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<article xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:oasis="http://docs.oasis-open.org/ns/oasis-exchange/table" xml:lang="en" dtd-version="3.0">
  <front>
    <journal-meta><journal-id journal-id-type="publisher">CP</journal-id><journal-title-group>
    <journal-title>Climate of the Past</journal-title>
    <abbrev-journal-title abbrev-type="publisher">CP</abbrev-journal-title><abbrev-journal-title abbrev-type="nlm-ta">Clim. Past</abbrev-journal-title>
  </journal-title-group><issn pub-type="epub">1814-9332</issn><publisher>
    <publisher-name>Copernicus Publications</publisher-name>
    <publisher-loc>Göttingen, Germany</publisher-loc>
  </publisher></journal-meta>
    <article-meta>
      <article-id pub-id-type="doi">10.5194/cp-14-2053-2018</article-id><title-group><article-title>What climate signal is contained in decadal- to centennial-scale isotope
variations from Antarctic ice cores?</article-title><alt-title>Timescale dependence of Antarctic isotope variations</alt-title>
      </title-group><?xmltex \runningtitle{Timescale dependence of Antarctic isotope variations}?><?xmltex \runningauthor{T. M\"{u}nch and T. Laepple}?>
      <contrib-group>
        <contrib contrib-type="author" corresp="yes" rid="aff1 aff2">
          <name><surname>Münch</surname><given-names>Thomas</given-names></name>
          <email>thomas.muench@awi.de</email>
        <ext-link>https://orcid.org/0000-0002-5492-7544</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>Laepple</surname><given-names>Thomas</given-names></name>
          
        <ext-link>https://orcid.org/0000-0001-8108-7520</ext-link></contrib>
        <aff id="aff1"><label>1</label><institution>Alfred-Wegener-Institut Helmholtz-Zentrum für Polar- und
Meeresforschung, Research Unit Potsdam, <?xmltex \hack{\break}?>Telegrafenberg A45, 14473 Potsdam,
Germany</institution>
        </aff>
        <aff id="aff2"><label>2</label><institution>University of Potsdam, Institute of Physics and Astronomy,
Karl-Liebknecht-Str. 24/25, 14476 Potsdam, Germany</institution>
        </aff>
      </contrib-group>
      <author-notes><corresp id="corr1">Thomas Münch (thomas.muench@awi.de)</corresp></author-notes><pub-date><day>20</day><month>December</month><year>2018</year></pub-date>
      
      <volume>14</volume>
      <issue>12</issue>
      <fpage>2053</fpage><lpage>2070</lpage>
      <history>
        <date date-type="received"><day>21</day><month>August</month><year>2018</year></date>
           <date date-type="rev-request"><day>27</day><month>August</month><year>2018</year></date>
           <date date-type="rev-recd"><day>26</day><month>November</month><year>2018</year></date>
           <date date-type="accepted"><day>29</day><month>November</month><year>2018</year></date>
      </history>
      <permissions>
        
        
      <license license-type="open-access"><license-p>This work is licensed under the Creative Commons Attribution 4.0 International License. To view a copy of this licence, visit <ext-link ext-link-type="uri" xlink:href="https://creativecommons.org/licenses/by/4.0/">https://creativecommons.org/licenses/by/4.0/</ext-link></license-p></license></permissions><self-uri xlink:href="https://cp.copernicus.org/articles/14/2053/2018/cp-14-2053-2018.html">This article is available from https://cp.copernicus.org/articles/14/2053/2018/cp-14-2053-2018.html</self-uri><self-uri xlink:href="https://cp.copernicus.org/articles/14/2053/2018/cp-14-2053-2018.pdf">The full text article is available as a PDF file from https://cp.copernicus.org/articles/14/2053/2018/cp-14-2053-2018.pdf</self-uri>
      <abstract>
    <p id="d1e97">Ice-core-based records of isotopic composition are a proxy for past
temperatures and can thus provide information on polar climate variability
over a large range of timescales. However, individual isotope records are
affected by a multitude of processes that may mask the true temperature
variability. The relative magnitude of climate and non-climate contributions
is expected to vary as a function of timescale, and thus it is crucial to
determine those temporal scales on which the actual signal dominates the
noise. At present, there are no reliable estimates of this timescale
dependence of the signal-to-noise ratio (SNR). Here, we present a simple
method that applies spectral analyses to stable-isotope data from multiple
cores to estimate the SNR, and the signal and noise variability, as a
function of timescale. The method builds on separating the contributions from
a common signal and from local variations and includes a correction for the
effects of diffusion and time uncertainty. We apply our approach to firn-core
arrays from Dronning Maud Land (DML) in East Antarctica and from the West
Antarctic Ice Sheet (WAIS). For DML and decadal to multi-centennial
timescales, we find an increase in the SNR by nearly 1 order of magnitude
(<inline-formula><mml:math id="M1" display="inline"><mml:mrow><mml:mo>∼</mml:mo><mml:mn mathvariant="normal">0.2</mml:mn></mml:mrow></mml:math></inline-formula> at decadal and <inline-formula><mml:math id="M2" display="inline"><mml:mrow><mml:mo>∼</mml:mo><mml:mn mathvariant="normal">1.0</mml:mn></mml:mrow></mml:math></inline-formula> at multi-centennial scales). The estimated
spectrum of climate variability also shows increasing variability towards
longer timescales, contrary to what is traditionally inferred from single
records in this region. In contrast, the inferred variability spectrum for
WAIS stays close to constant over decadal to centennial timescales, and the
results even suggest a decrease in SNR over this range of timescales. We
speculate that these differences between DML and WAIS are related to
differences in the spatial and temporal scales of the isotope signal,
highlighting the potentially more homogeneous atmospheric conditions on the
Antarctic Plateau in contrast to the marine-influenced conditions on WAIS. In
general, our approach provides a methodological basis for separating local
proxy variability from coherent climate variations, which is applicable to a
large set of palaeoclimate records.</p>
  </abstract>
    </article-meta>
  </front>
<body>
      

