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  <front>
    <journal-meta><journal-id journal-id-type="publisher">CP</journal-id><journal-title-group>
    <journal-title>Climate of the Past</journal-title>
    <abbrev-journal-title abbrev-type="publisher">CP</abbrev-journal-title><abbrev-journal-title abbrev-type="nlm-ta">Clim. Past</abbrev-journal-title>
  </journal-title-group><issn pub-type="epub">1814-9332</issn><publisher>
    <publisher-name>Copernicus Publications</publisher-name>
    <publisher-loc>Göttingen, Germany</publisher-loc>
  </publisher></journal-meta>
    <article-meta>
      <article-id pub-id-type="doi">10.5194/cp-16-1565-2020</article-id><title-group><article-title>Bipolar volcanic synchronization of abrupt climate change in Greenland and Antarctic ice cores during the last glacial period</article-title><alt-title>Bipolar volcanic synchronization of abrupt climate change</alt-title>
      </title-group><?xmltex \runningtitle{Bipolar volcanic synchronization of abrupt climate change}?><?xmltex \runningauthor{A. Svensson et al.}?>
      <contrib-group>
        <contrib contrib-type="author" corresp="yes" rid="aff1">
          <name><surname>Svensson</surname><given-names>Anders</given-names></name>
          <email>as@gfy.ku.dk</email>
        <ext-link>https://orcid.org/0000-0002-4364-6085</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>Dahl-Jensen</surname><given-names>Dorthe</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>Steffensen</surname><given-names>Jørgen Peder</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>Blunier</surname><given-names>Thomas</given-names></name>
          
        <ext-link>https://orcid.org/0000-0002-6065-7747</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>Rasmussen</surname><given-names>Sune O.</given-names></name>
          
        <ext-link>https://orcid.org/0000-0002-4177-3611</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>Vinther</surname><given-names>Bo M.</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1 aff2">
          <name><surname>Vallelonga</surname><given-names>Paul</given-names></name>
          
        <ext-link>https://orcid.org/0000-0003-1055-7235</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>Capron</surname><given-names>Emilie</given-names></name>
          
        <ext-link>https://orcid.org/0000-0003-0784-1884</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>Gkinis</surname><given-names>Vasileios</given-names></name>
          
        <ext-link>https://orcid.org/0000-0002-5910-1549</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>Cook</surname><given-names>Eliza</given-names></name>
          
        <ext-link>https://orcid.org/0000-0001-7927-7974</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>Kjær</surname><given-names>Helle Astrid</given-names></name>
          
        <ext-link>https://orcid.org/0000-0002-3781-9509</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff3">
          <name><surname>Muscheler</surname><given-names>Raimund</given-names></name>
          
        <ext-link>https://orcid.org/0000-0003-2772-3631</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1 aff4">
          <name><surname>Kipfstuhl</surname><given-names>Sepp</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff4">
          <name><surname>Wilhelms</surname><given-names>Frank</given-names></name>
          
        <ext-link>https://orcid.org/0000-0001-7688-3135</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff5">
          <name><surname>Stocker</surname><given-names>Thomas F.</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff5">
          <name><surname>Fischer</surname><given-names>Hubertus</given-names></name>
          
        <ext-link>https://orcid.org/0000-0002-2787-4221</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff3 aff5">
          <name><surname>Adolphi</surname><given-names>Florian</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff5">
          <name><surname>Erhardt</surname><given-names>Tobias</given-names></name>
          
        <ext-link>https://orcid.org/0000-0002-6683-6746</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff5">
          <name><surname>Sigl</surname><given-names>Michael</given-names></name>
          
        <ext-link>https://orcid.org/0000-0002-9028-9703</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff6">
          <name><surname>Landais</surname><given-names>Amaelle</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff7">
          <name><surname>Parrenin</surname><given-names>Frédéric</given-names></name>
          
        <ext-link>https://orcid.org/0000-0002-9489-3991</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff8">
          <name><surname>Buizert</surname><given-names>Christo</given-names></name>
          
        <ext-link>https://orcid.org/0000-0002-2227-1747</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff9">
          <name><surname>McConnell</surname><given-names>Joseph R.</given-names></name>
          
        <ext-link>https://orcid.org/0000-0001-9051-5240</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff10">
          <name><surname>Severi</surname><given-names>Mirko</given-names></name>
          
        <ext-link>https://orcid.org/0000-0003-1511-6762</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff11">
          <name><surname>Mulvaney</surname><given-names>Robert</given-names></name>
          
        <ext-link>https://orcid.org/0000-0002-5372-8148</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff5">
          <name><surname>Bigler</surname><given-names>Matthias</given-names></name>
          
        <ext-link>https://orcid.org/0000-0003-0184-4013</ext-link></contrib>
        <aff id="aff1"><label>1</label><institution>Physics of Ice, Climate and Earth, Niels Bohr Institute, University of Copenhagen, Copenhagen, Denmark</institution>
        </aff>
        <aff id="aff2"><label>2</label><institution>Oceans Institute, University of Western Australia, Crawley, WA,
Australia</institution>
        </aff>
        <aff id="aff3"><label>3</label><institution>Quaternary Sciences, Department of Geology, Lund University, Lund,
Sweden</institution>
        </aff>
        <aff id="aff4"><label>4</label><institution>Stiftung Alfred-Wegener-Institut für Polar- und Meeresforschung, Bremerhaven, Germany</institution>
        </aff>
        <aff id="aff5"><label>5</label><institution>Climate and Environmental Physics, Physics Institute &amp; Oeschger
Centre for Climate Change Research,<?xmltex \hack{\break}?> University of Bern, Bern, Switzerland</institution>
        </aff>
        <aff id="aff6"><label>6</label><institution>Laboratoire des Sciences du Climat et de l'Environnement, IPSL, UMR
8212,<?xmltex \hack{\break}?> CEA-CNRS-UVSQ-UPS, Gif sur Yvette, France</institution>
        </aff>
        <aff id="aff7"><label>7</label><institution>Université Grenoble Alpes, CNRS, IRD, IGE, Grenoble, France</institution>
        </aff>
        <aff id="aff8"><label>8</label><institution>College of Earth, Ocean and Atmospheric Sciences, Oregon State
University, Corvallis, OR, USA</institution>
        </aff>
        <aff id="aff9"><label>9</label><institution>Desert Research Institute, Nevada System of Higher Education, Reno,
NV, USA</institution>
        </aff>
        <aff id="aff10"><label>10</label><institution>Department of Chemistry “Ugo Schiff”, University of Florence,
Florence, Italy</institution>
        </aff>
        <aff id="aff11"><label>11</label><institution>British Antarctic Survey, Cambridge, UK</institution>
        </aff>
      </contrib-group>
      <author-notes><corresp id="corr1">Anders Svensson (as@gfy.ku.dk)</corresp></author-notes><pub-date><day>19</day><month>August</month><year>2020</year></pub-date>
      
      <volume>16</volume>
      <issue>4</issue>
      <fpage>1565</fpage><lpage>1580</lpage>
      <history>
        <date date-type="received"><day>16</day><month>March</month><year>2020</year></date>
           <date date-type="rev-request"><day>6</day><month>April</month><year>2020</year></date>
           <date date-type="accepted"><day>14</day><month>July</month><year>2020</year></date>
      </history>
      <permissions>
        <copyright-statement>Copyright: © 2020 </copyright-statement>
        <copyright-year>2020</copyright-year>
      <license license-type="open-access"><license-p>This work is licensed under the Creative Commons Attribution 4.0 International License. To view a copy of this licence, visit <ext-link ext-link-type="uri" xlink:href="https://creativecommons.org/licenses/by/4.0/">https://creativecommons.org/licenses/by/4.0/</ext-link></license-p></license></permissions><self-uri xlink:href="https://cp.copernicus.org/articles/.html">This article is available from https://cp.copernicus.org/articles/.html</self-uri><self-uri xlink:href="https://cp.copernicus.org/articles/.pdf">The full text article is available as a PDF file from https://cp.copernicus.org/articles/.pdf</self-uri>
      <abstract><title>Abstract</title>
    <?pagebreak page1566?><p id="d1e380">The last glacial period is characterized by a number of millennial climate
events that have been identified in both Greenland and Antarctic ice cores
and that are abrupt in Greenland climate records. The mechanisms governing
this climate variability remain a puzzle that requires a precise
synchronization of ice cores from the two hemispheres to be resolved.
Previously, Greenland and Antarctic ice cores have been synchronized
primarily via their common records of gas concentrations or isotopes from
the trapped air and via cosmogenic isotopes measured on the ice. In this
work, we apply ice core volcanic proxies and annual layer counting to
identify large volcanic eruptions that have left a signature in both
Greenland and Antarctica. Generally, no tephra is associated with those
eruptions in the ice cores, so the source of the eruptions cannot be
identified. Instead, we identify and match sequences of volcanic eruptions
with bipolar distribution of sulfate, i.e. unique patterns of volcanic
events separated by the same number of years at the two poles. Using this
approach, we pinpoint 82 large bipolar volcanic eruptions throughout the
second half of the last glacial period (12–60 ka). This
improved ice core synchronization is applied to determine the bipolar
phasing of abrupt climate change events at decadal-scale precision. In
response to Greenland abrupt climatic transitions, we find a response in the
Antarctic water isotope signals (<inline-formula><mml:math id="M1" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> and deuterium excess)
that is both more immediate and more abrupt than that found with previous
gas-based interpolar synchronizations, providing additional support for our
volcanic framework. On average, the Antarctic bipolar seesaw climate
response lags the midpoint of Greenland abrupt <inline-formula><mml:math id="M2" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> transitions
by <inline-formula><mml:math id="M3" display="inline"><mml:mrow><mml:mn mathvariant="normal">122</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">24</mml:mn></mml:mrow></mml:math></inline-formula> years. The time difference between Antarctic signals in
deuterium excess and <inline-formula><mml:math id="M4" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula>, which likewise informs the time
needed to propagate the signal as described by the theory of the bipolar
seesaw but is less sensitive to synchronization errors, suggests an
Antarctic <inline-formula><mml:math id="M5" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> lag behind Greenland of <inline-formula><mml:math id="M6" display="inline"><mml:mrow><mml:mn mathvariant="normal">152</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">37</mml:mn></mml:mrow></mml:math></inline-formula> years.
These estimates are shorter than the 200 years suggested by earlier
gas-based synchronizations. As before, we find variations in the timing and
duration between the response at different sites and for different events
suggesting an interaction of oceanic and atmospheric teleconnection patterns
as well as internal climate variability.</p>
  </abstract>
    </article-meta>
  </front>
<body>
      

