Articles | Volume 20, issue 4
https://doi.org/10.5194/cp-20-991-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/cp-20-991-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
25 Apr 2024
Research article |
| 25 Apr 2024
| 25 Apr 2024
No detectable influence of the carbonate ion effect on changes in stable carbon isotope ratios (δ13C) of shallow dwelling planktic foraminifera over the past 160 kyr
Alfred-Wegener-Institut Helmholtz-Zentrum für Polar- und Meeresforschung, Bremerhaven, Germany
Stefan Mulitza
MARUM – Center for Marine Environmental Sciences and Faculty of Geosciences, University of Bremen, Bremen, Germany
Related authors
Martin Butzin, Ying Ye, Christoph Völker, Özgür Gürses, Judith Hauck, and Peter Köhler
Geosci. Model Dev., 17, 1709–1727, https://doi.org/10.5194/gmd-17-1709-2024, https://doi.org/10.5194/gmd-17-1709-2024, 2024
Short summary
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In this paper we describe the implementation of the carbon isotopes 13C and 14C into the marine biogeochemistry model FESOM2.1-REcoM3 and present results of long-term test simulations. Our model results are largely consistent with marine carbon isotope reconstructions for the pre-anthropogenic period, but also exhibit some discrepancies.
Luke Skinner, Francois Primeau, Aurich Jeltsch-Thömmes, Fortunat Joos, Peter Köhler, and Edouard Bard
Clim. Past, 19, 2177–2202, https://doi.org/10.5194/cp-19-2177-2023, https://doi.org/10.5194/cp-19-2177-2023, 2023
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Radiocarbon is best known as a dating tool, but it also allows us to track CO2 exchange between the ocean and atmosphere. Using decades of data and novel mapping methods, we have charted the ocean’s average radiocarbon ″age” since the last Ice Age. Combined with climate model simulations, these data quantify the ocean’s role in atmospheric CO2 rise since the last Ice Age while also revealing that Earth likely received far more cosmic radiation during the last Ice Age than hitherto believed.
Claudia Hinrichs, Peter Köhler, Christoph Völker, and Judith Hauck
Biogeosciences, 20, 3717–3735, https://doi.org/10.5194/bg-20-3717-2023, https://doi.org/10.5194/bg-20-3717-2023, 2023
Short summary
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This study evaluated the alkalinity distribution in 14 climate models and found that most models underestimate alkalinity at the surface and overestimate it in the deeper ocean. It highlights the need for better understanding and quantification of processes driving alkalinity distribution and calcium carbonate dissolution and the importance of accounting for biases in model results when evaluating potential ocean alkalinity enhancement experiments.
Ying Ye, Guy Munhoven, Peter Köhler, Martin Butzin, Judith Hauck, Özgür Gürses, and Christoph Völker
Geosci. Model Dev. Discuss., https://doi.org/10.5194/gmd-2023-181, https://doi.org/10.5194/gmd-2023-181, 2023
Preprint under review for GMD
Short summary
Short summary
Many biogeochemistry models assume all material reaching the seafloor is remineralized and returned to solution, which is sufficient for studies on short-term climate change. Under long-term climate change the storage of carbon in sediments slows down carbon cycling and influences feedbacks in the atmosphere-ocean-sediment system. Here we coupled a sediment model to an ocean biogeochemistry model and found a shift of carbon storage from the atmosphere to the ocean-sediment system.
Lennert B. Stap, Peter Köhler, and Gerrit Lohmann
Earth Syst. Dynam., 10, 333–345, https://doi.org/10.5194/esd-10-333-2019, https://doi.org/10.5194/esd-10-333-2019, 2019
Short summary
Short summary
Processes causing the same global-average radiative forcing might lead to different global temperature changes. We expand the theoretical framework by which we calculate paleoclimate sensitivity with an efficacy factor. Applying the revised approach to radiative forcing caused by CO2 and land ice albedo perturbations, inferred from data of the past 800 000 years, gives a new paleo-based estimate of climate sensitivity.
