys. Res.-Atmos., 100, 16241–16247, 1995.
Lin, J., Svensson, A., Hvidberg, C. S., Lohmann, J., Kristiansen, S., Dahl-Jensen, D., Steffensen, J. P., Rasmussen, S. O., Cook, E., Kjær, H. A., Vinther, B. M., Fischer, H., Stocker, T., Sigl, M., Bigler, M., Severi, M., Traversi, R., and Mulvaney, R.: Magnitude, frequency and climate forcing of global volcanism during the last glacial period as seen in Greenland and Antarctic ice cores (60–9 ka), Clim. Past, 18, 485-506, https://doi.org/10.5194/cp-18-485-2022, 2022.
Marshall, G. J.: Trends in the Southern Annular Mode from observations and reanalyses, J. Climate, 16, 4134–4143, 2003.
Marshall, G. J., Fogt, R. L., Turner, J., and Clem, K. R.: Can current reanalyses accurately portray changes in Southern Annular Mode structure prior to 1979?, Clim. Dynam., 59, 3717–3740, 2022.
Millero, F. J., Feistel, R., Wright, D. G., and McDougall, T. J.: The composition of Standard Seawater and the definition of the Reference-Composition Salinity Scale, Deep-Sea Res. Pt. I, 55, 50–72, 2008.
Ming, A., Winton, V. H. L., Keeble, J., Abraham, N. L., Dalvi, M. C., Griffiths, P., Caillon, N., Jones, A. E., Mulvaney, R., Savarino, J., Frey, M., and Yang, X.: Stratospheric ozone changes from explosive tropical volcanoes: Modeling and ice core constraints, J. Geophys. Res.-Atmos., 125, e2019JD032290, https://doi.org/10.1029/2019JD032290, 2020.
Moore, J. and Paren, J.: A new technique for dielectric logging of Antarctic ice cores, Le Journal de Physique Colloques, 48, C1-155–C151–160, 1987.
Morin, S., Savarino, J., Frey, M. M., Yan, N., Bekki, S., Bottenheim, J. W., and Martins, J. M.: Tracing the origin and fate of NOx in the Arctic atmosphere using stable isotopes in nitrate, Science, 322, 730–732, 2008.
Mulvaney, R. and Wolff, E. W.: Evidence for winter/spring denitrification of the stratosphere in the nitrate record of Antarctic firn cores, J. Geophys. Res.-Atmos., 98, 5213–5220, 1993.
Mulvaney, R., Bremner, S., Tait, A., and Audley, N.: A medium-depth ice core drill, Memoirs of National Institute of Polar Research, 82–90, https://nipr.repo.nii.ac.jp/record/2432/files/KJ00000012984.pdf (last access: 28 May 2024), 2002.
Nye, J.: Correction factor for accumulation measured by the thickness of the annual layers in an ice sheet, J. Glaciol., 4, 785–788, 1963.
Oerter, H., Wilhelms, F., Jung-Rothenhäusler, F., Göktas, F., Miller, H., Graf, W., and Sommer, S.: Accumulation rates in Dronning Maud Land, Antarctica, as revealed by dielectric-profiling measurements of shallow firn cores, Ann. Glaciol., 30, 27–34, 2000.
Plummer, C. T., Curran, M. A. J., van Ommen, T. D., Rasmussen, S. O., Moy, A. D., Vance, T. R., Clausen, H. B., Vinther, B. M., and Mayewski, P. A.: An independently dated 2000-yr volcanic record from Law Dome, East Antarctica, including a new perspective on the dating of the 1450s CE eruption of Kuwae, Vanuatu, Clim. Past, 8, 1929–1940, https://doi.org/10.5194/cp-8-1929-2012, 2012.
Rankin, A., Auld, V., and Wolff, E.: Frost flowers as a source of fractionated sea salt aerosol in the polar regions, Geophys. Res. Lett., 27, 3469–3472, 2000.
Rankin, A. M., Wolff, E. W., and Mulvaney, R.: A reinterpretation of sea-salt records in Greenland and Antarctic ice cores?, Ann. Glaciol., 39, 276–282, 2004.