<sec id="Ch1.S1" sec-type="intro">
  <label>1</label><title>Introduction</title>
      <p id="d1e469">Greenland and Antarctic ice cores provide high-resolution records of abrupt
climate events occurring throughout the last glacial period (11.7–115 ka). In Greenland ice cores, Dansgaard–Oeschger (DO) events describe a
series of characteristic climate events (Dansgaard et al., 1993; North
Greenland Ice Core Project members, 2004) that involve warming transitions
of up to 16.5 <inline-formula><mml:math id="M7" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C (Kindler et al., 2014) occurring within
decades (Erhardt et al., 2019). Each DO event consists of a
relatively mild climatic period, referred to as a Greenland Interstadial
(GI), that is followed by a cold climatic period, known as a Greenland
Stadial (GS). The duration of GIs and GSs range from centuries to millennia.
Detailed investigation of the stratigraphy of the 25 major DO events
originally identified has revealed that some of the events are composed of
several separate warming and cooling events, leading to a total of 31–33
abrupt warming events during the last glacial period depending on the
definition employed
(Rasmussen et al.,
2014). Whereas the onset of a GI event is abrupt and occurs in less than a
century, the cooling transitions from GI to GS are more gradual and
typically occur over several centuries. DO events are believed to originate
in the North Atlantic but have a global climatic impact that is documented
in a wide range of paleoclimate archives across the Northern (Voelker
and workshop participants, 2002) and Southern Hemispheres
(Pedro et al., 2018). In Antarctic ice cores, the
corresponding Antarctic Isotopic Maxima (AIM) are characteristic warm events
that are more gradual and of smaller amplitude than the Greenland events
(EPICA community members, 2006). The AIMs are believed to be related to
the DO events through the so-called bipolar seesaw mechanism
(Bender et al., 1994; Stocker and Johnsen, 2003), but the
detailed mechanism is a matter of debate (Landais et al., 2015; Pedro et
al., 2018). Knowledge of the exact phasing of climate in the two hemispheres
is crucial for deciphering the driving mechanism of the abrupt climate
variability of the last glacial period and the climatic teleconnection
patterns that connect the two hemispheres.</p>
      <p id="d1e481">Three different techniques have been applied to progressively improve the
synchronization of Greenland and Antarctic ice cores: globally well-mixed
atmospheric gases – in particular the methane concentration (Blunier et
al., 1998; Lemieux-Dudon et al., 2010; Rhodes et al., 2015; WAIS Divide
Project Members, 2015) and the isotopic compositions of O<inline-formula><mml:math id="M8" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula> – <inline-formula><mml:math id="M9" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula><inline-formula><mml:math id="M10" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">atm</mml:mi></mml:msub></mml:math></inline-formula> (Bender et al., 1994; Capron et al., 2010), cosmogenic
isotopes such as <inline-formula><mml:math id="M11" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">10</mml:mn></mml:msup><mml:mi mathvariant="normal">Be</mml:mi></mml:mrow></mml:math></inline-formula> (Raisbeck et al., 2017; Steinhilber et al.,
2012), and the identification of large volcanic eruptions with bipolar sulfate
deposition (Sigl et al., 2013; Svensson et al., 2013). A strength of the
bipolar methane matching approach is that atmospheric methane concentrations
change almost in phase with abrupt Greenland climate change allowing for
those events to be synchronized in ice cores. A weakness of the bipolar gas
matching approach is the dependency on a precise determination of the
so-called <inline-formula><mml:math id="M12" display="inline"><mml:mi mathvariant="normal">Δ</mml:mi></mml:math></inline-formula>age that refers to the offset in age between the ice and
the air enclosed in an ice core at a given depth (Blunier et
al., 2007; Schwander and Stauffer, 1984). Modelling past <inline-formula><mml:math id="M13" display="inline"><mml:mi mathvariant="normal">Δ</mml:mi></mml:math></inline-formula>age
requires an understanding of the physical processes taking place in the firn
as well as knowledge or assumptions about past accumulation and temperature
variations, introducing substantial age uncertainties associated with the
synchronization.</p>
      <p id="d1e540">Cosmogenic isotope production rates are modulated by the Earth's magnetic
field and by solar variability, and they therefore carry a global signal
that is shared by Greenland and Antarctic cosmogenic ice core records.
Bipolar ice core synchronization using cosmogenic isotopes has mostly been
done in the Holocene (Mekhaldi et al., 2015; Sigl et al., 2015;
Steinhilber et al., 2012) and around the geomagnetic Laschamp event that
occurred some 41 kyr ago (Raisbeck et al., 2017, 2007).
Furthermore, the ice core cosmogenic signal enables the comparison with
<inline-formula><mml:math id="M14" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">14</mml:mn></mml:msup><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula> records of other archives, such as dendrochronologies (Adolphi
and Muscheler, 2016; Sigl et al., 2016) and stalagmites
(Adolphi et al., 2018). Weaknesses of this technique
include the sparsity of significant events, climatic influences on
radionuclide transport and deposition masking the cosmogenic signal, and the
very costly and time-consuming analyses that limit the possibility of
obtaining continuous high-resolution records. Furthermore, archive noise in
the ice core records hampers unambiguous peak detection and synchronization.</p>
      <p id="d1e555">This study focuses on volcanic bipolar synchronization of ice cores in the
second half of the last glacial period (12–60 ka). The volcanic record of
the last glacial period in Greenland ice cores includes more than 100 confirmed Icelandic and high-latitude eruptions that have left predominantly
cryptotephra (invisible to the naked eye) deposits in the ice (Abbott and
Davies, 2012; Bourne et al., 2015; Cook et al., 2020); and there are presumably many more Icelandic eruptions that have not been identified as
such. In addition to those, a large number of more distant eruptions have
left an acidity signature in the ice cores but no tephra
(Zielinski et al., 1997). In fact, during the last glacial
only tephra from mid- and high-latitude eruptions has been identified in
Greenland, whereas, to date, there is no evidence of tropical, low-latitude,
or even continental European tephra in Greenland. Whether the lower-latitude
tephra never makes it to Greenland or whether it is too small to be
identified by conventional optical microscopy techniques and thus masked<?pagebreak page1567?> by
more abundant, similar-sized background dust of continental origin is an
open question.</p>
      <p id="d1e559">In Antarctica, there are many visible tephra layers of Antarctic origin as
well as a large number of acidity spikes associated with more distant
eruptions (Narcisi et al., 2017; Severi et al., 2007). It has been
proposed that tephra of tropical origin is present in the WAIS Divide ice
core, but the evidence is solely based on dust size distributions and not on
geochemical fingerprinting (Koffman et al., 2013). A
pioneering study has suggested to have identified a bipolar tephra at around
1257 CE (Palais et al., 1992), and there is recent support for
that conclusion suggesting that the source is the Indonesian Samalas volcano
(Lavigne et al., 2013).</p>
      <p id="d1e562">Although the ice core records lack bipolar tephra layers they do hold
evidence of volcanic eruptions that are powerful enough to leave sulfuric
acid in the stratosphere, from where it may be distributed to both Greenland
and Antarctica. More than 80 such events have been identified for the last
2500 years (Sigl et al., 2015). For the
earlier part of the Holocene, which has been less intensely studied, some 75
bipolar events have been found (Veres et al.,
2013), and from around the time of the Indonesian Toba eruption occurring in
Sumatra some 74 kyr ago, a handful of bipolar volcanic events have been
identified (Svensson et al.,
2013). Recently, there has been progress in identifying stratospheric
volcanic peaks in ice cores based on their sulfur isotopic fingerprints
(Burke et al., 2019; Gautier et al., 2019). In this work, we expand the
bipolar volcanic matching approach systematically throughout the 12–60 ka
time interval.</p>
</sec>
<sec id="Ch1.S2">
  <label>2</label><title>Methods</title>
      <p id="d1e573">The approach taken to synchronize Greenland and Antarctic ice cores is to
identify large volcanic eruptions with a bipolar acidity or sulfur or sulfate
signature. Because such events generally do not leave tephra in ice cores
from both polar regions, individual eruptions cannot be matched
geochemically between the two hemispheres, as there is no way to verify that
they have the same source. What can be matched up, however, are sequences of
eruptions that show the same relative timing in both Greenland and
Antarctica. To determine the time interval between eruptions, and thereby
the relative timing of events, annual layer counting is carried out over the
volcanic sequence in both Greenland and Antarctic ice cores. When identical
volcanic peak patterns are identified in north and south, it is seen as a
strong indication of a bipolar link. There is, however, always a risk of
making an incorrect link, because an assumed volcanic sequence could consist
of regional (non-bipolar) eruptions with coincidental similar temporal
spacing.</p>
      <p id="d1e576">The peak heights of the recorded eruption intensities in a bipolar volcanic
ice core sequence cannot be expected to be similar at the two poles, because
the strength of the recorded signal depends on the geographical location of
the eruption, the atmospheric circulation at the time of the eruption, and
the variability in deposition of acids at the ice coring sites
(Gautier et al., 2016). Furthermore, the annual layer counting
comes with an uncertainty that adds to the possibility of making an
incorrect bipolar match (Rasmussen et al.,
2006). On the other hand, the bipolar timing of Greenland and Antarctic ice
core records is already well constrained by existing gas- and
<inline-formula><mml:math id="M15" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">10</mml:mn></mml:msup><mml:mi mathvariant="normal">Be</mml:mi></mml:mrow></mml:math></inline-formula>-based bipolar synchronizations. At the onset of each GI, the
uncertainty in the bipolar methane matching between the Greenland NGRIP and
the Antarctic WDC ice cores is around a century (WAIS Divide Project
Members, 2015), which constrains the time windows for matching of bipolar
volcanic sequences. Similarly, the cosmogenic isotope link around the time
of the Laschamp event firmly constrains the volcanic matching in that time
period (Raisbeck et al., 2017). Therefore, the
risk of making false bipolar volcanic matches is strongly reduced by the
existing bipolar synchronization.</p>
      <p id="d1e591">We perform annual layer counting in sections of the Greenland NGRIP
(North Greenland Ice Core Project members, 2004) and the Antarctic EPICA
(European Project for Ice Coring in Antarctica) Dronning Maud Land (EDML)
(EPICA community members, 2006) ice cores using high-resolution records
of chemical impurities (Bigler, 2004; Ruth et al., 2008), dust (Ruth
et al., 2003; Wegner et al., 2015), and visual grey-scale intensity
(Faria et al., 2018; Svensson et al., 2005). The approach is the same as
that applied for the glacial section of the Greenland Ice core Chronology
2005 (GICC05) (Andersen et al., 2006; Svensson et al., 2008). For this
study, most sections of the NGRIP ice core have been recounted, and the
Greenland timescale has been slightly modified as the bipolar matching
allows for obtaining an improved precision from annual counting in both
NGRIP and EDML. For most of the glacial period, the EDML ice core has not
previously been layer-counted, but for the investigated time interval the
annual layer thicknesses are comparable to those of NGRIP
(Veres et al., 2013) and layer counting can be
done in a similar way. Examples of annual layer counting in NGRIP and EDML
across four intervals applied to match up patterns of bipolar volcanic
eruptions are shown in Figs. S17–S20 in the Supplement. The WAIS Divide ice core chronology
2014 (WD2014) timescale has been applied for guidance, and for most of the
intervals within the layer-counted section of WD2014 there is agreement
within error estimates between the EDML and WDC interval durations. The
bipolar layer counting is not continuous but is focused on periods of
abrupt climate variability or high volcanic activity. In order to allow for
comparison to published records, ages in all tables and figures have been
converted to GICC05 ages using the year 2000 CE as a datum (referred to as
“b2k”). We note that ages published on the Antarctic Ice Core Chronology
2012 (AICC2012) or the WD2014 timescale use the year 1950 CE as a datum, and
so ages reported relative to b2k will be 50 years greater than those in
AICC2012 and WD2014.</p>
      <?pagebreak page1568?><p id="d1e594">In order to obtain a robust identification of volcanic sequences in the ice
cores, all available acidity records from the Greenland GRIP
(Wolff et al., 1997), GISP2 (Mayewski et
al., 1997; Taylor et al., 1997), NGRIP (Bigler, 2004), and NEEM
(Schüpbach et al., 2018) ice cores have been included. For
Antarctica, records from the EDML ice core from the Atlantic sector
(EPICA community members, 2006), the EDC core from the East Antarctic
Plateau (EPICA community members, 2004), and the West Antarctic Ice Sheet
Divide (WDC) (Fudge et al., 2016; Sigl et al., 2016; WAIS Divide Project
Members, 2013) ice core are used. Records of sulfur, sulfate, chloride, and
electrical conductivity measurements (ECM) of the ice (Hammer et
al., 1980), dielectric profiling (DEP) (Moore et al., 1989;
Wilhelms et al., 1998), and the liquid conductivity of meltwater are also
employed as good indicators of volcanic signals in ice cores. With the
inclusion of those records, the ability of distinguishing large global
volcanic events from more regional eruptions is improved, in particular for
Antarctica.</p>
      <p id="d1e598">The Greenland ice cores used here previously have been synchronized by
volcanic events (Rasmussen et al., 2013; Seierstad et al., 2014).
Likewise, the Antarctic ice cores have been linked internally by volcanic
matching (Buizert et al., 2018; Ruth et al., 2007). In addition to the
published volcanic match points made for Antarctica, some 25 additional
Antarctic match points have been identified in the present study to
strengthen the synchronization in the neighbourhood of Greenland abrupt
climate change events. The non-bipolar or “local” volcanic matching applied
here is in agreement with the published synchronizations for Greenland and
Antarctica, respectively.</p>
      <p id="d1e601">To investigate the bipolar climate signal, we employ stable water isotopes
(<inline-formula><mml:math id="M16" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula>) from the GRIP (Dansgaard et al., 1993; Johnsen et
al., 2001), GISP2 (Grootes et al., 1993; Stuiver and
Grootes, 2000), NGRIP (Gkinis et al., 2014; North Greenland Ice Core
Project members, 2004), and NEEM (Schüpbach et al., 2018) ice cores
as well as <inline-formula><mml:math id="M17" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> and deuterium excess from the EDML
(EPICA community members, 2006; Stenni et al., 2010b), EDC
(EPICA community members, 2004; Stenni et al., 2010b), WDC
(Markle et al., 2016; WAIS Divide Project Members, 2013), Dome Fuji (DF)
(Kawamura et al., 2007; Watanabe et al., 2003), and Talos Dome (TAL)
(Landais et al., 2015; Stenni et al., 2010a) ice cores. The sources of
the employed datasets are listed in Table S1.</p>
</sec>
<sec id="Ch1.S3">
  <label>3</label><title>Results</title>
      <p id="d1e638">The bipolar volcanic match points identified in the 12–60 ka interval are
shown in Fig. 1 and listed in Table S2. Of the 87 bipolar match points
listed, five are previously published cosmogenic match points associated
with the Laschamp geomagnetic excursion occurring in the 40.5–42.0 ka
interval (Raisbeck et al., 2017). For the interval
16.5–24.5 ka, roughly corresponding to the Last Glacial Maximum (LGM), the
ice cores are notoriously difficult to match up, and no bipolar match points
are reported. We note that most of the identified bipolar match points fall
within Greenland interstadial periods and rather few are located in
stadials. The main reasons for this are the elevated dust concentrations in
the colder periods that mute the ice conductivity signal as well as the
elevated sulfuric background signal of colder periods that obscures the
volcanic signal of the ice
(Seierstad et al., 2014). Besides
this, precise annual layer counting is also more difficult in the colder
periods where accumulation is lower (Andersen et al., 2006).
Wind-scouring is another factor affecting low-accumulation Antarctic sites
particularly during colder periods.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F1" specific-use="star"><?xmltex \currentcnt{1}?><label>Figure 1</label><caption><p id="d1e643">Greenland (NGRIP) and Antarctic (EDML, WDC, and EDC) climate records
(<inline-formula><mml:math id="M18" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula>) throughout the 10–60 ka time period based on volcanic
matching. Ages are on the GICC05 timescale relative to the year 2000 CE
(“b2k”). Grey vertical lines show the position of bipolar volcanic match
points identified in this study (Table S2) together with five match points
based on cosmogenic isotopes around 41 ka
(Raisbeck et al., 2017). Blue-shaded intervals
indicate the Greenland Interstadial (GI) periods according to the definition
of Rasmussen et al. (2014). The bipolar synchronization for the 16.5–24.5 ka interval is
tentative as there are no bipolar match points in that interval.</p></caption>
        <?xmltex \igopts{width=369.885827pt}?><graphic xlink:href="https://cp.copernicus.org/articles/16/1565/2020/cp-16-1565-2020-f01.png"/>

