Articles | Volume 16, issue 1
Clim. Past, 16, 17–27, 2020
https://doi.org/10.5194/cp-16-17-2020
Clim. Past, 16, 17–27, 2020
https://doi.org/10.5194/cp-16-17-2020

Research article 07 Jan 2020

Research article | 07 Jan 2020

Experimental evaluation of oxygen isotopic exchange between inclusion water and host calcite in speleothems

Ryu Uemura et al.

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Cited articles

Affolter, S., Fleitmann, D., and Leuenberger, M.: New online method for water isotope analysis of speleothem fluid inclusions using laser absorption spectroscopy (WS-CRDS), Clim. Past, 10, 1291–1304, https://doi.org/10.5194/cp-10-1291-2014, 2014. 
Arienzo, M. M., Swart, P. K., and Vonhof, H. B.: Measurement of δ18O and δ2H values of fluid inclusion water in speleothems using cavity ring-down spectroscopy compared with isotope ratio mass spectrometry, Rapid Commun. Mass Spectrom., 27, 2616–2624, https://doi.org/10.1002/rcm.6723, 2013. 
Baker, A., Hartmann, A., Duan, W., Hankin, S., Comas-Bru, L., Cuthbert, M. O., Treble, P. C., Banner, J., Genty, D., Baldini, L. M., Bartolome, M., Moreno, A., Perez-Mejias, C., and Werner, M.: Global analysis reveals climatic controls on the oxygen isotope composition of cave drip water, Nat. Commun., 10, 2984, https://doi.org/10.1038/s41467-019-11027-w, 2019. 
Cheng, H., Lawrence Edwards, R., Shen, C.-C., Polyak, V. J., Asmerom, Y., Woodhead, J., Hellstrom, J., Wang, Y., Kong, X., Spötl, C., Wang, X., and Calvin Alexander, E.: Improvements in 230Th dating, 230Th and 234U half-life values, and U–Th isotopic measurements by multi-collector inductively coupled plasma mass spectrometry, Earth Planet. Sc. Lett., 371–372, 82–91, https://doi.org/10.1016/j.epsl.2013.04.006, 2013. 
Clark, I. and Fritz, P.: Water-Rock Interaction, in: Environmental Isotopes in Hydrogeology, Lewis Publishers, New York, 245–266, 1999. 
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Short summary
The oxygen isotopic ratio of water in fluid inclusions in speleothems is an important proxy for the changes in past hydroclimate and temperatures. This isotopic ratio, however, may be affected by isotopic exchange between the water and the host calcite. Here we evaluate this exchange reaction based on a laboratory experiment. We demonstrated that the exchange was detectable but not significant for temperature reconstruction, likely because the reaction occurred only with a thin calcite layer.