Raphael, M.: A zonal wave 3 index for the Southern Hemisphere, Geophys. Res. Lett., 31, L23212, https://doi.org/10.1029/2004GL020365, 2004.
Rayner, N., Parker, D. E., Horton, E., Folland, C. K., Alexander, L. V., Rowell, D., Kent, E. C., and Kaplan, A.: Global analyses of sea surface temperature, sea ice, and night marine air temperature since the late nineteenth century, J. Geophys. Rese.-Atmos., 108, 4407, https://doi.org/10.1029/2002JD002670, 2003.
Reijmer, C. and Oerlemans, J.: Temporal and spatial variability of the surface energy balance in Dronning Maud Land, East Antarctica, J. Geophys. Res.-Atmos., 107, ACL 9-1–ACL 9-12, 2002.
Reijmer, C., Van den Broeke, M., and Scheele, M.: Air parcel trajectories and snowfall related to five deep drilling locations in Antarctica based on the ERA-15 dataset, J. Climate, 15, 1957–1968, 2002.
Ruth, U., Barnola, J. M., Beer, J., Bigler, M., Blunier, T., Castellano, E., Fischer, H., Fundel, F., Huybrechts, P., Kaufmann, P., Kipfstuhl, S., Lambrecht, A., Morganti, A., Oerter, H., Parrenin, F., Rybak, O., Severi, M., Udisti, R., Wilhelms, F., and Wolff, E.: “EDML1”” a chronology for the EPICA deep ice core from Dronning Maud Land, Antarctica, over the last 150 000 years, Clim. Past, 3, 475–484, https://doi.org/10.5194/cp-3-475-2007, 2007.
Savarino, J., Kaiser, J., Morin, S., Sigman, D. M., and Thiemens, M. H.: Nitrogen and oxygen isotopic constraints on the origin of atmospheric nitrate in coastal Antarctica, Atmos. Chem. Phys., 7, 1925–1945, https://doi.org/10.5194/acp-7-1925-2007, 2007.
Shi, G., Chai, J., Zhu, Z., Hu, Z., Chen, Z., Yu, J., Ma, T., Ma, H., An, C., and Jiang, S.: Isotope fractionation of nitrate during volatilization in snow: a field investigation in Antarctica, Geophys. Res. Lett., 46, 3287–3297, 2019.
Shi, G., Hu, Y., Ma, H., Jiang, S., Chen, Z., Hu, Z., An, C., Sun, B., and Hastings, M. G.: Snow nitrate isotopes in central Antarctica record the prolonged period of stratospheric ozone depletion from ∼ 1960 to 2000, Geophys. Res. Lett., 49, e2022GL098986, https://doi.org/10.1029/2022GL098986, 2022a.
Shi, G., Li, C., Li, Y., Chen, Z., Ding, M., Ma, H., Jiang, S., An, C., Guo, J., and Sun, B.: Isotopic constraints on sources, production, and phase partitioning for nitrate in the atmosphere and snowfall in coastal East Antarctica, Earth Planet. Sc. Lett., 578, 117300, https://doi.org/10.1016/j.epsl.2021.117300, 2022b.
Sigl, M., McConnell, J. R., Layman, L., Maselli, O., McGwire, K., Pasteris, D., Dahl-Jensen, D., Steffensen, J. P., Vinther, B., and Edwards, R.: A new bipolar ice core record of volcanism from WAIS Divide and NEEM and implications for climate forcing of the last 2000 years, J. Geophys. Res.-Atmos., 118, 1151–1169, 2013.
Sigl, M., McConnell, J. R., Toohey, M., Curran, M., Das, S. B., Edwards, R., Isaksson, E., Kawamura, K., Kipfstuhl, S., and Krüger, K.: Insights from Antarctica on volcanic forcing during the Common Era, Nat. Clim. Change, 4, 693–697, 2014.