      </fig>

      <p id="d1e665">All of the bipolar volcanic match points are identified in the Greenland
NGRIP and the Antarctic EDML ice cores, and most of them are also identified
in the Antarctic WDC and EDC ice cores. About half of the bipolar match
points are also identified in the Greenland GRIP, GISP2, and NEEM ice cores,
but the lower resolution of available sulfate and conductivity records for
those cores is often insufficient for precise identification of weaker
volcanic events. The Greenland ice cores are however internally synchronized
throughout the last glacial period (Rasmussen et al., 2013; Seierstad et
al., 2014) by northern hemispheric eruptions, typically Icelandic in origin,
that leave a stronger fingerprint in Greenland. Therefore, for most of the
bipolar match points all of the Greenland ice cores are precisely matched by
interpolation between Greenland match points.</p>

<?xmltex \floatpos{p}?><table-wrap id="Ch1.T1" specific-use="star"><?xmltex \currentcnt{1}?><label>Table 1</label><caption><p id="d1e672">Bipolar onsets and terminations.
Depths of the Greenland interstadial onsets <bold>(a)</bold> and terminations <bold>(b)</bold> in the
NGRIP, NEEM, GRIP, GISP2, EDML, EDC, and WDC ice cores based on volcanic
matching. The NGRIP onsets are defined as the midpoints of the <inline-formula><mml:math id="M19" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> transitions and are identical to those applied in WAIS Divide
Project Members (2015) except for the onset of GI-1. The Greenland match
points are from Seierstad et al. (2014), Antarctic match points are from
Buizert et al. (2018), and the bipolar
match points are from Table S2. Corresponding GICC05 ages are provided with
reference to year 2000 CE. “Distance” refers to the temporal distance to the nearest bipolar match point in Table S2 with negative values signifying the match point occurring before the onset or termination. The relative uncertainty
of the bipolar matching is stated as 10 % of the “distance” assuming a
5 % maximum counting error of the annual layer counting in both Greenland
and Antarctica. “YD-PB” refers to the Younger Dryas–Preboreal transition
(the onset of the Holocene) and “BA-YD” refers to the Bølling–Allerød–Younger Dryas transition (the onset of GS-1). All EDC depths are on the
EDC99 depth scale.</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="11">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="right"/>
     <oasis:colspec colnum="3" colname="col3" align="right"/>
     <oasis:colspec colnum="4" colname="col4" align="right"/>
     <oasis:colspec colnum="5" colname="col5" align="right"/>
     <oasis:colspec colnum="6" colname="col6" align="right"/>
     <oasis:colspec colnum="7" colname="col7" align="right"/>
     <oasis:colspec colnum="8" colname="col8" align="right"/>
     <oasis:colspec colnum="9" colname="col9" align="right"/>
     <oasis:colspec colnum="10" colname="col10" align="right"/>
     <oasis:colspec colnum="11" colname="col11" align="right"/>
     <oasis:thead>
       <oasis:row>
         <oasis:entry colname="col1"><bold>(a)</bold></oasis:entry>
         <oasis:entry rowsep="1" namest="col2" nameend="col8" align="center">Greenland interstadial onset depth (m) </oasis:entry>
         <oasis:entry colname="col9">GICC05 age</oasis:entry>
         <oasis:entry colname="col10">Distance</oasis:entry>
         <oasis:entry colname="col11">Uncertainty</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1">GI-event</oasis:entry>
         <oasis:entry colname="col2">NGRIP</oasis:entry>
         <oasis:entry colname="col3">NEEM</oasis:entry>
         <oasis:entry colname="col4">GRIP</oasis:entry>
         <oasis:entry colname="col5">GISP2</oasis:entry>
         <oasis:entry colname="col6">EDML</oasis:entry>
         <oasis:entry colname="col7">EDC</oasis:entry>
         <oasis:entry colname="col8">WDC</oasis:entry>
         <oasis:entry colname="col9">(yr b2k)</oasis:entry>
         <oasis:entry colname="col10">(yr)</oasis:entry>
         <oasis:entry colname="col11">(yr)</oasis:entry>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>
         <oasis:entry colname="col1">YD-PB</oasis:entry>
         <oasis:entry colname="col2">1490.89</oasis:entry>
         <oasis:entry colname="col3">1418.75</oasis:entry>
         <oasis:entry colname="col4">1622.08</oasis:entry>
         <oasis:entry colname="col5">1675.61</oasis:entry>
         <oasis:entry colname="col6">676.46</oasis:entry>
         <oasis:entry colname="col7">356.32</oasis:entry>
         <oasis:entry colname="col8">1962.70</oasis:entry>
         <oasis:entry colname="col9">11 669</oasis:entry>
         <oasis:entry colname="col10"><inline-formula><mml:math id="M20" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">20</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col11">2</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">1</oasis:entry>
         <oasis:entry colname="col2">1604.64</oasis:entry>
         <oasis:entry colname="col3">1489.26</oasis:entry>
         <oasis:entry colname="col4">1753.34</oasis:entry>
         <oasis:entry colname="col5">1797.78</oasis:entry>
         <oasis:entry colname="col6">792.70</oasis:entry>
         <oasis:entry colname="col7">421.58</oasis:entry>
         <oasis:entry colname="col8">2238.95</oasis:entry>
         <oasis:entry colname="col9">14 693</oasis:entry>
         <oasis:entry colname="col10"><inline-formula><mml:math id="M21" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">13</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col11">1</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">3</oasis:entry>
         <oasis:entry colname="col2">1869.00</oasis:entry>
         <oasis:entry colname="col3">1640.94</oasis:entry>
         <oasis:entry colname="col4">2025.32</oasis:entry>
         <oasis:entry colname="col5">2056.57</oasis:entry>
         <oasis:entry colname="col6">1123.54</oasis:entry>
         <oasis:entry colname="col7">586.08</oasis:entry>
         <oasis:entry colname="col8">2742.16</oasis:entry>
         <oasis:entry colname="col9">27 776</oasis:entry>
         <oasis:entry colname="col10"><inline-formula><mml:math id="M22" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">20</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col11">2</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">4</oasis:entry>
         <oasis:entry colname="col2">1891.27</oasis:entry>
         <oasis:entry colname="col3">1654.11</oasis:entry>
         <oasis:entry colname="col4">2045.81</oasis:entry>
         <oasis:entry colname="col5">2076.33</oasis:entry>
         <oasis:entry colname="col6">1145.97</oasis:entry>
         <oasis:entry colname="col7">598.37</oasis:entry>
         <oasis:entry colname="col8">2782.83</oasis:entry>
         <oasis:entry colname="col9">28 888</oasis:entry>
         <oasis:entry colname="col10"><inline-formula><mml:math id="M23" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">51</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col11">5</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">5.1</oasis:entry>
         <oasis:entry colname="col2">1919.48</oasis:entry>
         <oasis:entry colname="col3">1671.51</oasis:entry>
         <oasis:entry colname="col4">2070.21</oasis:entry>
         <oasis:entry colname="col5">2099.96</oasis:entry>
         <oasis:entry colname="col6">1179.08</oasis:entry>
         <oasis:entry colname="col7">619.07</oasis:entry>
         <oasis:entry colname="col8">2835.50</oasis:entry>
         <oasis:entry colname="col9">30 781</oasis:entry>
         <oasis:entry colname="col10">498</oasis:entry>
         <oasis:entry colname="col11">50</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">5.2</oasis:entry>
         <oasis:entry colname="col2">1951.66</oasis:entry>
         <oasis:entry colname="col3">1690.04</oasis:entry>
         <oasis:entry colname="col4">2098.82</oasis:entry>
         <oasis:entry colname="col5">2127.52</oasis:entry>
         <oasis:entry colname="col6">1207.26</oasis:entry>
         <oasis:entry colname="col7">637.16</oasis:entry>
         <oasis:entry colname="col8">2874.01</oasis:entry>
         <oasis:entry colname="col9">32 500</oasis:entry>
         <oasis:entry colname="col10">68</oasis:entry>
         <oasis:entry colname="col11">7</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">6</oasis:entry>
         <oasis:entry colname="col2">1974.48</oasis:entry>
         <oasis:entry colname="col3">1703.17</oasis:entry>
         <oasis:entry colname="col4">2118.52</oasis:entry>
         <oasis:entry colname="col5">2147.03</oasis:entry>
         <oasis:entry colname="col6">1229.98</oasis:entry>
         <oasis:entry colname="col7">650.73</oasis:entry>
         <oasis:entry colname="col8">2903.17</oasis:entry>
         <oasis:entry colname="col9">33 737</oasis:entry>
         <oasis:entry colname="col10">409</oasis:entry>
         <oasis:entry colname="col11">41</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">7</oasis:entry>
         <oasis:entry colname="col2">2009.62</oasis:entry>
         <oasis:entry colname="col3">1723.26</oasis:entry>
         <oasis:entry colname="col4">2148.80</oasis:entry>
         <oasis:entry colname="col5">2177.90</oasis:entry>
         <oasis:entry colname="col6">1260.99</oasis:entry>
         <oasis:entry colname="col7">670.24</oasis:entry>
         <oasis:entry colname="col8">2949.01</oasis:entry>
         <oasis:entry colname="col9">35 487</oasis:entry>
         <oasis:entry colname="col10"><inline-formula><mml:math id="M24" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">71</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col11">7</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">8</oasis:entry>
         <oasis:entry colname="col2">2069.88</oasis:entry>
         <oasis:entry colname="col3">1758.82</oasis:entry>
         <oasis:entry colname="col4">2200.19</oasis:entry>
         <oasis:entry colname="col5">2232.03</oasis:entry>
         <oasis:entry colname="col6">1312.67</oasis:entry>
         <oasis:entry colname="col7">702.32</oasis:entry>
         <oasis:entry colname="col8">3012.40</oasis:entry>
         <oasis:entry colname="col9">38 215</oasis:entry>
         <oasis:entry colname="col10"><inline-formula><mml:math id="M25" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">20</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col11">2</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">9</oasis:entry>
         <oasis:entry colname="col2">2099.50</oasis:entry>
         <oasis:entry colname="col3">1777.43</oasis:entry>
         <oasis:entry colname="col4">2223.52</oasis:entry>
         <oasis:entry colname="col5">2255.87</oasis:entry>
         <oasis:entry colname="col6">1354.20</oasis:entry>
         <oasis:entry colname="col7">726.08</oasis:entry>
         <oasis:entry colname="col8">3057.51</oasis:entry>
         <oasis:entry colname="col9">40 154</oasis:entry>
         <oasis:entry colname="col10"><inline-formula><mml:math id="M26" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">24</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col11">2</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">10</oasis:entry>
         <oasis:entry colname="col2">2123.98</oasis:entry>
         <oasis:entry colname="col3">1791.21</oasis:entry>
         <oasis:entry colname="col4">2243.22</oasis:entry>
         <oasis:entry colname="col5">2276.30</oasis:entry>
         <oasis:entry colname="col6">1378.51</oasis:entry>
         <oasis:entry colname="col7">741.14</oasis:entry>
         <oasis:entry colname="col8">3085.75</oasis:entry>
         <oasis:entry colname="col9">41 457</oasis:entry>
         <oasis:entry colname="col10">83</oasis:entry>
         <oasis:entry colname="col11">8</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">11</oasis:entry>
         <oasis:entry colname="col2">2157.58</oasis:entry>
         <oasis:entry colname="col3">1810.16</oasis:entry>
         <oasis:entry colname="col4">2270.82</oasis:entry>
         <oasis:entry colname="col5">2304.00</oasis:entry>
         <oasis:entry colname="col6">1412.29</oasis:entry>
         <oasis:entry colname="col7">762.45</oasis:entry>
         <oasis:entry colname="col8">3123.76</oasis:entry>
         <oasis:entry colname="col9">43 346</oasis:entry>
         <oasis:entry colname="col10">18</oasis:entry>
         <oasis:entry colname="col11">2</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">12</oasis:entry>
         <oasis:entry colname="col2">2221.96</oasis:entry>
         <oasis:entry colname="col3">1846.28</oasis:entry>
         <oasis:entry colname="col4">2323.98</oasis:entry>
         <oasis:entry colname="col5">2358.79</oasis:entry>
         <oasis:entry colname="col6">1465.79</oasis:entry>
         <oasis:entry colname="col7">800.57</oasis:entry>
         <oasis:entry colname="col8">3188.00</oasis:entry>
         <oasis:entry colname="col9">46 843</oasis:entry>
         <oasis:entry colname="col10"><inline-formula><mml:math id="M27" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">177</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col11">18</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">13</oasis:entry>
         <oasis:entry colname="col2">2256.73</oasis:entry>
         <oasis:entry colname="col3">1865.21</oasis:entry>
         <oasis:entry colname="col4">2350.38</oasis:entry>
         <oasis:entry colname="col5">2385.39</oasis:entry>
         <oasis:entry colname="col6">1506.61</oasis:entry>
         <oasis:entry colname="col7">828.05</oasis:entry>
         <oasis:entry colname="col8">3231.20</oasis:entry>
         <oasis:entry colname="col9">49 271</oasis:entry>
         <oasis:entry colname="col10"><inline-formula><mml:math id="M28" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">48</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col11">5</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">14</oasis:entry>
         <oasis:entry colname="col2">2345.39</oasis:entry>
         <oasis:entry colname="col3">1911.86</oasis:entry>
         <oasis:entry colname="col4">2420.68</oasis:entry>
         <oasis:entry colname="col5">2454.73</oasis:entry>
         <oasis:entry colname="col6">1583.95</oasis:entry>
         <oasis:entry colname="col7">882.69</oasis:entry>
         <oasis:entry colname="col8">3307.14</oasis:entry>
         <oasis:entry colname="col9">54 213</oasis:entry>
         <oasis:entry colname="col10">36</oasis:entry>
         <oasis:entry colname="col11">4</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">15.1</oasis:entry>
         <oasis:entry colname="col2">2355.17</oasis:entry>
         <oasis:entry colname="col3">1917.40</oasis:entry>
         <oasis:entry colname="col4">2427.86</oasis:entry>
         <oasis:entry colname="col5">2461.37</oasis:entry>
         <oasis:entry colname="col6">1596.44</oasis:entry>
         <oasis:entry colname="col7">891.17</oasis:entry>
         <oasis:entry colname="col8">3317.75</oasis:entry>
         <oasis:entry colname="col9">54 990</oasis:entry>
         <oasis:entry colname="col10"><inline-formula><mml:math id="M29" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">15</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col11">2</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">15.2</oasis:entry>
         <oasis:entry colname="col2">2366.15</oasis:entry>
         <oasis:entry colname="col3">1923.24</oasis:entry>
         <oasis:entry colname="col4">2435.93</oasis:entry>
         <oasis:entry colname="col5">2469.02</oasis:entry>
         <oasis:entry colname="col6">1609.21</oasis:entry>
         <oasis:entry colname="col7">900.36</oasis:entry>
         <oasis:entry colname="col8">3326.36</oasis:entry>
         <oasis:entry colname="col9">55 787</oasis:entry>
         <oasis:entry colname="col10">406</oasis:entry>
         <oasis:entry colname="col11">41</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">16.1</oasis:entry>
         <oasis:entry colname="col2">2398.71</oasis:entry>
         <oasis:entry colname="col3">1940.25</oasis:entry>
         <oasis:entry colname="col4">2460.18</oasis:entry>
         <oasis:entry colname="col5">2491.91</oasis:entry>
         <oasis:entry colname="col6">1643.43</oasis:entry>
         <oasis:entry colname="col7">925.25</oasis:entry>
         <oasis:entry colname="col8">3347.52</oasis:entry>
         <oasis:entry colname="col9">58 037</oasis:entry>
         <oasis:entry colname="col10"><inline-formula><mml:math id="M30" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">152</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col11">15</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">16.2</oasis:entry>
