Articles | Volume 18, issue 2
https://doi.org/10.5194/cp-18-183-2022
https://doi.org/10.5194/cp-18-183-2022
Research article
 | 
02 Feb 2022
Research article |  | 02 Feb 2022

Atmospheric CO2 estimates for the Miocene to Pleistocene based on foraminiferal δ11B at Ocean Drilling Program Sites 806 and 807 in the Western Equatorial Pacific

Maxence Guillermic, Sambuddha Misra, Robert Eagle, and Aradhna Tripati

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Cited articles

Aggarwal, S. K., and You, C. F.: A review on the determination of isotope ratios of boron with mass spectrometry, Mass Spectrom. Rev., 36, 499–519, 2017. 
Allen, K. A. and Hönisch, B.: The planktic foraminiferal B/Ca proxy for seawater carbonate chemistry, A critical evaluation, Earth Planet. Sc. Lett., 345–348, 203–211, 2012. 
Allen, K. A., Hönisch, B., Eggins, S. M., Yu, J., Spero, H. J., and Elderfield, H.: Controls on boron incorporation in cultured tests of the planktic foraminifer Orbulina universa, Earth Planet. Sc. Lett., 309, 291–301, 2011. 
Babila, T., Huang, K. F., Rosenthal, Y., Conte, M. H., and Lin, H. L.: Development of B/Ca as a seawater pH proxy using sediment trap time series, abstract, available at: https://acswebcontent.acs.org/prfar/2010/nugget/11019/11019.pdf (last access: 10 December 2021​​​​​​​), 2010. 
Badger, M. P. S., Lear, C. H., Pancost, R. D., Foster, G. L., Bailey, T. R., Leng, M. J., and Abels, H. A.: CO2 drawdown following the middle Miocene expansion of the Antarctic Ice Sheet, Paleoceanography, 28, 42–53, 2013. 
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Short summary
Here we reconstruct atmospheric CO2 values across major climate transitions over the past 16 million years (Myr) from two sites in the West Pacific Warm Pool using a pH proxy on surface-dwelling foraminifera. We are able to reproduce pCO2 data from ice cores; therefore we apply the same framework to older samples to create a long-term pH and pCO2 reconstruction. We give quantitative constraints on pH and pCO2 changes over the main climate transitions of the last 16 Myr.