<?xml version="1.0" encoding="UTF-8"?>
<!DOCTYPE article PUBLIC "-//NLM//DTD Journal Publishing DTD v3.0 20080202//EN" "https://jats.nlm.nih.gov/nlm-dtd/publishing/3.0/journalpublishing3.dtd">
<article xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" article-type="research-article" dtd-version="3.0" xml:lang="en">
<front>
<journal-meta>
<journal-id journal-id-type="publisher">CP</journal-id>
<journal-title-group>
<journal-title>Climate of the Past</journal-title>
<abbrev-journal-title abbrev-type="publisher">CP</abbrev-journal-title>
<abbrev-journal-title abbrev-type="nlm-ta">Clim. Past</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1814-9332</issn>
<publisher><publisher-name>Copernicus Publications</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/cp-4-311-2008</article-id>
<title-group>
<article-title>The carbon cycle during the Mid Pleistocene Transition: the Southern Ocean Decoupling Hypothesis</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Köhler</surname>
<given-names>P.</given-names>
<ext-link>https://orcid.org/0000-0003-0904-8484</ext-link>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Bintanja</surname>
<given-names>R.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Alfred Wegener Institute for Polar and Marine Research, PO Box 120161, 27515 Bremerhaven, Germany</addr-line>
</aff>
<aff id="aff2">
<label>2</label>
<addr-line>KNMI (Royal Netherlands Meteorological Institute), Wilhelminalaan 10, 3732 GK De Bilt, Netherlands</addr-line>
</aff>
<pub-date pub-type="epub">
<day>02</day>
<month>12</month>
<year>2008</year>
</pub-date>
<volume>4</volume>
<issue>4</issue>
<fpage>311</fpage>
<lpage>332</lpage>
<permissions>
<copyright-statement>Copyright: &#x000a9; 2008 P. Köhler</copyright-statement>
<copyright-year>2008</copyright-year>
<license license-type="open-access">
<license-p>This work is licensed under the Creative Commons Attribution 3.0 Unported License. To view a copy of this licence, visit <ext-link ext-link-type="uri"  xlink:href="https://creativecommons.org/licenses/by/3.0/">https://creativecommons.org/licenses/by/3.0/</ext-link></license-p>
</license>
</permissions>
<self-uri xlink:href="https://cp.copernicus.org/articles/4/311/2008/cp-4-311-2008.html">This article is available from https://cp.copernicus.org/articles/4/311/2008/cp-4-311-2008.html</self-uri>
<self-uri xlink:href="https://cp.copernicus.org/articles/4/311/2008/cp-4-311-2008.pdf">The full text article is available as a PDF file from https://cp.copernicus.org/articles/4/311/2008/cp-4-311-2008.pdf</self-uri>
<abstract>
<p>Various hypotheses were proposed within recent years for the interpretation
of the Mid Pleistocene Transition (MPT), which occurred during past
2 000 000 years (2 Myr). We here add to already existing theories on the
MPT some data and model-based aspects focusing on the dynamics of the carbon
cycle. We find that the average glacial/interglacial (G/IG) amplitudes in
benthic &amp;delta;&lt;sup&gt;13&lt;/sup&gt;C derived from sediment cores in the deep Pacific ocean increased
across the MPT by ~40%, while similar amplitudes in the global
benthic &amp;delta;&lt;sup&gt;18&lt;/sup&gt;C stack LR04 increased by a factor of two over the same time
interval. The global carbon cycle box model BICYCLE is used for the
interpretation of these observed changes in the carbon cycle. Our simulation
approach is based on regression analyses of various paleo-climatic proxies
with the LR04 benthic &amp;delta;&lt;sup&gt;18&lt;/sup&gt;C stack over the last 740 kyr, which are then used
to extrapolate changing climatic boundary conditions over the whole 2 Myr
time window. The observed dynamics in benthic &amp;delta;&lt;sup&gt;13&lt;/sup&gt;C cannot be explained if
similar relations between LR04 and the individual climate variables are
assumed prior and after the MPT. According to our analysis a model-based
reconstruction of G/IG amplitudes in deep Pacific &amp;delta;&lt;sup&gt;13&lt;/sup&gt;C before the MPT is
possible if we assume a different response to the applied forcings in the
Southern Ocean prior and after the MPT. This behaviour is what we call the