         <oasis:entry colname="col2">2402.25</oasis:entry>
         <oasis:entry colname="col3">1942.05</oasis:entry>
         <oasis:entry colname="col4">2462.74</oasis:entry>
         <oasis:entry colname="col5">2494.33</oasis:entry>
         <oasis:entry colname="col6">1647.22</oasis:entry>
         <oasis:entry colname="col7">928.01</oasis:entry>
         <oasis:entry colname="col8">3349.52</oasis:entry>
         <oasis:entry colname="col9">58 258</oasis:entry>
         <oasis:entry colname="col10"><inline-formula><mml:math id="M31" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">103</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col11">10</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">17.1</oasis:entry>
         <oasis:entry colname="col2">2414.82</oasis:entry>
         <oasis:entry colname="col3">1948.37</oasis:entry>
         <oasis:entry colname="col4">2472.05</oasis:entry>
         <oasis:entry colname="col5">2503.02</oasis:entry>
         <oasis:entry colname="col6">1660.55</oasis:entry>
         <oasis:entry colname="col7">937.91</oasis:entry>
         <oasis:entry colname="col8">3356.71</oasis:entry>
         <oasis:entry colname="col9">59 067</oasis:entry>
         <oasis:entry colname="col10"><inline-formula><mml:math id="M32" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">125</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col11">12</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1">17.2</oasis:entry>
         <oasis:entry colname="col2">2420.35</oasis:entry>
         <oasis:entry colname="col3">1951.08</oasis:entry>
         <oasis:entry colname="col4">2476.15</oasis:entry>
         <oasis:entry colname="col5">2506.86</oasis:entry>
         <oasis:entry colname="col6">1667.53</oasis:entry>
         <oasis:entry colname="col7">942.84</oasis:entry>
         <oasis:entry colname="col8">3360.52</oasis:entry>
         <oasis:entry colname="col9">59 435</oasis:entry>
         <oasis:entry colname="col10"><inline-formula><mml:math id="M33" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">132</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col11">13</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><bold>(b)</bold></oasis:entry>
         <oasis:entry rowsep="1" namest="col2" nameend="col8" align="center">Greenland interstadial termination depth (m) </oasis:entry>
         <oasis:entry colname="col9">GICC05 age</oasis:entry>
         <oasis:entry colname="col10">Distance</oasis:entry>
         <oasis:entry colname="col11">Uncertainty</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1">GI-event</oasis:entry>
         <oasis:entry colname="col2">NGRIP</oasis:entry>
         <oasis:entry colname="col3">NEEM</oasis:entry>
         <oasis:entry colname="col4">GRIP</oasis:entry>
         <oasis:entry colname="col5">GISP2</oasis:entry>
         <oasis:entry colname="col6">EDML</oasis:entry>
         <oasis:entry colname="col7">EDC</oasis:entry>
         <oasis:entry colname="col8">WDC</oasis:entry>
         <oasis:entry colname="col9">(yr b2k)</oasis:entry>
         <oasis:entry colname="col10">(yr)</oasis:entry>
         <oasis:entry colname="col11">(yr)</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">BA-YD</oasis:entry>
         <oasis:entry colname="col2">1524.21</oasis:entry>
         <oasis:entry colname="col3">1442.83</oasis:entry>
         <oasis:entry colname="col4">1659.79</oasis:entry>
         <oasis:entry colname="col5">1710.70</oasis:entry>
         <oasis:entry colname="col6">728.33</oasis:entry>
         <oasis:entry colname="col7">385.53</oasis:entry>
         <oasis:entry colname="col8">2074.86</oasis:entry>
         <oasis:entry colname="col9">12 826</oasis:entry>
         <oasis:entry colname="col10">70</oasis:entry>
         <oasis:entry colname="col11">7</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">3</oasis:entry>
         <oasis:entry colname="col2">1861.91</oasis:entry>
         <oasis:entry colname="col3">1636.91</oasis:entry>
         <oasis:entry colname="col4">2018.50</oasis:entry>
         <oasis:entry colname="col5">2050.17</oasis:entry>
         <oasis:entry colname="col6">1118.41</oasis:entry>
         <oasis:entry colname="col7">583.69</oasis:entry>
         <oasis:entry colname="col8">2733.94</oasis:entry>
         <oasis:entry colname="col9">27 548</oasis:entry>
         <oasis:entry colname="col10"><inline-formula><mml:math id="M34" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">247</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col11">25</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">4</oasis:entry>
         <oasis:entry colname="col2">1882.59</oasis:entry>
         <oasis:entry colname="col3">1649.04</oasis:entry>
         <oasis:entry colname="col4">2037.69</oasis:entry>
         <oasis:entry colname="col5">2068.53</oasis:entry>
         <oasis:entry colname="col6">1140.75</oasis:entry>
         <oasis:entry colname="col7">595.17</oasis:entry>
         <oasis:entry colname="col8">2773.18</oasis:entry>
         <oasis:entry colname="col9">28 599</oasis:entry>
         <oasis:entry colname="col10">144</oasis:entry>
         <oasis:entry colname="col11">14</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">5.1</oasis:entry>
         <oasis:entry colname="col2">1916.45</oasis:entry>
         <oasis:entry colname="col3">1669.74</oasis:entry>
         <oasis:entry colname="col4">2067.61</oasis:entry>
         <oasis:entry colname="col5">2097.44</oasis:entry>
         <oasis:entry colname="col6">1176.51</oasis:entry>
         <oasis:entry colname="col7">617.40</oasis:entry>
         <oasis:entry colname="col8">2831.89</oasis:entry>
         <oasis:entry colname="col9">30 621</oasis:entry>
         <oasis:entry colname="col10">354</oasis:entry>
         <oasis:entry colname="col11">35</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">5.2</oasis:entry>
         <oasis:entry colname="col2">1939.71</oasis:entry>
         <oasis:entry colname="col3">1683.41</oasis:entry>
         <oasis:entry colname="col4">2087.98</oasis:entry>
         <oasis:entry colname="col5">2117.21</oasis:entry>
         <oasis:entry colname="col6">1199.75</oasis:entry>
         <oasis:entry colname="col7">632.37</oasis:entry>
         <oasis:entry colname="col8">2863.36</oasis:entry>
         <oasis:entry colname="col9">32 042</oasis:entry>
         <oasis:entry colname="col10">9</oasis:entry>
         <oasis:entry colname="col11">1</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">6</oasis:entry>
         <oasis:entry colname="col2">1964.52</oasis:entry>
         <oasis:entry colname="col3">1697.55</oasis:entry>
         <oasis:entry colname="col4">2109.93</oasis:entry>
         <oasis:entry colname="col5">2138.17</oasis:entry>
         <oasis:entry colname="col6">1223.04</oasis:entry>
         <oasis:entry colname="col7">646.48</oasis:entry>
         <oasis:entry colname="col8">2894.41</oasis:entry>
         <oasis:entry colname="col9">33 374</oasis:entry>
         <oasis:entry colname="col10">47</oasis:entry>
         <oasis:entry colname="col11">5</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">7</oasis:entry>
         <oasis:entry colname="col2">1990.58</oasis:entry>
         <oasis:entry colname="col3">1712.44</oasis:entry>
         <oasis:entry colname="col4">2132.00</oasis:entry>
         <oasis:entry colname="col5">2160.68</oasis:entry>
         <oasis:entry colname="col6">1248.60</oasis:entry>
         <oasis:entry colname="col7">662.24</oasis:entry>
         <oasis:entry colname="col8">2929.30</oasis:entry>
         <oasis:entry colname="col9">34 753</oasis:entry>
         <oasis:entry colname="col10">36</oasis:entry>
         <oasis:entry colname="col11">4</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">8</oasis:entry>
         <oasis:entry colname="col2">2027.43</oasis:entry>
         <oasis:entry colname="col3">1733.94</oasis:entry>
         <oasis:entry colname="col4">2163.25</oasis:entry>
         <oasis:entry colname="col5">2193.23</oasis:entry>
         <oasis:entry colname="col6">1282.58</oasis:entry>
         <oasis:entry colname="col7">683.27</oasis:entry>
         <oasis:entry colname="col8">2976.19</oasis:entry>
         <oasis:entry colname="col9">36 620</oasis:entry>
         <oasis:entry colname="col10"><inline-formula><mml:math id="M35" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">504</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col11">50</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">9</oasis:entry>
         <oasis:entry colname="col2">2095.51</oasis:entry>
         <oasis:entry colname="col3">1775.13</oasis:entry>
         <oasis:entry colname="col4">2220.41</oasis:entry>
         <oasis:entry colname="col5">2252.62</oasis:entry>
         <oasis:entry colname="col6">1351.26</oasis:entry>
         <oasis:entry colname="col7">724.27</oasis:entry>
         <oasis:entry colname="col8">3054.08</oasis:entry>
         <oasis:entry colname="col9">39 955</oasis:entry>
         <oasis:entry colname="col10">40</oasis:entry>
         <oasis:entry colname="col11">4</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">10</oasis:entry>
         <oasis:entry colname="col2">2112.53</oasis:entry>
         <oasis:entry colname="col3">1784.96</oasis:entry>
         <oasis:entry colname="col4">2233.80</oasis:entry>
         <oasis:entry colname="col5">2266.44</oasis:entry>
         <oasis:entry colname="col6">1369.94</oasis:entry>
         <oasis:entry colname="col7">735.89</oasis:entry>
         <oasis:entry colname="col8">3075.84</oasis:entry>
         <oasis:entry colname="col9">40 968</oasis:entry>
         <oasis:entry colname="col10"><inline-formula><mml:math id="M36" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">39</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col11">4</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">11</oasis:entry>
         <oasis:entry colname="col2">2135.66</oasis:entry>
         <oasis:entry colname="col3">1798.19</oasis:entry>
         <oasis:entry colname="col4">2252.48</oasis:entry>
         <oasis:entry colname="col5">2285.68</oasis:entry>
         <oasis:entry colname="col6">1394.25</oasis:entry>
         <oasis:entry colname="col7">750.63</oasis:entry>
         <oasis:entry colname="col8">3103.22</oasis:entry>
         <oasis:entry colname="col9">42 281</oasis:entry>
         <oasis:entry colname="col10">31</oasis:entry>
         <oasis:entry colname="col11">3</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">12</oasis:entry>
         <oasis:entry colname="col2">2171.17</oasis:entry>
         <oasis:entry colname="col3">1818.25</oasis:entry>
         <oasis:entry colname="col4">2281.50</oasis:entry>
         <oasis:entry colname="col5">2314.92</oasis:entry>
         <oasis:entry colname="col6">1429.09</oasis:entry>
         <oasis:entry colname="col7">773.57</oasis:entry>
         <oasis:entry colname="col8">3142.52</oasis:entry>
         <oasis:entry colname="col9">44 358</oasis:entry>
         <oasis:entry colname="col10"><inline-formula><mml:math id="M37" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">144</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col11">14</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">13</oasis:entry>
         <oasis:entry colname="col2">2242.85</oasis:entry>
         <oasis:entry colname="col3">1857.83</oasis:entry>
         <oasis:entry colname="col4">2339.54</oasis:entry>
         <oasis:entry colname="col5">2374.51</oasis:entry>
         <oasis:entry colname="col6">1494.80</oasis:entry>
         <oasis:entry colname="col7">819.77</oasis:entry>
         <oasis:entry colname="col8">3219.51</oasis:entry>
         <oasis:entry colname="col9">48 490</oasis:entry>
         <oasis:entry colname="col10">48</oasis:entry>
         <oasis:entry colname="col11">5</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">14</oasis:entry>
         <oasis:entry colname="col2">2261.49</oasis:entry>
         <oasis:entry colname="col3">1867.76</oasis:entry>
         <oasis:entry colname="col4">2354.09</oasis:entry>
         <oasis:entry colname="col5">2389.14</oasis:entry>
         <oasis:entry colname="col6">1511.69</oasis:entry>
         <oasis:entry colname="col7">831.58</oasis:entry>
         <oasis:entry colname="col8">3236.02</oasis:entry>
         <oasis:entry colname="col9">49 602</oasis:entry>
         <oasis:entry colname="col10">282</oasis:entry>
         <oasis:entry colname="col11">28</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">15.1</oasis:entry>
         <oasis:entry colname="col2">2353.66</oasis:entry>
         <oasis:entry colname="col3">1916.55</oasis:entry>
         <oasis:entry colname="col4">2426.76</oasis:entry>
         <oasis:entry colname="col5">2460.35</oasis:entry>
         <oasis:entry colname="col6">1595.02</oasis:entry>
         <oasis:entry colname="col7">890.21</oasis:entry>
         <oasis:entry colname="col8">3316.61</oasis:entry>
         <oasis:entry colname="col9">54 901</oasis:entry>
         <oasis:entry colname="col10"><inline-formula><mml:math id="M38" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">101</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col11">10</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">15.2</oasis:entry>
         <oasis:entry colname="col2">2359.92</oasis:entry>
         <oasis:entry colname="col3">1920.06</oasis:entry>
         <oasis:entry colname="col4">2431.35</oasis:entry>
         <oasis:entry colname="col5">2464.59</oasis:entry>
         <oasis:entry colname="col6">1603.35</oasis:entry>
         <oasis:entry colname="col7">896.01</oasis:entry>
         <oasis:entry colname="col8">3322.51</oasis:entry>
         <oasis:entry colname="col9">55 419</oasis:entry>
         <oasis:entry colname="col10">35</oasis:entry>
         <oasis:entry colname="col11">4</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">16.1</oasis:entry>
         <oasis:entry colname="col2">2375.88</oasis:entry>
         <oasis:entry colname="col3">1928.41</oasis:entry>
         <oasis:entry colname="col4">2442.94</oasis:entry>
         <oasis:entry colname="col5">2475.66</oasis:entry>
         <oasis:entry colname="col6">1621.92</oasis:entry>
         <oasis:entry colname="col7">908.87</oasis:entry>
         <oasis:entry colname="col8">3333.90</oasis:entry>
         <oasis:entry colname="col9">56 605</oasis:entry>
         <oasis:entry colname="col10"><inline-formula><mml:math id="M39" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">444</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col11">44</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">16.2</oasis:entry>
         <oasis:entry colname="col2">2400.56</oasis:entry>
         <oasis:entry colname="col3">1941.21</oasis:entry>
         <oasis:entry colname="col4">2461.50</oasis:entry>
         <oasis:entry colname="col5">2493.16</oasis:entry>
         <oasis:entry colname="col6">1645.82</oasis:entry>
         <oasis:entry colname="col7">927.02</oasis:entry>
         <oasis:entry colname="col8">3348.82</oasis:entry>
         <oasis:entry colname="col9">58 174</oasis:entry>
         <oasis:entry colname="col10"><inline-formula><mml:math id="M40" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">8</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col11">1</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">17.1</oasis:entry>
         <oasis:entry colname="col2">2406.52</oasis:entry>
         <oasis:entry colname="col3">1944.20</oasis:entry>
         <oasis:entry colname="col4">2465.91</oasis:entry>
         <oasis:entry colname="col5">2497.28</oasis:entry>
         <oasis:entry colname="col6">1652.67</oasis:entry>
         <oasis:entry colname="col7">932.01</oasis:entry>
         <oasis:entry colname="col8">3352.41</oasis:entry>
         <oasis:entry colname="col9">58 594</oasis:entry>
         <oasis:entry colname="col10">243</oasis:entry>
         <oasis:entry colname="col11">24</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">17.2</oasis:entry>
         <oasis:entry colname="col2">2417.77</oasis:entry>
         <oasis:entry colname="col3">1949.85</oasis:entry>
         <oasis:entry colname="col4">2474.23</oasis:entry>
         <oasis:entry colname="col5">2505.06</oasis:entry>
         <oasis:entry colname="col6">1665.07</oasis:entry>
         <oasis:entry colname="col7">941.18</oasis:entry>
         <oasis:entry colname="col8">3359.21</oasis:entry>
         <oasis:entry colname="col9">59 307</oasis:entry>
         <oasis:entry colname="col10"><inline-formula><mml:math id="M41" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">9</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col11">1</oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table></table-wrap>

