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  <front>
    <journal-meta><journal-id journal-id-type="publisher">CP</journal-id><journal-title-group>
    <journal-title>Climate of the Past</journal-title>
    <abbrev-journal-title abbrev-type="publisher">CP</abbrev-journal-title><abbrev-journal-title abbrev-type="nlm-ta">Clim. Past</abbrev-journal-title>
  </journal-title-group><issn pub-type="epub">1814-9332</issn><publisher>
    <publisher-name>Copernicus Publications</publisher-name>
    <publisher-loc>Göttingen, Germany</publisher-loc>
  </publisher></journal-meta>
    <article-meta>
      <article-id pub-id-type="doi">10.5194/cp-14-991-2018</article-id><title-group><article-title>Paleoceanography and ice sheet variability offshore Wilkes Land, Antarctica – Part 1: Insights from late Oligocene astronomically paced contourite sedimentation</article-title><alt-title>Late Oligocene contourite sedimentation in the Wilkes Land</alt-title>
      </title-group><?xmltex \runningtitle{Late Oligocene contourite sedimentation in the Wilkes Land}?><?xmltex \runningauthor{A.~Salabarnada et al.}?>
      <contrib-group>
        <contrib contrib-type="author" corresp="yes" rid="aff1 aff10">
          <name><surname>Salabarnada</surname><given-names>Ariadna</given-names></name>
          <email>a.salabarnada@csic.es</email>
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>Escutia</surname><given-names>Carlota</given-names></name>
          
        <ext-link>https://orcid.org/0000-0002-4932-8619</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff2">
          <name><surname>Röhl</surname><given-names>Ursula</given-names></name>
          
        <ext-link>https://orcid.org/0000-0001-9469-7053</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>Nelson</surname><given-names>C. Hans</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff3">
          <name><surname>McKay</surname><given-names>Robert</given-names></name>
          
        <ext-link>https://orcid.org/0000-0002-5602-6985</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff4">
          <name><surname>Jiménez-Espejo</surname><given-names>Francisco J.</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff5">
          <name><surname>Bijl</surname><given-names>Peter K.</given-names></name>
          
        <ext-link>https://orcid.org/0000-0002-1710-4012</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff5">
          <name><surname>Hartman</surname><given-names>Julian D.</given-names></name>
          
        <ext-link>https://orcid.org/0000-0001-6256-9989</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff6">
          <name><surname>Strother</surname><given-names>Stephanie L.</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff6">
          <name><surname>Salzmann</surname><given-names>Ulrich</given-names></name>
          
        <ext-link>https://orcid.org/0000-0001-5598-5327</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>Evangelinos</surname><given-names>Dimitris</given-names></name>
          
        <ext-link>https://orcid.org/0000-0002-4978-3056</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>López-Quirós</surname><given-names>Adrián</given-names></name>
          
        <ext-link>https://orcid.org/0000-0002-7522-2834</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff7">
          <name><surname>Flores</surname><given-names>José Abel</given-names></name>
          
        <ext-link>https://orcid.org/0000-0003-1909-293X</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff5">
          <name><surname>Sangiorgi</surname><given-names>Francesca</given-names></name>
          
        <ext-link>https://orcid.org/0000-0003-4233-6154</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff8">
          <name><surname>Ikehara</surname><given-names>Minoru</given-names></name>
          
        <ext-link>https://orcid.org/0000-0002-2695-4713</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff5 aff9">
          <name><surname>Brinkhuis</surname><given-names>Henk</given-names></name>
          
        <ext-link>https://orcid.org/0000-0003-0253-6610</ext-link></contrib>
        <aff id="aff1"><label>1</label><institution>Instituto Andaluz de Ciencias de la Tierra, CSIC-Univ. de Granada, Armilla, 18100, Spain</institution>
        </aff>
        <aff id="aff2"><label>2</label><institution>MARUM – Center for Marine Environmental Sciences, University of Bremen, Leobener Strasse 8, 28359 Bremen, Germany</institution>
        </aff>
        <aff id="aff3"><label>3</label><institution>Antarctic Research Centre, Victoria University of Wellington, Wellington, 6140, New Zealand</institution>
        </aff>
        <aff id="aff4"><label>4</label><institution>Department of Biogeochemistry, Japan Agency for Marine-Earth Science and Technology,<?xmltex \hack{\break}?> Yokosuka, Kanagawa, 237-0061, Japan</institution>
        </aff>
        <aff id="aff5"><label>5</label><institution>Department of Earth Sciences, Marine Palynology and Palaeoceanography, Faculty of Geosciences, Laboratory of Palaeobotany and Palynology, Utrecht University, Princetonlaan 8a, 3584 CB Utrecht, the Netherlands</institution>
        </aff>
        <aff id="aff6"><label>6</label><institution>Department of Geography and Environmental Sciences, Faculty of Engineering and Environment,<?xmltex \hack{\break}?> Northumbria University, Newcastle upon Tyne, NE1 8ST, UK</institution>
        </aff>
        <aff id="aff7"><label>7</label><institution>Department of Geology, University of Salamanca, Salamanca, 37008, Spain</institution>
        </aff>
        <aff id="aff8"><label>8</label><institution>Center for Advanced Marine Core research, Kochi University, Nankoku, Kochi, 783-8502, Japan</institution>
        </aff>
        <aff id="aff9"><label>9</label><institution>NIOZ, Royal Netherlands Institute for Sea Research, and Utrecht University, Landsdiep 4,<?xmltex \hack{\break}?> 1797SZ 't Horntje, Texel, the Netherlands</institution>
        </aff>
        <aff id="aff10"><label>*</label><institution><?xmltex \bgroup\itshape?>Invited contribution by Ariadna Salabarnada, recipient of the EGU Climate: Past, Present &amp;<?xmltex \egroup?><?xmltex \hack{\break}?> <?xmltex \bgroup\itshape?>Future Outstanding Student Poster and PICO Award 2016.<?xmltex \egroup?></institution>
        </aff>
      </contrib-group>
      <author-notes><corresp id="corr1">Ariadna Salabarnada (a.salabarnada@csic.es)</corresp></author-notes><pub-date><day>10</day><month>July</month><year>2018</year></pub-date>
      
      <volume>14</volume>
      <issue>7</issue>
      <fpage>991</fpage><lpage>1014</lpage>
      <history>
        <date date-type="received"><day>16</day><month>November</month><year>2017</year></date>
           <date date-type="rev-request"><day>5</day><month>December</month><year>2017</year></date>
           <date date-type="rev-recd"><day>2</day><month>May</month><year>2018</year></date>
           <date date-type="accepted"><day>21</day><month>June</month><year>2018</year></date>
      </history>
      <permissions>
        <copyright-statement>Copyright: © 2018 </copyright-statement>
        <copyright-year>2018</copyright-year>
      <license license-type="open-access"><license-p>This work is licensed under the Creative Commons Attribution 4.0 International License. To view a copy of this licence, visit <ext-link ext-link-type="uri" xlink:href="https://creativecommons.org/licenses/by/4.0/">https://creativecommons.org/licenses/by/4.0/</ext-link></license-p></license></permissions><self-uri xlink:href="https://cp.copernicus.org/articles/.html">This article is available from https://cp.copernicus.org/articles/.html</self-uri><self-uri xlink:href="https://cp.copernicus.org/articles/.pdf">The full text article is available as a PDF file from https://cp.copernicus.org/articles/.pdf</self-uri>
      <abstract><title>Abstract</title>
    <p id="d1e291">Antarctic ice sheet and Southern Ocean paleoceanographic configurations
during the late Oligocene are not well resolved. They are however important
to understand the influence of high-latitude Southern Hemisphere feedbacks on
global climate under <inline-formula><mml:math id="M1" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> scenarios (between 400 and 750 ppm)
projected by the IPCC for this century, assuming unabated <inline-formula><mml:math id="M2" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>
emissions. Sediments recovered by the Integrated Ocean Drilling Program
(IODP) at Site U1356, offshore of the Wilkes Land margin in East Antarctica,
provide an opportunity to study ice sheet and paleoceanographic
configurations during the late Oligocene (26–25 Ma). Our study, based on a
combination of sediment facies analysis, magnetic susceptibility, density,
and X-ray fluorescence geochemical data, shows that glacial and interglacial
sediments are continuously reworked by bottom currents, with maximum
velocities occurring during the interglacial periods. Glacial sediments
record poorly ventilated, low-oxygenation bottom water conditions,
interpreted as resulting from a northward shift of westerly winds and surface
oceanic fronts. Interglacial sediments record more oxygenated and ventilated
bottom water conditions and strong current velocities, which suggests
enhanced mixing of the water masses as a result of a southward shift of the
polar front. Intervals with preserved carbonated nannofossils within some of
the interglacial facies are interpreted as forming under warmer paleoclimatic
conditions when less corrosive warmer northern component water (e.g., North
Atlantic sourced deep water) had a greater influence on the site. Spectral
analysis on the late Oligocene sediment interval shows that the
glacial–interglacial cyclicity and related displacements of the Southern
Ocean frontal<?pagebreak page992?> systems between 26 and 25 Ma were forced mainly by obliquity.
The paucity of iceberg-rafted debris (IRD) throughout
the studied interval contrasts with earlier Oligocene and post-Miocene
Climate Optimum sections from Site U1356 and with late Oligocene strata from
the Ross Sea, which contain IRD and evidence for coastal glaciers and sea
ice. These observations, supported by elevated sea surface paleotemperatures,
the absence of sea ice, and reconstructions of fossil pollen between 26 and
25 Ma at Site U1356, suggest that open-ocean water conditions prevailed.
Combined, this evidence suggests that glaciers or ice caps likely occupied
the topographic highs and lowlands of the now marine Wilkes Subglacial Basin
(WSB). Unlike today, the continental shelf was not overdeepened and thus ice
sheets in the WSB were likely land-based, and marine-based ice sheet
expansion was likely limited to coastal regions.</p>
  </abstract>
    </article-meta>
  </front>
<body>
      

