Preprints
https://doi.org/10.5194/cp-2024-58
https://doi.org/10.5194/cp-2024-58
10 Sep 2024
 | 10 Sep 2024
Status: this preprint is currently under review for the journal CP.

A question of time and space: A model approach to the synchronicity of gypsum and halite during the Messinian Salinity Crisis

Ronja Monika Ebner and Paul Meijer

Abstract. Saltgiants, although well studies, still offer some unsolved questions. One example is the Messinian Saltgiant which formed during the Messinian Salinity Crisis (MSC, 5.97 to 5.33 Ma) in the Mediterranean Sea. While a common assumption is that gypsum precipitated in the marginal parts of the basin before halite formed in the deeper part of the basin, this could be not yet been confirmed. Indeed, it has also been suggested that, while the primary lower gypsum was forming, the deep basins was already accumulating halite. In this study we use box modeling to investigate the distribution of halite and gypsum deposits for different configurations. Due to a dimensionless description of basin restriction, our results can be transferred to other basins. With this approach we find that under the right conditions all configurations lead to a simultaneous but spatially separated precipitation of gypsum and halite. They would, however, not lead to the spatial pattern that is observed in the Mediterranean, i.e. halite deposition in the deep basins while gypsum is deposited in the margins. Based on those results we propose a timeline for a salinifying basin. For an average salinity above gypsum but below halite saturation, halite is first formed in a sufficiently restricted margin, and only once the average salinity approaches the one of halite saturation can it also form in open areas of the basin due to horizontal salinity gradients. Once the whole basin has reached halite saturation, gypsum only forms in margins with a positive local freshwater budget. Such a mechanism would produce less than 1 m of gypsum within 25 kyr. We thus conclude that a simultaneous, yet spatially separated precipitation of gypsum and halite within a one basin is possible, but unlikely to have led to the massive primary lower gypsum outcrops in the Mediterranean, while halite formed in the deeper parts of the same sub-basin.

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Ronja Monika Ebner and Paul Meijer

Status: open (until 05 Nov 2024)

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Ronja Monika Ebner and Paul Meijer

Model code and software

'a question of time and space' - model code Ronja M. Ebner https://zenodo.org/records/12511228

Ronja Monika Ebner and Paul Meijer

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Short summary
This work explores the spatial distribution of halite and gypsum within saltgiants that formed in a semi-enclosed basin via numerical box models. The results are compared to the Messinian saltgiant, while our description of restriction makes them transferrable to other basins. As such, we propose a general timeline for precipitation patterns. Our results indicate that is unlikely for Gypsum and Halite to precipitate simultaneously but spatially separated without additional internal restriction.