      <p id="d1e2541">The bipolar match points are unevenly distributed over the 12–60 ka
interval, but bipolar volcanic events have been identified within a range of
500 years of all major onsets and terminations of Greenland interstadials
(GIs) with the exception of GI-2 (Fig. 1). All of the Greenland abrupt
climate change events in that period (except for GI-2) are thus synchronized
with the Antarctic climate at high precision. The derived depths and ages
for the onsets and terminations of GI events are shown in Table 1. Based on
the 5 % average counting uncertainty during the last glacial period
(Svensson et al., 2008), the relative uncertainty of the bipolar
linking related to the GI events is taken as 10 % of the distance to the
nearest bipolar match point (Table 1). On average, this relative uncertainty
is less than 15 years and reaches a maximum of 50 years. The definition of
GI onsets and terminations applied in this study are the midpoints of the
NGRIP isotopic transitions as identified in WAIS Divide Project Members (2015), except for the onset of GI-1 (the Bølling–Allerød), which is taken from Steffensen et al. (2008).</p>
      <p id="d1e2544">In the following sections, we provide examples of the bipolar
synchronization from selected time intervals. In the Supplement
detailed figures are provided for all the DO events (Figs. S1–S14).</p>
<?pagebreak page1570?><sec id="Ch1.S3.SS1">
  <label>3.1</label><title>The termination of GI-1/onset of the Younger Dryas</title>
      <p id="d1e2554">The onset of the Younger Dryas (GS-1) is synchronized between the two
hemispheres by four large acidity spikes clustered around 13 ka and spanning
110 years (Fig. 2). The two outermost spikes are most significant, but all
four spikes are present in all investigated cores. All four volcanic
eruptions are interpreted as bipolar and they are therefore most likely
associated with low-latitude eruptions. This is in conflict with the
hypothesis that one of them should be related to the German Laacher See
eruption (Baldini et al., 2018) that is believed to have a
primarily northern hemispheric fingerprint (Graf and
Timmreck, 2001). A tephra layer in the NGRIP ice core occurring close to the
oldest of the four spikes has previously been tentatively associated with a
Hekla eruption (Mortensen et al., 2005), but with the clear
bipolar signature there is likely a temporal overlap between this Icelandic
and an additional lower-latitude eruption. We notice that the eruption
associated with the very significant North Atlantic Vedde Ash layer (Lane
et al., 2012; Mortensen et al., 2005) located at 12.17 ka in the Greenland
ice cores (Rasmussen et al., 2006) has potentially left a weak acidic signal in Antarctica.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F2" specific-use="star"><?xmltex \currentcnt{2}?><label>Figure 2</label><caption><p id="d1e2559">Bipolar volcanic synchronization of the investigated ice cores across the
transition from GI-1/Bølling–Allerød (BA) to GS-1/Younger Dryas
(YD) <bold>(a)</bold> and the onset of GI-8 <bold>(b)</bold>. Grey vertical lines
are bipolar volcanic match points (Table S2). The records have different
units; some are uncalibrated and peak heights are not comparable on an
absolute scale, which is the reason why no scales are provided.</p></caption>
          <?xmltex \igopts{width=426.791339pt}?><graphic xlink:href="https://cp.copernicus.org/articles/16/1565/2020/cp-16-1565-2020-f02.png"/>

        </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F3" specific-use="star"><?xmltex \currentcnt{3}?><label>Figure 3</label><caption><p id="d1e2576">Synchronized climate records of the investigated ice cores across the GS-1
onset <bold>(a)</bold> and the GI-8 onset <bold>(b)</bold> applying the volcanic
synchronization shown in Fig. 2. The acidity records in the bottom of the
figure are for reference and are also shown in Fig. 2. All other records are
<inline-formula><mml:math id="M42" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> in per mille (see Fig. 1 for scales). Grey
vertical lines are bipolar volcanic match points (Table S2).</p></caption>
          <?xmltex \igopts{width=426.791339pt}?><graphic xlink:href="https://cp.copernicus.org/articles/16/1565/2020/cp-16-1565-2020-f03.png"/>