<sec id="Ch1.S1" sec-type="intro">
  <label>1</label><title>Introduction</title>
      <p id="d1e325">Today, ice sheets on Antarctica contain about 26.5 million km<inline-formula><mml:math id="M3" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msup></mml:math></inline-formula> of ice,
which has the potential for raising global average sea level by 58 m, with
the East Antarctic Ice Sheet constituting 53.3 m of this sea level
equivalent (Fretwell et al., 2013). Satellite observations indicate
significant rates of change in most of the West Antarctic Ice Sheet (WAIS)
and some sectors of the East Antarctic Ice Sheet (EAIS). These include
thinning at their seaward margins (Pritchard et al., 2012) and accelerating
ice shelves' basal melt rates (Rignot et al., 2013; Shen et al., 2018). Given
the uncertainties in projections of future ice sheet melt, there has been a
growing number of studies of sedimentary sections from the surrounding
margins of Antarctica targeting records of past warm intervals (i.e.,
high-<inline-formula><mml:math id="M4" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> and elevated temperature climates) in order to better
understand ice sheets and Southern Ocean configurations under these
conditions. For example, the early Pliocene (5–3 Ma) has been targeted
because atmospheric <inline-formula><mml:math id="M5" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> concentrations were similar to today's
400 ppmv concentrations (Foster and Rohling, 2013; Zhang et al., 2013).
These studies have shown that early Pliocene Southern Ocean surface waters
were warmer (i.e., between 2.5<inline-formula><mml:math id="M6" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M7" display="inline"><mml:mi mathvariant="italic">&gt;</mml:mi></mml:math></inline-formula> 4 <inline-formula><mml:math id="M8" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C) than
present and that the summer sea ice cover was greatly reduced or even absent
(Bohaty and Hardwood, 1998; Whitehead and Bohaty, 2003; Escutia et al., 2009;
Cook et al., 2013). They also record the periodic collapse of both the WAIS
and EAIS marine-based margins (Naish et al., 2009; Pollard and DeConto, 2009;
Cook et al., 2013; Reinardy et al., 2015; DeConto and Pollard, 2016). Foster
and Rohling (2013) provide a sigmoidal relationship between eustatic sea
level and atmospheric <inline-formula><mml:math id="M9" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> levels whereby sea levels stabilize at
<inline-formula><mml:math id="M10" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 22 <inline-formula><mml:math id="M11" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 12 m above the present-day level between about 400 and
650 ppm, suggesting loss of the Greenland Ice Sheet (6–7 m s.l.e.) and
the marine-based West Antarctic Ice Sheet (<inline-formula><mml:math id="M12" display="inline"><mml:mo lspace="0mm">+</mml:mo></mml:math></inline-formula>7 m s.l.e.). This implies
that continental EAIS volumes remained relatively stable during these times
but experienced mass loss of some (or all) of its marine–based margins,
relative to the present day. With <inline-formula><mml:math id="M13" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> concentrations at
<inline-formula><mml:math id="M14" display="inline"><mml:mi mathvariant="italic">&gt;</mml:mi></mml:math></inline-formula> 650 ppm, they infer further increases in sea level,
suggesting this as a threshold for initiating the retreat of the terrestrial
margins of EAIS. With sustained warming, <inline-formula><mml:math id="M15" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> concentrations of more
than 650 ppmv are within the projections for this century (Solomon, 2007;
Field et al., 2014). The last time the atmosphere is thought to have
experienced <inline-formula><mml:math id="M16" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> concentrations above 650 ppmv was during the
Oligocene (23.03–33.9 Ma), when <inline-formula><mml:math id="M17" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> values remained between 400
and <inline-formula><mml:math id="M18" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 750–800 ppm (Pagani et al., 2005; Beerling and Royer, 2011;
Zhang et al., 2013).</p>
      <?pagebreak page993?><p id="d1e474">Geological records of heavy isotope values <inline-formula><mml:math id="M19" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 2.5 ‰ and
far-field sea level records from passive margins during the Oligocene suggest
that, following the continental-wide expansion of ice during the
Eocene–Oligocene Transition that culminated at the Oi-1 event (33.6 Ma),
the Antarctic ice cover was at least <inline-formula><mml:math id="M20" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 50 % of the current volume
(e.g., Kominz and Pekar, 2001; Zachos et al., 2001; Coxall et al., 2005;
Pekar et al., 2006; Liebrand et al., 2011, 2017; Mudelsee et al., 2014). The
early part of the Oligocene records a significant <inline-formula><mml:math id="M21" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula>
decreasing slope with high-latitude sites exhibiting a strong
deglaciation/warming that persisted until <inline-formula><mml:math id="M22" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 32 Ma (Mudelsee et al.,
2014). This was followed by seemingly stable conditions on Antarctica as
evidenced by minimal <inline-formula><mml:math id="M23" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M24" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Mg</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M25" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M26" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ca</mml:mi></mml:mrow></mml:math></inline-formula>
changes (Billups and Schrag, 2003; Lear et al., 2004; Mudelsee et al., 2014).
A slight glaciation/cooling is recorded before 28 to <inline-formula><mml:math id="M27" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 27 Ma, which
was followed by an up to 1 ‰ long-term decrease in the
<inline-formula><mml:math id="M28" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> isotope records that was interpreted as resulting from
the deglaciation of large parts of the Antarctic ice sheets during a
significant warming trend in the late Oligocene (27–26 Ma) (Zachos et al.,
2001). Nevertheless, there are marked differences between the late Oligocene
low <inline-formula><mml:math id="M29" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> values recorded at Pacific, Indian, and Atlantic
Ocean sites (e.g., Pälike et al., 2006; Cramer et al., 2009; Liebrand et
al., 2011; Mudelsee et al., 2014; Hauptvogel et al., 2017) and the sustained
high <inline-formula><mml:math id="M30" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> values recorded at Southern Ocean sites (Pekar et
al., 2006; Mudelsee et al., 2014). High <inline-formula><mml:math id="M31" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> values in the
Southern Ocean sediments are in agreement with the ice proximal record
recovered by the Cape Roberts Project (CRP) in the Ross Sea, which shows the
existence of glaciers/ice sheets at sea level (Barrett et al., 2007;
Hauptvogel et al., 2017). Based on the study of the isotopic record in
sediments from the Atlantic, the Indian, and the equatorial Pacific, Pekar et
al. (2006) explained this conundrum of a glaciated Antarctica and varying
intra-basinal <inline-formula><mml:math id="M32" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> values with the coeval existence of two
deep-water masses, one sourced from Antarctica and another, warmer bottom
water, sourced from lower latitudes. Superimposed on the above long-term
swings in the <inline-formula><mml:math id="M33" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> Oligocene record, fluctuations on
timescales shorter than several million years were identified in the
high-resolution benthic <inline-formula><mml:math id="M34" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">13</mml:mn></mml:msup><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula> record from ODP 1218 (Pälike
et al., 2006). These fluctuations in periods of 405 kyr and 1.2 Myr are
related to Earth's orbital variations in eccentricity and obliquity,
respectively, and have been referred to as the short-term “heartbeat” of
the Oligocene climate (Pälike et al., 2006). Oligocene records close to
Antarctica are needed to better resolve Antarctic ice sheet and
paleoceanographic configurations at different timescales and under scenarios
of increasing atmospheric <inline-formula><mml:math id="M35" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> concentrations.</p>
      <p id="d1e658">Integrated Ocean Drilling Program (IODP) Expedition 318 drilled a transect of
sites across the eastern Wilkes Land margin at the seaward termination of the
Wilkes Subglacial Basin (WSB) (Escutia et al., 2011, 2014) (Fig. 1).
Relatively good recovery (78.2 %) of late Oligocene (26–25 Ma)
sediments from Site U1356 between 689.4 and 641.4 m below the sea floor
(m b.s.f.) provides an opportunity to study ice sheet and ocean
configurations during the late Oligocene and to relate them to other
Antarctic and global records. In this paper, we present a new
glacial–interglacial sedimentation and paleoceanographic model for the
distal glaciomarine record of the Wilkes Land margin constructed on the basis
of sedimentological data (visual core description, facies analysis, computed
tomography images, and high-resolution scanning electron microscopy images),
physical properties (i.e., magnetic susceptibility of the bulk sediment and
grain density), and X-ray fluorescence data (XRF). We also provide insights
into the configuration of the ice sheet in this sector of the east Antarctic
margin and evidence for orbital forcing of the glaciomarine
glacial–interglacial sedimentation at Site U1356.</p>
      <p id="d1e661">Together with the companion
papers that study the dinoflagellate cyst assemblages (Bijl et al., 2018b),
and TEX86-based sea surface temperature reconstructions (Hartman et al.,
2018), we explore the role of oceanic forcing and ice sheet configuration
during astronomically paced glacial and interglacial periods of the Oligocene
and Miocene in the Wilkes Land Margin.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F1" specific-use="star"><?xmltex \currentcnt{1}?><label>Figure 1</label><caption><p id="d1e667">Location of IODP 318 Site U1356 (Escutia et al., 2010) on the
Adélie Coast continental rise. Bed topography from IBSCO2 (Arndt et al.,
2013).
Schematic position of the different water masses at present and locations of
Antarctic Bottom Water formation (Orsi, 1995) are indicated. The position of
the Oligocene Polar Front (Scher et al., 2015) is also shown. ASF: Antarctic
Slope Front; SB: southern boundary; SACCF: Southern Antarctic Counter Current
Front; ARB: Adélie Rift Block.</p></caption>
        <?xmltex \igopts{width=341.433071pt}?><graphic xlink:href="https://cp.copernicus.org/articles/14/991/2018/cp-14-991-2018-f01.pdf"/>

      </fig>

</sec>
<sec id="Ch1.S2">
  <label>2</label><title>Materials and methods</title>
<sec id="Ch1.S2.SS1">
  <label>2.1</label><title>Site U1356 description</title>
      <p id="d1e691">Site U1356 (63<inline-formula><mml:math id="M36" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>18.6138<inline-formula><mml:math id="M37" display="inline"><mml:msup><mml:mi/><mml:mo>′</mml:mo></mml:msup></mml:math></inline-formula> S, 135<inline-formula><mml:math id="M38" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>59.9376<inline-formula><mml:math id="M39" display="inline"><mml:msup><mml:mi/><mml:mo>′</mml:mo></mml:msup></mml:math></inline-formula> E) is located
at 3992 m water depth in front of the glaciated margin of the eastern Wilkes
Land Coast of East Antarctica and penetrated 1006 m into the flank of a
levee deposit in the transition between the lower continental rise and the
abyssal plain (Escutia et al., 2011; Fig. 1). Overall recovery was 35 %
with sediments dated to between the early Eocene and Pliocene, but several
intervals provide good stratigraphic control (Escutia et al., 2011; Tauxe et
al., 2012). The Oligocene section was recovered between 895 and
430.8 m b.s.f. (cores U1356-95R-3 83 cm to U1356-46R). Our study focuses
on the relatively high-recovery (78.2 %) interval within the late
Oligocene, which spans 689.4 to 641.4 m b.s.f. (cores U1356-72R to -68R).
The sediments from this interval are part of shipboard lithostratigraphic
Unit V, which is characterized by light greenish-grey, strongly bioturbated
claystones and micritic limestones interbedded with dark brown, sparsely
bioturbated, parallel- and ripple-laminated claystones with minor
cross-laminated interbeds (Escutia et al., 2011). The bioturbated and
calcareous claystones and limestones were broadly interpreted as representing
pelagic sedimentation superimposed on the background hemipelagic sedimentary
input (Escutia et al., 2011). The laminated claystones and ripple
cross-laminated sandstones were interpreted as likely resulting from variations
in bottom current strength and fine-grained terrigenous supply (Escutia et
al., 2011). In addition, a notable absence of iceberg-rafted debris (IRD)
(<inline-formula><mml:math id="M40" display="inline"><mml:mi mathvariant="italic">&gt;</mml:mi></mml:math></inline-formula> 250 <inline-formula><mml:math id="M41" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi></mml:mrow></mml:math></inline-formula>m) in this interval relative to underlying
and overlying strata was also recorded.</p>
      <p id="d1e746">The late Oligocene depositional setting of Site U1356 was, however, different
to that of today. The stratigraphic evolution of the region testifies to the
progradation of the continental shelf taking place after continental ice
sheet buildup during the Eocene–Oligocene Transition (EOT; 33.6 Ma;
Eittreim et al., 1995; Escutia et al., 2005, 2014), which resulted in
(1) seismic and sedimentary facies on the continental rise becoming more
proximal up-section (Hayes and Frakes, 1975; Escutia et al., 2000, 2005, 2014) and (2) high sedimentation
rates during the Oligocene (Escutia et al., 2011; Tauxe et al., 2012). In
this context, the studied late Oligocene sediments from Site U1356 record
distal continental rise deposition in an incipient/low-relief levee of a
submarine channel. As progradation continued, a complex network of
well-developed channels and high-relief levee systems developed on the
continental rise (Escutia et al., 2000) from the latest Oligocene onwards.</p>
      <p id="d1e749">Today, Site U1356 lies close to the southern boundary of the Antarctic
Circumpolar Current, near the Antarctic Divergence at <inline-formula><mml:math id="M42" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 63<inline-formula><mml:math id="M43" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> S
(Orsi et al., 1995; Bindoff et al., 2000) (Fig. 1). However, the
paleo-latitude of Site U1356 was around 58.5 <inline-formula><mml:math id="M44" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 2.5<inline-formula><mml:math id="M45" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> S (van
Hinsbergen et al., 2015) during the late Oligocene, i.e., more northerly than
today. Scher and Martin (2008) and Scher et al. (2015) reconstructed the
position of the early Oligocene Antarctic Divergence to be located around
60<inline-formula><mml:math id="M46" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> S (Fig. 1), based on the distribution of terrigenous and
biogenic (calcareous and siliceous microfossils) sedimentation, Nd isotopes,
and <inline-formula><mml:math id="M47" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Al</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M48" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M49" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ti</mml:mi></mml:mrow></mml:math></inline-formula> ratios through a core transect across the
Australian–Antarctic basin in the Southern Ocean. According to these
interpretations, Site U1356 lay far to the north of the Antarctic Divergence
zone and was closer to the polar front during the Oligocene.</p>
</sec>
<sec id="Ch1.S2.SS2">
  <label>2.2</label><title>Age model</title>
      <?pagebreak page994?><p id="d1e825">The age model for Site U1356 was established on the basis of the
magnetostratigraphic datums constrained by marine diatom, radiolaria,
calcareous nannoplankton, and dinocyst biostratigraphic control (Escutia et
al., 2011; Tauxe et al., 2012; Bijl et al., 2018a). The late Oligocene interval contains three magnetostratigraphic
datums (Table 1): (1) Chron C8n.1n (<inline-formula><mml:math id="M50" display="inline"><mml:mi>o</mml:mi></mml:math></inline-formula>) between 643.70 and 643.65 m b.s.f.
(U1356-68R-2), (2) C8n.2n (<inline-formula><mml:math id="M51" display="inline"><mml:mi>y</mml:mi></mml:math></inline-formula>) between 652.60 and 652.55 m b.s.f.
(U1356-69R-2), and (3) C8n.2n (<inline-formula><mml:math id="M52" display="inline"><mml:mi>o</mml:mi></mml:math></inline-formula>) between 679.90 and 678.06 m b.s.f.
(U1356-71R). For this study, the age model by Tauxe et al. (2012), which was
calibrated to the GTS2004 Time Scale (Gradstein et at., 2004), has been updated using the GTS 2012 Astronomic Age
Model (Vandenberghe et al., 2012). Based on this calibration, the age of sediments between
678.98 and 643.37 m b.s.f. is 25.99 and 25.26 Ma, respectively (Fig. 2;
Table 1).</p>

<?xmltex \floatpos{t}?><table-wrap id="Ch1.T1" specific-use="star"><?xmltex \currentcnt{1}?><label>Table 1</label><caption><p id="d1e852">Age model by Tauxe et al. (2012) and transformed ages to GPTS 2012.</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="7">
     <oasis:colspec colnum="1" colname="col1" align="center"/>
     <oasis:colspec colnum="2" colname="col2" align="center"/>
     <oasis:colspec colnum="3" colname="col3" align="center"/>
     <oasis:colspec colnum="4" colname="col4" align="center"/>
     <oasis:colspec colnum="5" colname="col5" align="center"/>
     <oasis:colspec colnum="6" colname="col6" align="center"/>
     <oasis:colspec colnum="7" colname="col7" align="center"/>
     <oasis:thead>
       <oasis:row>
         <oasis:entry colname="col1">Core section</oasis:entry>
         <oasis:entry colname="col2">Top depth</oasis:entry>
         <oasis:entry colname="col3">Bottom depth</oasis:entry>
         <oasis:entry colname="col4">Depth used</oasis:entry>
         <oasis:entry colname="col5">GPTS 2004</oasis:entry>
         <oasis:entry colname="col6">GPTS 2012</oasis:entry>
         <oasis:entry colname="col7">Chron</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Site U1356</oasis:entry>
         <oasis:entry colname="col2">(m b.s.f.)</oasis:entry>
         <oasis:entry colname="col3">(m b.s.f.)</oasis:entry>
         <oasis:entry colname="col4">(m)</oasis:entry>
         <oasis:entry colname="col5">(Myr)</oasis:entry>
         <oasis:entry colname="col6">(Myr)</oasis:entry>
         <oasis:entry colname="col7"/>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Exp. 318</oasis:entry>
         <oasis:entry colname="col2"/>
         <oasis:entry colname="col3"/>
         <oasis:entry colname="col4"/>
         <oasis:entry colname="col5">(Tauxe</oasis:entry>
         <oasis:entry colname="col6"/>
         <oasis:entry colname="col7"/>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2"/>
         <oasis:entry colname="col3"/>
         <oasis:entry colname="col4"/>
         <oasis:entry colname="col5">et al., 2012)</oasis:entry>
         <oasis:entry colname="col6"/>
         <oasis:entry colname="col7"/>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>
         <oasis:entry colname="col1">68R-2</oasis:entry>
         <oasis:entry colname="col2">643.10</oasis:entry>
         <oasis:entry colname="col3">643.65</oasis:entry>
         <oasis:entry colname="col4">643.37</oasis:entry>
         <oasis:entry colname="col5">25.444</oasis:entry>
         <oasis:entry colname="col6">25.260</oasis:entry>
         <oasis:entry colname="col7">C8n.1n (<inline-formula><mml:math id="M53" display="inline"><mml:mi>o</mml:mi></mml:math></inline-formula>)</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">69R-2</oasis:entry>
         <oasis:entry colname="col2">652.55</oasis:entry>
         <oasis:entry colname="col3">652.60</oasis:entry>
         <oasis:entry colname="col4">652.57</oasis:entry>
         <oasis:entry colname="col5">25.492</oasis:entry>
         <oasis:entry colname="col6">25.300</oasis:entry>
         <oasis:entry colname="col7">C8n.2n (<inline-formula><mml:math id="M54" display="inline"><mml:mi>y</mml:mi></mml:math></inline-formula>)</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">71R-6</oasis:entry>
         <oasis:entry colname="col2">678.06</oasis:entry>
         <oasis:entry colname="col3">679.90</oasis:entry>
         <oasis:entry colname="col4">678.98</oasis:entry>
         <oasis:entry colname="col5">26.154</oasis:entry>
         <oasis:entry colname="col6">25.990</oasis:entry>
         <oasis:entry colname="col7">C8n.2n (<inline-formula><mml:math id="M55" display="inline"><mml:mi>o</mml:mi></mml:math></inline-formula>)</oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table></table-wrap>