Peter Köhler, Christoph Nehrbass-Ahles, Jochen Schmitt, Thomas F. Stocker, and Hubertus Fischer
Earth Syst. Sci. Data, 9, 363–387, https://doi.org/10.5194/essd-9-363-2017, https://doi.org/10.5194/essd-9-363-2017, 2017
Short summary
Short summary
We document our best available data compilation of published ice core records of the greenhouse gases CO2, CH4, and N2O and recent measurements on firn air and atmospheric samples covering the time window from 156 000 years BP to the beginning of the year 2016 CE. A smoothing spline method is applied to translate the discrete and irregularly spaced data points into continuous time series. The radiative forcing for each greenhouse gas is computed using well-established, simple formulations.
Peter Köhler, Lennert B. Stap, Anna S. von der Heydt, Bas de Boer, and Roderik S. W. van de Wal
Clim. Past Discuss., https://doi.org/10.5194/cp-2016-23, https://doi.org/10.5194/cp-2016-23, 2016
Revised manuscript not accepted
Short summary
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Evidence indicate that specific equilibrium climate sensitivity, the global annual mean surface temperature change as a response to a change in radiative forcing, is state dependent. We here show that the interpretation of data in the state-dependent case is not straightforward. We analyse the differences of a point-wise approach and one based on a piece-wise linear analysis, combine both, compare with potential model results and apply the theoretical concepts to data of the last 800 kyr.
P. Köhler, B. de Boer, A. S. von der Heydt, L. B. Stap, and R. S. W. van de Wal
Clim. Past, 11, 1801–1823, https://doi.org/10.5194/cp-11-1801-2015, https://doi.org/10.5194/cp-11-1801-2015, 2015
Short summary
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We find that the specific equilibrium climate sensitivity due to radiative forcing of CO2 and land ice albedo has been state-dependent for the last 2.1Myr (most of the Pleistocene). Its value is ~45% larger during intermediate glaciated climates and interglacial periods than during Pleistocene full glacial conditions. The state dependency is mainly caused by a latitudinal dependency in ice sheet area changes. Due to uncertainties in CO2, firm conclusions for the Pliocene are not yet possible.
R. Schneider, J. Schmitt, P. Köhler, F. Joos, and H. Fischer
Clim. Past, 9, 2507–2523, https://doi.org/10.5194/cp-9-2507-2013, https://doi.org/10.5194/cp-9-2507-2013, 2013
R. S. W. van de Wal, B. de Boer, L. J. Lourens, P. Köhler, and R. Bintanja
Clim. Past, 7, 1459–1469, https://doi.org/10.5194/cp-7-1459-2011, https://doi.org/10.5194/cp-7-1459-2011, 2011
P. Köhler, G. Knorr, D. Buiron, A. Lourantou, and J. Chappellaz
Clim. Past, 7, 473–486, https://doi.org/10.5194/cp-7-473-2011, https://doi.org/10.5194/cp-7-473-2011, 2011
P. Köhler and A. Huth
Biogeosciences, 7, 2531–2543, https://doi.org/10.5194/bg-7-2531-2010, https://doi.org/10.5194/bg-7-2531-2010, 2010
P. Köhler
Clim. Past Discuss., https://doi.org/10.5194/cpd-6-1453-2010, https://doi.org/10.5194/cpd-6-1453-2010, 2010
Revised manuscript has not been submitted
P. Köhler and R. Bintanja
Clim. Past, 4, 311–332, https://doi.org/10.5194/cp-4-311-2008, https://doi.org/10.5194/cp-4-311-2008, 2008
P. Köhler, H. Fischer, J. Schmitt, and G. Munhoven
Biogeosciences, 3, 539–556, https://doi.org/10.5194/bg-3-539-2006, https://doi.org/10.5194/bg-3-539-2006, 2006
P. Köhler and H. Fischer
Clim. Past, 2, 57–78, https://doi.org/10.5194/cp-2-57-2006, https://doi.org/10.5194/cp-2-57-2006, 2006
Martin Butzin, Ying Ye, Christoph Völker, Özgür Gürses, Judith Hauck, and Peter Köhler
Geosci. Model Dev., 17, 1709–1727, https://doi.org/10.5194/gmd-17-1709-2024, https://doi.org/10.5194/gmd-17-1709-2024, 2024
Short summary
Short summary
In this paper we describe the implementation of the carbon isotopes 13C and 14C into the marine biogeochemistry model FESOM2.1-REcoM3 and present results of long-term test simulations. Our model results are largely consistent with marine carbon isotope reconstructions for the pre-anthropogenic period, but also exhibit some discrepancies.
