Articles | Volume 19, issue 12
https://doi.org/10.5194/cp-19-2493-2023
https://doi.org/10.5194/cp-19-2493-2023
Research article
 | 
12 Dec 2023
Research article |  | 12 Dec 2023

Orbital CO2 reconstruction using boron isotopes during the late Pleistocene, an assessment of accuracy

Elwyn de la Vega, Thomas B. Chalk, Mathis P. Hain, Megan R. Wilding, Daniel Casey, Robin Gledhill, Chongguang Luo, Paul A. Wilson, and Gavin L. Foster

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Cited articles

Ahn, J., Brook, E. J., Mitchell, L., Rosen, J., McConnell, J. R., Taylor, K., Etheridge, D., and Rubino, M.: Atmospheric CO2 over the last 1000 years: A high-resolution record from the West Antarctic Ice Sheet (WAIS) Divide ice core, Global Biogeochem. Cy., 26, GB2027, https://doi.org/10.1029/2011GB004247, 2012. 
Anagnostou, E., John, E. H., Edgar, K. M., Foster, G. L., Ridgwell, A., Inglis, G. N., Pancost, R. D., Lunt, D. J., and Pearson, P. N.: Changing atmospheric CO2 concentration was the primary driver of early Cenozoic climate, Nature, 533, 380–384, 2016. 
Anagnostou, E., Williams, B., Westfield, I., Foster, G., and Ries, J.: Calibration of the pH-δ11B and temperature-Mg/Li proxies in the long-lived high-latitude crustose coralline red alga Clathromorphum compactum via controlled laboratory experiments, Geochim. Cosmochim. Ac., 254, 142–155, 2019. 
Anagnostou, E., John, E. H., Babila, T., Sexton, P., Ridgwell, A., Lunt, D. J., Pearson, P. N., Chalk, T., Pancost, R. D., and Foster, G.: Proxy evidence for state-dependence of climate sensitivity in the Eocene greenhouse, Nat. Commun., 11, 1–9, 2020. 
Anand, P., Elderfield, H., and Conte, M. H.: Calibration of Mg/Ca thermometry in planktonic foraminifera from a sediment trap time series, Paleoceanography, 18, 1050, https://doi.org/10.1029/2002PA000846, 2003. 
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Short summary
We evaluate how faithfully the boron isotope composition of foraminifera records atmospheric CO2 by comparing it to the high-fidelity CO2 record from the Antarctic ice cores. We evaluate potential factors and find that partial dissolution of foraminifera shells, assumptions of seawater chemistry, and the biology of foraminifera all have a negligible effect on reconstructed CO2. This gives confidence in the use of boron isotopes beyond the interval when ice core CO2 is available.