      <?xmltex \floatpos{t}?><fig id="Ch1.F2" specific-use="star"><?xmltex \currentcnt{2}?><label>Figure 2</label><caption><p id="d1e1067">Magnetic susceptibility (MS) and natural gamma radiation
(NGR) physical properties and selected X-ray fluorescence (XRF) data (in
total counts) and elemental ratios plotted against the new detailed U1356
facies log between 689.4 and 641.4 m b.s.f.</p></caption>
          <?xmltex \igopts{width=497.923228pt}?><graphic xlink:href="https://cp.copernicus.org/articles/14/991/2018/cp-14-991-2018-f02.png"/>

        </fig>

</sec>
<sec id="Ch1.S2.SS3">
  <label>2.3</label><title>Facies analyses</title>
      <p id="d1e1084">Detailed facies analyses provide a stratigraphic framework on which we base
our sedimentary processes and paleoenvironmental interpretations. Lithofacies
are determined on the basis of detailed visual logging of the core during a
visit to the IODP Gulf Coast Repository (GCR), expanding on the
lower-resolution preliminary descriptions in Escutia et al. (2011). We logged
the lithology, sedimentary texture (i.e., shape, size, and distribution of
particles), and structures with a focus on the contacts between the beds and
on bioturbation at a millimeter- to centimeter-scale resolution in cores
expanding from 896 to 95.4 m b.s.f. (cores U1356-95R to -11R) (see Figs. S1
and S2 in the Supplement). Physical property data were measured during IODP
Exp. 318 using the Whole Round Multisensor Logger. Magnetic susceptibility
measurements were taken at 2.5 cm intervals, and natural gamma radiation
(NGR) was measured every 10 cm (Escutia et al., 2011). In this paper, we
focus on the interval between 689.4 and 641.4 m b.s.f., which comprises
cores 72R to 68R (Fig. 2).</p>
      <p id="d1e1087">X-ray computed tomography scans (CT scans) measure changes in density and
allow for the analysis of fine-scale stratigraphic changes and internal
structures of sedimentary deposits in a nondestructive manner (e.g., Duliu,
1999; St-Onge and Long, 2009; Van Daele et al., 2014; Fouinat et al., 2017).
To further characterize the different facies in our cores, selected intervals
of Core U1356-71R-6 (678.11 to 676.91 m b.s.f.) and Core U1356-71R-2 (672.8
to 671.35 m b.s.f.) were CT-scanned at the Kochi Core Center (KCC) (Japan),
with the GE Medical systems LightSpeed Ultra 16. 2-D scout (shooting
conditions at 120 Kv with 100 mA; 3-D helical image with 120 Kv and
100 mA and FOV <inline-formula><mml:math id="M56" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 22.0). Image spatial resolution consists of
0.42 mm pixel<inline-formula><mml:math id="M57" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> with 0.625 mm of slice thickness (voxel spatial
resolution of 0.42 <inline-formula><mml:math id="M58" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 0.42 <inline-formula><mml:math id="M59" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 0.625 mm).</p>
      <p id="d1e1123">The type and composition of biogenic and terrigenous particles, particle
size, and morphology of each lithofacies was characterized with a
high-resolution scanning electron microscope (HR-SEM) at the Centro de
Instrumentación Científica (University of Granada, Spain).</p>
</sec>
<sec id="Ch1.S2.SS4">
  <label>2.4</label><title>X-ray fluorescence analyses</title>
      <p id="d1e1134">Detailed bulk-chemical composition records acquired by XRF core scanning
allow the accurate determination of sedimentological changes and the
assessment of the<?pagebreak page995?> contribution of the various components in the biogenic and
lithogenic fraction in marine sediments (Croudace et al., 2006). This
nondestructive method yields element intensities on the surface of split
sediment cores and provides statistically significant data for major and
minor elements (Richter et al., 2006; O'Regan et al., 2010; Wilhelms-Dick et
al., 2012). The data are given as element intensities in total counts.</p>
      <p id="d1e1137">XRF core scanning measurements were collected every 2 cm down-core over a
1 cm<inline-formula><mml:math id="M60" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:math></inline-formula> area with a split size of 10 mm, a current of 0.2 mA
(<inline-formula><mml:math id="M61" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Al</mml:mi></mml:mrow></mml:math></inline-formula>–<inline-formula><mml:math id="M62" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Fe</mml:mi></mml:mrow></mml:math></inline-formula>) and 1.5 mA (all other elements), and a sampling time
of 20 s, directly at the split core surface of the archive half with XRF
Core Scanner III at the MARUM – Center for Marine Environmental Sciences,
University of Bremen, Germany. Prior to the scanning, cores were thermally
equilibrated to room temperature; the surface was cleaned, flattened, and
covered with 4 <inline-formula><mml:math id="M63" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi></mml:mrow></mml:math></inline-formula>m thin SPEXCerti Prep Ultralene1 foil to protect
the sensor and prevent contamination during the scanning procedure. Scans
were collected during three separate runs using generator settings of 10 kV
for the elements <inline-formula><mml:math id="M64" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Al</mml:mi></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M65" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Si</mml:mi></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M66" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">S</mml:mi></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M67" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">K</mml:mi></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M68" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ca</mml:mi></mml:mrow></mml:math></inline-formula>,
<inline-formula><mml:math id="M69" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ti</mml:mi></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M70" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Mn</mml:mi></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M71" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Fe</mml:mi></mml:mrow></mml:math></inline-formula>; 30 kV for elements such as <inline-formula><mml:math id="M72" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Br</mml:mi></mml:mrow></mml:math></inline-formula>,
<inline-formula><mml:math id="M73" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Rb</mml:mi></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M74" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Zr</mml:mi></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M75" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Mo</mml:mi></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M76" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Pb</mml:mi></mml:mrow></mml:math></inline-formula>; and 50 kV for <inline-formula><mml:math id="M77" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ba</mml:mi></mml:mrow></mml:math></inline-formula>. The
data reported here were acquired by a Canberra X-PIPS silicon drift detector
(SDD; Model SXD 15C-150-500) with 150 eV X-ray resolution, the Canberra
Digital Spectrum Analyzer DAS 1000, and an Oxford Instruments 100 W Neptune
X-ray tube with rhodium (Rh) target material. Raw data spectra were processed
by the “Analysis of X-ray spectra by Iterative Least square software” (WIN
AXIL) package from Canberra Eurisys. Data points from disturbed intervals in
the core face (i.e., slight fractures and cracks) were removed.</p>
      <p id="d1e1288">The light elements <inline-formula><mml:math id="M78" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Al</mml:mi></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M79" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Si</mml:mi></mml:mrow></mml:math></inline-formula>, and <inline-formula><mml:math id="M80" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">K</mml:mi></mml:mrow></mml:math></inline-formula> show large element
variations (intra-element variations of 1 order of magnitude or more;
Fig. 2). Similar variations have been previously described in sediment cores
to indicate substantial analytical deviations due to physical sedimentary
properties (i.e., Tjallingii and Röhl et al., 2007; Hennekam and de
Lange, 2012). Accordingly, for this study we have discarded the continuous
records of <inline-formula><mml:math id="M81" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Al</mml:mi></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M82" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Si</mml:mi></mml:mrow></mml:math></inline-formula>, and <inline-formula><mml:math id="M83" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">K</mml:mi></mml:mrow></mml:math></inline-formula> and concentrated our
interpretations on <inline-formula><mml:math id="M84" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Al</mml:mi></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M85" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Si</mml:mi></mml:mrow></mml:math></inline-formula>, and <inline-formula><mml:math id="M86" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">K</mml:mi></mml:mrow></mml:math></inline-formula> values from the XRF
analyses in discrete samples (see below). As Titanium (<inline-formula><mml:math id="M87" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ti</mml:mi></mml:mrow></mml:math></inline-formula>) is
restricted to the terrigenous phase in sediments and is inert to diagenetic
processes (Calvert and Pedersen, 2007), we utilized <inline-formula><mml:math id="M88" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ti</mml:mi></mml:mrow></mml:math></inline-formula> to normalize
other chemical elements for the terrigenous fraction. Linear correlation
(r Pearson) above standardized values has been
done in order to find statistical relationships among the variables.</p>
      <p id="d1e1380">In addition, we conducted measurements of a total of 50 major and minor
trace elements in 25 discrete sediment samples collected at 0.4 and 1 m spacing to determine their chemical composition. For this, we used a
Pioneer-Bruker XRF spectrometer S4 at the Instituto
Andaluz de Ciencias de la Tierra (CSIC-UGR) in Spain, equipped with a Rh tube (60 kV, 150 mA) using internal standards. The samples were prepared in
a Vulcan 4Mfusion machine and the analyses performed using a standard-less
spectrum sweep with the Spectraplus software.</p>
</sec>
<sec id="Ch1.S2.SS5">
  <label>2.5</label><title>Spectral analyses</title>
      <p id="d1e1392">We selected key environmental indicators from XRF core scanner data and
elemental ratios (i.e., <inline-formula><mml:math id="M89" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Zr</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M90" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M91" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ba</mml:mi></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M92" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ba</mml:mi></mml:mrow></mml:math></inline-formula>,
<inline-formula><mml:math id="M93" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Zr</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M94" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M95" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ti</mml:mi></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M96" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ca</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M97" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M98" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ti</mml:mi></mml:mrow></mml:math></inline-formula>, magnetic
susceptibility (<inline-formula><mml:math id="M99" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">MS</mml:mi></mml:mrow></mml:math></inline-formula>)) to conduct spectral
analyses on the data from the interval between 689.4 to 641.4 m b.s.f.
(cores U1356-72R to 68R). We performed an evolutionary spectral and harmonic
analysis on each dataset using the Astrochron toolkit in the R software
(Meyers, 2014). A detailed methodology is provided in the Supplement,
following the Astrochron code of Wanlu et al. (2016). This method allows the
detection of nonstationary spectra variability within the time series. The
time series were analyzed on the depth scale and then, applying the Frequency
domain minimal tuning (Meyers et al., 2001), we converted spatial frequencies
to sedimentation rates using an average period of 41 kyr to transform them
to an age scale, on the basis of the already resolved age model. The
evolutionary average spectral misfit method was then used to resolve unevenly
sampled series and changing sedimentation rates (Meyers et al., 2012). This
method is used to test a range of plausible timescales and simultaneously
evaluate the reliability of the presence of astronomical cycles
(Sect. S2).</p>
</sec>
</sec>
<sec id="Ch1.S3">
  <label>3</label><title>Results</title>
<sec id="Ch1.S3.SS1">
  <label>3.1</label><title>Sedimentary facies</title>
      <p id="d1e1497">The revised Oligocene facies log (Figs. S1, S2) includes the high-recovery
interval between 689.4 and 641.4 m b.s.f.<?pagebreak page996?> (Fig. 2). The integration of our
lithofacies analyses, with physical properties (MS), CT scans, and HR-SEM
analyses, characterize an alternation between two main facies (Facies 1 and
2) (Figs. 2, 3, 4). Although these two facies were already visually
identified on shipboard, our analyses allow us a more detailed
characterization and interpretation of the depositional environments and the
processes involved in their development.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F3" specific-use="star"><?xmltex \currentcnt{3}?><label>Figure 3</label><caption><p id="d1e1502">Detailed images, CT scans, and HR-SEM from Facies 1 (F1) and Facies
2 (F2). <bold>(a)</bold> Example of F1 taken from Core 71R-2 119/146 cm, showing
faint laminations (fl) and bioturbation by <italic>Planolites</italic> (p).
<bold>(b)</bold> CT-scan 3-D image of the same core interval; note the pyritized
burrows (py). <bold>(c)</bold> Example of F2 taken from core 72R-1 18/53 cm).
<bold>(d–f)</bold> Close-ups of laminations from F1: ripples (r), planar
lamination (pl), and faint laminations (fl), with mud offshoots (mo).
<bold>(d)</bold> <italic>Chondrites</italic> (Ch) bioturbation inside F1.
<bold>(g)</bold> HR-SEM image of F1 (68R-4-86/88 cm) with detritic aspect and a
mudstone clay matrix, quartz grains (Qz), diagenetic calcite (arrows), and
dissolved coccoliths (circles). <bold>(h)</bold> HR-SEM image of F2 (71R-2
140/142 cm) silt-sized matrix and reworked calcareous nannofossils and
conchoidal quartz grain (C-Qz). <bold>(i)</bold> Detail of dissolved coccoliths
and diagenetic calcite mineral. <bold>(j)</bold> Detail of a dissolved and
reworked calcareous nannofossils and a fractured conchoidal quartz (C-Qz).</p></caption>
          <?xmltex \igopts{width=426.791339pt}?><graphic xlink:href="https://cp.copernicus.org/articles/14/991/2018/cp-14-991-2018-f03.pdf"/>

        </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F4" specific-use="star"><?xmltex \currentcnt{4}?><label>Figure 4</label><caption><p id="d1e1547">Detailed facies characterization of two representative sections
using <bold>(a)</bold> interpreted Facies F1 and F2; a high-resolution digital
image of the core sections <bold>(b)</bold>, facies log <bold>(c)</bold>, magnetic
susceptibility (MS) <bold>(d)</bold>, XRF <inline-formula><mml:math id="M100" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Zr</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M101" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M102" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ba</mml:mi></mml:mrow></mml:math></inline-formula> ratio <bold>(e)</bold>,
and XRF calcium counts <bold>(f)</bold>.</p></caption>
          <?xmltex \igopts{width=455.244094pt}?><graphic xlink:href="https://cp.copernicus.org/articles/14/991/2018/cp-14-991-2018-f04.pdf"/>