&quot;Southern Ocean Decoupling Hypothesis&quot;. This decoupling might potentially
be caused by a different cryosphere/ocean interaction and thus changes in the
deep and bottom water formation rates in the Southern Ocean before the MPT,
however an understanding from first principles remains elusive. Our
hypothesis is also proposing dynamics in atmospheric &lt;i&gt;p&lt;/i&gt;CO&lt;sub&gt;2&lt;/sub&gt; over the past
2 Myr. Simulated &lt;i&gt;p&lt;/i&gt;CO&lt;sub&gt;2&lt;/sub&gt; is varying between 180 and 260 &amp;mu;atm before the
MPT. The consequence of our Southern Ocean Decoupling Hypothesis is that the
slope in the relationship between Southern Ocean SST and atmospheric &lt;i&gt;p&lt;/i&gt;CO&lt;sub&gt;2&lt;/sub&gt;
is different before and after the MPT, something for which first indications
already exist in the 800 kyr CO&lt;sub&gt;2&lt;/sub&gt; record from the EPICA Dome C ice core. We
finally discuss how our findings are related to other hypotheses on the MPT.</p>
</abstract>
<counts><page-count count="22"/></counts>
</article-meta>
</front>
<body/>
<back>
<ref-list>
<title>References</title>
<ref id="ref1">
<label>1</label><mixed-citation publication-type="other" xlink:type="simple"> Archer, D E., Eshel, G., Winguth, A., Broecker, W., Pierrehumbert, R., Tobis, M., and Jacob, R.: Atmospheric $p$CO&lt;sub&gt;2&lt;/sub&gt; sensitivity to the biological pump in the ocean, Global Biogeochem. Cy., 14, 1219–1230, 2000. </mixed-citation>
</ref>
<ref id="ref2">
<label>2</label><mixed-citation publication-type="other" xlink:type="simple"> Becquey, S. and Gersonde, R.: Past hydrographic and climatic changes in the Subantarctic Zone of the South Atlantic – the Pleistocene record from ODP site 1090, Palaeogeography, Palaeoclimatology, Palaeoecology, 182, 221–239, 2002. </mixed-citation>
</ref>
<ref id="ref3">
<label>3</label><mixed-citation publication-type="other" xlink:type="simple"> Berger, A., Mélice, J L., and Loutre, M F.: On the origin of the 100-kyr cycles in the astronomical forcing, Paleoceanography, 20, PA4019, https://doi.org/10.1029/2005PA001173, 2005. </mixed-citation>
</ref>
<ref id="ref4">
<label>4</label><mixed-citation publication-type="other" xlink:type="simple"> Bickert, T. and Mackensen, A.: Last Glacial to Holocene Changes in South Atlantic Deep Water Circulation, in: The South Atlantic in the Late Quaternary: Reconstruction of Material Budgets and Current Systems, edited by: Wefer, G., Mulitza, S., and Ratmeyer, V., 671–695, Springer-Verlag, Berlin Heidelberg New York Tokyo, 2004. </mixed-citation>
</ref>
<ref id="ref5">
<label>5</label><mixed-citation publication-type="other" xlink:type="simple"> Bintanja, R. and van~de Wal, R. S W.: North American ice-sheet dynamics and the onset of the 100,000-year glacial cycles, Nature, 454, 869–872, https://doi.org/10.1038/nature07158, 2008. </mixed-citation>
</ref>
<ref id="ref6">
<label>6</label><mixed-citation publication-type="other" xlink:type="simple"> Bintanja, R., van~de Wal, R. S W., and Oerlemans, J.: Global ice volume variations through the last glacial cycle simulated by a 3-D ice-dynamics model, Quatern. Int., 95–96, 11–23, 2002. </mixed-citation>
</ref>
<ref id="ref7">
<label>7</label><mixed-citation publication-type="other" xlink:type="simple"> Bintanja, R., van~de Wal, R., and Oerlemans, J.: Modelled atmospheric temperatures and global sea levels over the past million years, Nature, 437, 125–128, https://doi.org/10.1038/nature03975, 2005. </mixed-citation>
</ref>
<ref id="ref8">
<label>8</label><mixed-citation publication-type="other" xlink:type="simple"> Boyle, E A.: Cadmium and $\delta^13$C paleochemical ocean distributions during the stage 2 glacial maximum, Annual Review in Earth and Planetary Sciences, 20, 245–287, 1992. </mixed-citation>
</ref>
<ref id="ref9">
<label>9</label><mixed-citation publication-type="other" xlink:type="simple"> Broecker, W., Lynch-Stieglitz, J., Archer, D., Hofmann, M., Maier-Reimer, E., Marchal, O., Stocker, T., and Gruber, N.: How strong is the Harvardton-Bear constraint?, Global Biogeochem. Cy., 13, 817–820, 1999. </mixed-citation>
</ref>
<ref id="ref10">