        </fig>

      <p id="d1e2605">Our bipolar volcanic linking allows for synchronizing the climate signal of
the investigated cores (Fig. 3). The four Greenland cores show quite
variable climate patterns for the termination of GI-1, making it difficult
to define the duration of the transition, but they all have the most
significant drop in isotopic values in the interval constrained by the two
bipolar events at 12.75 and 12.92 ka, respectively.</p>
      <p id="d1e2608"><?xmltex \hack{\newpage}?>It has been proposed that the Younger Dryas period/GS-1 was initiated by a
cosmic impact, for which there is indirect and debated evidence in a large
number of sites in the NH surrounding the North Atlantic region (Kennett
et al., 2015). A very significant Platinum (Pt) spike has been identified in
the GISP2 ice core (Petaev et al., 2013) and at
several North American sites (Moore et
al., 2017) that potentially originate from the same impact event. The Pt
spike occurs about 45 years after the volcanic quadruplet, i.e. after the
Greenland cooling has initiated but before it has reached its minimum (Fig. S1b). The hypothesis of the YD initiation by a cosmic impact is currently
debated (Holliday et al., 2020).</p>
<sec id="Ch1.S3.SS1.SSSx1" specific-use="unnumbered">
  <?xmltex \opttitle{The onset of Greenland Interstadial 1/B{\o}lling--Aller{\o}d}?><title>The onset of Greenland Interstadial 1/Bølling–Allerød</title>
      <?pagebreak page1571?><p id="d1e2618">The very steep Greenland onset of the GI-1/Bølling–Allerød period is
preceded by a 1.8 kyr long period of strong global volcanic activity (Fig. S2a). The bipolar phasing is well constrained by several significant
eruptions leading up to the onset, and the bipolar volcanic matching pattern
is easily recognized. In agreement with Steffensen et al. (2008),
we note that NGRIP appears to be the Greenland ice core with the steepest
<inline-formula><mml:math id="M43" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> transition at the GI-1 onset (Fig. S2b). The Antarctic ice
cores all peak close to 200 years after the Greenland mid-transition
in agreement with the methane matching of NGRIP and WDC (WAIS Divide
Project Members, 2015). The very strong volcanic double spike in NGRIP close
to 15.68 ka is associated with tephra from the explosive caldera-forming
Towada-H eruption (Bourne et al., 2016) located in
present-day Japan close to 40<inline-formula><mml:math id="M44" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N. This eruption appears to have no
significant Antarctic imprint.</p>
</sec>
</sec>
<sec id="Ch1.S3.SS2">
  <label>3.2</label><title>Greenland Stadial 3 (GS-3)</title>
      <p id="d1e2652">In the late GS-3, at 24.67 ka, there is a characteristic volcanic triplet
spike that constitutes a strong bipolar link (Fig. S3a). The three spikes
are separated by <inline-formula><mml:math id="M45" display="inline"><mml:mrow><mml:mn mathvariant="normal">20</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:math></inline-formula> and then <inline-formula><mml:math id="M46" display="inline"><mml:mrow><mml:mn mathvariant="normal">10</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:math></inline-formula> years, making the
match point unique (Fig. S3a inset). At 25.46 ka (b2k GICC05 age) we
hypothesize a record of traces from the Oruanui eruption from the Taupo
volcano in present-day New Zealand in the Greenland record. Tephra of this
eruption has been previously identified and dated to 25.37 ka (b2k WD2014
age) in the WDC ice core (Dunbar et al., 2017).
There appears to be a major Greenland acidity spike associated with this
eruption despite its latitude being close to 40<inline-formula><mml:math id="M47" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> S. Unfortunately,
there are no adjacent bipolar eruptions within several hundreds of years, making the bipolar Oruanui link somewhat uncertain. The nearest pair of
bipolar eruptions is found at 25.76 and 25.94 ka, leaving
enough room in the layer counting uncertainty for the Greenland acidity
spike to potentially be a “false match” offset by up to 30 years from the
Antarctic Oruanui spike. The link needs to be investigated by the bipolar
sulfur isotopes method to rule out a coeval local source for the NGRIP event
(Burke et al., 2019). Besides being relevant for
comparing Greenland and Antarctic ice core timescales
(Sigl et al., 2016),
the Oruanui eruption constitutes an important comparison point for <inline-formula><mml:math id="M48" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">14</mml:mn></mml:msup><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula>
ages and ice core chronologies as tephra from the eruption is widely
distributed (Muscheler et al., 2020).</p>
</sec>
<sec id="Ch1.S3.SS3">
  <label>3.3</label><title>The onset of Greenland Interstadial 8</title>
      <p id="d1e2708">The very prominent onset of GI-8 is associated with four significant bipolar
eruptions within a 400-year period (Fig. 2). The eruption occurring at 38.13 ka, close to a century after the onset, shows a very significant signal in
all acidity proxies of all investigated ice cores, and it appears to be one
of the largest eruptions of the last glacial period. We thus see it as a
potential candidate for the H1 horizon identified in Antarctica by
radio-echo sounding (Winter et al., 2019). Other prominent
bipolar events are situated at 37.97, 38.23, and 38.37 ka. The 38.23 ka event occurs right at the initiation of the GI-8 onset.</p>
      <p id="d1e2711">In the climate records across the GI-8 onset, the Greenland records behave
quite similarly, whereas the Antarctic records show rather distinct patterns
(Fig. 3). EDC expresses a prominent warming coinciding with the Greenland
warming; WDC also shows a warming although much less significant. Both EDC
and WDC exhibit a cooling trend<?pagebreak page1572?> initiating some decades after the Greenland
onset. In contrast, EDML shows a century-long cooling period starting right
at the Greenland onset. Being rather noisy, it is hard to separate signal
from noise in the Antarctic records based on just one warming event.
However, the stacking exercise across several warming events discussed below
reveals that the pattern expressed by the Antarctic records at the GI-8
onset is an archetypical expression of an Antarctic response to a major GI
onset.</p>
</sec>
<sec id="Ch1.S3.SS4">
  <label>3.4</label><title>Greenland interstadials 9 and 10</title>
      <p id="d1e2723">For the period 40–43 ka that covers GI-9 and GI-10, the bipolar matching is
very well constrained by 16 bipolar match points (Fig. S8a), five of which
are independent cosmogenic match points related to the Laschamp geomagnetic
excursion (Raisbeck et al., 2017). The volcanic
match presented here is in agreement within uncertainties with the
cosmogenic matching, and it replaces the existing bipolar volcanic matching
in this region (Svensson et al.,
2013) that has been shifted by some 30 years.</p>
      <p id="d1e2726">The onsets of GI-9 and GI-10 provide examples of less prominent GI events
where the Antarctic isotopic response pattern is different from that of the
larger events, such as GI-8 and GI-12 (Figs. 2 and S10b). For the GI-9
onset, it is practically impossible to distinguish a bipolar seesaw response
in the adjacent periods in the Antarctic climate records. For the GI-10
onset, EDC has a small spike and EDML has a dip, but none of them stand out
from the background. WDC appears to enter GI-10 without any climatic
response. For the smaller or weaker GI events the response pattern in
Antarctica is likewise smaller, making it harder to identify it within the
isotopic background variability (Fig. 1).</p>
</sec>
</sec>
<sec id="Ch1.S4">
  <label>4</label><title>Bipolar phasing of abrupt climate change</title>
      <p id="d1e2738">The characteristics of the climate record of the individual GI onsets may
vary from event to event, from ice core to ice core, and from proxy to proxy
both in Greenland and in Antarctica. In Greenland, the main pattern
associated with a GI onset is similar for all deep ice cores, but transition
durations and the relative phasing of individual parameters, such as water
isotopes and impurity concentrations, vary between events and to a lesser
degree between cores (Erhardt et al., 2019; Rasmussen et al., 2014;
Steffensen et al., 2008). In Antarctica, the investigated cores are located
further apart, they are exposed to the climatic influence from different
ocean basins, and they do in general show greater variability in relation to
the Greenland GI onsets than is the case for the more closely located
Greenland coring sites. In addition to the noise in water isotope records
caused by wind-driven redeposition at low-accumulation sites,
millennial-scale<?pagebreak page1573?> climate variability in Antarctica has a profoundly lower
signal-to-noise ratio than that in Greenland, contributing to the difficulty
of interpreting individual events.</p>
      <p id="d1e2741">Keeping in mind this variability among individual GI events, we find it
useful to extract a general pattern across the GI onsets and terminations by
aligning the individual events and stacking (or compositing) them, as has
been done using bipolar methane synchronization (Buizert et al., 2018;
WAIS Divide Project Members, 2015). The stacking provides us with an overall
phasing relation that may be helpful in unravelling the governing mechanisms
of the abrupt climate change, for example by comparison to model experiments
that typically do not capture the details of individual events
(Buizert et al., 2018). We stress that
the associated underlying assumption of the stacking approach, that the
complete temporal progression of all events is the result of the same
underlying process, may not be fully justified.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F4" specific-use="star"><?xmltex \currentcnt{4}?><label>Figure 4</label><caption><p id="d1e2746">Stacks of isotopic records across GI onsets <bold>(a, c, e)</bold> and terminations <bold>(b, d, f)</bold>
for the events listed in Table 1a and b, applying the bipolar
volcanic synchronization. The time “<inline-formula><mml:math id="M49" display="inline"><mml:mrow><mml:mi>t</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0</mml:mn></mml:mrow></mml:math></inline-formula>” refers to the midpoint of the
NGRIP onset for each GI event as defined in Table 1. <bold>(a, b)</bold> Stack of NGRIP
<inline-formula><mml:math id="M50" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> (blue; left axis) and WDC <inline-formula><mml:math id="M51" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CH</mml:mi><mml:mn mathvariant="normal">4</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> (green; right axis).
<bold>(c, d)</bold> Stack of Antarctic <inline-formula><mml:math id="M52" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> at the indicated locations and
the average curve (mean). <bold>(e, f)</bold> Stack of Antarctic <inline-formula><mml:math id="M53" display="inline"><mml:mrow><mml:msub><mml:mi>d</mml:mi><mml:mi>ln⁡</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> at the
indicated locations and the mean. The figure is modified from
Buizert et al. (2018). See Fig. S15 for Antarctic core site locations.</p></caption>
        <?xmltex \igopts{width=312.980315pt}?><graphic xlink:href="https://cp.copernicus.org/articles/16/1565/2020/cp-16-1565-2020-f04.png"/>

      </fig>

      <p id="d1e2832">In Fig. 4, we show the <inline-formula><mml:math id="M54" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> records of NGRIP together with five
Antarctic ice cores stacked across all of the GI onsets and terminations in
the 12–60 ka interval (except for GI-2), centred at the Greenland
transition midpoint as defined in Table 1. Besides the EDML, EDC, and WDC ice
cores applied for the bipolar synchronization in this study, we expand the
geographical coverage by including the Antarctic Dome Fuji
(DF)(Kawamura et al., 2007) and Talos Dome (TAL)
(Stenni et al., 2010a) records applying the existing Antarctic volcanic
synchronization (Buizert et al., 2018; Fujita et al., 2015; Severi et
al., 2012). Figure 5 shows the stacking of the five Antarctic ice cores from
Fig. 4, thus resulting in a stack of 21 events in five Antarctic ice cores totaling 105
events. We note that the Greenland onsets are aligned according to the
midpoint of the warming transition (set to <inline-formula><mml:math id="M55" display="inline"><mml:mrow><mml:mi>t</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0</mml:mn></mml:mrow></mml:math></inline-formula>), implying that the
initiation of the Greenland event occurs earlier than the alignment point. A
recent study suggests that the abrupt NGRIP <inline-formula><mml:math id="M56" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> and Calcium
(Ca) transition onsets on average precede the <inline-formula><mml:math id="M57" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> transition
midpoint by <inline-formula><mml:math id="M58" display="inline"><mml:mrow><mml:mn mathvariant="normal">25</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">7</mml:mn></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M59" display="inline"><mml:mrow><mml:mn mathvariant="normal">33</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">15</mml:mn></mml:mrow></mml:math></inline-formula> years, respectively
(Erhardt et al., 2019); in Figs. 4 and 5 this places the
Greenland <inline-formula><mml:math id="M60" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> and Ca event onsets at <inline-formula><mml:math id="M61" display="inline"><mml:mrow><mml:mi>t</mml:mi><mml:mo>=</mml:mo><mml:mo>-</mml:mo><mml:mn mathvariant="normal">25</mml:mn></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M62" display="inline"><mml:mrow><mml:mi>t</mml:mi><mml:mo>=</mml:mo><mml:mo>-</mml:mo><mml:mn mathvariant="normal">33</mml:mn></mml:mrow></mml:math></inline-formula> years, respectively.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F5"><?xmltex \currentcnt{5}?><label>Figure 5</label><caption><p id="d1e2954"><bold>(a)</bold> Stack of Greenland NGRIP isotopes and <inline-formula><mml:math id="M63" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CH</mml:mi><mml:mn mathvariant="normal">4</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> for the onsets of GI events listed in Table 1a. <bold>(b)</bold> Antarctic five-core mean <inline-formula><mml:math id="M64" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> (stack of <inline-formula><mml:math id="M65" display="inline"><mml:mrow><mml:mn mathvariant="normal">5</mml:mn><mml:mo>×</mml:mo><mml:mn mathvariant="normal">21</mml:mn></mml:mrow></mml:math></inline-formula> warming events). Black curve is the same as “mean” in Fig. 4, centre; grey curve applies the bipolar methane synchronization of WAIS Divide Project Members (2015). <bold>(c)</bold> Antarctic five-core mean deuterium excess (<inline-formula><mml:math id="M66" display="inline"><mml:mrow><mml:msub><mml:mi>d</mml:mi><mml:mi>ln⁡</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>). Black curve is the same as “mean” in Fig. 4e, f; grey curve applies the bipolar methane synchronization of WAIS Divide Project Members (2015). Orange curves are fitting functions using the change-point analysis applied in WAIS Divide Project Members (2015). The stated 2<inline-formula><mml:math id="M67" display="inline"><mml:mi mathvariant="italic">σ</mml:mi></mml:math></inline-formula> uncertainty estimates are obtained from a Monte Carlo sampling (see main text). When the same uncertainty estimate is made for the GI terminations (Fig. 4) the <inline-formula><mml:math id="M68" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> timing is at <inline-formula><mml:math id="M69" display="inline"><mml:mrow><mml:mn mathvariant="normal">101</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">29</mml:mn></mml:mrow></mml:math></inline-formula> years, the <inline-formula><mml:math id="M70" display="inline"><mml:mrow><mml:msub><mml:mi>d</mml:mi><mml:mi>ln⁡</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> transition onset is at <inline-formula><mml:math id="M71" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">59</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">58</mml:mn></mml:mrow></mml:math></inline-formula> years, and the <inline-formula><mml:math id="M72" display="inline"><mml:mrow><mml:msub><mml:mi>d</mml:mi><mml:mi>ln⁡</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> transition end is at <inline-formula><mml:math id="M73" display="inline"><mml:mrow><mml:mn mathvariant="normal">95</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">34</mml:mn></mml:mrow></mml:math></inline-formula> years; the duration between the <inline-formula><mml:math id="M74" display="inline"><mml:mrow><mml:msub><mml:mi>d</mml:mi><mml:mi>ln⁡</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> onset and the <inline-formula><mml:math id="M75" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> change point is <inline-formula><mml:math id="M76" display="inline"><mml:mrow><mml:mn mathvariant="normal">160</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">65</mml:mn></mml:mrow></mml:math></inline-formula> years. The earlier <inline-formula><mml:math id="M77" display="inline"><mml:mrow><mml:msub><mml:mi>d</mml:mi><mml:mi>ln⁡</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> onset for the GI termination probably reflects the GI terminations being generally more gradual than the GI onsets.</p></caption>
        <?xmltex \igopts{width=199.169291pt}?><graphic xlink:href="https://cp.copernicus.org/articles/16/1565/2020/cp-16-1565-2020-f05.png"/>