        </fig>

      <p id="d1e1599">Facies 1 (F1) consists of slightly bioturbated greenish claystones with
sparse (Fig. 3a) to common laminations (Figs. 2, 3a–f; Table 2). Laminae, as
described on shipboard, vary from 0.1 to 1 cm thick and, based on
nonquantitative<?pagebreak page997?> smear slide observations, are composed of well-sorted silt to
fine sand-size quartz grains (Escutia et al., 2011). Laminations can be
planar and wavy, with ripple cross lamination structures (Escutia et al.,
2011), and show faint internal truncation surfaces, mud offshoots, and
internal erosional surfaces (Fig. 3a–f). HR-SEM analyses of the claystones
show that the matrix is composed of clay-size particles and clay minerals
(Fig. 3g, i). In addition, they show rare calcareous nannofossils that are
partially dissolved (Fig. 3g, i). Authigenic carbonate crystals are also
identified (Fig. 3i). Bioturbation in F1 is scarce, ichnofossils in the
sediments are dominated mainly by <italic>Chondrites</italic> (Fig. 3d). CT scans
also show the presence of <italic>Skolithos</italic>, with their vertical thin tubes
filled with high-density material suggesting they are pyritized (Fig. 3b).
Pyrite was also observed in shipboard smear slides in small abundances from
the laminated facies in the studied interval (Escutia et al., 2011). Magnetic
susceptibility values within the laminated facies are low, between 40 and
70 MS instrumental units (iu), with higher values when silt laminations are
more abundant (Figs. 2, 4). NGR is anticorrelated with MS, with high values
in F1 varying between 50 and 65 counts per second (cps) (Fig. 2).</p>

<?xmltex \floatpos{t}?><table-wrap id="Ch1.T2" specific-use="star"><?xmltex \currentcnt{2}?><label>Table 2</label><caption><p id="d1e1611">Types of facies differentiated by physical, geochemical,
and biological character and their interpretation in terms of sedimentary
processes and paleoclimate.</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="4">
     <oasis:colspec colnum="1" colname="col1" align="justify" colwidth="66pt"/>
     <oasis:colspec colnum="2" colname="col2" align="justify" colwidth="35pt" colsep="1"/>
     <oasis:colspec colnum="3" colname="col3" align="justify" colwidth="183pt"/>
     <oasis:colspec colnum="4" colname="col4" align="justify" colwidth="153pt"/>
     <oasis:thead>
       <oasis:row rowsep="1">

         <oasis:entry colname="col1"/>

         <oasis:entry colname="col2"/>

         <oasis:entry colname="col3">Facies 1 (F1)</oasis:entry>

         <oasis:entry colname="col4">Facies 2 (F2)</oasis:entry>

       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row rowsep="1">

         <oasis:entry namest="col1" nameend="col2" align="left" colsep="1">Lithological description </oasis:entry>

         <oasis:entry colname="col3">Bioturbated green claystones with thin silt laminae with planar and cross-bedded laminations</oasis:entry>

         <oasis:entry colname="col4">Highly bioturbated, thicker pale-brown,<?xmltex \hack{\hfill\break}?>silty claystones</oasis:entry>

       </oasis:row>
       <oasis:row>

         <?xmltex \mrwidth{66pt}?><oasis:entry rowsep="1" colname="col1" morerows="1">Contacts</oasis:entry>

         <oasis:entry rowsep="1" colname="col2">Top</oasis:entry>

         <oasis:entry rowsep="1" colname="col3">Gradual, bioturbated</oasis:entry>

         <oasis:entry rowsep="1" colname="col4">Sharp</oasis:entry>

       </oasis:row>
       <oasis:row rowsep="1">

         <oasis:entry colname="col2">Bottom</oasis:entry>

         <oasis:entry colname="col3">Sharp</oasis:entry>

         <oasis:entry colname="col4">Gradual, bioturbated</oasis:entry>

       </oasis:row>
       <oasis:row rowsep="1">

         <oasis:entry namest="col1" nameend="col2" align="left" colsep="1">Bioturbation </oasis:entry>

         <oasis:entry colname="col3">Sparse bioturbation; primary structures preserved</oasis:entry>

         <oasis:entry colname="col4">Strongly bioturbated; massive; no primary<?xmltex \hack{\hfill\break}?>structures preserved</oasis:entry>

       </oasis:row>
       <oasis:row rowsep="1">

         <oasis:entry namest="col1" nameend="col2" align="left" colsep="1">Nannos </oasis:entry>

         <oasis:entry colname="col3">Barren to rare</oasis:entry>

         <oasis:entry colname="col4">Barren to variable abundance and<?xmltex \hack{\hfill\break}?>preservation</oasis:entry>

       </oasis:row>
       <oasis:row rowsep="1">

         <oasis:entry namest="col1" nameend="col2" align="left" colsep="1">IRD </oasis:entry>

         <oasis:entry colname="col3">No</oasis:entry>

         <oasis:entry colname="col4">No</oasis:entry>

       </oasis:row>
       <oasis:row rowsep="1">

         <oasis:entry namest="col1" nameend="col2" align="left" colsep="1">Magnetic susceptibility (MS) </oasis:entry>

         <oasis:entry colname="col3">Low in claystones and high in silty laminations</oasis:entry>

         <oasis:entry colname="col4">High</oasis:entry>

       </oasis:row>
       <oasis:row>

         <oasis:entry colname="col1">XRF-scanner</oasis:entry>

         <oasis:entry rowsep="1" colname="col2"><inline-formula><mml:math id="M103" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Zr</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>

         <oasis:entry rowsep="1" colname="col3">Low in claystones and high in silty laminations</oasis:entry>

         <oasis:entry rowsep="1" colname="col4">High (max. values on top)</oasis:entry>

       </oasis:row>
       <oasis:row>

         <oasis:entry colname="col1">element</oasis:entry>

         <oasis:entry rowsep="1" colname="col2"><inline-formula><mml:math id="M104" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ba</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>

         <oasis:entry rowsep="1" colname="col3">High (max. values on bottom)</oasis:entry>

         <oasis:entry rowsep="1" colname="col4">Low</oasis:entry>

       </oasis:row>
       <oasis:row rowsep="1">

         <oasis:entry colname="col1">concentration</oasis:entry>

         <oasis:entry colname="col2"><inline-formula><mml:math id="M105" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ca</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>

         <oasis:entry colname="col3">No</oasis:entry>

         <oasis:entry colname="col4">Variable, low to high</oasis:entry>

       </oasis:row>
       <oasis:row rowsep="1">

         <oasis:entry namest="col1" nameend="col2" align="left" colsep="1">Formation process </oasis:entry>

         <oasis:entry colname="col3">Bottom currents of fluctuating intensities</oasis:entry>

         <oasis:entry colname="col4">Bottom currents with higher velocity and<?xmltex \hack{\hfill\break}?>constant flux</oasis:entry>

       </oasis:row>
       <oasis:row>

         <oasis:entry namest="col1" nameend="col2" align="left" colsep="1">Facies interpretation </oasis:entry>

         <oasis:entry colname="col3">Cold periods; supply of terrigenous by density current flows, reworked by bottom currents</oasis:entry>

         <oasis:entry colname="col4">Well-oxygenated deep-sea sedimentation; <?xmltex \hack{\hfill\break}?>warm periods with reworking of sediments<?xmltex \hack{\hfill\break}?>by bottom currents</oasis:entry>

       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table></table-wrap>

      <p id="d1e1835">Facies 2 (F2) is composed by light greenish grey, strongly bioturbated
claystones and silty claystones (Figs. 2, 3; Table 2) with variable carbonate
content varying between 5 and 16 % based on our XRF analyses. No primary
structures are preserved due to the pervasive bioturbation (Fig. 3a–c).
Burrows are backfilled with homogeneous coarse material (silt/fine sand).
Different types of ichnofossils are present with <italic>Planolites </italic>and
<italic>Zoophycos</italic> being the most abundant (Fig. 3a, b). HR-SEM images show
(1) silt-size grains containing quartz grains with conchoidal fractures in
the corners and impact marks on the crystal faces, indicative of high-energy
environments and (2) biogenic carbonate consisting of moderately to poorly
preserved coccoliths, which exhibit dissolution of their borders, and to a
minor degree detrital carbonate grains (Fig. 3h–j). A total of 13
carbonate-rich layers have been observed within the studied interval F2,<?pagebreak page998?> and
they range in thickness from 10 to 110 cm. Facies 2 CT-scan images show an
increase in density (i.e., gradation towards lighter colors in the scan)
towards the top of each bioturbated interval (Fig. 3b). MS values are higher
in F2 compared to F1. Values vary from 50 to 150 instrumental units (iu) and
exhibit an inverse grading or a bigradational-like morphology (Figs. 2, 4),
while NGR is inversely correlated with minimum values occurring in F2
(between 35 and 55 cps) (Fig. 2).</p>
      <p id="d1e1844">Contacts between the two facies are sharp and apparently nonerosive, with
minimal omission surfaces or lags (Figs. 3, 4). However, when bioturbation is
present, gradual contacts in the transition from F1 to F2 also occur
(Fig. 3b). Both sharp and transitional contacts are well imaged on the MS
plots (Fig. 2).</p>
      <p id="d1e1847">In addition, where available, the CT-scan images confirm the shipboard and
our own visual observations regarding the absence of outsized clasts and
coarse sand grains in F1 and F2. Hauptvogel (2015), however, reports grains
that are <inline-formula><mml:math id="M106" display="inline"><mml:mi mathvariant="italic">&gt;</mml:mi></mml:math></inline-formula> 150 <inline-formula><mml:math id="M107" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi></mml:mrow></mml:math></inline-formula>m in size (fine sand fraction) as
IRD. He argues that grains of that size could only reach Site U1356 through
ice rafting given the distance of the site to shore, unless they were
delivered by gravity flows. Thick and coarse-grained mass transport deposits
(MTDs) during the latest Oligocene at Site U1356 (Escutia et al., 2011),
argue for coarse material being delivered to the site by gravity flows. In
addition, fine sand grains to gravel-size clasts have been reported from
channels on the lower continental rise off the Wilkes Land margin transported
by gravity flows, including turbidity flows (Payne et al.,
1972; Escutia et al., 2000; Busetti et al.,
2003). Given that during the late Oligocene, Site U1356 is located on a
low-relief levee of a submarine channel, one can expect delivery of
fine-grained sand and even coarser sediment to the site. In any case, even if
some background IRD is present in our record, we argue it is minimal compared
to elsewhere in the core.</p>
</sec>
<sec id="Ch1.S3.SS2">
  <label>3.2</label><title>Geochemistry</title>
      <p id="d1e1873">Down-core changes in the log ratios of various elements have been plotted
against the facies log (Figs. 2, 4). In addition, in order to determine
geochemical element associations, we<?pagebreak page999?> performed a Pearson correlation
coefficient analysis of major elements on the whole XRF-scanner dataset
(Table 3). This analysis highlights two main groups that are used as proxies
for terrigenous (i.e., <inline-formula><mml:math id="M108" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Zr</mml:mi></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M109" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ti</mml:mi></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M110" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Rb</mml:mi></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M111" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ba</mml:mi></mml:mrow></mml:math></inline-formula>) vs.
biogenic (i.e., <inline-formula><mml:math id="M112" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ca</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M113" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> carbonate) sedimentation.</p>

<?xmltex \floatpos{t}?><table-wrap id="Ch1.T3" specific-use="star"><?xmltex \currentcnt{3}?><label>Table 3</label><caption><p id="d1e1927">R Pearson Linear correlation between XRF-scanner elements.</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="11">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="right"/>
     <oasis:colspec colnum="3" colname="col3" align="right"/>
     <oasis:colspec colnum="4" colname="col4" align="right"/>
     <oasis:colspec colnum="5" colname="col5" align="right"/>
     <oasis:colspec colnum="6" colname="col6" align="right"/>
     <oasis:colspec colnum="7" colname="col7" align="right"/>
     <oasis:colspec colnum="8" colname="col8" align="right"/>
     <oasis:colspec colnum="9" colname="col9" align="right"/>
     <oasis:colspec colnum="10" colname="col10" align="right"/>
     <oasis:colspec colnum="11" colname="col11" align="right"/>
     <oasis:thead>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M114" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">MS</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M115" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">S</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M116" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ca</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M117" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ti</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col6"><inline-formula><mml:math id="M118" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Mn</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col7"><inline-formula><mml:math id="M119" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Fe</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col8"><inline-formula><mml:math id="M120" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Br</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col9"><inline-formula><mml:math id="M121" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Rb</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col10"><inline-formula><mml:math id="M122" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Zr</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col11"><inline-formula><mml:math id="M123" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Sr</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M124" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">S</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M125" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.214</oasis:entry>
         <oasis:entry colname="col3"/>
         <oasis:entry colname="col4"/>
         <oasis:entry colname="col5"/>
         <oasis:entry colname="col6"/>
         <oasis:entry colname="col7"/>
         <oasis:entry colname="col8"/>
         <oasis:entry colname="col9"/>
         <oasis:entry colname="col10"/>
         <oasis:entry colname="col11"/>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M126" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ca</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">0.226</oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M127" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.122</oasis:entry>
         <oasis:entry colname="col4"/>
         <oasis:entry colname="col5"/>
         <oasis:entry colname="col6"/>
         <oasis:entry colname="col7"/>
         <oasis:entry colname="col8"/>
         <oasis:entry colname="col9"/>
         <oasis:entry colname="col10"/>
         <oasis:entry colname="col11"/>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M128" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ti</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M129" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.212</oasis:entry>
         <oasis:entry colname="col3">0.620</oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M130" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.290</oasis:entry>
         <oasis:entry colname="col5"/>
         <oasis:entry colname="col6"/>
         <oasis:entry colname="col7"/>
         <oasis:entry colname="col8"/>
         <oasis:entry colname="col9"/>
         <oasis:entry colname="col10"/>
         <oasis:entry colname="col11"/>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M131" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Mn</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">0.151</oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M132" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.121</oasis:entry>
         <oasis:entry colname="col4">0.858</oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M133" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.246</oasis:entry>
         <oasis:entry colname="col6"/>
         <oasis:entry colname="col7"/>
         <oasis:entry colname="col8"/>
         <oasis:entry colname="col9"/>
         <oasis:entry colname="col10"/>
         <oasis:entry colname="col11"/>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M134" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Fe</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">0.0419</oasis:entry>
         <oasis:entry colname="col3">0.0449</oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M135" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.396</oasis:entry>
         <oasis:entry colname="col5">0.510</oasis:entry>
         <oasis:entry colname="col6"><inline-formula><mml:math id="M136" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.324</oasis:entry>
         <oasis:entry colname="col7"/>
         <oasis:entry colname="col8"/>
         <oasis:entry colname="col9"/>
         <oasis:entry colname="col10"/>
         <oasis:entry colname="col11"/>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M137" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Br</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M138" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.297</oasis:entry>
         <oasis:entry colname="col3">0.111</oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M139" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.438</oasis:entry>
         <oasis:entry colname="col5">0.118</oasis:entry>
         <oasis:entry colname="col6"><inline-formula><mml:math id="M140" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.363</oasis:entry>
         <oasis:entry colname="col7">0.056</oasis:entry>
         <oasis:entry colname="col8"/>
         <oasis:entry colname="col9"/>
         <oasis:entry colname="col10"/>
         <oasis:entry colname="col11"/>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M141" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Rb</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M142" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.282</oasis:entry>
         <oasis:entry colname="col3">0.036</oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M143" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.576</oasis:entry>
         <oasis:entry colname="col5">0.286</oasis:entry>
         <oasis:entry colname="col6"><inline-formula><mml:math id="M144" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.489</oasis:entry>
         <oasis:entry colname="col7">0.455</oasis:entry>
         <oasis:entry colname="col8">0.493</oasis:entry>
         <oasis:entry colname="col9"/>
         <oasis:entry colname="col10"/>
         <oasis:entry colname="col11"/>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M145" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Zr</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">0.480</oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M146" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.164</oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M147" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.036</oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M148" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.099</oasis:entry>
         <oasis:entry colname="col6"><inline-formula><mml:math id="M149" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.058</oasis:entry>
         <oasis:entry colname="col7"><inline-formula><mml:math id="M150" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.055</oasis:entry>
         <oasis:entry colname="col8">0.102</oasis:entry>
         <oasis:entry colname="col9">0.067</oasis:entry>
         <oasis:entry colname="col10"/>
         <oasis:entry colname="col11"/>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M151" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Sr</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">0.186</oasis:entry>
         <oasis:entry colname="col3">0.006</oasis:entry>
         <oasis:entry colname="col4">0.871</oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M152" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.074</oasis:entry>
         <oasis:entry colname="col6">0.677</oasis:entry>
         <oasis:entry colname="col7"><inline-formula><mml:math id="M153" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.345</oasis:entry>
         <oasis:entry colname="col8"><inline-formula><mml:math id="M154" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.303</oasis:entry>
         <oasis:entry colname="col9"><inline-formula><mml:math id="M155" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.515</oasis:entry>
         <oasis:entry colname="col10">0.040</oasis:entry>
         <oasis:entry colname="col11"/>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M156" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ba</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M157" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.290</oasis:entry>
         <oasis:entry colname="col3">0.339</oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M158" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.234</oasis:entry>
         <oasis:entry colname="col5">0.662</oasis:entry>
         <oasis:entry colname="col6"><inline-formula><mml:math id="M159" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.210</oasis:entry>
         <oasis:entry colname="col7">0.354</oasis:entry>
         <oasis:entry colname="col8">0.343</oasis:entry>
         <oasis:entry colname="col9">0.402</oasis:entry>
         <oasis:entry colname="col10">0.018</oasis:entry>
         <oasis:entry colname="col11">0.039</oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table></table-wrap>