<label>10</label><mixed-citation publication-type="other" xlink:type="simple"> Brook, E J., Wolff, E., Dahl-Jensen, D., Fischer, H., and Steig, E J.: The future of ice coring: International Partnership in Ice Core Sciences (IPICS), PAGES News, 14, 6–9, 2006. </mixed-citation>
</ref>
<ref id="ref11">
<label>11</label><mixed-citation publication-type="other" xlink:type="simple"> Clark, P U., Archer, D., Pollard, D., Blum, J D., Rial, J A., Brovkin, V., Mix, A C., Pisias, N G., and Roy, M.: The Middle Pleistocene Transition: characteristics, mechanisms, and implications for long-term changes in atmospheric $p$CO&lt;sub&gt;2&lt;/sub&gt;, Quaternary Sci. Rev., 25, 3150–3184, https://doi.org/10.1016/j.quascirev.2006.07.008, 2007. </mixed-citation>
</ref>
<ref id="ref12">
<label>12</label><mixed-citation publication-type="other" xlink:type="simple"> Curry, W B. and Oppo, D W.: Glacial water mass geometry and the distribution of $\delta^13$C of $\sum$CO&lt;sub&gt;2&lt;/sub&gt; in the western Atlantic Ocean, Paleoceanography, 20, PA1017, https://doi.org/10.1029/2004PA001021, 2005. </mixed-citation>
</ref>
<ref id="ref13">
<label>13</label><mixed-citation publication-type="other" xlink:type="simple"> Emanuel, W R., Killough, G G., Post, W M., and Shugart, H H.: Modeling terrestrial ecosystems in the global carbon cycle with shifts in carbon storage capacity by land-use change, Ecology, 65, 970–983, 1984. </mixed-citation>
</ref>
<ref id="ref14">
<label>14</label><mixed-citation publication-type="other" xlink:type="simple"> EPICA-community-members: Eight glacial cycles from an Antarctic ice core, Nature, 429, 623–628, 2004. </mixed-citation>
</ref>
<ref id="ref15">
<label>15</label><mixed-citation publication-type="other" xlink:type="simple"> Friedlingstein, P., Cox, P., Betts, R., Bopp, L., von Bloh, W., Brovkin, V., Cadule, P., Doney, S., Eby, Fung, I., Bala, G., John, J., Joos, F., Kato, T., Kawamiya, M., Knorr, W., Lindsay, K., Matthews, H D., Raddatz, T., Rayner, P., Reick, C., Roeckner, E., Schnitzler, K.-G., Schnur, R., Strassmann, K., Weaver, A J., Yoshikawa, C., and Zeng, N.: Climate-carbon cycle feedback analysis: results from the C$^4$MIP model intercomparison, J. Climate, 19, 3337–3353, 2006. </mixed-citation>
</ref>
<ref id="ref16">
<label>16</label><mixed-citation publication-type="other" xlink:type="simple"> Gaillardet, J., Dupré, B., Louvat, P., and Allègre, C J.: Global silicate weathering and CO&lt;sub&gt;2&lt;/sub&gt; consumption rates deduced from the chemistry of large rivers, Chemical Geol., 159, 3–30, 1999. </mixed-citation>
</ref>
<ref id="ref17">
<label>17</label><mixed-citation publication-type="other" xlink:type="simple"> Ganachaud, A. and Wunsch, C.: Improved estimates of global ocean circulation, heat transport and mixing from hydrographic data, Nature, 408, 453–457, 2000. </mixed-citation>
</ref>
<ref id="ref18">
<label>18</label><mixed-citation publication-type="other" xlink:type="simple"> Ghil, M., Allen, M R., Dettinger, M D., Ide, K., Kondrashov, D., Mann, M E., Robertson, A W., Saunders, A., Tian, Y., Varadi, F., and Yiou, P.: Advanced spectral methods for climatic time series, Rev. Geophys., 40, 1003, https://doi.org/10.1029/2000RG000092, 2002. </mixed-citation>
</ref>
<ref id="ref19">
<label>19</label><mixed-citation publication-type="other" xlink:type="simple"> Hays, J D., Imbrie, J., and Shackelton, N J.: Variations in the Earth&apos;s Orbit: Pacemaker of the Ice Ages, Science, 194, 1121–1132, 1976. </mixed-citation>
</ref>
<ref id="ref20">
<label>20</label><mixed-citation publication-type="other" xlink:type="simple"> Hellmer, H H.: Impact of Antarctic ice shelf basal melting on sea ice and deep ocean propoerties, Geophys. Res. Lett., 31, L10307, https://doi.org/10.1029/2004GL019506, 2004. </mixed-citation>
</ref>
<ref id="ref21">
<label>21</label><mixed-citation publication-type="other" xlink:type="simple"> Hönisch, B. and Hemming, N G.: Surface ocean pH response to variations in pCO&lt;sub&gt;2&lt;/sub&gt; through two full glacial cycles, Earth Planet. Sci. Lett., 236, 305–314, https://doi.org/10.1016/j.epsl.2005.04.027, 2005. </mixed-citation>
</ref>
<ref id="ref22">