      </fig>

      <p id="d1e3147">For Antarctica, the stacked EDC, WDC, and EDML records show distinct <inline-formula><mml:math id="M78" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> patterns similar to those identified for the onset of GI-8 (Fig. 3). EDC, WDC, and TAL show a peak of accelerated warming, the onset of which
is synchronous with Greenland warming and that lasts for close to a century.
DF likewise shows an accelerated warming, albeit somewhat later than the
aforementioned cores. This direct Antarctic warming response to the
Greenland warming is likely to be associated with fast atmospheric changes
on a global scale (Markle et al., 2016). In
particular, it has been proposed that a northward shift in the SH westerlies
in response to NH warming (Lee et al., 2011; Pedro et al., 2018) may
drive a warming anomaly in most of the Antarctic continent through enhanced
zonal heat transport in the atmosphere (Buizert et al., 2018; Marshall
and Thompson, 2016).</p>
      <p id="d1e3163">Another process that is likely to contribute to the alignment of the water
isotope records at the GI onsets is the local cycle of
sublimation–condensation in summer on the Greenland and Antarctic ice sheets
that is currently under investigation (Kopec et al., 2019; Pang et al.,
2019). Sublimation affects the isotope concentration and the deuterium
excess of snow through kinetic fractionation. Snow sublimation requires
large amounts of energy, and it is controlled by the relative humidity, which
in turn is linked to the large-scale atmospheric circulation. Sublimation
effects are poorly constrained on the East Antarctic Plateau.</p>
      <p id="d1e3166">EDML, however, shows an immediate cooling response that is distinct among
the cores investigated (Figs. 4 and S15), perhaps reflecting regional
effects such as wind-driven changes to the Weddell Sea stratification, gyre
circulation, sea-ice extent, or polynya activity.</p>
      <p id="d1e3170">Based on the volcanic bipolar synchronization, the general Antarctic
response time (Fig. 5) to a Greenland warming event is shorter than that
obtained from bipolar methane linking (WAIS Divide Project Members,
2015). Instead of the 200-year lag found in the methane-based
synchronization, we find an average response time of <inline-formula><mml:math id="M79" display="inline"><mml:mrow><mml:mn mathvariant="normal">122</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">24</mml:mn></mml:mrow></mml:math></inline-formula> years
(2<inline-formula><mml:math id="M80" display="inline"><mml:mi mathvariant="italic">σ</mml:mi></mml:math></inline-formula> uncertainty) using the same fitting routine as used in WAIS
Divide Project Members (2015) (see discussion of uncertainty estimates
below). This difference is mostly due to uncertainty in the WDC <inline-formula><mml:math id="M81" display="inline"><mml:mi mathvariant="normal">Δ</mml:mi></mml:math></inline-formula>age
calculation; the new synchronization suggests that the glacial <inline-formula><mml:math id="M82" display="inline"><mml:mi mathvariant="normal">Δ</mml:mi></mml:math></inline-formula>age
was too small by around 70 years on average (Fig. S16).</p>
      <p id="d1e3206">Besides <inline-formula><mml:math id="M83" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula>, we also stack records of Antarctic deuterium
excess using the logarithmic definition (<inline-formula><mml:math id="M84" display="inline"><mml:mrow><mml:msub><mml:mi>d</mml:mi><mml:mi>ln⁡</mml:mi></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> introduced by Uemura et al. (2012).
Markle et al. (2016) showed that in the WAIS
Divide ice core, <inline-formula><mml:math id="M85" display="inline"><mml:mrow><mml:msub><mml:mi>d</mml:mi><mml:mi>ln⁡</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> abruptly increases in synchrony with the onset of
GIs; at the termination of GIs, <inline-formula><mml:math id="M86" display="inline"><mml:mrow><mml:msub><mml:mi>d</mml:mi><mml:mi>ln⁡</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> abruptly decreases.
Markle et al. (2016) used a climate model
simulation with moisture tagging to show that this relationship could be
explained by north–south shifts in the location of moisture sources
associated with changes in the shifts of the Southern Hemisphere (SH)
subpolar jet, and westerly winds. This is consistent with work of
Schmidt et al. (2007), who had previously shown with climate model
simulations that the deuterium excess should be inversely correlated with
the Southern Annular Mode (SAM) index.
Masson-Delmotte et al. (2010)
made a similar argument on the basis of the EDC core, but without sufficient
dating precision to demonstrate the close relationship found by
Markle et al. (2016). These findings were
later extended to multiple Antarctic sites by
Buizert et al. (2018).</p>
      <p id="d1e3257">Stacks using a methane-based synchronization show a <inline-formula><mml:math id="M87" display="inline"><mml:mrow><mml:msub><mml:mi>d</mml:mi><mml:mi>ln⁡</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> transition that
takes <inline-formula><mml:math id="M88" display="inline"><mml:mrow><mml:mo>∼</mml:mo><mml:mn mathvariant="normal">220</mml:mn></mml:mrow></mml:math></inline-formula> years, followed by a broad peak (Fig. 5); in
contrast, our volcanic synchronization suggests a shorter transition (<inline-formula><mml:math id="M89" display="inline"><mml:mrow><mml:mn mathvariant="normal">152</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">37</mml:mn></mml:mrow></mml:math></inline-formula> years) and a much sharper <inline-formula><mml:math id="M90" display="inline"><mml:mrow><mml:msub><mml:mi>d</mml:mi><mml:mi>ln⁡</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> transition. Any chronological
errors in the bipolar synchronization will misalign the events being
composited, thereby broadening the climatic features in the stacked record.
The fact that our volcanic synchronization yields sharper features<?pagebreak page1574?> is thus
indirect evidence that it is more accurate than existing gas-based
synchronizations. The duration of the <inline-formula><mml:math id="M91" display="inline"><mml:mrow><mml:msub><mml:mi>d</mml:mi><mml:mi>ln⁡</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> transition we observe in our
stack is still an upper bound on its true duration, given that our event
alignment includes uncertainties due to annual layer counting to the nearest
volcanic tie point as well as potentially incorrectly identified volcanic
tie points. It was suggested that the gradual <inline-formula><mml:math id="M92" display="inline"><mml:mrow><mml:msub><mml:mi>d</mml:mi><mml:mi>ln⁡</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> trends before and
after the transition follow the gradual source-water sea-surface–temperature
trends of the SH via the bipolar seesaw
(Markle et al., 2016).</p>
      <p id="d1e3327">Our volcanic bipolar synchronization also shifts the onset of the <inline-formula><mml:math id="M93" display="inline"><mml:mrow><mml:msub><mml:mi>d</mml:mi><mml:mi>ln⁡</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>
transition towards older ages, placing it at <inline-formula><mml:math id="M94" display="inline"><mml:mrow><mml:mi>t</mml:mi><mml:mo>=</mml:mo><mml:mo>-</mml:mo><mml:mn mathvariant="normal">30</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">29</mml:mn></mml:mrow></mml:math></inline-formula> years
(2<inline-formula><mml:math id="M95" display="inline"><mml:mi mathvariant="italic">σ</mml:mi></mml:math></inline-formula> uncertainty) relative to the Greenland <inline-formula><mml:math id="M96" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula>
transition midpoint. Such an early onset may seem surprising but is
actually in very good agreement with other Greenland proxies that suggest
that low-latitude changes precede the Greenland <inline-formula><mml:math id="M97" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> signals.
In particular, changes in Greenland dust or Ca concentrations appear to lead
the Greenland <inline-formula><mml:math id="M98" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> by a decade at the onset of the transitions
(Erhardt et al., 2019), which has been attributed to early
changes in the Inter-Tropical Convergence Zone (ITCZ) position and atmospheric circulation
(Steffensen et al., 2008). Meridional shifts in the SH
eddy-driven jet and westerlies are suggested to be dynamically linked to the
ITCZ position (Ceppi et al., 2013). The onset of the
Greenland Ca transition (presumably reflecting NH atmospheric circulation
shifts) precedes the Greenland <inline-formula><mml:math id="M99" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> transition midpoint (which
we set as <inline-formula><mml:math id="M100" display="inline"><mml:mrow><mml:mi>t</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0</mml:mn></mml:mrow></mml:math></inline-formula>) by <inline-formula><mml:math id="M101" display="inline"><mml:mrow><mml:mn mathvariant="normal">33</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">15</mml:mn></mml:mrow></mml:math></inline-formula> years on average (Erhardt et
al., 2019), in good agreement with the <inline-formula><mml:math id="M102" display="inline"><mml:mrow><mml:mn mathvariant="normal">30</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">29</mml:mn></mml:mrow></mml:math></inline-formula> years we find for the
onset of SH atmospheric circulation changes.</p>
      <p id="d1e3455">The Antarctic <inline-formula><mml:math id="M103" display="inline"><mml:mrow><mml:msub><mml:mi>d</mml:mi><mml:mi>ln⁡</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M104" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> signals (Fig. 5) are recorded in
the same physical ice cores, and therefore the uncertainty in their relative
phasing is small and only related to the stacking of the Antarctic cores and
the change-point determinations. Errors in the bipolar synchronization will
blur the abruptness of their transitions but should not alter their
relative phasing; by contrast, the phasing relative to Greenland proxies is
very sensitive to bipolar synchronization errors. The <inline-formula><mml:math id="M105" display="inline"><mml:mrow><mml:mn mathvariant="normal">152</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">37</mml:mn></mml:mrow></mml:math></inline-formula>-year
duration between the onset of the <inline-formula><mml:math id="M106" display="inline"><mml:mrow><mml:msub><mml:mi>d</mml:mi><mml:mi>ln⁡</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> response and the breakpoint in
the <inline-formula><mml:math id="M107" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> curve therefore represents a robust estimate of the
climatic lag of the mean Antarctic temperature response behind the first
atmospheric manifestation of the GI event in the Southern Hemisphere high
latitudes.</p>
      <p id="d1e3518">At the terminations of GI events, the stacked NGRIP <inline-formula><mml:math id="M108" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> shows
a less prominent but still sharp transition over a <inline-formula><mml:math id="M109" display="inline"><mml:mrow><mml:mo>∼</mml:mo><mml:mn mathvariant="normal">100</mml:mn></mml:mrow></mml:math></inline-formula>-year
interval (Fig. 4). For <inline-formula><mml:math id="M110" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula>, all of the stacked Antarctic cores
reach a minimum in the interval 100–150 years following the Greenland
termination, with the strongest response seen for TAL. For <inline-formula><mml:math id="M111" display="inline"><mml:mrow><mml:msub><mml:mi>d</mml:mi><mml:mi>ln⁡</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, EDC and
DF show a significant response related to the Greenland terminations,
whereas the other Antarctic cores express a less coherent signal. Note that
EDML has its coldest temperatures near <inline-formula><mml:math id="M112" display="inline"><mml:mrow><mml:mi>t</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0</mml:mn></mml:mrow></mml:math></inline-formula>, suggesting again a fast
response at this site of opposite sign to that in the DO warming case.</p>
<?pagebreak page1575?><sec id="Ch1.S4.SSx1" specific-use="unnumbered">
  <title>Uncertainty estimate of stacked records</title>
      <p id="d1e3586">To estimate the uncertainty in the change-point analysis of the stacked
records (Fig. 5) we use a Monte Carlo scheme with 1000 iterations (WAIS
Divide Project Members, 2015). In each iteration, the alignment of the
individual events is shifted randomly prior to the stacking, and the
change point is identified in the new stack using an automated algorithm.
The applied time shifts are randomly drawn from normal distribution with
widths corresponding to the following event-specific uncertainties: (1) the
uncertainty in the NGRIP event midpoint detection (WAIS Divide Project
Members, 2015); (2) the uncertainty in the Antarctic layer count from the
bipolar eruption to the event (Table 1a); (3) the uncertainty in the
Antarctic volcanic synchronization
(Buizert et al., 2018).  In each
iteration, the user-specified parameters of the fitting algorithm (such as
the time interval used in the fitting) are likewise perturbed randomly. The
stated 2<inline-formula><mml:math id="M113" display="inline"><mml:mi mathvariant="italic">σ</mml:mi></mml:math></inline-formula> uncertainty values therefore reflect uncertainty in the
bipolar synchronization, stacking procedure, and change-point detection.</p>
      <p id="d1e3596">The Antarctic delay times and uncertainties identified for <inline-formula><mml:math id="M114" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula>
and <inline-formula><mml:math id="M115" display="inline"><mml:mrow><mml:msub><mml:mi>d</mml:mi><mml:mi>ln⁡</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, respectively, are valid for the stacked (averaged) transitions
(Fig. 5) but are not representative of the variation among individual
transitions. When performing an event-by-event fitting of the Antarctic
five-core average we find a much greater range of delay times. For the <inline-formula><mml:math id="M116" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> change point, the mean and standard deviation of the
individual event timings is <inline-formula><mml:math id="M117" display="inline"><mml:mrow><mml:mi>t</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">138</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">89</mml:mn></mml:mrow></mml:math></inline-formula> years; for the <inline-formula><mml:math id="M118" display="inline"><mml:mrow><mml:msub><mml:mi>d</mml:mi><mml:mi>ln⁡</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> it is
<inline-formula><mml:math id="M119" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">6</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">78</mml:mn></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M120" display="inline"><mml:mrow><mml:mn mathvariant="normal">116</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">80</mml:mn></mml:mrow></mml:math></inline-formula> years for transition beginning and
end, respectively. This larger variability reflects both differences in
timing between individual events as well as the much smaller
signal-to-noise ratio when fitting individual events.</p>
</sec>
</sec>
<sec id="Ch1.S5" sec-type="conclusions">
  <label>5</label><title>Conclusions and outlook</title>
      <p id="d1e3700">Overall, our new bipolar volcanic synchronization confirms the
centennial-scale delay of the mean Antarctic bipolar seesaw temperature
response behind abrupt Greenland DO variability (WAIS Divide Project
Members, 2015); however, the improved age control offered by volcanic
synchronization significantly reduces the estimated duration of this delay
compared to previous work based on <inline-formula><mml:math id="M121" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CH</mml:mi><mml:mn mathvariant="normal">4</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> synchronization. Our reduced
estimates are more in line with, but still larger than, results from climate
model simulations (Pedro et al., 2018; Vettoretti and Peltier, 2015)
that typically give an oceanic response on multi-decadal timescales.</p>
      <p id="d1e3714">WAIS Divide Project Members (2015) interpreted the <inline-formula><mml:math id="M122" display="inline"><mml:mrow><mml:mn mathvariant="normal">208</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">96</mml:mn></mml:mrow></mml:math></inline-formula>-year delay
they observed as characteristic of an oceanic teleconnection. The reduced
delay timescale we infer here (<inline-formula><mml:math id="M123" display="inline"><mml:mrow><mml:mn mathvariant="normal">122</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">24</mml:mn></mml:mrow></mml:math></inline-formula> years) is still consistent
with the original interpretation. However, the new observations urge some
caution. Despite our best efforts, the new bipolar volcanic framework likely
contains some incorrect matches, and as the bipolar synchronization
continues to be refined, the inferred Antarctic delay may be reduced
further. The divergent climate response at various sites (Figs. 4, S15
and WAIS Divide Project Members, 2015) as well as the relatively
gradual transition in <inline-formula><mml:math id="M124" display="inline"><mml:mrow><mml:msub><mml:mi>d</mml:mi><mml:mi>ln⁡</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> over <inline-formula><mml:math id="M125" display="inline"><mml:mrow><mml:mo>∼</mml:mo><mml:mn mathvariant="normal">145</mml:mn></mml:mrow></mml:math></inline-formula> years (suspiciously
similar to the updated timescale Antarctic temperature delay presented here)
perhaps suggest a more complex interplay of atmospheric and oceanic
processes that is currently very poorly understood (see, e.g.,
Kostov et al., 2017). We suggest future work along two
parallel lines of inquiry.</p>
      <?pagebreak page1576?><p id="d1e3762">First, further refinement and confirmation of our bipolar synchronization is
called for. Analysis of sulfur mass-independent isotopic fractionation
(Burke et al., 2019) is needed for the proposed
bipolar volcanic events. For low-latitude eruptions to show up in both the
Arctic and Antarctic almost certainly requires the injection of materials into
the stratosphere, which is reflected in <inline-formula><mml:math id="M126" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="normal">Δ</mml:mi><mml:mn mathvariant="normal">33</mml:mn></mml:msup><mml:mi mathvariant="normal">S</mml:mi></mml:mrow></mml:math></inline-formula>. High-resolution
records of <inline-formula><mml:math id="M127" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">10</mml:mn></mml:msup><mml:mi mathvariant="normal">Be</mml:mi></mml:mrow></mml:math></inline-formula> can further refine bipolar matching
(Adolphi et al., 2018) in critical intervals where
the volcanic record is ambiguous. Second, climate modelling studies are
needed to better understand the interaction between atmospheric and oceanic
changes during the Dansgaard–Oeschger cycle. In particular the anomalous response of the
EDML site during both Heinrich (Landais et al., 2015)
and Dansgaard–Oeschger (Buizert et al.,
2018) abrupt climate change calls for detailed investigation.</p>
      <p id="d1e3790">The volcanic bipolar synchronization has a wide range of potential
applications that go beyond the objectives of this paper. These include the
development of consistent bipolar ice core timescales, constraining
ice core delta-gas ages, the investigation of impacts of volcanism on abrupt
climate change, the quantification of the last glacial global volcanic eruption record, and the discussion of solar variability through the synchronization of cosmogenic isotopes. Furthermore, the precise bipolar synchronization should allow for an improved understanding of the mechanisms governing the glacial climate through a comparison to model studies and non-ice core records.</p>
</sec>