      <p id="d1e2603">Titanium (<inline-formula><mml:math id="M160" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ti</mml:mi></mml:mrow></mml:math></inline-formula>), Zirconium (<inline-formula><mml:math id="M161" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Zr</mml:mi></mml:mrow></mml:math></inline-formula>), and Rubidium (<inline-formula><mml:math id="M162" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Rb</mml:mi></mml:mrow></mml:math></inline-formula>) are
primarily derived from terrigenous sources, where <inline-formula><mml:math id="M163" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ti</mml:mi></mml:mrow></mml:math></inline-formula> represents the
background terrigenous input. During sediment transport <inline-formula><mml:math id="M164" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Zr</mml:mi></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M165" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Rb</mml:mi></mml:mrow></mml:math></inline-formula>,
and <inline-formula><mml:math id="M166" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ti</mml:mi></mml:mrow></mml:math></inline-formula> tend to become concentrated in particular grain-size fractions
due to the varying resistance of the minerals in which these elements
principally occur. <inline-formula><mml:math id="M167" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Zr</mml:mi></mml:mrow></mml:math></inline-formula> tends to become more concentrated in fine sand
and coarse-silt fractions, Ti in somewhat finer fractions, and Rb principally
in the clay-sized fraction (Veldkamp and Kroonenberg 1993; Dypvik and Harris
2001). The lack of correlation between <inline-formula><mml:math id="M168" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Zr</mml:mi></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M169" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ti</mml:mi></mml:mrow></mml:math></inline-formula> (Fig. 2;
Table 3) implies that they are settled in different minerals and processes.
The <inline-formula><mml:math id="M170" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Zr</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M171" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M172" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Rb</mml:mi></mml:mrow></mml:math></inline-formula> ratio has been applied as a sediment grain-size
proxy in marine records (Schneider, et al., 1997; Dypvik and Harris 2001;
Croudace et al., 2006; Campagne et al., 2015). <inline-formula><mml:math id="M173" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Zr</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M174" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M175" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Al</mml:mi></mml:mrow></mml:math></inline-formula> has
been interpreted as an indicator for the accumulation of heavy minerals due
to bottom currents (Bahr et al., 2014). In our cores,
<inline-formula><mml:math id="M176" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Zr</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M177" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M178" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Rb</mml:mi></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M179" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Zr</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M180" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M181" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ti</mml:mi></mml:mrow></mml:math></inline-formula> ratios have a
near-identical variability down-core (Fig. 2). We utilize the high-amplitude
<inline-formula><mml:math id="M182" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Zr</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M183" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M184" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ti</mml:mi></mml:mrow></mml:math></inline-formula> signal in our records as an indicator of larger
grain size and current velocity (Fig. 2). The <inline-formula><mml:math id="M185" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Zr</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M186" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M187" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ti</mml:mi></mml:mrow></mml:math></inline-formula> ratio
varies between 0.1 and 1 and exhibits maximum values within F2 showing an
increasing upwards or bigradational patterns (Fig. 2). Although minimum
<inline-formula><mml:math id="M188" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Zr</mml:mi></mml:mrow></mml:math></inline-formula> values (cps) are found in F1, laminations with coarser-grained
sediment within this claystone facies are also characterized by elevated
<inline-formula><mml:math id="M189" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Zr</mml:mi></mml:mrow></mml:math></inline-formula> values similar to those in F2 (Figs. 3, 4; Table 3). The
<inline-formula><mml:math id="M190" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Zr</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M191" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M192" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ti</mml:mi></mml:mrow></mml:math></inline-formula> pattern is positively correlated with magnetic
susceptibility throughout the studied interval (Fig. 2).</p>
      <p id="d1e2869">The <inline-formula><mml:math id="M193" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Zr</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M194" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M195" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ti</mml:mi></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M196" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Zr</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M197" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M198" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Rb</mml:mi></mml:mrow></mml:math></inline-formula>, and
<inline-formula><mml:math id="M199" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Zr</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M200" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M201" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ba</mml:mi></mml:mrow></mml:math></inline-formula> ratios covary characterizing the laminations within
F1 and the alternation between F1 and F2 by defining the contacts between
them (Figs. 2, 4). They also mark the coarsening upwards or bigradational
tendency in F2 (Fig. 4). Of the three ratios, the <inline-formula><mml:math id="M202" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Zr</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M203" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M204" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ba</mml:mi></mml:mrow></mml:math></inline-formula>
ratio is the one that highlights these patterns best (Figs. 2, 4).</p>
      <?pagebreak page1000?><p id="d1e2966">Barium (<inline-formula><mml:math id="M205" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ba</mml:mi></mml:mrow></mml:math></inline-formula>) is present in marine sediments mainly in detrital
plagioclase crystals and in the form of barite (<inline-formula><mml:math id="M206" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">BaSO</mml:mi><mml:mn mathvariant="normal">4</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>; Tribovillard
et al., 2006). In the studied sediments, <inline-formula><mml:math id="M207" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ba</mml:mi></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M208" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ti</mml:mi></mml:mrow></mml:math></inline-formula> have a
correlation factor of r<inline-formula><mml:math id="M209" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:math></inline-formula> = 0.66 (Table 3), which is taken to indicate
that Barium is predominantly present as a constituent of the continental
terrigenous fraction and/or that biogenic barite was sorted by bottom
currents. <inline-formula><mml:math id="M210" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ba</mml:mi></mml:mrow></mml:math></inline-formula> has maximum values (10 000 total counts) at the base of
F1 and decreases upwards in a sawtooth pattern, reaching minimum
concentrations within F2 (5000 total counts) (Fig. 2; Table 3). The detrital
fraction of <inline-formula><mml:math id="M211" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ba</mml:mi></mml:mrow></mml:math></inline-formula> in the open ocean has been used in other studies as a
tracer of shelf waters (Moore and Dymond, 1991; Abrahamsen et al., 2009;
Roeske, 2011), and the <inline-formula><mml:math id="M212" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ba</mml:mi></mml:mrow></mml:math></inline-formula> record is also affected by current intensity
in other depositional contourite systems (Bahr et al., 2014) preventing its
use as paleo-productivity proxy in environments dominated by contour
currents.</p>
      <p id="d1e3038">Variations in Ca, Mn, and Sr are strongly intercorrelated (Fig. 2) with
r<inline-formula><mml:math id="M213" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:math></inline-formula> <inline-formula><mml:math id="M214" display="inline"><mml:mi mathvariant="italic">&gt;</mml:mi></mml:math></inline-formula> 0.87 (Table 3). Biogenic calcite precipitated by
coccoliths and foraminifera have greater Sr concentration than inorganically
precipitated calcite or dolomite (Hodell et al., 2008). The positive Ca and
Sr correlation could therefore potentially be used to differentiate between
terrigenous Ca sources (e.g., feldspars and clays) and biogenic carbonates
(e.g., Richter et al., 2006; Foubert and Henriet, 2009; Rothwell and
Croudace, 2015). Based on these observations, we interpret the <inline-formula><mml:math id="M215" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ca</mml:mi></mml:mrow></mml:math></inline-formula> in
our sediments as being mainly of biogenic origin (<inline-formula><mml:math id="M216" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CaCO</mml:mi><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>). This
interpretation is supported by HR-SEM images taken from carbonate-rich
intervals of F2, which show abundant coccoliths (Fig. 3d). Peaks in Ca in our
record (Fig. 2) coincide with the carbonate-rich layers listed in the
previous section. Additional peaks in the record may indicate carbonate-rich
layers that we have been unable to identify visually.</p>
      <p id="d1e3076">In order to estimate the <inline-formula><mml:math id="M217" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CaCO</mml:mi><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> content continuously throughout the
studied interval we use a calibration (r<inline-formula><mml:math id="M218" display="inline"><mml:mrow><mml:msubsup><mml:mi/><mml:mrow><mml:mi mathvariant="normal">U</mml:mi><mml:mn mathvariant="normal">1356</mml:mn></mml:mrow><mml:mn mathvariant="normal">2</mml:mn></mml:msubsup><mml:mo>=</mml:mo></mml:mrow></mml:math></inline-formula> 0.81) between
the natural logarithm (ln) of the <inline-formula><mml:math id="M219" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ca</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M220" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M221" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ti</mml:mi></mml:mrow></mml:math></inline-formula> ratio
(ln(<inline-formula><mml:math id="M222" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ca</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M223" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M224" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ti</mml:mi></mml:mrow></mml:math></inline-formula>)) from the XRF core scanner data and the XRF
discrete <inline-formula><mml:math id="M225" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CaCO</mml:mi><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> measurements (weight %) from Site U1356 as
applied in other studies (Zachos et al., 2004; Liebrand et al., 2016)
(Fig. 5). “<inline-formula><mml:math id="M226" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CaCO</mml:mi><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> est.” is used throughout the text to refer to
carbonate content estimated by the ln(<inline-formula><mml:math id="M227" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ca</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M228" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M229" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ti</mml:mi></mml:mrow></mml:math></inline-formula>) ratio.
<inline-formula><mml:math id="M230" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CaCO</mml:mi><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> est. concentrations are generally low (between 0 and
16 %). Carbonates are mostly present in F2, varying between 5 and
16 %, although small contents (from 0 to 5 %) can be seen in the
intervals of F1 with scarce laminations (Fig. 4). <inline-formula><mml:math id="M231" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CaCO</mml:mi><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> est. peaks
in some intervals have a particular morphology producing a double peak in the
beginning and/or the end of bioturbated F2 (Figs. 2, 4).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F5"><?xmltex \currentcnt{5}?><label>Figure 5</label><caption><p id="d1e3224">Linear correlation between CaO % (discrete XRF) and
ln(<inline-formula><mml:math id="M232" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ca</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M233" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M234" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ti</mml:mi></mml:mrow></mml:math></inline-formula>) (XRF scanner) values in order to estimate carbonate contents
(<inline-formula><mml:math id="M235" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CaCO</mml:mi><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> est. %).</p></caption>
          <?xmltex \igopts{width=184.942913pt}?><graphic xlink:href="https://cp.copernicus.org/articles/14/991/2018/cp-14-991-2018-f05.png"/>