<sec id="Ch1.S1" sec-type="intro">
  <title>Introduction</title>
      <p id="d1e127">Ice cores represent key archives for studying polar climate variability on
timescales beyond instrumental observations. The isotopic composition of water
stored in the ice serves as a proxy for reconstructing past temperature
variations (<?xmltex \hack{\mbox\bgroup}?><xref ref-type="bibr" rid="bib1.bibx6" id="altparen.1"/><?xmltex \hack{\egroup}?>; <?xmltex \hack{\mbox\bgroup}?><xref ref-type="bibr" rid="bib1.bibx26" id="altparen.2"/><?xmltex \hack{\egroup}?>; <?xmltex \hack{\mbox\bgroup}?><xref ref-type="bibr" rid="bib1.bibx27" id="altparen.3"/><?xmltex \hack{\egroup}?>) over a wide range of
timescales ranging from subannual to glacial–interglacial variations. This can
provide valuable insights into the timescale dependence of climate
variability, which is thought to be an inherent property of the climate system
(<?xmltex \hack{\mbox\bgroup}?><xref ref-type="bibr" rid="bib1.bibx18" id="altparen.4"/><?xmltex \hack{\egroup}?>; <?xmltex \hack{\mbox\bgroup}?><xref ref-type="bibr" rid="bib1.bibx46" id="altparen.5"/><?xmltex \hack{\egroup}?>; <?xmltex \hack{\mbox\bgroup}?><xref ref-type="bibr" rid="bib1.bibx38" id="altparen.6"/><?xmltex \hack{\egroup}?>; <?xmltex \hack{\mbox\bgroup}?><xref ref-type="bibr" rid="bib1.bibx55" id="altparen.7"/><?xmltex \hack{\egroup}?>).</p>
      <?pagebreak page2054?><p id="d1e167">However, the interpretation of isotope records in terms of local atmospheric
temperatures is complicated by a multitude of processes that distort the
original relationship present in precipitation
<xref ref-type="bibr" rid="bib1.bibx12 bib1.bibx58 bib1.bibx59 bib1.bibx66 bib1.bibx4" id="paren.8"><named-content content-type="pre">e.g.</named-content></xref>.
To a first approximation, changes in isotopic composition are only recorded in
the ice if there is snowfall, while the role of water vapour exchange processes
in between precipitation events is still debated
(<?xmltex \hack{\mbox\bgroup}?><xref ref-type="bibr" rid="bib1.bibx59" id="altparen.9"/><?xmltex \hack{\egroup}?>; <?xmltex \hack{\mbox\bgroup}?><xref ref-type="bibr" rid="bib1.bibx64" id="altparen.10"/><?xmltex \hack{\egroup}?>; <?xmltex \hack{\mbox\bgroup}?><xref ref-type="bibr" rid="bib1.bibx4" id="altparen.11"/><?xmltex \hack{\egroup}?>; <?xmltex \hack{\mbox\bgroup}?><xref ref-type="bibr" rid="bib1.bibx54" id="altparen.12"/><?xmltex \hack{\egroup}?>; <?xmltex \hack{\mbox\bgroup}?><xref ref-type="bibr" rid="bib1.bibx43" id="altparen.13"/><?xmltex \hack{\egroup}?>). Both the
seasonality and interannual variability in the seasonality of precipitation
events is known to strongly affect the isotopic composition of snow layers by
introducing a bias to the mean values, e.g. the annual average
<xref ref-type="bibr" rid="bib1.bibx61 bib1.bibx57 bib1.bibx35" id="paren.14"/>, and by adding variability to the signal
<xref ref-type="bibr" rid="bib1.bibx51 bib1.bibx37" id="paren.15"/>. Furthermore, uneven deposition of snow, in
combination with steady and strong surface winds, lead to constant erosion,
drift and vertical mixing of the surface snow, giving rise to strong spatial
variability <xref ref-type="bibr" rid="bib1.bibx10 bib1.bibx42 bib1.bibx43" id="paren.16"/>. Finally, once the snow is
deposited, the diffusion of vapour through the firn column smoothes the isotope
variations <xref ref-type="bibr" rid="bib1.bibx21 bib1.bibx69" id="paren.17"/>. This significantly reduces the
high-frequency power spectral density of the variations
<xref ref-type="bibr" rid="bib1.bibx22 bib1.bibx67" id="paren.18"/> and substantially shapes the isotope
variability <xref ref-type="bibr" rid="bib1.bibx37" id="paren.19"/>. Overall, these processes are to a first
approximation not directly linked to variations in temperature and therefore
add a significant amount of noise to the isotope records, especially in
low-accumulation regions on the Antarctic Plateau. This has been demonstrated by
the low representativity of individual ice-core measurements
<xref ref-type="bibr" rid="bib1.bibx29 bib1.bibx42" id="paren.20"/> and questions the usability of a direct
interpretation of high-resolution isotope variations in terms of temperature
variability <xref ref-type="bibr" rid="bib1.bibx37" id="paren.21"/>, particularly when the climate signal itself is
only relatively weak. While deep ice cores show a consistent picture for the
strong glacial–interglacial variations <xref ref-type="bibr" rid="bib1.bibx28" id="paren.22"><named-content content-type="pre">e.g.</named-content></xref>, it may be
questionable whether the Holocene variability recorded in individual cores
depicts the true temperature variability <xref ref-type="bibr" rid="bib1.bibx32" id="paren.23"/>. Spatial or
temporal averaging of isotope records thus provide important tools to reduce
overall noise <xref ref-type="bibr" rid="bib1.bibx11 bib1.bibx42 bib1.bibx65" id="paren.24"/>.</p>
      <p id="d1e238">Previous studies provided first insights into the relationship between climate
signal and noise for short spatial and temporal scales
<xref ref-type="bibr" rid="bib1.bibx10 bib1.bibx42" id="paren.25"/>. However, an extension to longer scales, which is
important for the interpretation of Holocene temperature reconstructions, is
still missing. Furthermore, in order to correct the isotope-inferred variability
estimates for the noise contribution, it is necessary to know the variance of
the noise across timescales, i.e. its spectral shape. Here, we present a simple
spectral method to separate the local noise from spatially coherent signals
using information from several isotope records, including a correction for
diffusion and time uncertainty. We apply our model to two spatial arrays of firn
cores: (1) from Dronning Maud Land in East Antarctica and (2) from the West
Antarctic Ice Sheet. Our objective is to derive an improved estimate of the
temperature variability in both regions and to learn about the timescale
dependence of the signal-to-noise ratio in ice-core isotope data. For Dronning
Maud Land, our results confirm the noise levels inferred in previous studies on
short temporal scales <xref ref-type="bibr" rid="bib1.bibx42 bib1.bibx43" id="paren.26"/> and also suggest white noise
on longer timescales, which results in an increase in the isotopic
signal-to-noise ratio (SNR). Unexpectedly, the SNR inferred from the West
Antarctic data is found to show the opposite timescale dependence. These results
may point towards marked differences in the spatial and temporal scales of the
isotope signals and reveal gaps in our current understanding of the underlying
processes.</p>
</sec>
<sec id="Ch1.S2">
  <title>Data and methods</title>
<sec id="Ch1.S2.SS1">
  <title>Isotope records from Dronning Maud
Land and West Antarctica</title>
      <p id="d1e258">We analyse published oxygen isotope records of annually dated firn cores from
two contrasting Antarctic regions (Table <xref ref-type="table" rid="Ch1.T1"/>): (1) Dronning
Maud Land (DML) on the Antarctic Plateau and (2) the West Antarctic Ice Sheet
(WAIS). While the DML core sites are located in a rather flat region relatively
isolated from the coast (average elevation <inline-formula><mml:math id="M3" display="inline"><mml:mn mathvariant="normal">2900</mml:mn></mml:math></inline-formula> m), the WAIS core sites are
lower in elevation (<inline-formula><mml:math id="M4" display="inline"><mml:mn mathvariant="normal">1600</mml:mn></mml:math></inline-formula> m on average) and therefore potentially more
influenced by marine conditions.</p>
      <p id="d1e277">For DML, we use a total of <inline-formula><mml:math id="M5" display="inline"><mml:mn mathvariant="normal">15</mml:mn></mml:math></inline-formula> records, which were collected during the EPICA
(European Project for Ice Coring in Antarctica) pre-site survey
<xref ref-type="bibr" rid="bib1.bibx47" id="paren.27"/> and published in <xref ref-type="bibr" rid="bib1.bibx14" id="text.28"/>. All records cover at least
the last <inline-formula><mml:math id="M6" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 200 years and form our first data set, DML1. Three of these records
(B31–B33) span the last <inline-formula><mml:math id="M7" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 1000 years and are therefore included in a
second separate data set for this time span (DML2). Core B32 is in close
proximity (<inline-formula><mml:math id="M8" display="inline"><mml:mrow><mml:mo>∼</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:math></inline-formula> km) to the deep EPICA DML (EDML) ice-core site at Kohnen
Station <xref ref-type="bibr" rid="bib1.bibx8" id="paren.29"/>. The record chronologies were
established from seasonal layer counting of chemical impurity records
constrained by tie points from the dating of volcanic ash layers
<xref ref-type="bibr" rid="bib1.bibx14" id="paren.30"/>. The resulting uncertainty of the chronologies has been
reported to be <inline-formula><mml:math id="M9" display="inline"><mml:mrow><mml:mo>∼</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:math></inline-formula> % of the time interval to the nearest tie point
<xref ref-type="bibr" rid="bib1.bibx14" id="paren.31"/>, which translates to a maximum time uncertainty of <inline-formula><mml:math id="M10" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula>
1.2 years for the short records and of <inline-formula><mml:math id="M11" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 3.5 years for the long records. Since our
method (Sect. <xref ref-type="sec" rid="Ch1.S2.SS2"/>) relies on all records having equal lengths, we
restrict the time span for the DML1 data set to the period from
<inline-formula><mml:math id="M12" display="inline"><mml:mn mathvariant="normal">1801</mml:mn></mml:math></inline-formula> to <inline-formula><mml:math id="M13" display="inline"><mml:mn mathvariant="normal">1994</mml:mn></mml:math></inline-formula> CE and to the period from <inline-formula><mml:math id="M14" display="inline"><mml:mn mathvariant="normal">1000</mml:mn></mml:math></inline-formula> to <inline-formula><mml:math id="M15" display="inline"><mml:mn mathvariant="normal">1994</mml:mn></mml:math></inline-formula> CE for the DML2 data
set.</p>
      <p id="d1e382">The WAIS data set selected for this study consists of five isotope records
<xref ref-type="bibr" rid="bib1.bibx63" id="paren.32"/> collected during the US ITASE (International Trans-Antarctic
Scientific Expedition) project <xref ref-type="bibr" rid="bib1.bibx39" id="paren.33"/>, including the core WDC2005A
from the WAIS Divide ice core (WDC; <xref ref-type="bibr" rid="bib1.bibx68" id="altparen.34"/>), and
cover the time interval from <inline-formula><mml:math id="M16" display="inline"><mml:mn mathvariant="normal">1800</mml:mn></mml:math></inline-formula> to <inline-formula><mml:math id="M17" display="inline"><mml:mn mathvariant="normal">2000</mml:mn></mml:math></inline-formula> CE. The oxygen isotope data of cores
ITASE-2000-4 and ITASE-2000-5, previously published at subannual resolution
<xref ref-type="bibr" rid="bib1.bibx63" id="paren.35"/>, have been block-averaged in this study to obtain annual
resolution data. The core selection was based on the constraint of covering<?pagebreak page2055?> a
similarly large area and sufficiently long time period to allow a meaningful
comparison with the DML1 records. The relative time uncertainty between the WAIS
records, based on dating through annual layer counting of chemical trace species
validated by identification of volcanic marker horizons, was reported to be no
more than 1 year <xref ref-type="bibr" rid="bib1.bibx62" id="paren.36"/>.</p>