Luke Skinner, Francois Primeau, Aurich Jeltsch-Thömmes, Fortunat Joos, Peter Köhler, and Edouard Bard
Clim. Past, 19, 2177–2202, https://doi.org/10.5194/cp-19-2177-2023, https://doi.org/10.5194/cp-19-2177-2023, 2023
Short summary
Short summary
Radiocarbon is best known as a dating tool, but it also allows us to track CO2 exchange between the ocean and atmosphere. Using decades of data and novel mapping methods, we have charted the ocean’s average radiocarbon ″age” since the last Ice Age. Combined with climate model simulations, these data quantify the ocean’s role in atmospheric CO2 rise since the last Ice Age while also revealing that Earth likely received far more cosmic radiation during the last Ice Age than hitherto believed.
Claudia Hinrichs, Peter Köhler, Christoph Völker, and Judith Hauck
Biogeosciences, 20, 3717–3735, https://doi.org/10.5194/bg-20-3717-2023, https://doi.org/10.5194/bg-20-3717-2023, 2023
Short summary
Short summary
This study evaluated the alkalinity distribution in 14 climate models and found that most models underestimate alkalinity at the surface and overestimate it in the deeper ocean. It highlights the need for better understanding and quantification of processes driving alkalinity distribution and calcium carbonate dissolution and the importance of accounting for biases in model results when evaluating potential ocean alkalinity enhancement experiments.
Ying Ye, Guy Munhoven, Peter Köhler, Martin Butzin, Judith Hauck, Özgür Gürses, and Christoph Völker
Geosci. Model Dev. Discuss., https://doi.org/10.5194/gmd-2023-181, https://doi.org/10.5194/gmd-2023-181, 2023
Preprint under review for GMD
Short summary
Short summary
Many biogeochemistry models assume all material reaching the seafloor is remineralized and returned to solution, which is sufficient for studies on short-term climate change. Under long-term climate change the storage of carbon in sediments slows down carbon cycling and influences feedbacks in the atmosphere-ocean-sediment system. Here we coupled a sediment model to an ocean biogeochemistry model and found a shift of carbon storage from the atmosphere to the ocean-sediment system.
Stefan Mulitza, Torsten Bickert, Helen C. Bostock, Cristiano M. Chiessi, Barbara Donner, Aline Govin, Naomi Harada, Enqing Huang, Heather Johnstone, Henning Kuhnert, Michael Langner, Frank Lamy, Lester Lembke-Jene, Lorraine Lisiecki, Jean Lynch-Stieglitz, Lars Max, Mahyar Mohtadi, Gesine Mollenhauer, Juan Muglia, Dirk Nürnberg, André Paul, Carsten Rühlemann, Janne Repschläger, Rajeev Saraswat, Andreas Schmittner, Elisabeth L. Sikes, Robert F. Spielhagen, and Ralf Tiedemann
Earth Syst. Sci. Data, 14, 2553–2611, https://doi.org/10.5194/essd-14-2553-2022, https://doi.org/10.5194/essd-14-2553-2022, 2022
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Stable isotope ratios of foraminiferal shells from deep-sea sediments preserve key information on the variability of ocean circulation and ice volume. We present the first global atlas of harmonized raw downcore oxygen and carbon isotope ratios of various planktonic and benthic foraminiferal species. The atlas is a foundation for the analyses of the history of Earth system components, for finding future coring sites, and for teaching marine stratigraphy and paleoceanography.
André Paul, Stefan Mulitza, Rüdiger Stein, and Martin Werner
Clim. Past, 17, 805–824, https://doi.org/10.5194/cp-17-805-2021, https://doi.org/10.5194/cp-17-805-2021, 2021
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Maps and fields of near-sea-surface temperature differences between the past and present can be used to visualize and quantify climate changes and perform simulations with climate models. We used a statistical method to map sparse and scattered data for the Last Glacial Maximum time period (23 000 to 19 000 years before present) to a regular grid. The estimated global and tropical cooling would imply an equilibrium climate sensitivity in the lower to middle part of the currently accepted range.