<label>22</label><mixed-citation publication-type="other" xlink:type="simple"> Hoogakker, B. A A., Rohling, E J., Palmer, M R., Tyrrell, T., and Rothwell, R G.: Underlying causes for long-term global ocean fluctuations over the last 1.2 Myr, Earth Planet. Sci. Lett., 248, 15–29; https://doi.org/10.1016/j.epsl.2006.05.007, 2006. </mixed-citation>
</ref>
<ref id="ref23">
<label>23</label><mixed-citation publication-type="other" xlink:type="simple"> Huhn, O., Hellmer, H H., Rhein, M., Rodehacke, C., Roether, W., Schodlok, M P., and Schröder, M.: Evidence of deep- and bottom-water formation in the western Weddell Sea, Deep-Sea Res. II, 55, 1098–1116, https://doi.org/10.1016/j.dsr2.2007.12.015, 2008. </mixed-citation>
</ref>
<ref id="ref24">
<label>24</label><mixed-citation publication-type="other" xlink:type="simple"> Huybers, P.: Glacial variability over the last two million years: an extended depth-derived agemodel, continuous obliquity pacing, and the Pleistocene progression, Quaternary Sci. Rev., 26, 37–55, https://doi.org/10.1016/j.quascirev.2006.07.013, 2007. </mixed-citation>
</ref>
<ref id="ref25">
<label>25</label><mixed-citation publication-type="other" xlink:type="simple"> Imbrie, J., Berger, A., Boyle, E A., Clemens, S C., Duffy, A., Howard, W R., Kukla, G., Kutzbach, J., Martinson, D G., McIntyre, A., Mix, A C., Molfino, B., Morley, J J., Peterson, L C., Pisias, N G., Prell, W L., Raymo, M E., Shackleton, N J., and Toggweiler, J R.: On the structure and origin of major glaciation cycles. 2, The 100,000-year cycle, Paleoceanography, 8, 699–735, 1993. </mixed-citation>
</ref>
<ref id="ref26">
<label>26</label><mixed-citation publication-type="other" xlink:type="simple"> Jin, X., Gruber, N., Dunne, J P., Sarmiento, J L., and Armstrong, R A.: Diagnosing the contribution of phytoplankton functional groups to the production and export of particulate organic carbon, CaCO&lt;sub&gt;3&lt;/sub&gt;, and opal from global nutrient and alkalinity distributions, Global Biogeochem. Cy., 20, GB2015, https://doi.org/10.1029/2005GB002532, 2006. </mixed-citation>
</ref>
<ref id="ref27">
<label>27</label><mixed-citation publication-type="other" xlink:type="simple"> Jouzel, J., Masson-Delmotte, V., Cattani, O., Dreyfus, G., Falourd, S., Hoffmann, G., Minster, B., Nouet, J., Barnola, J M., Chappellaz, J., Fischer, H., Gallet, J C., Johnsen, S., Leuenberger, M., Loulergue, L., Luethi, D., Oerter, H., Parrenin, F., Raisbeck, G., Raynaud, D., Schilt, A., Schwander, J., Selmo, E., Souchez, R., Spahni, R., Stauffer, B., Steffensen, J P., Stenni, B., Stocker, T F., Tison, J L., Werner, M., and Wolff, E W.: Orbital and millennial Antarctic climate variability over the last 800 000 years, Science, 317, 793–796, 10.1126/science.1141038, 2007. </mixed-citation>
</ref>
<ref id="ref28">
<label>28</label><mixed-citation publication-type="other" xlink:type="simple"> Knox, F. and McElroy, M.: Changes in atmospheric CO&lt;sub&gt;2&lt;/sub&gt;: Influence of the marine biota at high latitude, J. Geophys. Res., 89, 4629–4637, 1984. </mixed-citation>
</ref>
<ref id="ref29">
<label>29</label><mixed-citation publication-type="other" xlink:type="simple"> Köhler, P. and Fischer, H.: Simulating changes in the terrestrial biosphere during the last glacial/interglacial transition, Global Planet. Change, 43, 33–55, https://doi.org/10.1016/j.gloplacha.2004.02.005, 2004. </mixed-citation>
</ref>
<ref id="ref30">
<label>30</label><mixed-citation publication-type="other" xlink:type="simple"> Köhler, P. and Fischer, H.: Simulating low frequency changes in atmospheric CO&lt;sub&gt;2&lt;/sub&gt; during the last 740 000 years, Clim. Past, 2, 57–78, 2006. </mixed-citation>
</ref>
<ref id="ref31">
<label>31</label><mixed-citation publication-type="other" xlink:type="simple"> Köhler, P., Fischer, H., Munhoven, G., and Zeebe, R E.: Quantitative interpretation of atmospheric carbon records over the last glacial termination, Global Biogeochem. Cy., 19, GB4020, https://doi.org/10.1029/2004GB002345, 2005. </mixed-citation>
</ref>
<ref id="ref32">
<label>32</label><mixed-citation publication-type="other" xlink:type="simple"> Köhler, P., Fischer, H., Schmitt, J., and Munhoven, G.: On the application and interpretation of Keeling plots in paleo climatic research –- Deciphering \dc of atmospheric \coo measured in ice cores, Biogeosciences, 3, 539–556, 2006a. </mixed-citation>