<?xmltex \floatpos{t}?><table-wrap id="Ch1.T1" specific-use="star"><caption><p id="d1e418">Overview of the firn cores (sorted into three data sets) used in this
study. Listed are the covered time spans of each core array (in yr CE), the
number of records in each array (<inline-formula><mml:math id="M18" display="inline"><mml:mi>n</mml:mi></mml:math></inline-formula>), the region of origin
(latitude–longitude range), the range of site elevations, local accumulation
rates (<inline-formula><mml:math id="M19" display="inline"><mml:mover accent="true"><mml:mi>b</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover></mml:math></inline-formula>) and <inline-formula><mml:math id="M20" display="inline"><mml:mn mathvariant="normal">10</mml:mn></mml:math></inline-formula> m firn temperatures (<inline-formula><mml:math id="M21" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mi mathvariant="normal">firn</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>) reported
in the original publications, and the range of intercore distances (<inline-formula><mml:math id="M22" display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula>). The
range of WAIS firn temperatures is based on ERA-Interim annual mean anomalies
<xref ref-type="bibr" rid="bib1.bibx7" id="paren.37"/> with respect to the WDC2005A site.</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="9">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="right"/>
     <oasis:colspec colnum="3" colname="col3" align="left"/>
     <oasis:colspec colnum="4" colname="col4" align="right"/>
     <oasis:colspec colnum="5" colname="col5" align="right"/>
     <oasis:colspec colnum="6" colname="col6" align="right"/>
     <oasis:colspec colnum="7" colname="col7" align="right"/>
     <oasis:colspec colnum="8" colname="col8" align="right"/>
     <oasis:colspec colnum="9" colname="col9" align="left"/>
     <oasis:thead>
       <oasis:row>
         <oasis:entry colname="col1">Core array</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M30" display="inline"><mml:mi>n</mml:mi></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3">Region</oasis:entry>
         <oasis:entry colname="col4">Elevation</oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M31" display="inline"><mml:mover accent="true"><mml:mi>b</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover></mml:math></inline-formula></oasis:entry>
         <oasis:entry rowsep="1" namest="col6" nameend="col7" align="center"><inline-formula><mml:math id="M32" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mi mathvariant="normal">firn</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> (<inline-formula><mml:math id="M33" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C) </oasis:entry>
         <oasis:entry colname="col8"><inline-formula><mml:math id="M34" display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col9">Data reference</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1">(Time span)</oasis:entry>
         <oasis:entry colname="col2"/>
         <oasis:entry colname="col3">(Lat–long)</oasis:entry>
         <oasis:entry colname="col4">(m a.s.l.)</oasis:entry>
         <oasis:entry colname="col5">(<inline-formula><mml:math id="M35" display="inline"><mml:mrow><mml:mi mathvariant="normal">kg</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">yr</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>)</oasis:entry>
         <oasis:entry colname="col6">min</oasis:entry>
         <oasis:entry colname="col7">max</oasis:entry>
         <oasis:entry colname="col8">(km)</oasis:entry>
         <oasis:entry colname="col9"/>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>
         <oasis:entry colname="col1">DML1<inline-formula><mml:math id="M36" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">a</mml:mi></mml:msup></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">15</oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M37" display="inline"><mml:mn mathvariant="normal">74.5</mml:mn></mml:math></inline-formula>–<inline-formula><mml:math id="M38" display="inline"><mml:mn mathvariant="normal">75.6</mml:mn></mml:math></inline-formula><inline-formula><mml:math id="M39" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> S</oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M40" display="inline"><mml:mn mathvariant="normal">2630</mml:mn></mml:math></inline-formula>–<inline-formula><mml:math id="M41" display="inline"><mml:mrow><mml:msup><mml:mn mathvariant="normal">3160</mml:mn><mml:mi mathvariant="normal">d</mml:mi></mml:msup></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M42" display="inline"><mml:mn mathvariant="normal">40</mml:mn></mml:math></inline-formula>–<inline-formula><mml:math id="M43" display="inline"><mml:mrow><mml:msup><mml:mn mathvariant="normal">90</mml:mn><mml:mi mathvariant="normal">d</mml:mi></mml:msup></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col6"><inline-formula><mml:math id="M44" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:msup><mml:mn mathvariant="normal">46</mml:mn><mml:mi mathvariant="normal">d</mml:mi></mml:msup></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col7"><inline-formula><mml:math id="M45" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:msup><mml:mn mathvariant="normal">40</mml:mn><mml:mi mathvariant="normal">d</mml:mi></mml:msup></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col8"><inline-formula><mml:math id="M46" display="inline"><mml:mn mathvariant="normal">1</mml:mn></mml:math></inline-formula>–<inline-formula><mml:math id="M47" display="inline"><mml:mn mathvariant="normal">370</mml:mn></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col9">
                    <xref ref-type="bibr" rid="bib1.bibx15" id="normal.42"/>
                  </oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">(<inline-formula><mml:math id="M48" display="inline"><mml:mn mathvariant="normal">1801</mml:mn></mml:math></inline-formula>–<inline-formula><mml:math id="M49" display="inline"><mml:mn mathvariant="normal">1994</mml:mn></mml:math></inline-formula>)</oasis:entry>
         <oasis:entry colname="col2"/>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M50" display="inline"><mml:mn mathvariant="normal">6.5</mml:mn></mml:math></inline-formula><inline-formula><mml:math id="M51" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> W–<inline-formula><mml:math id="M52" display="inline"><mml:mn mathvariant="normal">6.5</mml:mn></mml:math></inline-formula><inline-formula><mml:math id="M53" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> E</oasis:entry>
         <oasis:entry colname="col4"/>
         <oasis:entry colname="col5"/>
         <oasis:entry colname="col6"/>
         <oasis:entry colname="col7"/>
         <oasis:entry colname="col8"/>
         <oasis:entry colname="col9"/>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">DML2<inline-formula><mml:math id="M54" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">b</mml:mi></mml:msup></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">3</oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M55" display="inline"><mml:mn mathvariant="normal">75.0</mml:mn></mml:math></inline-formula>–<inline-formula><mml:math id="M56" display="inline"><mml:mn mathvariant="normal">75.6</mml:mn></mml:math></inline-formula><inline-formula><mml:math id="M57" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> S</oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M58" display="inline"><mml:mn mathvariant="normal">2670</mml:mn></mml:math></inline-formula>–<inline-formula><mml:math id="M59" display="inline"><mml:mrow><mml:msup><mml:mn mathvariant="normal">3160</mml:mn><mml:mi mathvariant="normal">d</mml:mi></mml:msup></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M60" display="inline"><mml:mn mathvariant="normal">50</mml:mn></mml:math></inline-formula>–<inline-formula><mml:math id="M61" display="inline"><mml:mrow><mml:msup><mml:mn mathvariant="normal">60</mml:mn><mml:mi mathvariant="normal">d</mml:mi></mml:msup></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col6"><inline-formula><mml:math id="M62" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:msup><mml:mn mathvariant="normal">46</mml:mn><mml:mi mathvariant="normal">d</mml:mi></mml:msup></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col7"><inline-formula><mml:math id="M63" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:msup><mml:mn mathvariant="normal">44</mml:mn><mml:mi mathvariant="normal">d</mml:mi></mml:msup></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col8"><inline-formula><mml:math id="M64" display="inline"><mml:mn mathvariant="normal">120</mml:mn></mml:math></inline-formula>–<inline-formula><mml:math id="M65" display="inline"><mml:mn mathvariant="normal">280</mml:mn></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col9">
                    <xref ref-type="bibr" rid="bib1.bibx15" id="normal.43"/>
                  </oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">(<inline-formula><mml:math id="M66" display="inline"><mml:mn mathvariant="normal">1000</mml:mn></mml:math></inline-formula>–<inline-formula><mml:math id="M67" display="inline"><mml:mn mathvariant="normal">1994</mml:mn></mml:math></inline-formula>)</oasis:entry>
         <oasis:entry colname="col2"/>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M68" display="inline"><mml:mn mathvariant="normal">3.4</mml:mn></mml:math></inline-formula><inline-formula><mml:math id="M69" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> W–<inline-formula><mml:math id="M70" display="inline"><mml:mn mathvariant="normal">6.5</mml:mn></mml:math></inline-formula><inline-formula><mml:math id="M71" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> E</oasis:entry>
         <oasis:entry colname="col4"/>
         <oasis:entry colname="col5"/>
         <oasis:entry colname="col6"/>
         <oasis:entry colname="col7"/>
         <oasis:entry colname="col8"/>
         <oasis:entry colname="col9"/>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">WAIS<inline-formula><mml:math id="M72" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">c</mml:mi></mml:msup></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">5</oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M73" display="inline"><mml:mn mathvariant="normal">77.7</mml:mn></mml:math></inline-formula>–<inline-formula><mml:math id="M74" display="inline"><mml:mn mathvariant="normal">80.6</mml:mn></mml:math></inline-formula><inline-formula><mml:math id="M75" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> S</oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M76" display="inline"><mml:mn mathvariant="normal">1350</mml:mn></mml:math></inline-formula>–<inline-formula><mml:math id="M77" display="inline"><mml:mrow><mml:msup><mml:mn mathvariant="normal">1830</mml:mn><mml:mrow><mml:mi mathvariant="normal">e</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">f</mml:mi></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M78" display="inline"><mml:mn mathvariant="normal">140</mml:mn></mml:math></inline-formula>–<inline-formula><mml:math id="M79" display="inline"><mml:mrow><mml:msup><mml:mn mathvariant="normal">220</mml:mn><mml:mrow><mml:mi mathvariant="normal">e</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">f</mml:mi></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col6"><inline-formula><mml:math id="M80" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:msup><mml:mn mathvariant="normal">30</mml:mn><mml:mrow><mml:mi mathvariant="normal">f</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">g</mml:mi></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col7"><inline-formula><mml:math id="M81" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:msup><mml:mn mathvariant="normal">28</mml:mn><mml:mrow><mml:mi mathvariant="normal">f</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">g</mml:mi></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col8"><inline-formula><mml:math id="M82" display="inline"><mml:mn mathvariant="normal">20</mml:mn></mml:math></inline-formula>–<inline-formula><mml:math id="M83" display="inline"><mml:mn mathvariant="normal">340</mml:mn></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col9">
                    <xref ref-type="bibr" rid="bib1.bibx60" id="normal.44"/>
                  </oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">(<inline-formula><mml:math id="M84" display="inline"><mml:mn mathvariant="normal">1800</mml:mn></mml:math></inline-formula>–<inline-formula><mml:math id="M85" display="inline"><mml:mn mathvariant="normal">2000</mml:mn></mml:math></inline-formula>)</oasis:entry>
         <oasis:entry colname="col2"/>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M86" display="inline"><mml:mn mathvariant="normal">111.2</mml:mn></mml:math></inline-formula>–<inline-formula><mml:math id="M87" display="inline"><mml:mn mathvariant="normal">124.0</mml:mn></mml:math></inline-formula><inline-formula><mml:math id="M88" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> W</oasis:entry>
         <oasis:entry colname="col4"/>
         <oasis:entry colname="col5"/>
         <oasis:entry colname="col6"/>
         <oasis:entry colname="col7"/>
         <oasis:entry colname="col8"/>
         <oasis:entry colname="col9"/>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table><table-wrap-foot><p id="d1e467"><inline-formula><mml:math id="M23" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">a</mml:mi></mml:msup></mml:math></inline-formula> Firn cores FB9804, FB9805, FB9807–FB9811,
FB9813–FB9817, B31–B33. <inline-formula><mml:math id="M24" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">b</mml:mi></mml:msup></mml:math></inline-formula> Firn cores B31–B33.
<inline-formula><mml:math id="M25" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">c</mml:mi></mml:msup></mml:math></inline-formula> Firn cores WDC2005A, ITASE-1999-1,
ITASE-2000-1, ITASE-2000-4, ITASE-2000-5.
<inline-formula><mml:math id="M26" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">d</mml:mi></mml:msup></mml:math></inline-formula> <xref ref-type="bibr" rid="bib1.bibx47" id="text.38"/>. <inline-formula><mml:math id="M27" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">e</mml:mi></mml:msup></mml:math></inline-formula> <xref ref-type="bibr" rid="bib1.bibx30" id="text.39"/>.
<inline-formula><mml:math id="M28" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">f</mml:mi></mml:msup></mml:math></inline-formula> <xref ref-type="bibr" rid="bib1.bibx68" id="text.40"/>.
<inline-formula><mml:math id="M29" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">g</mml:mi></mml:msup></mml:math></inline-formula> <xref ref-type="bibr" rid="bib1.bibx7" id="text.41"/>.</p></table-wrap-foot></table-wrap>