Lukas Jonkers, Olivier Cartapanis, Michael Langner, Nick McKay, Stefan Mulitza, Anne Strack, and Michal Kucera
Earth Syst. Sci. Data, 12, 1053–1081, https://doi.org/10.5194/essd-12-1053-2020, https://doi.org/10.5194/essd-12-1053-2020, 2020
Michael Langner and Stefan Mulitza
Clim. Past, 15, 2067–2072, https://doi.org/10.5194/cp-15-2067-2019, https://doi.org/10.5194/cp-15-2067-2019, 2019
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Collections of paleoclimate data provide valuable information on the functioning of the Earth system but are often difficult to manage due to the inconsistency of data formats and reconstruction methods. We present a software toolbox that combines a simple document-based database with functionality for the visualization and management of marine proxy data. The program allows the efficient homogenization of larger paleoceanographic data sets into quality-controlled and transparent data products.
Lennert B. Stap, Peter Köhler, and Gerrit Lohmann
Earth Syst. Dynam., 10, 333–345, https://doi.org/10.5194/esd-10-333-2019, https://doi.org/10.5194/esd-10-333-2019, 2019
Short summary
Short summary
Processes causing the same global-average radiative forcing might lead to different global temperature changes. We expand the theoretical framework by which we calculate paleoclimate sensitivity with an efficacy factor. Applying the revised approach to radiative forcing caused by CO2 and land ice albedo perturbations, inferred from data of the past 800 000 years, gives a new paleo-based estimate of climate sensitivity.
Charlotte Breitkreuz, André Paul, Stefan Mulitza, Javier García-Pintado, and Michael Schulz
Geosci. Model Dev. Discuss., https://doi.org/10.5194/gmd-2019-32, https://doi.org/10.5194/gmd-2019-32, 2019
Publication in GMD not foreseen
Short summary
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We present a technique for ocean state estimation based on the combination of a simple data assimilation method with a state reduction approach. The technique proves to be very efficient and successful in reducing the model-data misfit and reconstructing a target ocean circulation from synthetic observations. In an application to Last Glacial Maximum proxy data the model-data misfit is greatly reduced but some misfit remains. Two different ocean states are found with similar model-data misfit.
Rike Völpel, André Paul, Annegret Krandick, Stefan Mulitza, and Michael Schulz
Geosci. Model Dev., 10, 3125–3144, https://doi.org/10.5194/gmd-10-3125-2017, https://doi.org/10.5194/gmd-10-3125-2017, 2017
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This study presents the implementation of stable water isotopes in the MITgcm and describes the results of an equilibrium simulation under pre-industrial conditions. The model compares well to observational data and measurements of plankton tow records and thus opens wide prospects for long-term simulations in a paleoclimatic context.
Peter Köhler, Christoph Nehrbass-Ahles, Jochen Schmitt, Thomas F. Stocker, and Hubertus Fischer
Earth Syst. Sci. Data, 9, 363–387, https://doi.org/10.5194/essd-9-363-2017, https://doi.org/10.5194/essd-9-363-2017, 2017
Short summary
Short summary
We document our best available data compilation of published ice core records of the greenhouse gases CO2, CH4, and N2O and recent measurements on firn air and atmospheric samples covering the time window from 156 000 years BP to the beginning of the year 2016 CE. A smoothing spline method is applied to translate the discrete and irregularly spaced data points into continuous time series. The radiative forcing for each greenhouse gas is computed using well-established, simple formulations.
Raphaël Morard, Franck Lejzerowicz, Kate F. Darling, Béatrice Lecroq-Bennet, Mikkel Winther Pedersen, Ludovic Orlando, Jan Pawlowski, Stefan Mulitza, Colomban de Vargas, and Michal Kucera
Biogeosciences, 14, 2741–2754, https://doi.org/10.5194/bg-14-2741-2017, https://doi.org/10.5194/bg-14-2741-2017, 2017
Short summary
Short summary
The exploitation of deep-sea sedimentary archive relies on the recovery of mineralized skeletons of pelagic organisms. Planktonic groups leaving preserved remains represent only a fraction of the total marine diversity. Environmental DNA left by non-fossil organisms is a promising source of information for paleo-reconstructions. Here we show how planktonic-derived environmental DNA preserves ecological structure of planktonic communities. We use planktonic foraminifera as a case study.