        </fig>

      <p id="d1e3268">Mn(II) is soluble under anoxic conditions and precipitates as Mn(IV)
oxyhydroxides under oxidizing conditions (Tribovillard et al., 2006).
Manganese is frequently remobilized to the sedimentary pore fluids under
reducing conditions. Dissolved <inline-formula><mml:math id="M236" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Mn</mml:mi></mml:mrow></mml:math></inline-formula> can thus migrate in the sedimentary
column and (re)precipitate when oxic conditions are encountered (Calvert and
Pedersen, 1996). As such, large Mn enrichments primarily reflect changing
oxygen levels at the sediment–water interface (Jaccard et al., 2016). The
strongly correlated peaks of <inline-formula><mml:math id="M237" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Mn</mml:mi></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M238" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ca</mml:mi></mml:mrow></mml:math></inline-formula> (Fig. 2; Table 3)
suggest that at least some of the Mn is present in the studied interval as
<inline-formula><mml:math id="M239" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Mn</mml:mi></mml:mrow></mml:math></inline-formula> carbonates and/or <inline-formula><mml:math id="M240" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Mn</mml:mi></mml:mrow></mml:math></inline-formula> oxyhydroxides under the oxic
sediment–water interphase (Calvert and Pedersen, 1996, 2007; Tribovillard et
al., 2006).</p>
      <p id="d1e3311"><inline-formula><mml:math id="M241" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Br</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M242" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M243" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ti</mml:mi></mml:mrow></mml:math></inline-formula> has been previously used as an indicator of organic
matter in sediments (e.g., Agnihotri et al., 2008; Ziegler et al., 2008; Bahr
et al., 2014). Br <inline-formula><mml:math id="M244" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M245" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ti</mml:mi></mml:mrow></mml:math></inline-formula> in our record shows generally low values
(Fig. 2), most likely because the organic matter content in both facies types
is relatively low (<inline-formula><mml:math id="M246" display="inline"><mml:mi mathvariant="italic">&lt;</mml:mi></mml:math></inline-formula> 0.5 %, Escutia et al., 2011). However, it
exhibits some variability (0.01 to 0.05 <inline-formula><mml:math id="M247" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Br</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M248" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M249" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ti</mml:mi></mml:mrow></mml:math></inline-formula> ratio)
within the two facies, with higher ratio values in F1. Darker colored
sediments in F1 are in agreement with these higher <inline-formula><mml:math id="M250" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Br</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M251" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M252" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ti</mml:mi></mml:mrow></mml:math></inline-formula>
values inside F1.</p>
      <p id="d1e3405">In addition to the elemental analyses of the XRF-scanned data, we use the
detrital <inline-formula><mml:math id="M253" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Al</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M254" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M255" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ti</mml:mi></mml:mrow></mml:math></inline-formula> ratio in discrete XRF bulk<?pagebreak page1001?> sediment
samples to reflect changes in terrigenous provenance (Kuhn and Diekmann,
2002; Scher et al., 2015). The <inline-formula><mml:math id="M256" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Al</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M257" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M258" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ti</mml:mi></mml:mrow></mml:math></inline-formula> ratio varies between
17 and 21, with the highest values found within F1 and the lowest in F2
(Fig. 2).</p>
</sec>
<sec id="Ch1.S3.SS3">
  <label>3.3</label><title>Spectral analysis</title>
      <p id="d1e3463">To detect periodical signals, a spectral analysis of time series was
performed on the <inline-formula><mml:math id="M259" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Zr</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M260" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M261" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ba</mml:mi></mml:mrow></mml:math></inline-formula> and other elemental proxies (i.e.,
<inline-formula><mml:math id="M262" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ba</mml:mi></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M263" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Zr</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M264" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M265" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ti</mml:mi></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M266" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CaCO</mml:mi><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>, magnetic
susceptibility) using the Astrochron R software (Meyers, 2014; Figs. 6,
S3–S10).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F6" specific-use="star"><?xmltex \currentcnt{6}?><label>Figure 6</label><caption><p id="d1e3534">Spectral analysis results of the <inline-formula><mml:math id="M267" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Zr</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M268" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M269" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ba</mml:mi></mml:mrow></mml:math></inline-formula> obliquity
tuned and anchored data. <bold>(a)</bold> <inline-formula><mml:math id="M270" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Zr</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M271" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M272" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ba</mml:mi></mml:mrow></mml:math></inline-formula> ratio tuned
with Astrochron (Meyers, 2014) and anchored to the top of the C8n.2n (<inline-formula><mml:math id="M273" display="inline"><mml:mi>o</mml:mi></mml:math></inline-formula>)
chron. <bold>(b)</bold> EHA and <bold>(c)</bold> MTM spectral analysis on
<inline-formula><mml:math id="M274" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Zr</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M275" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M276" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ba</mml:mi></mml:mrow></mml:math></inline-formula> tuned data. EHA normalized power with 300 kyr
window with discrete prolate spheroidal sequence (DPSS) tapers.
<bold>(d)</bold> EHA amplitude for the eccentricity, obliquity (tilt), and precession (ETP) solution (Laskar et al.,
2004) calculated for the same period of time with 3DPSS tapers and 200 kyr
window.</p></caption>
          <?xmltex \igopts{width=412.564961pt}?><graphic xlink:href="https://cp.copernicus.org/articles/14/991/2018/cp-14-991-2018-f06.pdf"/>

        </fig>

      <p id="d1e3633">Multiple-taper spectral analysis method (MTM) in <inline-formula><mml:math id="M277" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Zr</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M278" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M279" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ba</mml:mi></mml:mrow></mml:math></inline-formula> show a clear
and statistically significant (<inline-formula><mml:math id="M280" display="inline"><mml:mi mathvariant="italic">&gt;</mml:mi></mml:math></inline-formula> 90 %) cyclicity every 2 m
(0.5 cycles m<inline-formula><mml:math id="M281" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>) and at 4.67 m (0.21 cycles m<inline-formula><mml:math id="M282" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>) and a less
significant one (<inline-formula><mml:math id="M283" display="inline"><mml:mi mathvariant="italic">&gt;</mml:mi></mml:math></inline-formula> 80 %) at 1 m (0.94 cycles m<inline-formula><mml:math id="M284" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>)
(Fig. S3). On the basis of a linearly calculated sedimentation rate between
the two extreme tie points (Table 1), we obtained a sedimentation rate of
approximately 5 cm kyr<inline-formula><mml:math id="M285" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>. Within this sedimentation rate, the
0.5 cycles m<inline-formula><mml:math id="M286" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> peak corresponds to the 41 kyr obliquity frequency, and
the 0.21 and 0.94 cycles m<inline-formula><mml:math id="M287" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> correspond to the 95 and 21 kyr shorter
eccentricity periods and precession frequencies, respectively.</p>
      <p id="d1e3747">After an initial analysis, we ran an evolutive harmonic analysis (EHA)
(Astrochron; Meyers, 2014) with three data tapers for the untuned
<inline-formula><mml:math id="M288" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Zr</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M289" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M290" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ba</mml:mi></mml:mrow></mml:math></inline-formula> in depth domain with 2 cm resolution (Fig. S3).
The statistical significance of spectral peaks was tested relative to the
null hypothesis of a robust red noise background (AR(1) modeling of median
smoothing) at a confidence level of 95 % (Mann and Lees, 1996). Despite a
short core gap in the middle of the time series, obliquity (41 kyr)
dominates throughout the time series (Fig. 6). The sedimentation rates
obtained by this method vary between 4.6 and 5.4 cm kyr<inline-formula><mml:math id="M291" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> for the
studied section, similar to those obtained with linearly calculated
sedimentation rates. Additionally, the Nyquist frequency for
<inline-formula><mml:math id="M292" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Zr</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M293" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M294" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ba</mml:mi></mml:mrow></mml:math></inline-formula> data is 1 m<inline-formula><mml:math id="M295" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> (0.5 kyr), which implies the
site is sampled sufficiently to resolve precessional-scale variations; however, core gaps prevent identification of long eccentricity cycles
(Fig. S6). Time series were anchored to the more robust paleomagnetic tie
point in the U1356 age model, which is 25.99 Ma at 678.78 m b.s.f.
(Fig. S7).</p>
      <p id="d1e3821">Apart from obliquity, spectral analyses of the tuned age model reveal an
alignment of the eccentricity and precession bands (Figs. 6, S8). For
example, a marked cyclicity at the obliquity periods of 41 kyr is seen at
<inline-formula><mml:math id="M296" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ba</mml:mi></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M297" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Zr</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M298" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M299" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ti</mml:mi></mml:mrow></mml:math></inline-formula> (99 % confidence); eccentricity at 100 kyr and precession at 20 kyr (95 %
confidence) are also seen (Fig. S9). We also observe coherent power above the 90 % significance
level at <inline-formula><mml:math id="M300" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 54 and <inline-formula><mml:math id="M301" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 29 kyr periods, which are secondary
components of obliquity. The anchored age model provides an unprecedented
500 yr resolution (2.5 cm sampling) of the data during the late Oligocene.
Orbital frequencies were tested in each core section individually in the
<inline-formula><mml:math id="M302" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Zr</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M303" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M304" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ba</mml:mi></mml:mrow></mml:math></inline-formula> dataset on the depth scale in order to assure that
cyclicity is not an artifact related to the gaps in the series (Fig. S10).</p>
</sec>
</sec>
<sec id="Ch1.S4">
  <label>4</label><title>Discussion</title>
      <p id="d1e3902">Based on the integration of the facies characterized on the basis of
sedimentological data (visual core description, facies analysis, CT scans,
HR-SEM), physical properties (magnetic susceptibility, NGR), and geochemical
data (XRF), we provide for the late Oligocene interval (26 to 25 <inline-formula><mml:math id="M305" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ma</mml:mi></mml:mrow></mml:math></inline-formula>)
(1) a new glacial–interglacial sedimentation model for the distal
glaciomarine record in the Wilkes Land margin dominated by bottom current
reworking of both glacial and interglacial deposits; (2) insights into the
configuration of the ice sheet in this sector of the east Antarctic margin;
(3) changes in the paleoceanographic glacial–interglacial configuration; and
(4) evidence for orbital forcing of the glaciomarine glacial–interglacial
sedimentation at Site U1356.</p>
<sec id="Ch1.S4.SS1">
  <label>4.1</label><title>Glacial and interglacial contourite sedimentation off Wilkes
Land</title>
      <p id="d1e3920">Laminated claystones (F1) from Site U1356 were originally interpreted by the
shipboard science team to have formed during glacial times relating to
variations in bottom current strength and fine-grained terrigenous supply.
Conversely, the bioturbated claystones and micritic limestones (F2) were
interpreted as resulting from mostly hemipelagic sedimentation during
interglacial times (Escutia et al., 2011). Alternations between laminated
deposits and bioturbated hemipelagic deposits, similar to those in F1 and
F2, have been previously reported to characterize Pleistocene and Pliocene