</sec>
<sec id="Ch1.S2.SS2">
  <title>Model for the separation of signal and noise in the
spectral domain</title>
      <p id="d1e1303">Our approach in general assumes that individual isotope records from a certain
region contain two contributions: (i) a signal common to all cores from that
region and (ii) independent noise components, which are, for example, related
to spatial variability from redistribution of snow (stratigraphic noise) or to
precipitation intermittency. By utilising several records we can disentangle
both contributions and estimate the underlying common and noise signals. The
approach is similar to the analysis of variance <xref ref-type="bibr" rid="bib1.bibx10" id="paren.45"><named-content content-type="pre">e.g.</named-content></xref> but
uses the power spectra of the time series to derive timescale-dependent
estimates.</p>
      <p id="d1e1311">More formally, given a core array of <inline-formula><mml:math id="M89" display="inline"><mml:mi>n</mml:mi></mml:math></inline-formula> isotope records, the power spectral
density (PSD) of an individual record from site <inline-formula><mml:math id="M90" display="inline"><mml:mi>i</mml:mi></mml:math></inline-formula>, <inline-formula><mml:math id="M91" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="script">X</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>(</mml:mo><mml:mi>f</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>, where
<inline-formula><mml:math id="M92" display="inline"><mml:mi>f</mml:mi></mml:math></inline-formula> denotes frequency, is the sum
<inline-formula><mml:math id="M93" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="script">X</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>(</mml:mo><mml:mi>f</mml:mi><mml:mo>)</mml:mo><mml:mo>=</mml:mo><mml:mi mathvariant="script">C</mml:mi><mml:mo>(</mml:mo><mml:mi>f</mml:mi><mml:mo>)</mml:mo><mml:mo>+</mml:mo><mml:msub><mml:mi mathvariant="script">N</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>(</mml:mo><mml:mi>f</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>, where <inline-formula><mml:math id="M94" display="inline"><mml:mrow><mml:mi mathvariant="script">C</mml:mi><mml:mo>(</mml:mo><mml:mi>f</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> and
<inline-formula><mml:math id="M95" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="script">N</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>(</mml:mo><mml:mi>f</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> are the original spectra of the common signal and the noise
component prior to the smoothing by molecular diffusion of water
vapour within the porous firn <xref ref-type="bibr" rid="bib1.bibx22 bib1.bibx67" id="paren.46"/>. To relate this
with the actual measured signal, <inline-formula><mml:math id="M96" display="inline"><mml:mrow><mml:msub><mml:mover accent="true"><mml:mi mathvariant="script">X</mml:mi><mml:mo stretchy="false" mathvariant="normal">^</mml:mo></mml:mover><mml:mi>i</mml:mi></mml:msub><mml:mo>(</mml:mo><mml:mi>f</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>, we additionally have
to account for the measurement process, which adds additional noise to the
diffused record. <inline-formula><mml:math id="M97" display="inline"><mml:mrow><mml:msub><mml:mover accent="true"><mml:mi mathvariant="script">X</mml:mi><mml:mo mathvariant="normal" stretchy="false">^</mml:mo></mml:mover><mml:mi>i</mml:mi></mml:msub><mml:mo>(</mml:mo><mml:mi>f</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> is thus given by
            <disp-formula id="Ch1.E1" content-type="numbered"><mml:math id="M98" display="block"><mml:mrow><mml:msub><mml:mover accent="true"><mml:mi mathvariant="script">X</mml:mi><mml:mo stretchy="false" mathvariant="normal">^</mml:mo></mml:mover><mml:mi>i</mml:mi></mml:msub><mml:mo>(</mml:mo><mml:mi>f</mml:mi><mml:mo>)</mml:mo><mml:mo>=</mml:mo><mml:msub><mml:mi mathvariant="script">G</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>(</mml:mo><mml:mi>f</mml:mi><mml:mo>)</mml:mo><mml:mfenced close="]" open="["><mml:mrow><mml:mi mathvariant="script">C</mml:mi><mml:mo>(</mml:mo><mml:mi>f</mml:mi><mml:mo>)</mml:mo><mml:mo>+</mml:mo><mml:msub><mml:mi mathvariant="script">N</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>(</mml:mo><mml:mi>f</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:mfenced><mml:mo>+</mml:mo><mml:mi mathvariant="normal">Σ</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></disp-formula>
          Here, <inline-formula><mml:math id="M99" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="script">G</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>(</mml:mo><mml:mi>f</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> is a linear transfer function that acts as a low-pass
filter and accounts for the diffusion process
(Appendix <xref ref-type="sec" rid="App1.Ch1.S1"/>), and <inline-formula><mml:math id="M100" display="inline"><mml:mi mathvariant="normal">Σ</mml:mi></mml:math></inline-formula> is the measurement error. At
annual resolution, <inline-formula><mml:math id="M101" display="inline"><mml:mi mathvariant="normal">Σ</mml:mi></mml:math></inline-formula> is typically at least 1 order of magnitude smaller
than the stratigraphic noise level <xref ref-type="bibr" rid="bib1.bibx42" id="paren.47"/> and is therefore neglected
in the following. We now calculate the mean spectrum, <inline-formula><mml:math id="M102" display="inline"><mml:mrow><mml:mi mathvariant="script">M</mml:mi><mml:mo>(</mml:mo><mml:mi>f</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>, of all
individual spectra <inline-formula><mml:math id="M103" display="inline"><mml:mrow><mml:msub><mml:mover accent="true"><mml:mi mathvariant="script">X</mml:mi><mml:mo mathvariant="normal" stretchy="false">^</mml:mo></mml:mover><mml:mi>i</mml:mi></mml:msub><mml:mo>(</mml:mo><mml:mi>f</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>. Assuming that the statistical
properties of the individual noise terms are identical for all <inline-formula><mml:math id="M104" display="inline"><mml:mi>n</mml:mi></mml:math></inline-formula> records, we
obtain
            <disp-formula id="Ch1.E2" content-type="numbered"><mml:math id="M105" display="block"><mml:mrow><mml:mi mathvariant="script">M</mml:mi><mml:mo>(</mml:mo><mml:mi>f</mml:mi><mml:mo>)</mml:mo><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mn mathvariant="normal">1</mml:mn><mml:mi>n</mml:mi></mml:mfrac></mml:mstyle><mml:munderover><mml:mo movablelimits="false">∑</mml:mo><mml:mrow><mml:mi>i</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow><mml:mi>n</mml:mi></mml:munderover><mml:msub><mml:mover accent="true"><mml:mi mathvariant="script">X</mml:mi><mml:mo mathvariant="normal" stretchy="false">^</mml:mo></mml:mover><mml:mi>i</mml:mi></mml:msub><mml:mo>(</mml:mo><mml:mi>f</mml:mi><mml:mo>)</mml:mo><mml:mo>=</mml:mo><mml:mover accent="true"><mml:mi mathvariant="script">G</mml:mi><mml:mo mathvariant="normal">‾</mml:mo></mml:mover><mml:mo>(</mml:mo><mml:mi>f</mml:mi><mml:mo>)</mml:mo><mml:mfenced close="]" open="["><mml:mrow><mml:mi mathvariant="script">C</mml:mi><mml:mo>(</mml:mo><mml:mi>f</mml:mi><mml:mo>)</mml:mo><mml:mo>+</mml:mo><mml:mi mathvariant="script">N</mml:mi><mml:mo>(</mml:mo><mml:mi>f</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:mfenced><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>
          where <inline-formula><mml:math id="M106" display="inline"><mml:mrow><mml:mover accent="true"><mml:mi mathvariant="script">G</mml:mi><mml:mo mathvariant="normal">‾</mml:mo></mml:mover><mml:mo>(</mml:mo><mml:mi>f</mml:mi><mml:mo>)</mml:mo><mml:mo>=</mml:mo><mml:mn mathvariant="normal">1</mml:mn><mml:mo>/</mml:mo><mml:mi>n</mml:mi><mml:msubsup><mml:mo>∑</mml:mo><mml:mrow><mml:mi>i</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow><mml:mi>n</mml:mi></mml:msubsup><mml:msub><mml:mi mathvariant="script">G</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>(</mml:mo><mml:mi>f</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> is the
average diffusion transfer function. In contrast to forming the spectral mean,
we can also average the <inline-formula><mml:math id="M107" display="inline"><mml:mi>n</mml:mi></mml:math></inline-formula> isotope records in the time domain and then
calculate the PSD of this “stacked” record. Here, the noise component will be
reduced by a factor of <inline-formula><mml:math id="M108" display="inline"><mml:mi>n</mml:mi></mml:math></inline-formula> compared to the mean spectrum in Eq. (<xref ref-type="disp-formula" rid="Ch1.E2"/>), since we assume independent noise between the
sites. Additionally, we have to take into account the time uncertainty of the
dated records. This does not affect the overall shape of broadband spectra
<xref ref-type="bibr" rid="bib1.bibx53" id="paren.48"/> but diminishes the correlation between the records
<xref ref-type="bibr" rid="bib1.bibx17" id="paren.49"/> and thus their spectral coherence, which reduces the variance
of the common signal in the stacked record. The PSD of the stacked record is
thus
            <disp-formula id="Ch1.E3" content-type="numbered"><mml:math id="M109" display="block"><mml:mrow><mml:mi mathvariant="script">S</mml:mi><mml:mo>(</mml:mo><mml:mi>f</mml:mi><mml:mo>)</mml:mo><mml:mo>≈</mml:mo><mml:mover accent="true"><mml:mi mathvariant="script">G</mml:mi><mml:mo mathvariant="normal">‾</mml:mo></mml:mover><mml:mo>(</mml:mo><mml:mi>f</mml:mi><mml:mo>)</mml:mo><mml:mfenced close="]" open="["><mml:mrow><mml:mi mathvariant="normal">Φ</mml:mi><mml:mo>(</mml:mo><mml:mi>f</mml:mi><mml:mo>)</mml:mo><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mi mathvariant="script">C</mml:mi><mml:mo>(</mml:mo><mml:mi>f</mml:mi><mml:mo>)</mml:mo><mml:mo>+</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mn mathvariant="normal">1</mml:mn><mml:mi>n</mml:mi></mml:mfrac></mml:mstyle><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mi mathvariant="script">N</mml:mi><mml:mo>(</mml:mo><mml:mi>f</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:mfenced><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>
          where <inline-formula><mml:math id="M110" display="inline"><mml:mrow><mml:mi mathvariant="normal">Φ</mml:mi><mml:mo>(</mml:mo><mml:mi>f</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> is a linear transfer function accounting for the effect of time
uncertainty. Applying the average diffusion transfer function,
<inline-formula><mml:math id="M111" display="inline"><mml:mrow><mml:mover accent="true"><mml:mi mathvariant="script">G</mml:mi><mml:mo mathvariant="normal">‾</mml:mo></mml:mover><mml:mo>(</mml:mo><mml:mi>f</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>, also to the spectrum of the stacked record is a
valid approximation in the case of similar <inline-formula><mml:math id="M112" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="script">G</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>(</mml:mo><mml:mi>f</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>, which we
confirmed for our records (Appendix <xref ref-type="sec" rid="App1.Ch1.S1"/>). From the
expressions for the mean spectrum (<inline-formula><mml:math id="M113" display="inline"><mml:mi mathvariant="script">M</mml:mi></mml:math></inline-formula>, Eq. <xref ref-type="disp-formula" rid="Ch1.E2"/>)
and the spectrum of the stacked record (<inline-formula><mml:math id="M114" display="inline"><mml:mi mathvariant="script">S</mml:mi></mml:math></inline-formula>,
Eq. <xref ref-type="disp-formula" rid="Ch1.E3"/>) we can now derive expressions for the spectra of
the common signal <inline-formula><mml:math id="M115" display="inline"><mml:mi mathvariant="script">C</mml:mi></mml:math></inline-formula> and the noise <inline-formula><mml:math id="M116" display="inline"><mml:mi mathvariant="script">N</mml:mi></mml:math></inline-formula> (omitting the
explicit frequency dependence in the notation here),