</ref>
<ref id="ref33">
<label>33</label><mixed-citation publication-type="other" xlink:type="simple"> Köhler, P., Muscheler, R., and Fischer, H.: A model-based interpretation of low frequency changes in the carbon cycle during the last 120 000 years and its implications for the reconstruction of atmospheric $\Delta^14$C, Geochemistry, Geophysics, Geosystems, 7, Q11N06, https://doi.org/10.1029/2005GC001228, 2006b. </mixed-citation>
</ref>
<ref id="ref34">
<label>34</label><mixed-citation publication-type="other" xlink:type="simple"> Kroopnick, P M.: The distribution of $^13$C of $\sum$CO&lt;sub&gt;2&lt;/sub&gt; in the world oceans, Deep-Sea Res. A., 32, 57–84, 1985. </mixed-citation>
</ref>
<ref id="ref35">
<label>35</label><mixed-citation publication-type="other" xlink:type="simple"> Le Quéré, C., Rödenbeck, C., Buitenhuis, E T., Conway, T J., Langenfelds, R., Gomez, A., Labuschagne, C., Ramonet, M., Nakazawa, T., Metzl, N., Gillett, N., and Heimann, M.: Saturation of the Southern Ocean \coo sink due to recent climate change, Science, 316, 1735–1738. https://doi.org/10.1126/science.1136188, 2007. </mixed-citation>
</ref>
<ref id="ref36">
<label>36</label><mixed-citation publication-type="other" xlink:type="simple"> Lisiecki, L E. and Raymo, M E.: A Pliocene-Pleistocene stack of 57 globally distributed benthic $\delta^18$O records, Paleoceanography, 20, PA1003, https://doi.org/10.1029/2004PA001071, 2005. </mixed-citation>
</ref>
<ref id="ref37">
<label>37</label><mixed-citation publication-type="other" xlink:type="simple"> Lisiecki, L E. and Raymo, M E.: Plio-Pleistocene climate evoluation: trends and transitions in glacial cycle dynamics, Quaternary Sci. Rev., 26, 56–89; https://doi.org/10.1016/j.quascirev.2006.09.005, 2007. </mixed-citation>
</ref>
<ref id="ref38">
<label>38</label><mixed-citation publication-type="other" xlink:type="simple"> Liu, Z., Cleaveland, L C., and Herbert, T D.: Early onset and origin of 100-kyr cycles in Pleistocene tropical SST records, Earth Planet. Sci. Lett., 265, 703–715, https://doi.org/10.1016/j.epsl.2007.11.016, 2008. </mixed-citation>
</ref>
<ref id="ref39">
<label>39</label><mixed-citation publication-type="other" xlink:type="simple"> Loulergue, L., Parrenin, F., Blunier, T., Barnola, J.-M., Spahni, R., Schilt, A., Raisbeck, G., and Chappellaz, J.: New constraints on the gas age-ice age difference along the EPICA ice cores, 0-50 kyr, Clim. Past, 3, 527–540, 2007. </mixed-citation>
</ref>
<ref id="ref40">
<label>40</label><mixed-citation publication-type="other" xlink:type="simple"> Lovenduski, N S., Gruber, N., Doney, S C., and Lima, I D.: Enhanced \coo\ outgassing in the Southern Ocean from a positive phase of the Southern Annular Mode, Global Biogeochem. Cy., 21, GB2026, https://doi.org/10.1029/2006GB002900, 2007. </mixed-citation>
</ref>
<ref id="ref41">
<label>41</label><mixed-citation publication-type="other" xlink:type="simple"> Lüthi, D., Floch, M L., Bereiter, B., Blunier, T., Barnola, J.-M., Siegenthaler, U., Raynaud, D., Jouzel, J., Fischer, H., Kawamura, K., and Stocker, T F.: High-resolution \coo concentration record 650 000–800 000 years before present, Nature, 453, 379–382,; https://doi.org/10.1038/nature06949, 2008. </mixed-citation>
</ref>
<ref id="ref42">
<label>42</label><mixed-citation publication-type="other" xlink:type="simple"> Marchitto, T M., Lynch-Stieglitz, J., and Hemming, S R.: Deep Pacific CaCO&lt;sub&gt;3&lt;/sub&gt; compensation and glacial-interglacial atmospheric CO&lt;sub&gt;2&lt;/sub&gt;, Earth Planet. Sci. Lett., 231, 317–336, 2005. </mixed-citation>
</ref>
<ref id="ref43">
<label>43</label><mixed-citation publication-type="other" xlink:type="simple"> Marinov, I., Follows, M., Gnanadesikan, A., Sarmiento, J L., and Slater, R D.: How does ocean biology affect atmospheric \pcoo? Theory and models, J. Geophys. Res., 113, C07032, https://doi.org/10.1029/2007JC004598, 2008. </mixed-citation>
</ref>
<ref id="ref44">