glacial–interglacial continental rise sedimentation, respectively, on this
sector of the Wilkes Land margin (Escutia et al., 2003; Patterson et al.,
2014). Gravity flows (mainly turbidity flows) are the dominant process during
glacial times, resulting in laminated deposits. Interglacial sedimentation is
dominated by hemipelagic deposition with higher opal and biogenic content
(Escutia et al., 2003; Busetti et al., 2003). Erosion and redeposition of
fine-grained sediment by bottom contour currents has also been reported as
another important process during Pleistocene and Plio-Quaternary
interglacials (Escutia et al., 2002, 2003; Busetti et al.,
2003).</p>
      <p id="d1e3923">Despite being sparse, the occurrence of bioturbation in our laminated
sediments in F1, which slightly affects both claystones and silt
laminations, indicates slow and continuous sedimentation. This is not
consistent with instantaneous turbidite deposition, which would be expected
at the Site U1356 located on the left low-relief levee of a contiguous
channel during the late Oligocene. It is, however, consistent with
fine-grained turbidite overbank deposits being consequently entrained by
bottom currents. Silt layer sedimentary structures similar to those
described by Rebesco and Camerlenghi (2008) and Rebesco et al. (2014) indicate that there is current
reworking of the sediments. For example, silt layers can be continuous or
discontinuous with wavy and irregular morphologies, and within layers,
sedimentary structures such as cross laminations are common (Fig. 3c–f).
Within the cross laminae, mud offshoots, and internal erosional surfaces are
distinctive features of fluctuating currents where successive traction and
suspension events are superimposed, indicating bottom current sedimentation as the principal process for the F1 laminated claystones
(Shanmugam et al., 1993; Stow, 2002). Based on these observations, we
interpret F1 as glacial laminated muddy contourites following the
classification of Stow and Faugères (2008). The F1 sedimentary
structures suggest bottom currents with fluctuating intensities, which result
in laminations and internal structures forming during peak current
velocities (Lucchi and Rebesco, 2007; Martín-Chivelet et al., 2008;
Rebesco et al., 2014). Laminated, fossil-barren, glaciogenic deposits,
consistent with those of Facies F1, have been observed on younger
sedimentary sections in glaciated margins and interpreted as contour current-modified turbidite deposits and as muddy contourites (Anderson et al., 1979;
Mackensen et al., 1989; Grobe and Mackensen, 1992; Pudsey, 1992; Gilbert et
al., 1998; Pudsey and Howe, 1998; Pudsey and Camerlenghi, 1998; Anderson,
1999; Williams and Handwerger, 2005; Lucchi and Rebesco, 2007, Escutia et
al., 2009). This particular type of contourite facies is associated with
glaciomarine deposition during times of glacial advance and has been
interpreted as resulting from unusual, climate-related,<?pagebreak page1003?> environmental
conditions of suppressed primary productivity and oxygen-poor deep waters
(Lucchi and Rebesco, 2007).</p>
      <p id="d1e3926">Bioturbated sediments in F2 were previously interpreted as interglacial
hemipelagic deposits (Escutia et al., 2011). In this study, we interpret F2
as hemipelagic and overbank deposits reworked by bottom currents. The coarser
grain size in F2 compared to F1 (silty clay matrix as seen in HR-SEM,
Fig. 3g–j), the distribution of heavy minerals as indicated by the
<inline-formula><mml:math id="M306" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Zr</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M307" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M308" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ba</mml:mi></mml:mrow></mml:math></inline-formula>, and the elevated values of the magnetic
susceptibility record with a bigradational pattern within the facies
(Figs. 2, 4) support the notion that interglacial sediments of F2 have been
heavily modified by bottom currents. Hemipelagic sediments are expected to be
homogeneous in terms of grain size and grading is not expected. Current
winnowing of hemipelagic deposits and the removal of the fine-grained fraction
can produce the higher accumulation of heavy (indicated by the <inline-formula><mml:math id="M309" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Zr</mml:mi></mml:mrow></mml:math></inline-formula>) and
ferromagnetic (indicated by MS) minerals observed in F2 compared to F1
(Fig. 2; Table 2). High MS values result from stronger bottom current deposition and/or increased terrigenous input (e.g., Pudsey,
2000; Hepp, 2007). Also,
bigradational trends have been previously described in contourite sediments
and interpreted as recording an increase followed by a decrease in the current
velocities (e.g., Martín-Chivelet et al., 2008). The bigradational
patterns in the <inline-formula><mml:math id="M310" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Zr</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M311" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M312" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ba</mml:mi></mml:mrow></mml:math></inline-formula> and MS plots (Figs. 2, 4) are
therefore interpreted as depicting a constant and smooth increase followed by a
decrease in current velocity with little gradual changes in flow strength. In
addition, the presence of grains of quartz with conchoidal fractures and
reworked coccolithophores with signs of dissolution (Fig. 3h, j) support the
reworking of background hemipelagic and turbidite overbank sediments by
bottom currents in a high-energy environment (Damiani et al., 2006).
Following the classification by Stow and Faugères (2008), we interpret
that F2 has more silty massive contourites resulting from higher and more
constant bottom current velocity compared to F1.</p>
      <p id="d1e3984">Transitions between the F1 and F2 facies are characterized by
glacial-to-interglacial contacts that may be sharp or diffuse due to
bioturbation and are characterized by a gradual change in physical and
geochemical sediment parameters (Figs. 3, 4; Table 3).
Interglacial-to-glacial contacts (F2 to F1), on the other hand, are
characterized by an apparently non-erosional sharp lithological boundary.
The sharp lithological boundaries between interglacial to glacial
transitions can be explained by maximum current intensities achieved at the
end of the interglacials (Shanmugam, 2008; Rebesco et al., 2014).</p>
</sec>
<sec id="Ch1.S4.SS2">
  <label>4.2</label><title>Ice sheet configuration during the warm late Oligocene</title>
      <p id="d1e3995">Early Oligocene and post-mid Miocene climate transition sediments from Site
U1356 contain granule and larger clasts (<inline-formula><mml:math id="M313" display="inline"><mml:mi mathvariant="italic">&gt;</mml:mi></mml:math></inline-formula> 2mm) interpreted as
IRD (Escutia et al., 2011; Sangiorgi et al., 2018; Fig. S1). In addition,
dinocyst assemblages indicate the presence of sea ice (Houben et al., 2013).
Based on this, one could expect the site to be within the reach of icebergs
calving from an expanded ice sheet grounded at the coast or beyond in the
late Oligocene. This is supported by Pliocene–Pleistocene sedimentary
sections in adjacent continental rise sites containing IRD (Escutia et al.,
2011; Patterson et al., 2014). In addition to the paucity of IRD in our
studied interval, the absence of sea-ice-loving species <italic>Selenopemphix antarctica</italic>, and abundant gonyaulacoid phototrophic dinocysts suggest warm to temperate surface
waters (Bijl et al., 2018b). A sea-ice-free scenario during
the late Oligocene is also supported by elevated sea surface temperatures
(i.e., average summer temperatures are <inline-formula><mml:math id="M314" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 19 <inline-formula><mml:math id="M315" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C) based on
biomarker sea surface temperatures (TEX<inline-formula><mml:math id="M316" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">86</mml:mn></mml:msub></mml:math></inline-formula> data in Hartman et al.,
2018). Furthermore, the presence of in situ terrestrial
palynomorphs suggests that during the late Oligocene, margins nearby were in
part free of ice sheets and covered by a cool to temperate vegetation with
trees and shrubs (Salzmann et al., 2016; Strother et al., 2017). All these
observations suggest a reduced ice sheet and partly ice-free margins in the
Wilkes margin during the late Oligocene.</p>
      <p id="d1e4033">These observations are consistent with the iceberg survivability modeling in
the Southern Ocean for the warm Pliocene intervals, which shows the distance
that icebergs could travel before melting was significantly reduced (Cook et
al., 2014). Warm Pliocene summer sea surface temperatures up to 6 <inline-formula><mml:math id="M317" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C
warmer than today during interglacials and prolonged Pliocene warm intervals
have been reported in the Ross Sea (e.g., Naish et al., 2009; McKay et al.,
2012) and other locations around Antarctica (Whitehead and Bohaty, 2003;
Whitehead et al., 2005; Escutia et al., 2009; Bart and Iwai, 2012). Contrary
to what we observe in our late Oligocene record and in the Miocene Climatic
Optimum (Sangiorgi et al., 2018), abundant IRD was delivered to continental
rise sites adjacent to Site U1356 during the warm Pliocene (Escutia et al.,
2011; Patterson et al., 2014). This was interpreted by Cook et al. (2017) to
suggest that a considerable number of icebergs (iceberg armadas) had to be
produced in order to reach the site under these warm Pliocene conditions. We
argue that the lack of IRD delivery to Site U1356 during the studied warm
late Oligocene interval can result from the different WSB late Oligocene
paleo-topographic setting. Paleo-topographic reconstructions from
34 Myr ago (Wilson et al., 2012) and the early Miocene (Gasson et al.,
2016) show the WSB to be an area of lowlands and shallow seas in contrast to
the overdeepened marine basin that it is today (Fretwell et al., 2013). This
paleo-topographic configuration would have precluded widespread marine ice
sheet instability during the Oligocene. This difference is important, as an
ice sheet grounded on an overdeepened continental shelf can experience marine
ice sheet instability, a runaway process relating to ice sheet retreat across
a reverse slope continental shelf (Weertman, 1974), which is proposed to be a
driver for retreat of the EAIS in the WSB during the warm Pliocene (Cook et
al., 2013). Conversely, a<?pagebreak page1004?> shallower continental shelf allows for the
potential expansion of grounded ice sheets into the marine margin during
warmer-than-present climates (Wilson et al., 2012), and thus direct records
are required to assess the climate threshold for such an advance.</p>
      <p id="d1e4045">In comparison to the distal U1356 Wilkes Land margin record, the Ross Sea
Embayment ice proximal sediments obtained by the CRP contain Oligocene to
Early Miocene palynomorphs, foraminifera, and clay assemblages that point to
a progressive decrease in fresh meltwater, cooling, and intensifying glacial
conditions (Leckie and Webb, 1983; Hannah et al., 2000, 2001; Raine and
Askin, 2001; Thorn, 2001; Ehrmann et al., 2005; Barrett, 2007). Therefore,
the coastal CRP sediment record does not support a significant loss of ice or
warming during the late Oligocene (Barrett, 2007). The high sedimentation
rates during the late-Oligocene–early-Miocene recorded at Deep Sea Drilling
Project (DSDP) Site 270 were interpreted as reflecting turbid plumes of
glaciomarine sediments derived from polythermal-style glaciers or ice sheets
that were calving into an open Ross Sea, without an ice shelf (Kemp and
Barrett, 1975). In addition, seismic data indicate that during the late to
mid-Oligocene widespread expansion of a marine-based ice sheet onto the outer
Ross Sea shelf did not take place, but instead glaciers and ice caps drained
from local highs and advanced only into shallow marine areas rather than
there being a whole-scale marine ice sheet advance
(Brancolini et al., 1995; De Santis et al., 2013; Bart and De Santis, 2012).</p>
      <p id="d1e4048">Combined, this evidence suggests that during the late Oligocene,
marine-terminating glaciers, ice caps, and glaciers persisted along the
Transantarctic Mountain front reaching the Ross Sea coastal areas, but it may
have been more confined within a warmer WSB margin. This is also supported by
vegetation reconstructions derived from fossil pollen from both margins,
which, for the middle Miocene and late Oligocene, indicate higher terrestrial
temperatures and more tree taxa at Wilkes Land (Salzmann et al., 2016;
Sangiorgi et al., 2018) than the Ross Sea (Askin and Raine, 2000; Prebble et
al., 2006). This is consistent with the ice sheet modeled configuration for
Miocene topographies with <inline-formula><mml:math id="M318" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> scenarios of 500–840 ppm (Gasson et
al., 2016; Levy et al., 2016; Fig. 7).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F7" specific-use="star"><?xmltex \currentcnt{7}?><label>Figure 7</label><caption><p id="d1e4065">Paleoceanographic reconstructions based on our interpretations for
Facies 1 and 2. <bold>(a)</bold> Modeled ice thickness for the mid-Miocene ice
sheet by Gasson et al. (2016). <bold>(b)</bold> Glacial periods with
low-obliquity configuration. Westerlies and polar front (PF) move northwards.
There is enhanced proto-AABW formation. Low-ventilation conditions occur at
the ocean–sediment interface, and mixing of waters masses is diminished.
Bottom currents are weak and fluctuating, producing laminated sediments.
<bold>(b)</bold> Interglacials occur during high-obliquity configuration.
Westerlies and the PF move southwards, close to the Site U1356. Proto-AABW
formation is reduced. Intrusions of proto-CDW/NADW-like water mass reach
southernmost positions. <bold>(c)</bold> During warm interglacials, NADW-like is
enhanced and CaCO3 sedimentation is more abundant. <bold>(b, c)</bold> Bottom
water ventilation and upwelling are more vigorous, with stronger bottom
currents that result in fully bioturbated and silt-sized sediments.</p></caption>
          <?xmltex \igopts{width=327.206693pt}?><graphic xlink:href="https://cp.copernicus.org/articles/14/991/2018/cp-14-991-2018-f07.pdf"/>