                <disp-formula id="Ch1.E4" specific-use="align" content-type="subnumberedsingle"><mml:math id="M117" display="block"><mml:mtable displaystyle="true"><mml:mlabeledtr id="Ch1.E4.1"><mml:mtd/><mml:mtd><mml:mrow><mml:mstyle class="stylechange" displaystyle="true"/><mml:mi mathvariant="script">C</mml:mi></mml:mrow></mml:mtd><mml:mtd><mml:mrow><mml:mstyle class="stylechange" displaystyle="true"/><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mi>n</mml:mi><mml:mrow><mml:mi>n</mml:mi><mml:mo>-</mml:mo><mml:msup><mml:mi mathvariant="normal">Φ</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:mfrac></mml:mstyle><mml:msup><mml:mi mathvariant="normal">Φ</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup><mml:msup><mml:mover accent="true"><mml:mi mathvariant="script">G</mml:mi><mml:mo mathvariant="normal">‾</mml:mo></mml:mover><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup><mml:mo mathsize="2.0em">[</mml:mo><mml:mi mathvariant="script">S</mml:mi><mml:mo>-</mml:mo><mml:msup><mml:mi>n</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup><mml:mi mathvariant="script">M</mml:mi><mml:mo mathsize="2.0em">]</mml:mo><mml:mo>,</mml:mo></mml:mrow></mml:mtd></mml:mlabeledtr><mml:mlabeledtr id="Ch1.E4.2"><mml:mtd/><mml:mtd><mml:mrow><mml:mstyle class="stylechange" displaystyle="true"/><mml:mi mathvariant="script">N</mml:mi></mml:mrow></mml:mtd><mml:mtd><mml:mrow><mml:mstyle class="stylechange" displaystyle="true"/><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mi>n</mml:mi><mml:mrow><mml:mi>n</mml:mi><mml:mo>-</mml:mo><mml:msup><mml:mi mathvariant="normal">Φ</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:mfrac></mml:mstyle><mml:msup><mml:mover accent="true"><mml:mi mathvariant="script">G</mml:mi><mml:mo mathvariant="normal">‾</mml:mo></mml:mover><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup><mml:mo mathsize="2.0em">[</mml:mo><mml:mi mathvariant="script">M</mml:mi><mml:mo>-</mml:mo><mml:msup><mml:mi mathvariant="normal">Φ</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup><mml:mi mathvariant="script">S</mml:mi><mml:mo mathsize="2.0em">]</mml:mo><mml:mo>.</mml:mo></mml:mrow></mml:mtd></mml:mlabeledtr></mml:mtable></mml:math></disp-formula></p>
</sec>
<sec id="Ch1.S2.SS3">
  <title>Transfer functions for
vapour diffusion and time uncertainty</title>
      <p id="d1e2056">For estimating the transfer functions for diffusion and time uncertainty, the
inverses of which are used to correct the signal and noise spectra
(Eq. <xref ref-type="disp-formula" rid="Ch1.E4"/>), we use numerical simulations, since no closed form
expressions are available. For this, we create surrogate records mimicking the
individual core arrays and simulate the effects of diffusion and time
uncertainty on the surrogate spectra of the stacked records. We model the firn
diffusion as the convolution of the original time series with a Gaussian kernel
<xref ref-type="bibr" rid="bib1.bibx22" id="paren.50"/>. The width of the kernel is set by the diffusion length
<inline-formula><mml:math id="M118" display="inline"><mml:mi mathvariant="italic">σ</mml:mi></mml:math></inline-formula>, which is site-specific and a function of depth. For modelling the time
uncertainty we use the approach of <xref ref-type="bibr" rid="bib1.bibx5" id="text.51"/>. Model parameters are the
rates of missing and double-counted annual layers, which we set to match the
reported time uncertainties of the isotope records.
Appendix <xref ref-type="sec" rid="App1.Ch1.S2"/> gives a detailed description of the simulations
including the estimated transfer functions
(Fig. <xref ref-type="fig" rid="App1.Ch1.F1"/>). Because the diffusion correction
(<inline-formula><mml:math id="M119" display="inline"><mml:mrow><mml:msup><mml:mover accent="true"><mml:mi mathvariant="script">G</mml:mi><mml:mo mathvariant="normal">‾</mml:mo></mml:mover><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> in Eq. <xref ref-type="disp-formula" rid="Ch1.E4"/>) strongly amplifies
both the raw spectra as well as their uncertainties on the fast frequencies, we
restrict our analyses to the frequency region where the estimated transfer
function, <inline-formula><mml:math id="M120" display="inline"><mml:mover accent="true"><mml:mi mathvariant="script">G</mml:mi><mml:mo mathvariant="normal">‾</mml:mo></mml:mover></mml:math></inline-formula>, assumes values <inline-formula><mml:math id="M121" display="inline"><mml:mrow><mml:mo>≥</mml:mo><mml:mn mathvariant="normal">0.5</mml:mn></mml:mrow></mml:math></inline-formula>, equivalent to a correction factor
<inline-formula><mml:math id="M122" display="inline"><mml:mrow><mml:mo>≤</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:math></inline-formula> in Eq. (<xref ref-type="disp-formula" rid="Ch1.E4"/>). This avoids large uncertainties and
translates to a maximum frequency that is used for the analyses (hereafter
the cut-off frequency) of <inline-formula><mml:math id="M123" display="inline"><mml:mrow><mml:mn mathvariant="normal">1</mml:mn><mml:mo>/</mml:mo><mml:mn mathvariant="normal">5</mml:mn></mml:mrow></mml:math></inline-formula> yr<inline-formula><mml:math id="M124" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> for DML1, <inline-formula><mml:math id="M125" display="inline"><mml:mrow><mml:mn mathvariant="normal">1</mml:mn><mml:mo>/</mml:mo><mml:mn mathvariant="normal">8.5</mml:mn></mml:mrow></mml:math></inline-formula> yr<inline-formula><mml:math id="M126" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> for DML2 and
<inline-formula><mml:math id="M127" display="inline"><mml:mrow><mml:mn mathvariant="normal">1</mml:mn><mml:mo>/</mml:mo><mml:mn mathvariant="normal">2.8</mml:mn></mml:mrow></mml:math></inline-formula> yr<inline-formula><mml:math id="M128" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> for WAIS (Fig. <xref ref-type="fig" rid="App1.Ch1.F1"/>).</p>
</sec>
<?pagebreak page2056?><sec id="Ch1.S2.SS4">
  <title>Timescale-dependent estimate of the signal-to-noise ratio</title>
      <p id="d1e2212">The frequency-dependent SNR, <inline-formula><mml:math id="M129" display="inline"><mml:mrow><mml:mi>F</mml:mi><mml:mo>(</mml:mo><mml:mi>f</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>, is defined as the ratio of the signal and
noise spectra,
            <disp-formula id="Ch1.E5" content-type="numbered"><mml:math id="M130" display="block"><mml:mrow><mml:mi>F</mml:mi><mml:mo>(</mml:mo><mml:mi>f</mml:mi><mml:mo>)</mml:mo><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:mi mathvariant="script">C</mml:mi><mml:mo>(</mml:mo><mml:mi>f</mml:mi><mml:mo>)</mml:mo></mml:mrow><mml:mrow><mml:mi mathvariant="script">N</mml:mi><mml:mo>(</mml:mo><mml:mi>f</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:mfrac></mml:mstyle><mml:mo>.</mml:mo></mml:mrow></mml:math></disp-formula>
          As we explicitly neglect measurement noise, this quantity is unaffected by the
effect of diffusion or its correction (Eq. <xref ref-type="disp-formula" rid="Ch1.E4"/>) but directly
influenced by time uncertainty, which biases the uncorrected SNR towards
zero. Typically, firn or ice-core isotope records are averaged onto a fixed
temporal resolution <inline-formula><mml:math id="M131" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>t</mml:mi></mml:mrow></mml:math></inline-formula> (the “averaging period”) during
preprocessing. The signal-to-noise variance ratio after this averaging step is
given by
            <disp-formula id="Ch1.E6" content-type="numbered"><mml:math id="M132" display="block"><mml:mrow><mml:mover accent="true"><mml:mi>F</mml:mi><mml:mo mathvariant="normal">‾</mml:mo></mml:mover><mml:mo>(</mml:mo><mml:msub><mml:mi>f</mml:mi><mml:mi mathvariant="normal">Nyq</mml:mi></mml:msub><mml:mo>)</mml:mo><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:msubsup><mml:mo>∫</mml:mo><mml:mrow><mml:msub><mml:mi>f</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow><mml:mrow><mml:msub><mml:mi>f</mml:mi><mml:mi mathvariant="normal">Nyq</mml:mi></mml:msub></mml:mrow></mml:msubsup><mml:mi mathvariant="script">C</mml:mi><mml:mo>(</mml:mo><mml:mi>f</mml:mi><mml:mo>)</mml:mo><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mi mathvariant="normal">d</mml:mi><mml:mi>f</mml:mi></mml:mrow><mml:mrow><mml:msubsup><mml:mo>∫</mml:mo><mml:mrow><mml:msub><mml:mi>f</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow><mml:mrow><mml:msub><mml:mi>f</mml:mi><mml:mi mathvariant="normal">Nyq</mml:mi></mml:msub></mml:mrow></mml:msubsup><mml:mi mathvariant="script">N</mml:mi><mml:mo>(</mml:mo><mml:mi>f</mml:mi><mml:mo>)</mml:mo><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mi mathvariant="normal">d</mml:mi><mml:mi>f</mml:mi></mml:mrow></mml:mfrac></mml:mstyle><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>
          where <inline-formula><mml:math id="M133" display="inline"><mml:mrow><mml:msub><mml:mi>f</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> is the lowest frequency of the spectral estimates and <inline-formula><mml:math id="M134" display="inline"><mml:mrow><mml:msub><mml:mi>f</mml:mi><mml:mi mathvariant="normal">Nyq</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>
is the Nyquist frequency for the chosen averaging period, i.e. <inline-formula><mml:math id="M135" display="inline"><mml:mrow><mml:mn mathvariant="normal">1</mml:mn><mml:mo>/</mml:mo><mml:mo>(</mml:mo><mml:mn mathvariant="normal">2</mml:mn><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>t</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>. Since our records have different lengths, we choose a common minimum value
for <inline-formula><mml:math id="M136" display="inline"><mml:mrow><mml:msub><mml:mi>f</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> of <inline-formula><mml:math id="M137" display="inline"><mml:mrow><mml:mn mathvariant="normal">1</mml:mn><mml:mo>/</mml:mo><mml:mn mathvariant="normal">100</mml:mn></mml:mrow></mml:math></inline-formula> yr<inline-formula><mml:math id="M138" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> for the integrations in Eq. (<xref ref-type="disp-formula" rid="Ch1.E6"/>). The
value of <inline-formula><mml:math id="M139" display="inline"><mml:mover accent="true"><mml:mi>F</mml:mi><mml:mo mathvariant="normal">‾</mml:mo></mml:mover></mml:math></inline-formula> can then be used to obtain the correlation between the
time series of the common signal <inline-formula><mml:math id="M140" display="inline"><mml:mi>c</mml:mi></mml:math></inline-formula> and a stacked record <inline-formula><mml:math id="M141" display="inline"><mml:mover accent="true"><mml:mi>x</mml:mi><mml:mo mathvariant="normal">‾</mml:mo></mml:mover></mml:math></inline-formula>
built from the spatial average of <inline-formula><mml:math id="M142" display="inline"><mml:mi>n</mml:mi></mml:math></inline-formula> individual records <xref ref-type="bibr" rid="bib1.bibx10" id="paren.52"/>:
            <disp-formula id="Ch1.E7" content-type="numbered"><mml:math id="M143" display="block"><mml:mrow><mml:mi>r</mml:mi><mml:mo>(</mml:mo><mml:mi>c</mml:mi><mml:mo>,</mml:mo><mml:mover accent="true"><mml:mi>x</mml:mi><mml:mo mathvariant="normal">‾</mml:mo></mml:mover><mml:mo>)</mml:mo><mml:mo>(</mml:mo><mml:msub><mml:mi>f</mml:mi><mml:mi mathvariant="normal">Nyq</mml:mi></mml:msub><mml:mo>)</mml:mo><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mn mathvariant="normal">1</mml:mn><mml:msqrt><mml:mrow><mml:mn mathvariant="normal">1</mml:mn><mml:mo>+</mml:mo><mml:msup><mml:mfenced close=")" open="("><mml:mrow><mml:mi>n</mml:mi><mml:mover accent="true"><mml:mi>F</mml:mi><mml:mo mathvariant="normal">‾</mml:mo></mml:mover><mml:mo>(</mml:mo><mml:msub><mml:mi>f</mml:mi><mml:mi mathvariant="normal">Nyq</mml:mi></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:mfenced><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:msqrt></mml:mfrac></mml:mstyle><mml:mo>.</mml:mo></mml:mrow></mml:math></disp-formula></p>
</sec>
<sec id="Ch1.S2.SS5">
  <title>Spectral analysis</title>
      <p id="d1e2557">Missing years in the published records (<inline-formula><mml:math id="M144" display="inline"><mml:mrow><mml:mo>∼</mml:mo><mml:mn mathvariant="normal">1.6</mml:mn></mml:mrow></mml:math></inline-formula> % of all data points) are
linearly interpolated. Power spectra are then estimated using Thomson's
multitaper method with three windows <xref ref-type="bibr" rid="bib1.bibx50" id="paren.53"/> with linear detrending
before analysis. This approach is known to introduce a small bias at the lowest
frequencies, and we omit the lowest frequency from all plots and calculations.
In general, spectral smoothing is necessary to improve the quality of the
estimates from short time series. Here, we use a Gaussian smoothing kernel with
varying width that is proportional to the applied frequency and thus constant in
logarithmic frequency space <xref ref-type="bibr" rid="bib1.bibx31" id="paren.54"/>. The smoothing width in
logarithmic units is chosen to be <inline-formula><mml:math id="M145" display="inline"><mml:mn mathvariant="normal">0.1</mml:mn></mml:math></inline-formula> for the WAIS data and <inline-formula><mml:math id="M146" display="inline"><mml:mn mathvariant="normal">0.15</mml:mn></mml:math></inline-formula> for the DML
data. To avoid biased estimates at the low- and high-frequency boundaries, the
kernel is truncated on both sides to maintain its symmetry. Logarithmic
smoothing preserves power-law scaling of spectra and is thus useful for climate
spectra.</p>
</sec>
</sec>
<sec id="Ch1.S3">
  <title>Results</title>
<sec id="Ch1.S3.SS1">
  <title>Illustrating the methodological
approach</title>
      <p id="d1e2602">In order to illustrate our method (Sect. <xref ref-type="sec" rid="Ch1.S2.SS2"/>), we first use the DML1
data set to demonstrate the individual steps involved in the analysis.</p>
      <p id="d1e2607">Each power spectrum derived from an individual record of the DML1 firn-core
array provides a timescale-dependent representation of the isotope variations in
the study region (Fig. <xref ref-type="fig" rid="Ch1.F1"/>, thin grey lines). The differences
between the individual spectra are not only due to differences in the isotope
variability between the records, but also caused by the spectral uncertainty
from the finite length of each record. The mean spectrum, <inline-formula><mml:math id="M147" display="inline"><mml:mi mathvariant="script">M</mml:mi></mml:math></inline-formula>, of all
individual spectra reduces this spectral uncertainty and thus provides a more
robust estimate of the single records' spectrum (Fig. <xref ref-type="fig" rid="Ch1.F1"/>,
black line). It shows a two-part structure with a near-constant PSD above
decadal timescales (i.e. is “white”) and a strong decrease in spectral power
towards shorter timescales, which is expected from vapour diffusion in the firn
(Eq. <xref ref-type="disp-formula" rid="Ch1.E2"/> and Appendix <xref ref-type="sec" rid="App1.Ch1.S2"/>).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F1"><caption><p id="d1e2627">Detailed results of estimated PSD for the DML1 data set. Thin grey lines show
the individual power spectra for each record with the mean spectrum indicated
by the thick black line. The dashed black line shows the null hypothesis
according to which all isotope variations are noise; the brown line depicts
the spectrum from averaging all records in the time domain (the stacked
record). The extent of the blue (red) shading is proportional to the
uncorrected PSD of the signal (noise) (Eq. <xref ref-type="disp-formula" rid="Ch1.E4"/>). The
vertical dashed line denotes the cut-off period for the diffusion correction
(see Methods).</p></caption>
          <?xmltex \igopts{width=236.157874pt}?><graphic xlink:href="https://cp.copernicus.org/articles/14/2053/2018/cp-14-2053-2018-f01.png"/>