Sigl, M., Toohey, M., McConnell, J. R., Cole-Dai, J., and Severi, M.: Volcanic stratospheric sulfur injections and aerosol optical depth during the Holocene (past 11 500 years) from a bipolar ice-core array, Earth Syst. Sci. Data, 14, 3167–3196, https://doi.org/10.5194/essd-14-3167-2022, 2022.
Sommer, S., Appenzeller, C., Röthlisberger, R., Hutterli, M. A., Stauffer, B., Wagenbach, D., Oerter, H., Wilhelms, F., Miller, H., and Mulvaney, R.: Glacio-chemical study spanning the past 2 kyr on three ice cores from Dronning Maud Land, Antarctica: 1. Annually resolved accumulation rates, J. Geophys. Rese.-Atmos., 105, 29411–29421, https://doi.org/10.1029/2000jd900449, 2000.
Thomas, E. R., Allen, C. S., Etourneau, J., King, A. C., Severi, M., Winton, V. H. L., Mueller, J., Crosta, X., and Peck, V. L.: Antarctic sea ice proxies from marine and ice core archives suitable for reconstructing sea ice over the past 2000 years, Geosciences, 9, 506, https://doi.org/0.3390/geosciences9120506, 2019.
Thomas, E. R., Vladimirova, D. O., Tetzner, D. R., Emanuelsson, B. D., Chellman, N., Dixon, D. A., Goosse, H., Grieman, M. M., King, A. C. F., Sigl, M., Udy, D. G., Vance, T. R., Winski, D. A., Winton, V. H. L., Bertler, N. A. N., Hori, A., Laluraj, C. M., McConnell, J. R., Motizuki, Y., Takahashi, K., Motoyama, H., Nakai, Y., Schwanck, F., Simões, J. C., Lindau, F. G. L., Severi, M., Traversi, R., Wauthy, S., Xiao, C., Yang, J., Mosely-Thompson, E., Khodzher, T. V., Golobokova, L. P., and Ekaykin, A. A.: Ice core chemistry database: an Antarctic compilation of sodium and sulfate records spanning the past 2000 years, Earth Syst. Sci. Data, 15, 2517–2532, https://doi.org/10.5194/essd-15-2517-2023, 2023.
Titchner, H. A. and Rayner, N. A.: The Met Office Hadley Centre sea ice and sea surface temperature data set, version 2: 1. Sea ice concentrations, Journal of Geophysical Research: Atmospheres, 119, 2864-2889, 2014.
Traufetter, F., Oerter, H., Fischer, H., Weller, R., and Miller, H.: Spatio-temporal variability in volcanic sulphate deposition over the past 2 kyr in snow pits and firn cores from Amundsenisen, Antarctica, J. Glaciol., 50, 137–146, 2004.
Turner, J., Phillips, T., Thamban, M., Rahaman, W., Marshall, G. J., Wille, J. D., Favier, V., Winton, H., Thomas, E., and Wang, Z.: The Dominant Role of Extreme Precipitation Events in Antarctic Snowfall Variability, Geophys. Res. Lett., 46, 3502–3511, https://doi.org/10.1029/2018GL081517, 2019.
Vega, C. P., Isaksson, E., Schlosser, E., Divine, D., Martma, T., Mulvaney, R., Eichler, A., and Schwikowski-Gigar, M.: Variability of sea salts in ice and firn cores from Fimbul Ice Shelf, Dronning Maud Land, Antarctica, The Cryosphere, 12, 1681–1697, https://doi.org/10.5194/tc-12-1681-2018, 2018.
Wagenbach, D., Ducroz, F., Mulvaney, R., Keck, L., Minikin, A., Legrand, M., Hall, J., and Wolff, E.: Sea-salt aerosol in coastal Antarctic regions, J. Geophys. Res.-Atmos., 103, 10961–10974, 1998.
Welker, C., Martius, O., Froidevaux, P., Reijmer, C. H., and Fischer, H.: A climatological analysis of high-precipitation events in Dronning Maud Land, Antarctica, and associated large-scale atmospheric conditions, J. Geophys. Res.-Atmos., 119, 11932–11954, 2014.
Weller, R. and Wagenbach, D.: Year-round chemical aerosol records in continental Antarctica obtained by automatic samplings, Tellus B, 59, 755–765, 2007.