<label>44</label><mixed-citation publication-type="other" xlink:type="simple"> Martin, J H.: Glacial-interglacial CO&lt;sub&gt;2&lt;/sub&gt; change: the iron hypothesis, Paleoceanography, 5, 1–13, 1990. </mixed-citation>
</ref>
<ref id="ref45">
<label>45</label><mixed-citation publication-type="other" xlink:type="simple"> Maslin, M A. and Ridgwell, A J.: Mid-Pleistocene Revolution and the &quot;eccentricity myth&quot;, in: Early-Middle Pleistocene transitions: the land-ocean evidence, edited by: Head, M J. and Gibbard, P L., vol. 247 of Special Publications, 19–34, Geological Society, London, 2005. </mixed-citation>
</ref>
<ref id="ref46">
<label>46</label><mixed-citation publication-type="other" xlink:type="simple"> Milankovitch, M.: Kanon der Erdbestrahlung und seine Anwendung auf das Eiszeitenproblem, Special Publications Vol 132, vol 33 of Section Mathematics and Natural Sciences, Royal Serbian Acadademy, Belgrad, 1941. </mixed-citation>
</ref>
<ref id="ref47">
<label>47</label><mixed-citation publication-type="other" xlink:type="simple"> Mix, A C., Pisias, N G., Rugh, W., Wilson, J., Morey, A., and Hagelberg, T K.: Benthic foraminiferal stable isotope record from site 849 (0–5 Ma): local and global climate changes, in: Proceedings of the Ocean Drilling Program, Scientific Results Vol 138, edited by: Pisias, N G., Mayer, L., Janecek, T., Palmer-Julson, A., and van Andel, T., 371–412, College Station, Texas, USA, 1995. </mixed-citation>
</ref>
<ref id="ref48">
<label>48</label><mixed-citation publication-type="other" xlink:type="simple"> Munhoven, G.: Modelling glacial-interglacial atmospheric CO&lt;sub&gt;2&lt;/sub&gt; variations: the role of continental weathering, Ph.D. thesis, Université de Liège, Liège, Belgium, 1997. </mixed-citation>
</ref>
<ref id="ref49">
<label>49</label><mixed-citation publication-type="other" xlink:type="simple"> Munhoven, G.: Glacial-interglacial changes of continental weathering: estimates of the related CO&lt;sub&gt;2&lt;/sub&gt; and HCO$_3^-$ flux variations and their uncertainties, Global Planet. Change, 33, 155–176, 2002. </mixed-citation>
</ref>
<ref id="ref50">
<label>50</label><mixed-citation publication-type="other" xlink:type="simple"> Munhoven, G. and François, L M.: Glacial-interglacial variability of atmospheric CO&lt;sub&gt;2&lt;/sub&gt; due to changing continental silicate rock weathering: a model study, J. Geophys. Res., 101(D16), 21 423–21 437, 1996. </mixed-citation>
</ref>
<ref id="ref51">
<label>51</label><mixed-citation publication-type="other" xlink:type="simple"> Parekh, P., Joos, F., and Müller, S A.: The interplay between aeolian iron fluxes and ligands in controlling carbon dioxide fluctuations during Antarctic warm events, Paleoceanography, 23, PA4202, https://doi.org/10.1029/2007PA001531, 2008. </mixed-citation>
</ref>
<ref id="ref52">
<label>52</label><mixed-citation publication-type="other" xlink:type="simple"> Parrenin, F., Barnola, J.-M., Beer, J., Blunier, T., Castellano, E., Chappellaz, J., Dreyfus, G., Fischer, H., Fujita, S., Jouzel, J., Kawamura, K., Lemieux-Dudon, B., Loulergue, L., Masson-Delmotte, V., Narcisi, B., Petit, J.-R., Raisbeck, G., Raynaud, D., Ruth, U., Schwander, J., Severi, M., Spahni, R., Steffensen, J. P., Svensson, A., Udisti, R., Waelbroeck, C., and Wolff, E.: The EDC3 chronology for the EPICA Dome C ice core, Clim. Past, 3, 485–497, 2007a. </mixed-citation>
</ref>
<ref id="ref53">
<label>53</label><mixed-citation publication-type="other" xlink:type="simple"> Parrenin, F., Loulergue, L., and Wolff, E.: EPICA Dome C Ice Core Timescales EDC3, vol. # 2007-083 of Data Contribution Series, IGBP PAGES/World Data Center for Paleoclimatology, NOAA/NCDC Paleoclimatology Program, Boulder CO, USA, 2007b. </mixed-citation>
</ref>
<ref id="ref54">
<label>54</label><mixed-citation publication-type="other" xlink:type="simple"> Petit, J R., Jouzel, J., Raynaud, D., Barkov, N I., Barnola, J.-M., Basile, I., Bender, M., Chappellaz, J., Davis, M., Delaygue, G., Delmotte, M., Kotlyakov, V M., Legrand, M., Lipenkov, V Y., Lorius, C., Pépin, L., Ritz, C., Saltzman, E., and Stievenard, M.: Climate and atmospheric history of the past 420 000 years from the Vostok ice core, Antarctica, Nature, 399, 429–436, 1999. </mixed-citation>