        </fig>

</sec>
<sec id="Ch1.S4.SS3">
  <label>4.3</label><title>Paleoceanographic implications</title>
      <p id="d1e4097">Sediment physical properties and geochemical signatures of F1 and F2 are here
related to changes in bottom-water–sediment interphase
oxygenation/ventilation during successive glacial and interglacial periods
(Table 2). We interpret that these changes are linked to shifts in water
masses driven by a north–south displacement of the position of the
westerlies and associated changes in the intensity of frontal mixing or
location of the polar front and Antarctic Divergence (Fig. 7). Based on our
observations, we propose a model to explain the interpreted changes in bottom
water conditions at Site U1356 during successive glacial and interglacial
times (Fig. 7).</p>
<sec id="Ch1.S4.SS3.SSS1">
  <label>4.3.1</label><title>Glacial paleoceanographic configuration</title>
      <p id="d1e4107">The <italic>Chondrites</italic>-like bioturbation with pyrite infilling the tubes of
<italic>Skolithos</italic> within F1 (Fig. 3b, d) has previously been reported to
characterize low-oxygen conditions at the water–sediment interphase (Bromley
and Ekdale, 1984). In addition, pyritized diatoms are present throughout the
Oligocene section of this site but are found preferentially inside F1. The
presence of pyritized diatoms was interpreted during Expedition 318 as
indicating a prolific production and syn-sedimentary diagenesis in a
restricted circulation (low-oxygen) environment, mainly during glacial
periods (Escutia et al., 2011). Reducing conditions in the sediment also help
to preserve primary sedimentary structures of the silt layers in F1 because
bioturbation is limited. Higher amounts of organic matter in F1 compared to
F2 are suggested by increased values of the <inline-formula><mml:math id="M319" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Br</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M320" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M321" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ti</mml:mi></mml:mrow></mml:math></inline-formula> ratio
(Fig. 2). The higher organic content most likely produces a poorly ventilated
environment with near-reducing conditions at the water–sediment interphase,
where pyrite can precipitate (Tribovillard et al., 2006). In spite of this,
total oxygen depletion did not occur as indicated by the palynomorphs good
preservation within F1 (Bijl et al., 2018b).</p>
      <p id="d1e4139">Low MS values such as those recorded within F1 (Fig. 4; Table 2) have been
reported around Antarctica and attributed to magnetic mineral dissolution
caused by dilution and/or primary diagenesis effects on the sediments due to
the higher concentration in organic matter or to changing redox conditions
(Korff et al., 2016). Several authors have postulated that oxygen-depleted
Antarctic Bottom Water (AABW) occupying the abyssal zones of the oceans can
change the redox conditions in the sediment, trapping and preserving
dissolved and particulate organic matter and, consequently, reducing and
dissolving both biogenic and detrital magnetite (Florindo et al., 2003; Hepp
et al., 2009; Korff et al., 2016). At present, Site U1356 is influenced by
AABW forming in the adjacent Wilkes Land shelf (Orsi et al., 1999; Fukamachi
et al., 2000) and in the Ross Sea, spilling over to the Wilkes Land
continental shelf (Fukamachi et al., 2010) (Fig. 1). Our records suggest a
reduced continental ice sheet in the eastern Wilkes Land margin and a reduced
sea ice presence compared to today (Bijl et al., 2018b). Under these
conditions, bottom water formation and downwelling can still occur (with or
without the presence of sea ice) as a result of density contrasts related to
seasonal changes in surface water temperature and salinity (Huber and Sloan,
2001; Otto-Bliesner et al., 2002). Moreover, stable Nd isotopic composition
in Eocene–Oligocene sediments from Site U1356 is consistent with modern-day
formation of bottom water from Adélie Land, as reported by Huck et
al. (2017).</p>
      <p id="d1e4142">Our evidence above points to the deposition of F1 during glacial cycles under
poorly ventilated, low-oxygenation<?pagebreak page1005?> conditions at the water–sediment
interface (Fig. 7a). We postulate that during glacial periods, westerly winds
and surface oceanic fronts migrate towards the equator, generating a more
stratified ocean and reduced upwelling closer to the margin, with sporadic
and fluctuating currents (Fig. 7a). Records of the Last Glacial Maximum show
that this northward migration results in a weakening of the upwelling of the
Circumpolar Deep Water (CDW; Govin et al., 2009), increasing stratification,
and reduced mixing of water masses, also due to an enhanced sea ice
formation; this was not seen during the late Oligocene.</p>
</sec>
<?pagebreak page1006?><sec id="Ch1.S4.SS3.SSS2">
  <label>4.3.2</label><title>Interglacial paleoceanographic configurations</title>
      <p id="d1e4153">We differentiate between two interglacial paleoceanographic configurations
based on the presence of some intervals of micritic limestone with calcareous
nannofossils.</p>
      <p id="d1e4156">In general, the higher degree of bioturbation in F2 with no primary
structures preserved and the ichnofacies association (i.e.,
<italic>Planolites</italic> and <italic>Zoophycos</italic>) suggest a more oxygenated
environment in comparison with F1. This is supported by the covariance of
<inline-formula><mml:math id="M322" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Mn</mml:mi></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M323" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CaCO</mml:mi><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> est. (Fig. 4) where <inline-formula><mml:math id="M324" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Mn</mml:mi></mml:mrow></mml:math></inline-formula> enrichments can
be interpreted as redox change variations (Calvert and Pedersen, 2007;
Jaccard et al., 2016). More oxygenated conditions during interglacial periods
can be achieved under more ventilated and mixed water masses, with enhanced
current velocities. Enhanced currents during the deposition of F2 are
interpreted as such based on coarser grain size and the increased
accumulation of heavy and ferromagnetic minerals as indicated by the high
values of the <inline-formula><mml:math id="M325" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Zr</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M326" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M327" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ti</mml:mi></mml:mrow></mml:math></inline-formula> ratio and MS within F2 (Figs. 2, 4).
The bigradational pattern of the <inline-formula><mml:math id="M328" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Zr</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M329" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M330" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Ba</mml:mi></mml:mrow></mml:math></inline-formula> and the MS
(Fig. 4) is also interpreted as recording an increase followed by a decrease
in current velocities within F2.</p>
      <p id="d1e4239">The intervals of micritic limestone within F2 have preserved calcareous
nannofossils (Fig. 3d). The productivity of calcareous nannofossils and the
later preservation of these coccoliths in the sediment indicate specific
geochemical conditions enabling carbonate deposition and preservation.
Although today nannoplankton is abundant in surface waters at the Antarctic
Divergence (Eynaud et al., 1999), this rarely deposits on the deep ocean
floor because of corrosive bottom waters, which dissolve calcareous rain. A
number of studies in other areas of the Antarctic margin and the Southern
Ocean have correlated the presence of calcareous nannofossils with the
presence of temperate north component water masses (North Atlantic Deep
Water-like, NADW) that intrude close to the Antarctic continent and influence
the Southern Ocean during the late Oligocene (e.g., Nelson and Cooke, 2001;
Pekar et al., 2006; Villa and Persico, 2006; Scher and Martin, 2008), the
Miocene (DeCesare et al., 2013; Sangiorgi et al., 2018), and during more
recent times such as the Quaternary (Diekman, 2007; Kemp et al., 2010; Villa
et al., 2012).</p>
      <p id="d1e4242">The more oxygenated and ventilated conditions in our records suggest enhanced
mixing of the water masses (Fig. 7b, c). We postulate that during
interglacials westerly winds and the polar front are shifted south and become
more aligned. Under these conditions, the upwelling of deep waters is likely
promoted, facilitating the mixing and oxygenation of surface waters that form
the precursor to bottom water. A similar process has been reported for the
Holocene by Peck et al. (2015). Such a process would also generate increased
geostrophic current velocities of the bottom water mass, supported by the
coarser grain size and heavy mineral concentrations in the bioturbated F2
facies.</p>
      <p id="d1e4246"><?xmltex \hack{\newpage}?>Similar to what occurs under the present warming, bottom water formation
during interglacials is likely fresher and less dense due to enhanced
freshwater runoff from surface and subglacial melt of the continental ice
sheet (van Wijk and Rintoul, 2014). Today, a reduction in the volume of the
AABW is compensated for by the expansion of the CDW (van Wijk and Rintoul,
2014), which forms by the mixing of abyssal, deep, and intermediate water
masses, including the AABW and the NADW (Johnson, 2008). We hypothesize that
during warmer interglacials, the influence of more northern-sourced water
masses into the proto-CDW, relative to Antarctic-sourced water (Fig. 7c),
could enable carbonate productivity and the preservation of coccolithophores
remains, seen on at least 13 occasions in our record. These data are also in
agreement with the <inline-formula><mml:math id="M331" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">13</mml:mn></mml:msup><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula> global isotope oscillations between 26
and 25 Ma (Cramer et al., 2009; Liebrand et al., 2017) that suggest low
values for an AABW and high <inline-formula><mml:math id="M332" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">13</mml:mn></mml:msup><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula> values for a NADW that may
represent the different oceanic primary production and ventilation rates, as
proposed in this work. In addition, <inline-formula><mml:math id="M333" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">13</mml:mn></mml:msup><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula> records in the
Atlantic show systematic offsets to lower values toward a North Atlantic
signal for most of the late Oligocene to early Miocene. These data suggest
the influence of two distinct deep-water sources: cooler southern component
water and warmer northern component water (Billups et al., 2002; Pekar et
al., 2006; Liebrand et al., 2011). In addition, the increased presence of
North Component Deep Waters influencing this sector of the eastern Wilkes
Land margin could be related to a slowdown of the southern limb of the
overturning circulation.</p>
</sec>
</sec>
<sec id="Ch1.S4.SS4">
  <label>4.4</label><title>Orbital forcing and glacial and interglacial cyclicity</title>
      <p id="d1e4299">The first spectral analysis on late Oligocene sediments from the eastern
Wilkes Land margin at Site U1356 shows that glacial–interglacial cycles,
resulting in changes in the oceanic configuration off Wilkes Land, are paced
with variations in Earth's orbit and seasonal insolation. Although the data
are somewhat discontinuous due to gaps in our record, they clearly show that
the glacial–interglacial cyclicity (every 2 m or 41 kyr) discussed above
has a persistent obliquity pacing throughout the late Oligocene interval
studied (26–25 Ma) in the Wilkes Land. Consequently, this obliquity-paced
cyclicity modulates the amount of deep-water production in the Southern Ocean
and exerts a major control on oceanic configuration and current strength.
Bottom current velocity fluctuations and ventilation of bottom sediments
respond to the forcings applied by the strength of the Southern Hemisphere
westerlies, by the position of the polar front (PF) in respect of the site,
and consequently by the water mass occupying the bottom of the basin at each
time. In addition to obliquity, precession is also present, which implies a
dynamic response of the EAIS and offshore oceanic water masses to orbital
forcing.</p>
      <p id="d1e4302">East Antarctic ice volume fluctuations at orbital periodicities in the
obliquity band in the Wilkes Land margin have<?pagebreak page1007?> been previously reported from
early warm Pliocene (3–5 Ma) sediments obtained from Site U1361 (Patterson
et al., 2014). In the Ross Sea, cyclicity in sediments collected by the CRP
from the late Oligocene, the late Miocene, and the early warm Pliocene period
was also paced by obliquity (Naish et al., 2001, 2009; McKay et al., 2009).
Similar orbital variability in the deep-water circulation patterns has also
been inferred to have occurred with the growth of the EAIS during the middle
Miocene between 15.5 to 12.5 Ma (Hall et al., 2003). In addition, other
studies have linked changes in Atlantic meridional overturning (Lisiecki et
al., 2008; Scher et al., 2015) and Antarctic circumpolar ocean circulation
(Toggweiler and Russell, 2008) to obliquity
forcing. An interglacial mechanism has been proposed whereby the southward
expansion of westerly winds and associated Ekman transport is compensated for
by enhanced upwelling of warmer, <inline-formula><mml:math id="M334" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>-rich CDW (Toggweiler et al.,
2008), which also promotes atmospheric warming. In the equatorial Pacific,
Pälike et al. (2006) also report strong obliquity in the benthic
<inline-formula><mml:math id="M335" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">13</mml:mn></mml:msup><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula> isotopic record between 26 and 25 Myr, implying that
changes in the carbon cycle (pacing glacial /interglacial periods) are
triggered in the high southern latitudes and transferred to the global
deep-ocean through the bottom water masses.</p>
</sec>
</sec>
<sec id="Ch1.S5" sec-type="conclusions">
  <label>5</label><title>Conclusions</title>
      <p id="d1e4339">Our study provides new insights regarding Antarctic ice sheet and
paleoceanographic configurations that prevailed in the eastern Wilkes Land
margin between 26 and 25 Ma. Sediments at IODP Site U1356 during this
interval are characterized by the alternation between two main facies (F1 and
F2), which are dominated by reworking by bottom currents with varying
intensities of glacial–interglacial gravity flows and hemipelagic deposits.
Claystones with silty laminations (F1) are interpreted as representing
fluctuating bottom current intensities during glacial periods. Massive
bioturbated silty clays and micritic limestones with coccoliths (F2) are
interpreted as interglacial deposits and record maximum velocities of bottom
currents at this site. The lack of iceberg-rafted debris (IRD), the absence
of sea ice, elevated sea surface temperatures throughout the studied
interval, and reconstructions of cool to temperate vegetation suggest that
reduced glaciers or ice caps occupied the topographic highs and lowlands of
the now overdeepened Wilkes Subglacial Basin between 26 and 25 Ma and that
iceberg calving was only a background process during this time due to the
lack of marine-terminating ice sheets.</p>
      <p id="d1e4342">Glacial sediments record poorly ventilated, low-oxygenation conditions at the
water–sediment interface that we postulate result when westerly winds and
surface oceanic fronts migrate towards the equator and overturning is reduced
near the Antarctic margin. During interglacial times, more oxygenated and
better-ventilated conditions are inferred to have prevailed, which would act
to enhance the mixing of the water masses with increased current velocities.
We postulate that during interglacials, westerly winds shifted south and
became more aligned with the Antarctic Divergence and polar fronts, which
promoted the upwelling of deep waters and facilitated the mixing and
oxygenation of bottom waters. Micritic limestone intervals within
interglacial F2 record warmer paleoclimatic conditions when the influence of
more northern-sourced water masses into the proto-CDW, relative to
Antarctic-sourced water (Fig. 7c), could enable carbonate productivity and
the preservation of coccolithophores remains. The preservation of carbonate
in some F2 intervals supports previous paleoceanographic studies that
consider at least a two-layer ocean with an Antarctic Bottom Water
(undersaturated with respect to calcium carbonate) and a proto-Circumpolar
Deep Water (CDW) with a greater influence of warmer Northern Component Deep
Water mass (NADW-like) to reconcile intra-basinal differences in
<inline-formula><mml:math id="M336" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> values (Pekar et al., 2006). Based on the number of
carbonate-rich layers, warmer NADW-like waters reached the site at least 13
times during the studied interval.</p>
      <p id="d1e4358">Spectral analysis on late Oligocene sediments from the eastern Wilkes Land
margin reveals that glacial–interglacial paleoceanographic changes during
the late Oligocene are regulated primarily by obliquity, although frequencies
in the eccentricity and precession band are also recorded. However, as we do
not have a measure of ice dynamics during this time (e.g., iceberg-rafted
debris), the orbital response of terrestrial ice in the Wilkes Land Basin
remains ambiguous, beyond what is inferred from the deep-sea isotope record.</p>
</sec>

      
      </body>
    <back><notes notes-type="codedataavailability"><title>Code and data availability</title>

      <p id="d1e4365">The datasets to this article are available at PANGAEA
(<uri>https://doi.pangaea.de/10.1594/PANGAEA.892208</uri>, Salabarnada et al.,
2018) and in the Supplement.</p>
  </notes><app-group>
        <supplementary-material position="anchor"><p id="d1e4371">The supplement related to this article is available online at: <inline-supplementary-material xlink:href="https://doi.org/10.5194/cp-14-991-2018-supplement" xlink:title="zip">https://doi.org/10.5194/cp-14-991-2018-supplement</inline-supplementary-material>.</p></supplementary-material>
        </app-group><notes notes-type="authorcontribution"><title>Author contributions</title>

      <p id="d1e4380">CE and AS designed the research. PKB, JH, FS, and HB provided insights
regarding biomarker-based sea surface temperatures and sea ice conditions
based on dinocysts. UR provided XRF core-scanning data. FJJE and UR provided
geochemical input. CHN and RM provided input with sedimentary and facies
interpretations. MI provided the CT-scan data. JAF provided input in the
paleoceanographic interpretations. DE and ALQ provided an Antarctic overview
and petrographic input. SR and US provided palynology insights. AS and CE
wrote the paper with input from all coauthors.</p>
  </notes><notes notes-type="competinginterests"><title>Competing interests</title>

      <p id="d1e4386">The authors declare that they have no conflict of
interest.</p>
  </notes><ack><title>Acknowledgements</title><p id="d1e4392">This research used samples and data provided by the Integrated Ocean Drilling
Program, now the International Ocean Discovery Program (IODP). We thank the
staff onboard IODP Exp. 318 and at the Gulf Coast, the Bremen, and the Kochi
IODP core repositories for assistance in core handling and shipping. We thank
Vera Lukies (MARUM) for technical support with XRF core scanning and Shizu
Yanagimoto (KOCHI) for technical support with CT scans. We also thank the
constructive comments of an anonymous reviewer and Steven Pekar that have helped to
improve this paper. Funding for this research is provided by the Spanish
Ministerio de Economía y Competitividad (grants CTM 2011-24079 and
CTM2014-60451-C2-1-P), co-funded by the European Union through FEDER funds.
Ulrich Salzmann thanks the Deutsche Forschungsgemeinschaft (DFG) (RO 1113/6).
Peter K. Bijl, Francesca Sangiorgi, and Julian D. Hartman acknowledge funding
through the NWO polar programme grant no 866.10.110. Peter K. Bijl
acknowledges funding through NWO-VENI grant no 863.13.002. Ulrich Salzmann
acknowledges funding received from the Natural Environment Research Council
(NERC grant NE/H000984/1).<?xmltex \hack{\newline}?><?xmltex \hack{\newline}?> Edited by: David
Thornalley<?xmltex \hack{\newline}?> Reviewed by: Stephen Pekar and one anonymous
referee</p></ack><ref-list>
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    <!--<article-title-html>Paleoceanography and ice sheet variability offshore Wilkes Land, Antarctica – Part 1: Insights from late Oligocene astronomically paced contourite sedimentation</article-title-html>
<abstract-html><p>Antarctic ice sheet and Southern Ocean paleoceanographic configurations
during the late Oligocene are not well resolved. They are however important
to understand the influence of high-latitude Southern Hemisphere feedbacks on
global climate under CO<sub>2</sub> scenarios (between 400 and 750&thinsp;ppm)
projected by the IPCC for this century, assuming unabated CO<sub>2</sub>
emissions. Sediments recovered by the Integrated Ocean Drilling Program
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provide an opportunity to study ice sheet and paleoceanographic
configurations during the late Oligocene (26–25&thinsp;Ma). Our study, based on a
combination of sediment facies analysis, magnetic susceptibility, density,
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sediments are continuously reworked by bottom currents, with maximum
velocities occurring during the interglacial periods. Glacial sediments
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interpreted as resulting from a northward shift of westerly winds and surface
oceanic fronts. Interglacial sediments record more oxygenated and ventilated
bottom water conditions and strong current velocities, which suggests
enhanced mixing of the water masses as a result of a southward shift of the
polar front. Intervals with preserved carbonated nannofossils within some of
the interglacial facies are interpreted as forming under warmer paleoclimatic
conditions when less corrosive warmer northern component water (e.g., North
Atlantic sourced deep water) had a greater influence on the site. Spectral
analysis on the late Oligocene sediment interval shows that the
glacial–interglacial cyclicity and related displacements of the Southern
Ocean frontal systems between 26 and 25&thinsp;Ma were forced mainly by obliquity.
The paucity of iceberg-rafted debris (IRD) throughout
the studied interval contrasts with earlier Oligocene and post-Miocene
Climate Optimum sections from Site U1356 and with late Oligocene strata from
the Ross Sea, which contain IRD and evidence for coastal glaciers and sea
ice. These observations, supported by elevated sea surface paleotemperatures,
the absence of sea ice, and reconstructions of fossil pollen between 26 and
25&thinsp;Ma at Site U1356, suggest that open-ocean water conditions prevailed.
Combined, this evidence suggests that glaciers or ice caps likely occupied
the topographic highs and lowlands of the now marine Wilkes Subglacial Basin
(WSB). Unlike today, the continental shelf was not overdeepened and thus ice
sheets in the WSB were likely land-based, and marine-based ice sheet
expansion was likely limited to coastal regions.</p></abstract-html>
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