Shuwen Sun, Enno Schefuß, Stefan Mulitza, Cristiano M. Chiessi, André O. Sawakuchi, Matthias Zabel, Paul A. Baker, Jens Hefter, and Gesine Mollenhauer
Biogeosciences, 14, 2495–2512, https://doi.org/10.5194/bg-14-2495-2017, https://doi.org/10.5194/bg-14-2495-2017, 2017
Peter Köhler, Lennert B. Stap, Anna S. von der Heydt, Bas de Boer, and Roderik S. W. van de Wal
Clim. Past Discuss., https://doi.org/10.5194/cp-2016-23, https://doi.org/10.5194/cp-2016-23, 2016
Revised manuscript not accepted
Short summary
Short summary
Evidence indicate that specific equilibrium climate sensitivity, the global annual mean surface temperature change as a response to a change in radiative forcing, is state dependent. We here show that the interpretation of data in the state-dependent case is not straightforward. We analyse the differences of a point-wise approach and one based on a piece-wise linear analysis, combine both, compare with potential model results and apply the theoretical concepts to data of the last 800 kyr.
P. Köhler, B. de Boer, A. S. von der Heydt, L. B. Stap, and R. S. W. van de Wal
Clim. Past, 11, 1801–1823, https://doi.org/10.5194/cp-11-1801-2015, https://doi.org/10.5194/cp-11-1801-2015, 2015
Short summary
Short summary
We find that the specific equilibrium climate sensitivity due to radiative forcing of CO2 and land ice albedo has been state-dependent for the last 2.1Myr (most of the Pleistocene). Its value is ~45% larger during intermediate glaciated climates and interglacial periods than during Pleistocene full glacial conditions. The state dependency is mainly caused by a latitudinal dependency in ice sheet area changes. Due to uncertainties in CO2, firm conclusions for the Pliocene are not yet possible.
R. Schneider, J. Schmitt, P. Köhler, F. Joos, and H. Fischer
Clim. Past, 9, 2507–2523, https://doi.org/10.5194/cp-9-2507-2013, https://doi.org/10.5194/cp-9-2507-2013, 2013
J. A. Collins, A. Govin, S. Mulitza, D. Heslop, M. Zabel, J. Hartmann, U. Röhl, and G. Wefer
Clim. Past, 9, 1181–1191, https://doi.org/10.5194/cp-9-1181-2013, https://doi.org/10.5194/cp-9-1181-2013, 2013
R. S. W. van de Wal, B. de Boer, L. J. Lourens, P. Köhler, and R. Bintanja
Clim. Past, 7, 1459–1469, https://doi.org/10.5194/cp-7-1459-2011, https://doi.org/10.5194/cp-7-1459-2011, 2011
P. Köhler, G. Knorr, D. Buiron, A. Lourantou, and J. Chappellaz
Clim. Past, 7, 473–486, https://doi.org/10.5194/cp-7-473-2011, https://doi.org/10.5194/cp-7-473-2011, 2011
P. Köhler and A. Huth
Biogeosciences, 7, 2531–2543, https://doi.org/10.5194/bg-7-2531-2010, https://doi.org/10.5194/bg-7-2531-2010, 2010
P. Köhler
Clim. Past Discuss., https://doi.org/10.5194/cpd-6-1453-2010, https://doi.org/10.5194/cpd-6-1453-2010, 2010
Revised manuscript has not been submitted
P. Köhler and R. Bintanja
Clim. Past, 4, 311–332, https://doi.org/10.5194/cp-4-311-2008, https://doi.org/10.5194/cp-4-311-2008, 2008
P. Köhler, H. Fischer, J. Schmitt, and G. Munhoven
Biogeosciences, 3, 539–556, https://doi.org/10.5194/bg-3-539-2006, https://doi.org/10.5194/bg-3-539-2006, 2006
P. Köhler and H. Fischer
Clim. Past, 2, 57–78, https://doi.org/10.5194/cp-2-57-2006, https://doi.org/10.5194/cp-2-57-2006, 2006
Related subject area
Subject: Carbon Cycle | Archive: Marine Archives | Timescale: Pleistocene
Deglacial export of pre-aged terrigenous carbon to the Bay of Biscay
Atmospheric CO2 estimates for the Miocene to Pleistocene based on foraminiferal δ11B at Ocean Drilling Program Sites 806 and 807 in the Western Equatorial Pacific
Nutrient utilization and diatom productivity changes in the low-latitude south-eastern Atlantic over the past 70 ka: response to Southern Ocean leakage
Coccolithophore productivity at the western Iberian Margin during the Middle Pleistocene (310–455 ka) – evidence from coccolith Sr∕Ca data
Carbon burial in deep-sea sediment and implications for oceanic inventories of carbon and alkalinity over the last glacial cycle
Eduardo Queiroz Alves, Wanyee Wong, Jens Hefter, Hendrik Grotheer, Tommaso Tesi, Torben Gentz, Karin Zonneveld, and Gesine Mollenhauer
Clim. Past, 20, 121–136, https://doi.org/10.5194/cp-20-121-2024, https://doi.org/10.5194/cp-20-121-2024, 2024
Short summary
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Our study reveals a previously unknown peat source for the massive influx of terrestrial organic matter that was exported from the European continent to the ocean during the last deglaciation. Our findings shed light on ancient terrestrial organic carbon mobilization, providing insights that are crucial for refining climate models.