</ref>
<ref id="ref55">
<label>55</label><mixed-citation publication-type="other" xlink:type="simple"> Pisias, N G. and Moore Jr., T C.: The evolution of Pleistocene climate: a time series approach, Earth Planet. Sci. Lett., 52, 450–458, 1981. </mixed-citation>
</ref>
<ref id="ref56">
<label>56</label><mixed-citation publication-type="other" xlink:type="simple"> Raymo, M E., Oppo, D W., and Curry, W.: The mid-Pleistocence climate transition: a deep sea carbon isotopic perspective, Paleoceanography, 12, 546–559, 1997. </mixed-citation>
</ref>
<ref id="ref57">
<label>57</label><mixed-citation publication-type="other" xlink:type="simple"> Raymo, M E., Oppo, D W., Flower, B P., Hodell, D A., McManus, J F., Venz, K A., Kleiven, K F., and McIntyre, K.: Stability of North Atlantic water masses in face of pronounced climate variability during the Pleistocene, Paleoceanography, 19, PA2008, https://doi.org/10.1029/2003PA000921, 2004. </mixed-citation>
</ref>
<ref id="ref58">
<label>58</label><mixed-citation publication-type="other" xlink:type="simple"> Raymo, M E., Lisiecki, L E., and Nisancioglu, K H.: Plio-Pleistocene ice volume, Antarctic climate, and the global $\delta^18$O record, Science, 313, 492–495; https://doi.org/10.1126/science.1123296, 2006. </mixed-citation>
</ref>
<ref id="ref59">
<label>59</label><mixed-citation publication-type="other" xlink:type="simple"> Sarmiento, J L. and Toggweiler, J R.: A new model for the role of the oceans in determining atmospheric $P_\rm CO_2$, Nature, 308, 621–624, 1984. </mixed-citation>
</ref>
<ref id="ref60">
<label>60</label><mixed-citation publication-type="other" xlink:type="simple"> Schlitzer, R.: Electronic atlas of WOCE hydrographic and tracer data now available, Eos, 81, 45, 2000. </mixed-citation>
</ref>
<ref id="ref61">
<label>61</label><mixed-citation publication-type="other" xlink:type="simple"> Schulz, K G. and Zeebe, R E.: Pleistocene glacial terminations triggered by synchronous changes in Southern and Northern Hemisphere insolation: The insolation canon hypothesis, Earth Planet. Sci. Lett., 249, 326–336; https://doi.org/10.1016/j.epsl.2006.07.004, 2006. </mixed-citation>
</ref>
<ref id="ref62">
<label>62</label><mixed-citation publication-type="other" xlink:type="simple"> Shackleton, N.: The 100 000-year ice-age cycle identified and found to lag temperature, carbon dioxide, and orbital eccentricity, Science, 289, 1897–1902, 2000. </mixed-citation>
</ref>
<ref id="ref63">
<label>63</label><mixed-citation publication-type="other" xlink:type="simple"> Shackleton, N J. and Opdyke, N D.: Oxygen-isotope amd paleomagnetic stratigraphy of Pacific core V28-239: Late Pliocene to latest Pleistocene, in: Investigation of Late Quaternary Paleoceanography, and Paleoclimatology, edited by: Cline, R M. and Hays, J D., vol. 145 of Geological Society of America Memoir, 449–464, 1976. </mixed-citation>
</ref>
<ref id="ref64">
<label>64</label><mixed-citation publication-type="other" xlink:type="simple"> Shackleton, N J., Berger, A., and Peltier, W P.: An alternative astronomical calibration of the lower Pleistocene timescale based on OPD site 677, Transactions of the Royal Society of Edinburgh: Earth Sciences, 81, 251–261, 1990. </mixed-citation>
</ref>
<ref id="ref65">
<label>65</label><mixed-citation publication-type="other" xlink:type="simple"> Siegenthaler, U. and Wenk, T.: Rapid atmospheric CO&lt;sub&gt;2&lt;/sub&gt; variations and ocean circulation, Nature, 308, 624–626, 1984. </mixed-citation>
</ref>
<ref id="ref66">
<label>66</label><mixed-citation publication-type="other" xlink:type="simple"> Siegenthaler, U., Stocker, T F., Monnin, E., Lüthi, D., Schwander, J., Stauffer, B., Raynaud, D., Barnola, J.-M., Fischer, H., Masson-Delmotte, V., and Jouzel, J.: Stable carbon cycle-climate relationship during the late Pleistocene, Science, 310, 1313–1317, https://doi.org/10.1126/science.1120130, 2005. </mixed-citation>
</ref>
<ref id="ref67">
<label>67</label><mixed-citation publication-type="other" xlink:type="simple"> Stephens, B B. and Keeling, R F.: The influence of Antarctic sea ice on glacial-interglacial CO&lt;sub&gt;2&lt;/sub&gt; variations, Nature, 404, 171–174, 2000. </mixed-citation>