Weller, R., Jones, A., Wille, A., Jacobi, H. W., McIntyre, H., Sturges, W., Huke, M., and Wagenbach, D.: Seasonality of reactive nitrogen oxides (NOy) at Neumayer Station, Antarctica, J. Geophys. Res.-Atmos., 107, ACH 2-1–ACH 2-11, 2002.
Wilhelms, F., Kipfstuhl, J., Miller, H., Heinloth, K., and Firestone, J.: Precise dielectric profiling of ice cores: a new device with improved guarding and its theory, J. Glaciol., 44, 171–174, 1998.
Wilhelms, F., Miller, H., Gerasimoff, M. D., Drücker, C., Frenzel, A., Fritzsche, D., Grobe, H., Hansen, S. B., Hilmarsson, S. Æ., Hoffmann, G., Hörnby, K., Jaeschke, A., Jakobsdóttir, S. S., Juckschat, P., Karsten, A., Karsten, L., Kaufmann, P. R., Karlin, T., Kohlberg, E., Kleffel, G., Lambrecht, A., Lambrecht, A., Lawer, G., Schärmeli, I., Schmitt, J., Sheldon, S. G., Takata, M., Trenke, M., Twarloh, B., Valero-Delgado, F., and Wilhelms-Dick, D.: The EPICA Dronning Maud Land deep drilling operation, Ann. Glaciol., 55, 355–366, https://doi.org/10.3189/2014AoG68A189, 2017.
Winton, V. H. L., Ming, A., Caillon, N., Hauge, L., Jones, A. E., Savarino, J., Yang, X., and Frey, M. M.: Deposition, recycling, and archival of nitrate stable isotopes between the air–snow interface: comparison between Dronning Maud Land and Dome C, Antarctica , Atmos. Chem. Phys., 20, 5861–5885, https://doi.org/10.5194/acp-20-5861-2020, 2020.
Winton, V. H. L. W., Caillon, N., Hauge, L., Mulvaney, R., Rix, J., Tuckwell, R., Savarino, J., and Frey, M.: Ice core chemistry, density, conductivity, dust, snow accumulation rate, and stable nitrate isotopic composition of the 120 m ISOL-ICE ice core, Dronning Maud Land, Antarctica (Version 1.0) [Data set], UK Polar Data Centre, Natural Environment Research Council, UK Research & Innovation [data set], https://doi.org/10.5285/9c972cfb-0ffa-4144-a943-da6eb82431d2, 2019.
Yang, J., Xiao, C., Liu, J., Li, S., and Qin, D.: Variability of Antarctic sea ice extent over the past 200 years, Sci. Bull., 66, 2394–2404, https://doi.org/10.1016/j.scib.2021.07.028, 2021.
Yang, X., Frey, M. M., Rhodes, R. H., Norris, S. J., Brooks, I. M., Anderson, P. S., Nishimura, K., Jones, A. E., and Wolff, E. W.: Sea salt aerosol production via sublimating wind-blown saline snow particles over sea ice: parameterizations and relevant microphysical mechanisms, Atmos. Chem. Phys., 19, 8407–8424, https://doi.org/10.5194/acp-19-8407-2019, 2019.
Zielinski, G. A., Mayewski, P. A., Meeker, L. D., Whitlow, S., Twickler, M. S., Morrison, M., Meese, D. A., Gow, A. J., and Alley, R. B.: Record of volcanism since 7000 BC from the GISP2 Greenland ice core and implications for the volcano-climate system, Science, 264, 948–952, 1994.
Short summary
In 2018, a new 120 m ice core was drilled in a region located under the Antarctic ozone hole. We present the first results including a 1300-year record of snow accumulation and aerosol chemistry. We investigate the aerosol and moisture source regions and atmospheric processes related to the ice core record and discuss what this means for developing a record of past ultraviolet radiation and ozone depletion using the stable isotopic composition of nitrate measured in the same ice core.
In 2018, a new 120 m ice core was drilled in a region located under the Antarctic ozone hole. We...