Maxence Guillermic, Sambuddha Misra, Robert Eagle, and Aradhna Tripati
Clim. Past, 18, 183–207, https://doi.org/10.5194/cp-18-183-2022, https://doi.org/10.5194/cp-18-183-2022, 2022
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Here we reconstruct atmospheric CO2 values across major climate transitions over the past 16 million years (Myr) from two sites in the West Pacific Warm Pool using a pH proxy on surface-dwelling foraminifera. We are able to reproduce pCO2 data from ice cores; therefore we apply the same framework to older samples to create a long-term pH and pCO2 reconstruction. We give quantitative constraints on pH and pCO2 changes over the main climate transitions of the last 16 Myr.
Katharine Hendry, Oscar Romero, and Vanessa Pashley
Clim. Past, 17, 603–614, https://doi.org/10.5194/cp-17-603-2021, https://doi.org/10.5194/cp-17-603-2021, 2021
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Productive eastern boundary upwelling systems (EBUs) are characterized by abundant siliceous algae and diatoms, and they play a key role in carbon fixation. Understanding past shifts in diatom production is critical for predicting the impact of future climate change. We combine existing sediment archives from the Benguela EBU with new diatom isotope analyses and modelling to reconstruct late Quaternary silica cycling, which we suggest depends on both upwelling intensity and surface utilization.
Catarina Cavaleiro, Antje H. L. Voelker, Heather Stoll, Karl-Heinz Baumann, and Michal Kucera
Clim. Past, 16, 2017–2037, https://doi.org/10.5194/cp-16-2017-2020, https://doi.org/10.5194/cp-16-2017-2020, 2020
Olivier Cartapanis, Eric D. Galbraith, Daniele Bianchi, and Samuel L. Jaccard
Clim. Past, 14, 1819–1850, https://doi.org/10.5194/cp-14-1819-2018, https://doi.org/10.5194/cp-14-1819-2018, 2018
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A data-based reconstruction of carbon-bearing deep-sea sediment shows significant changes in the global burial rate over the last glacial cycle. We calculate the impact of these deep-sea changes, as well as hypothetical changes in continental shelf burial and volcanic outgassing. Our results imply that these geological fluxes had a significant impact on ocean chemistry and the global carbon isotopic ratio, and that the natural carbon cycle was not in steady state during the Holocene.
Cited articles
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Bachan, A., Lau, K. V., Saltzman, M. R., Thomas, E., Kump, L. R., and Payne, J. L.: A model for the decrease in amplitude of carbon isotope excursions across the Phanerozoic, Am. J. Sci., 317, 641–676, https://doi.org/10.2475/06.2017.01, 2017. a
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Short summary
We constructed 160 kyr long mono-specific stacks of δ13C and of δ18O from the wider tropics from the planktic foraminifera G. ruber and/or T. sacculifer and compared them with carbon cycle simulations using the BICYCLE-SE model. In our stacks and our model-based interpretation, we cannot detect a species-specific isotopic fractionation during hard-shell formation as a function of carbonate chemistry in the surrounding seawater, something which is called a carbonate ion effect.
We constructed 160 kyr long mono-specific stacks of δ13C and of δ18O from the wider tropics from...