</ref>
<ref id="ref68">
<label>68</label><mixed-citation publication-type="other" xlink:type="simple"> Swingedouw, D., Fichefet, T., Huybrechts, P., Goosse, H., Driesschaert, E., and Loutre, M.-F.: Antarctic ice-sheet melting provides negative feedbacks on future climate warming, Geophys. Res. Lett., 35, L17705, https://doi.org/10.1029/2008GL034410, 2008. </mixed-citation>
</ref>
<ref id="ref69">
<label>69</label><mixed-citation publication-type="other" xlink:type="simple"> Toggweiler, J R., l Russell, J., and Carson, S R.: Midlatitude westerlies, atmospheric CO&lt;sub&gt;2&lt;/sub&gt;, and climate change during the ice ages, Paleoceanography, 21, PA2005; https://doi.org/10.1029/2005PA001154, 2006. </mixed-citation>
</ref>
<ref id="ref70">
<label>70</label><mixed-citation publication-type="other" xlink:type="simple"> Tschumi, T., Joos, F., and Parekh, P.: How important are Southern Hemisphere wind changes for low glacial carbon dioxide? A model study, Paleoceanography, 23, PA4208, https://doi.org/10.1029/2008PA001592, 2008. </mixed-citation>
</ref>
<ref id="ref71">
<label>71</label><mixed-citation publication-type="other" xlink:type="simple"> Venz, K A. and Hodell, D A.: New evidence for changes in Plio-Pleistocene deep water circulation from Southern Ocean ODP Leg 177 Site 1090, Palaeogeography, Palaeoclimatology, Palaeoecology, 182, 197–220, 2002. </mixed-citation>
</ref>
<ref id="ref72">
<label>72</label><mixed-citation publication-type="other" xlink:type="simple"> Wang, P., Tian, J., Cheng, X., Liu, C., and Xu, J.: Major Pleistocene stages in a carbon perspective: The South China Sea record and its global comparison, Paleoceanography, 19, PA4005, https://doi.org/10.1029/2003PA000991, 2004. </mixed-citation>
</ref>
<ref id="ref73">
<label>73</label><mixed-citation publication-type="other" xlink:type="simple"> Wang, P X.: Feeling the Earth&apos;s pulse from global monsoon records, Geophys. Res. A., 9, 05820; SRef–ID: 1607–7962/gra/EGU2007–A–05820, 2007. </mixed-citation>
</ref>
<ref id="ref74">
<label>74</label><mixed-citation publication-type="other" xlink:type="simple"> Watson, A J. and Naveira-Garabato, A C.: The role of Southern Ocean mixing and upwelling in glacial-interglacial atmospheric CO&lt;sub&gt;2&lt;/sub&gt; change, Tellus B, 58B, 73–87, 2006. </mixed-citation>
</ref>
<ref id="ref75">
<label>75</label><mixed-citation publication-type="other" xlink:type="simple"> Wolff, E W., Chappellaz, J A., Fischer, H., Krull, C., Miller, H., Stocker, T., and Watson, A J.: The EPICA challenge to the Earth System Modeling Community, EOS, 85, 363, 2004. </mixed-citation>
</ref>
<ref id="ref76">
<label>76</label><mixed-citation publication-type="other" xlink:type="simple"> Wolff, E W., Kull, C., Chappellaz, J., Fischer, H., Miller, H., Stocker, T F., Watson, A J., Flower, B., Joos, F., Köhler, P., Matsumoto, K., Monnin, E., Mudelsee, M., Paillard, D., and Shackleton, N.: Modeling past atmospheric CO&lt;sub&gt;2&lt;/sub&gt;: results of a challenge, EOS, 86(38), p 341, p 345, 2005. </mixed-citation>
</ref>
<ref id="ref77">
<label>77</label><mixed-citation publication-type="other" xlink:type="simple"> Wolff, E W., Fischer, H., Fundel, F., Ruth, U., Twarloh, B., Littot, G C., Mulvaney, R., Röthlisberger, R., de~Angelis, M., Boutron, C F., Hansson, M., Jonsell, U., Hutterli, M., Lambert, F., Kaufmann, P., Stauffer, B., Stocker, T F., Steffensen, J P., Bigler, M., Siggaard-Andersen, M L., Udisti, R., Becagli, S., Castellano, E., Severi, M., Wagenbach, D., Barbante, C., Gabrielli, P., and Gaspari, V.: Southern Ocean sea-ice extent, productivity and iron fluxes over the past eight glacial cycles, Nature, 440, 491–496, https://doi.org/10.1038/nature04614, 2006. </mixed-citation>
</ref>
<ref id="ref78">
<label>78</label><mixed-citation publication-type="other" xlink:type="simple"> Zeebe, R E., and Caldeira, K.: Close mass balance of long-term carbon fluxes from ice-core \coo and ocean chemistry records, Nature Geoscience, 1, 312–315; https://doi.org/10.1038/ngeo185, 2008. </mixed-citation>
</ref>
</ref-list>
</back>
</article>