      
      </body>
    <back><notes notes-type="dataavailability"><title>Data availability</title>

      <p id="d1e3797">No new datasets were obtained for this study. The applied datasets can be obtained from the original publications that are listed in Table S1 or in some cases by request to the authors of the original publications.</p>
  </notes><app-group>
        <supplementary-material position="anchor"><p id="d1e3800">The supplement related to this article is available online at: <inline-supplementary-material xlink:href="https://doi.org/10.5194/cp-16-1565-2020-supplement" xlink:title="zip">https://doi.org/10.5194/cp-16-1565-2020-supplement</inline-supplementary-material>.</p></supplementary-material>
        </app-group><notes notes-type="authorcontribution"><title>Author contributions</title>

      <p id="d1e3809">All authors contributed to obtaining the applied datasets. AS prepared the
paper with contributions from all co-authors. CB prepared Figs. 4 and 5.</p>
  </notes><notes notes-type="competinginterests"><title>Competing interests</title>

      <p id="d1e3815">The authors declare that they have no conflict of interest.</p>
  </notes><ack><title>Acknowledgements</title><p id="d1e3821">This project has received funding from the European Union's Horizon 2020
research and innovation programme under grant agreement no. 820970 (TiPES)
and is TiPES contribution no. 20. Anders Svensson, Sune O. Rasmussen, and Dorthe Dahl-Jensen have
received support from the Villum Investigator Project IceFlow (no. 16572).
Christo Buizert gratefully acknowledges financial support from the US National
Science Foundation (ANT-1643394). Sune O. Rasmussen and Emilie Capron gratefully
acknowledge support from the Carlsberg Foundation to the ChronoClimate
project. Florian Adolphi was supported by the Swedish Research Council
(Vetenskapsrådet; grant DNR2016-00218). Raimund Muscheler was partially supported by
the Swedish Research Council (grant DNR2013-8421). Michael Sigl acknowledges funding
from the European Research Council (ERC) under the European Union's Horizon
2020 research and innovation programme (grant agreement 820047). Thomas F. Stocker and Hubertus Fischer acknowledge the long-term support of ice core research at the
University of Bern by the Swiss National Science Foundation (grants
200020_172745 and 200020_172506). US NSF grants
0839093 and 1142166 to Joseph R. McConnell supported measurements in the WAIS Divide core.</p></ack><notes notes-type="financialsupport"><title>Financial support</title>

      <p id="d1e3826">This research has been supported by the European Union's Horizon 2020 research and innovation programme (grant no. 820970), the Villum Investigator (grant no. 16572), the US National Science Foundation (grant no. ANT-1643394), the Carlsberg Foundation (ChronoClimate project), the Swedish Research Council (grant no. DNR2016-00218), the Swedish Research Council (grant no. DNR2013-8421), the European Union's Horizon 2020 research and innovation programme (grant no. 820047), the Swiss National Science Foundation (grant nos. 200020_172745 and 200020_172506), and the US National Science Foundation (grant nos. 0839093 and 1142166).</p>
  </notes><notes notes-type="reviewstatement"><title>Review statement</title>

      <p id="d1e3832">This paper was edited by Carlo Barbante and reviewed by Eric Steig and two anonymous referees.</p>
  </notes><ref-list>
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<abstract-html><p>The last glacial period is characterized by a number of millennial climate
events that have been identified in both Greenland and Antarctic ice cores
and that are abrupt in Greenland climate records. The mechanisms governing
this climate variability remain a puzzle that requires a precise
synchronization of ice cores from the two hemispheres to be resolved.
Previously, Greenland and Antarctic ice cores have been synchronized
primarily via their common records of gas concentrations or isotopes from
the trapped air and via cosmogenic isotopes measured on the ice. In this
work, we apply ice core volcanic proxies and annual layer counting to
identify large volcanic eruptions that have left a signature in both
Greenland and Antarctica. Generally, no tephra is associated with those
eruptions in the ice cores, so the source of the eruptions cannot be
identified. Instead, we identify and match sequences of volcanic eruptions
with bipolar distribution of sulfate, i.e. unique patterns of volcanic
events separated by the same number of years at the two poles. Using this
approach, we pinpoint 82 large bipolar volcanic eruptions throughout the
second half of the last glacial period (12–60&thinsp;ka). This
improved ice core synchronization is applied to determine the bipolar
phasing of abrupt climate change events at decadal-scale precision. In
response to Greenland abrupt climatic transitions, we find a response in the
Antarctic water isotope signals (<i>δ</i><sup>18</sup>O and deuterium excess)
that is both more immediate and more abrupt than that found with previous
gas-based interpolar synchronizations, providing additional support for our
volcanic framework. On average, the Antarctic bipolar seesaw climate
response lags the midpoint of Greenland abrupt <i>δ</i><sup>18</sup>O transitions
by 122±24 years. The time difference between Antarctic signals in
deuterium excess and <i>δ</i><sup>18</sup>O, which likewise informs the time
needed to propagate the signal as described by the theory of the bipolar
seesaw but is less sensitive to synchronization errors, suggests an
Antarctic <i>δ</i><sup>18</sup>O lag behind Greenland of 152±37 years.
These estimates are shorter than the 200 years suggested by earlier
gas-based synchronizations. As before, we find variations in the timing and
duration between the response at different sites and for different events
suggesting an interaction of oceanic and atmospheric teleconnection patterns
as well as internal climate variability.</p></abstract-html>
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