        </fig>

      <p id="d1e2638">The mean spectrum divided by the number of records (<inline-formula><mml:math id="M148" display="inline"><mml:mrow><mml:mi mathvariant="script">M</mml:mi><mml:mo>/</mml:mo><mml:mi>n</mml:mi></mml:mrow></mml:math></inline-formula>; here,
<inline-formula><mml:math id="M149" display="inline"><mml:mrow><mml:mi>n</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">15</mml:mn></mml:mrow></mml:math></inline-formula>; Fig. <xref ref-type="fig" rid="Ch1.F1"/>, dashed line) is the expected<?pagebreak page2057?> spectrum if
all isotope variations present in the firn-core records were independent
noise. In comparison, averaging in the time domain across records that contain
noise and additionally a common (i.e. spatially coherent) signal will result in
a spectrum <inline-formula><mml:math id="M150" display="inline"><mml:mi mathvariant="script">S</mml:mi></mml:math></inline-formula>, where the noise component is also reduced by <inline-formula><mml:math id="M151" display="inline"><mml:mrow><mml:mn mathvariant="normal">1</mml:mn><mml:mo>/</mml:mo><mml:mi>n</mml:mi></mml:mrow></mml:math></inline-formula> but
with the common signal left unaltered (Eq. <xref ref-type="disp-formula" rid="Ch1.E3"/>, neglecting
time uncertainty), and which is thus located between the mean spectrum and the
mean spectrum divided by <inline-formula><mml:math id="M152" display="inline"><mml:mi>n</mml:mi></mml:math></inline-formula>. This spectrum <inline-formula><mml:math id="M153" display="inline"><mml:mi mathvariant="script">S</mml:mi></mml:math></inline-formula> for the DML1 stack
(Fig. <xref ref-type="fig" rid="Ch1.F1"/>, brown line) is for short timescales (periods from
<inline-formula><mml:math id="M154" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 3 to 5 years) nearly identical to the mean spectrum divided by <inline-formula><mml:math id="M155" display="inline"><mml:mi>n</mml:mi></mml:math></inline-formula>, which
suggests that here the variability of the individual records is consistent with
the null hypothesis of independent noise. The divergence from the white-noise
level close to the 2-year Nyquist period is likely an artefact from the jitter of
the annual averages as a result of the uncertainty in defining annual depth
increments upon dating. In contrast to the short periods below 10 years, the
individual records clearly contain a common isotope signal on longer timescales
that “survives” the averaging process when building the stacked record and
which increases in power with increasing timescale (Fig. <xref ref-type="fig" rid="Ch1.F1"/>,
brown line). Hence, the differences between <inline-formula><mml:math id="M156" display="inline"><mml:mi mathvariant="script">S</mml:mi></mml:math></inline-formula> and <inline-formula><mml:math id="M157" display="inline"><mml:mrow><mml:mi mathvariant="script">M</mml:mi><mml:mo>/</mml:mo><mml:mi>n</mml:mi></mml:mrow></mml:math></inline-formula>
and between <inline-formula><mml:math id="M158" display="inline"><mml:mi mathvariant="script">S</mml:mi></mml:math></inline-formula> and <inline-formula><mml:math id="M159" display="inline"><mml:mi mathvariant="script">M</mml:mi></mml:math></inline-formula> inform us about the
average signal and noise content of the individual isotope records, but they
need to be corrected for the residual amount of noise contained in <inline-formula><mml:math id="M160" display="inline"><mml:mi mathvariant="script">S</mml:mi></mml:math></inline-formula>
and for the loss of variance from diffusion and time uncertainty
(Eq. <xref ref-type="disp-formula" rid="Ch1.E4"/>).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F2" specific-use="star"><caption><p id="d1e2768">Estimated signal <bold>(a, c)</bold> and noise <bold>(b, d)</bold> spectra of Antarctic isotope
records. Results are shown based on the spectral correction model for the
records from Dronning Maud Land (DML, <bold>a</bold>, <bold>b</bold>) and from the West Antarctic Ice
Sheet (WAIS, <bold>c</bold>, <bold>d</bold>). The raw estimates (dotted lines) show the spectra
prior to any correction, while corrected estimates differentiate between the
correction for time uncertainty only (dashed lines) and the full correction
including time uncertainty and diffusion (solid lines). For DML, results
include both the short 200-year-long records (DML1; blue lines in
<bold>a</bold>, red lines in <bold>b</bold>) and the longer records covering the last
1000 years (DML2; black lines).</p></caption>
          <?xmltex \igopts{width=398.338583pt}?><graphic xlink:href="https://cp.copernicus.org/articles/14/2053/2018/cp-14-2053-2018-f02.png"/>

        </fig>

</sec>
<sec id="Ch1.S3.SS2">
  <title>Timescale dependence of
DML and WAIS signal and noise variability</title>
      <p id="d1e2808">After this detailed description for DML1, we now turn to the results of the
estimated signal and noise spectra for all three data sets. In general, the
shape of the signal spectra is, as a result of the corrections, clearly distinct
from the mean spectrum of the individual isotope variations. This is seen, for
example, in the corrected DML1 signal spectrum which indicates a much more
steady increase in PSD from short to long timescales
(Fig. <xref ref-type="fig" rid="Ch1.F2"/>a, solid blue line) compared to the mean
spectrum (Fig. <xref ref-type="fig" rid="Ch1.F1"/>, black line). This is confirmed by the
three 1000-year-long DML2 records, which have a common signal that exhibits a roughly similar power
spectrum in the range of timescales that overlap (<inline-formula><mml:math id="M161" display="inline"><mml:mo lspace="0mm">∼</mml:mo></mml:math></inline-formula> 10- to 100-year
period). We partly expect this, since the longer cores are also part of the DML1
data set, but the increase in signal power in this frequency band seems to be a
general feature over the last 1000 years. In addition, the DML2 signal
spectrum shows a further and similar increase for timescales beyond the
100-year period. This change in spectral shape from the mean to the signal
spectrum results from two contributions in the correction process: firstly, the
average isotope variability is corrected for the noise contribution
(“uncorrected signal”, dotted lines in
Fig. <xref ref-type="fig" rid="Ch1.F2"/>a). This correction is mostly apparent on the
longer timescales, leading to a higher slope in PSD of the signal spectrum
compared to the mean spectrum (for DML1, the signal increases from the 10- to
100-year period by a factor of <inline-formula><mml:math id="M162" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula>2.6, the mean spectrum by a factor of
<inline-formula><mml:math id="M163" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula>1.4). Secondly, the corrections for the loss in spectral power by the
effects of diffusion and time uncertainty (here important for time periods from
<inline-formula><mml:math id="M164" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 20- to 5-years) lead to a smaller increase in PSD of the signal spectra
with increasing timescale compared to the raw estimates (compare dotted,
dashed and solid lines in Fig. <xref ref-type="fig" rid="Ch1.F2"/>a). In sharp
contrast to DML, the corrections for the WAIS records yield a signal spectrum
(Fig. <xref ref-type="fig" rid="Ch1.F2"/>c, solid line) that exhibits a rather flat
appearance throughout and indicates decreasing PSD towards centennial
timescales. Much of the flat character is caused by the diffusion and time
uncertainty corrections, which strongly amplify the raw signal power on the
subdecadal timescales; the decrease in PSD on the long timescales is a result of
the correction for the noise contribution. We note, however, that the spectral
uncertainty at the lowest frequency is high, since fewer data points contribute
to the estimated PSD for lower frequencies when using logarithmic smoothing.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F3"><caption><p id="d1e2852">Estimated timescale dependence of ice-core isotope signal-to-noise
ratios. Results are shown for the DML (black) and WAIS (blue) isotope
records. The results for DML are based on combining the spectra from DML1 and
DML2 (see text).</p></caption>
          <?xmltex \igopts{width=213.395669pt}?><graphic xlink:href="https://cp.copernicus.org/articles/14/2053/2018/cp-14-2053-2018-f03.png"/>

        </fig>

      <p id="d1e2861">A difference between the regions can also be seen in the noise spectra
(Fig. <xref ref-type="fig" rid="Ch1.F2"/>b and d). Prior to any correction, the DML1 and
DML2 noise spectra are different on shorter timescales (<inline-formula><mml:math id="M165" display="inline"><mml:mi mathvariant="italic">≲</mml:mi></mml:math></inline-formula> 20-year
period), but become consistent with each other after the correction, showing
essentially white PSD (Fig. <xref ref-type="fig" rid="Ch1.F2"/>b). In comparison, the
corrected WAIS noise<?pagebreak page2058?> spectrum shows an increase in spatially incoherent isotope
variations towards longer timescales (Fig. 2d), which correlates with the decrease in
signal power on centennial timescales (Fig. <xref ref-type="fig" rid="Ch1.F2"/>c).</p>
      <p id="d1e2877">The corrected signal and noise spectra directly provide an estimate of the
timescale dependence of the SNR (Eq. <xref ref-type="disp-formula" rid="Ch1.E5"/>). To derive
a single estimate for DML, we combine the DML2 spectra for timescales above the
decadal period with the respective DML1 spectra from the subdecadal frequency
band. Again, the results are very different between DML and WAIS
(Fig. <xref ref-type="fig" rid="Ch1.F3"/>). For DML, the SNR shows a continuous increase with
timescale, with values ranging from <inline-formula><mml:math id="M166" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 0.1 at the 5-year period to
<inline-formula><mml:math id="M167" display="inline"><mml:mi mathvariant="italic">≲</mml:mi></mml:math></inline-formula> 0.2 at the decadal timescale and increasing further to <inline-formula><mml:math id="M168" display="inline"><mml:mrow><mml:mo>∼</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:math></inline-formula> at
multi-centennial timescales. The estimate for WAIS exhibits the opposite
timescale dependence, with SNR values of <inline-formula><mml:math id="M169" display="inline"><mml:mrow><mml:mo>∼</mml:mo><mml:mn mathvariant="normal">0.5</mml:mn></mml:mrow></mml:math></inline-formula>–<inline-formula><mml:math id="M170" display="inline"><mml:mn mathvariant="normal">0.7</mml:mn></mml:math></inline-formula> for interannual
timescales that continuously decrease to <inline-formula><mml:math id="M171" display="inline"><mml:mrow><mml:mo>∼</mml:mo><mml:mn mathvariant="normal">0.1</mml:mn></mml:mrow></mml:math></inline-formula> at centennial timescales.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F4" specific-use="star"><caption><p id="d1e2939">Estimated correlation of stacked isotope records from <bold>(a)</bold> DML and
<bold>(b)</bold> WAIS with their common signal as a function of the averaging
period and the number of firn cores included in the average. The correlations
are based on Eq. (<xref ref-type="disp-formula" rid="Ch1.E7"/>) with the same signal and noise spectra
that were used for Fig. <xref ref-type="fig" rid="Ch1.F3"/>.</p></caption>
          <?xmltex \igopts{width=455.244094pt}?><graphic xlink:href="https://cp.copernicus.org/articles/14/2053/2018/cp-14-2053-2018-f04.png"/>

        </fig>

      <p id="d1e2958">A complementary picture is obtained from the expected correlation between the
time series of a stacked record and the underlying common signal as a function
of both the number of averaged records and the temporal averaging period
(Eq. <xref ref-type="disp-formula" rid="Ch1.E7"/>, Fig. <xref ref-type="fig" rid="Ch1.F4"/>). For DML, the correlation
for an individual<?pagebreak page2059?> record at interannual resolution is rather low, with roughly
<inline-formula><mml:math id="M172" display="inline"><mml:mn mathvariant="normal">0.4</mml:mn></mml:math></inline-formula>–<inline-formula><mml:math id="M173" display="inline"><mml:mn mathvariant="normal">0.5</mml:mn></mml:math></inline-formula> (Fig. <xref ref-type="fig" rid="Ch1.F4"/>a); for WAIS, this correlation is
slightly higher (<inline-formula><mml:math id="M174" display="inline"><mml:mrow><mml:mo>∼</mml:mo><mml:mn mathvariant="normal">0.5</mml:mn></mml:mrow></mml:math></inline-formula>–<inline-formula><mml:math id="M175" display="inline"><mml:mn mathvariant="normal">0.6</mml:mn></mml:math></inline-formula>, Fig. <xref ref-type="fig" rid="Ch1.F4"/>b). For
longer averaging periods, the correlation for DML shows a steady increase with
the averaging period, in line with the increase in SNR, reaching values around
<inline-formula><mml:math id="M176" display="inline"><mml:mn mathvariant="normal">0.6</mml:mn></mml:math></inline-formula> for single records and multi-decadal averaging periods
(Fig. <xref ref-type="fig" rid="Ch1.F4"/>a). Naturally, the correlation further increases
with the number of averaged cores. For WAIS, the correlation with the underlying
signal decreases with the averaging period and only increases when more
records are averaged (Fig. <xref ref-type="fig" rid="Ch1.F4"/>b).</p>
</sec>
</sec>
<sec id="Ch1.S4">
  <title>Discussion</title>
<sec id="Ch1.S4.SS1">
  <title>Physical interpretation of the analysis</title>
      <p id="d1e3024">We presented a method and the results of separating the variability recorded by
Antarctic isotope records into two contributions: local variations (noise,
Eq. <xref ref-type="disp-formula" rid="Ch1.E4"/>b) and spatially coherent variations (signal,
Eq. <xref ref-type="disp-formula" rid="Ch1.E4"/>a). We now assess the physical meaning of these terms
by discussing the relevant spatial scales of the major processes that influence
the isotopic composition of the records: (i) temperature variations, (ii) atmospheric circulation, (iii) precipitation intermittency and
(iv) stratigraphic noise.</p>
      <p id="d1e3031">Classically, the isotopic composition of firn and ice cores is interpreted as
being related to variations in local air temperature
<xref ref-type="bibr" rid="bib1.bibx6 bib1.bibx26 bib1.bibx27" id="paren.55"/>. The extent to which spatially
distributed isotope records are influenced by a common temperature signal
then depends on the decorrelation scale of the temperature anomalies, which is,
for annual mean temperatures, typically of the order of hundreds to thousands of
kilometres and increases with timescale <xref ref-type="bibr" rid="bib1.bibx24" id="paren.56"/>. For our study
regions, annual mean temperature variations from the ERA-Interim reanalysis
<xref ref-type="bibr" rid="bib1.bibx7" id="paren.57"/> exhibit decorrelation scales of <inline-formula><mml:math id="M177" display="inline"><mml:mrow><mml:mo>∼</mml:mo><mml:mn mathvariant="normal">1200</mml:mn></mml:mrow></mml:math></inline-formula> km
(Appendix <xref ref-type="sec" rid="App1.Ch1.S3"/>), which are much larger than the individual
intercore distances (<inline-formula><mml:math id="M178" display="inline"><mml:mrow><mml:mo>&lt;</mml:mo><mml:mn mathvariant="normal">400</mml:mn></mml:mrow></mml:math></inline-formula> km, Table <xref ref-type="table" rid="Ch1.T1"/>). This implies
that, if the temperature variations were fully recorded by the array of
firn-core records, they would to a large extent contribute to the estimated
signal spectrum. In fact, for the temperature reanalysis fields in the study
regions, the average of all correlations between sites separated by less than
the maximum intercore distances (Fig. <xref ref-type="fig" rid="App1.Ch1.F2"/>) suggests that the
estimated signal spectra for DML (WAIS) would contain <inline-formula><mml:math id="M179" display="inline"><mml:mrow><mml:mn mathvariant="normal">87</mml:mn><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mi mathvariant="italic">%</mml:mi></mml:mrow></mml:math></inline-formula> (<inline-formula><mml:math id="M180" display="inline"><mml:mrow><mml:mn mathvariant="normal">94</mml:mn><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mi mathvariant="italic">%</mml:mi></mml:mrow></mml:math></inline-formula>) of the
total temperature variability, while the remaining fraction would be interpreted
as noise.</p>
      <p id="d1e3092">However, changes in large-scale atmospheric circulation can lead to variations
in the source and the pathways of the moisture, which can affect the isotopic
composition of the precipitation that is formed, independently of local
temperature changes <xref ref-type="bibr" rid="bib1.bibx56" id="paren.58"><named-content content-type="pre">e.g.</named-content></xref>. In general, the spatial
scales of such variations are unclear. For the studied DML core array, which is
located on the rather flat and remote Antarctic Plateau, one could expect that
the effect is small and possibly spatially coherent, thus contributing to the
estimated signal term. For WAIS, isotope data have been interpreted to also
reflect changes in atmospheric circulation and sea-ice cover of the adjacent
oceans <xref ref-type="bibr" rid="bib1.bibx33 bib1.bibx63" id="paren.59"/>. These processes might exhibit, through the
ice-sheet topography, a regional expression at the individual firn-core sites,
which are generally lower in elevation and located near the ice divide, as
suggested by the significant spatial differences in observed intercore
correlations <xref ref-type="bibr" rid="bib1.bibx33" id="paren.60"/>. Such effects would affect the estimated noise
component.</p>
      <?pagebreak page2060?><p id="d1e3106">Major additional contributions to the overall variability of isotope data arise
from precipitation intermittency, i.e. interannual variations in the seasonality
of precipitation events <xref ref-type="bibr" rid="bib1.bibx51 bib1.bibx37" id="paren.61"/>, and from stratigraphic
noise <xref ref-type="bibr" rid="bib1.bibx10 bib1.bibx29 bib1.bibx42" id="paren.62"/> created during deposition of the
snow. Both processes exhibit significantly different decorrelation scales. The
decorrelation scale of precipitation intermittency is related to the
decorrelation scale of the precipitation itself, which is expected to be
coherent on a local scale (i.e. <?xmltex \hack{\mbox\bgroup}?><inline-formula><mml:math id="M181" display="inline"><mml:mrow><mml:mo>∼</mml:mo><mml:mn mathvariant="normal">100</mml:mn></mml:mrow></mml:math></inline-formula> m<?xmltex \hack{\egroup}?>) and to decorrelate on scales
generally smaller than the temperature decorrelation scales. In both regions,
the similar analyses of ERA-Interim data as for the temperature variations
suggest decorrelation scales of the precipitation of <inline-formula><mml:math id="M182" display="inline"><mml:mn mathvariant="normal">300</mml:mn></mml:math></inline-formula>–<inline-formula><mml:math id="M183" display="inline"><mml:mn mathvariant="normal">500</mml:mn></mml:math></inline-formula> km
(Appendix <xref ref-type="sec" rid="App1.Ch1.S3"/>). This is supported by an analysis of
measurements from autonomic weather stations <xref ref-type="bibr" rid="bib1.bibx52" id="paren.63"/> that indicate
that accumulation in DML arises from many small (<inline-formula><mml:math id="M184" display="inline"><mml:mn mathvariant="normal">1</mml:mn></mml:math></inline-formula>–<inline-formula><mml:math id="M185" display="inline"><mml:mn mathvariant="normal">2</mml:mn></mml:math></inline-formula> cm) and a few larger
events (<inline-formula><mml:math id="M186" display="inline"><mml:mrow><mml:mi mathvariant="italic">≳</mml:mi><mml:mn mathvariant="normal">5</mml:mn></mml:mrow></mml:math></inline-formula> cm) of snowfall, where the major events occur only a few
times per year without any clear seasonality but often over large areas.  In
contrast, stratigraphic noise is a short-scale phenomenon. Its generation is
related to the uneven deposition <xref ref-type="bibr" rid="bib1.bibx10" id="paren.64"/> and the constant erosion and
redeposition of the surface snow by wind <xref ref-type="bibr" rid="bib1.bibx42" id="paren.65"/>. Both processes are
connected to the local surface undulations, as these directly interact with the
snow deposition but also strongly shape the near-surface wind field. This is
suggested by the observed decorrelation scale of the stratigraphic noise at EDML
(<inline-formula><mml:math id="M187" display="inline"><mml:mrow><mml:mo>&lt;</mml:mo><mml:mn mathvariant="normal">5</mml:mn></mml:mrow></mml:math></inline-formula> m, <xref ref-type="bibr" rid="bib1.bibx42" id="altparen.66"/>), which is similar to the typical scale of the
surface undulations.</p>
      <p id="d1e3193">These differences in decorrelation scales also become apparent when analysing
the relative contributions of both processes to the total isotope
variability. At EDML, stratigraphic noise provides <inline-formula><mml:math id="M188" display="inline"><mml:mrow><mml:mo>∼</mml:mo><mml:mn mathvariant="normal">50</mml:mn><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mi mathvariant="italic">%</mml:mi></mml:mrow></mml:math></inline-formula> of the total
variance on the seasonal timescale, as suggested from the average correlation of
individual shallow isotope profiles separated above (<inline-formula><mml:math id="M189" display="inline"><mml:mrow><mml:mo>&gt;</mml:mo><mml:mn mathvariant="normal">5</mml:mn></mml:mrow></mml:math></inline-formula> m) the decorrelation
scale of the stratigraphic noise but below <inline-formula><mml:math id="M190" display="inline"><mml:mn mathvariant="normal">1</mml:mn></mml:math></inline-formula> km
<xref ref-type="bibr" rid="bib1.bibx42 bib1.bibx43" id="paren.67"/>. A much higher noise level of at least <inline-formula><mml:math id="M191" display="inline"><mml:mrow><mml:mn mathvariant="normal">80</mml:mn><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mi mathvariant="italic">%</mml:mi></mml:mrow></mml:math></inline-formula> of
the total variance (i.e. higher by a factor of <inline-formula><mml:math id="M192" display="inline"><mml:mrow><mml:mo>≥</mml:mo><mml:mn mathvariant="normal">1.6</mml:mn></mml:mrow></mml:math></inline-formula>) has been independently
inferred from comparing the observed seasonal isotope variability to the
expectation from a profile that is a mixture of a deterministic seasonal cycle
and diffused noise <xref ref-type="bibr" rid="bib1.bibx37" id="paren.68"/>. The apparent mismatch with the noise
level from stratigraphic noise can be reconciled by asserting that a significant
part of the common isotope signal at EDML on the local scale is coherent noise
from precipitation intermittency, leading to an underestimation of the total
noise level when analysing only the interprofile correlations. On the larger
spatial scales of the firn-core arrays (array scale) analysed here, the
effect of precipitation intermittency should then appear, at least partly, as a
noise term, since the spatial precipitation patterns are expected to decorrelate
on these scales. Therefore, in general, the variability contribution by
stratigraphic noise will fully appear in the noise spectra, while precipitation
intermittency is expected to partly contribute to the noise spectra but also
partly appear in the signal spectra.</p>
      <p id="d1e3254">In summary, given the large decorrelation scales of atmospheric temperature
variations and the generally smaller scales of the other terms, one could
interpret the estimated isotope signal spectra to a first approximation as
temperature signals. However, this clearly will be an upper bound of the true
temperature signal, since other processes can also lead to spatially coherent
isotope signals. Furthermore, we have neglected the transfer function from
isotopic ratios to temperatures, and other less constrained effects that affect
the isotope signal from the atmosphere to the snow <xref ref-type="bibr" rid="bib1.bibx4" id="paren.69"><named-content content-type="pre">e.g.</named-content></xref>.</p>
</sec>
<sec id="Ch1.S4.SS2">
  <title>Interpretation of the estimated signal and noise spectra</title>
      <p id="d1e3268">The raw noise spectra, i.e. prior to correction, derived from the two DML data
sets, exhibit a clear imprint from the diffusional smoothing in the firn. This is
suggested by their common decrease in PSD towards shorter time periods
(Fig. <xref ref-type="fig" rid="Ch1.F2"/>b), since the effect of diffusion is stronger at higher
frequencies. It is corroborated by comparing the loss in PSD between the two
data sets, which for DML2 is stronger towards the high-frequency end and also
extends further towards longer time periods. This is due to the stronger
diffusional smoothing in the older sections of the cores that are only contained
in the DML2 records, since the diffusion process had more time to act there
since the deposition of the snow. The applied correction reconciles both noise
estimates, as it takes these differences into account, and reveals a
close-to-constant noise level (white noise) across the range from subdecadal
to multi-centennial timescales.</p>
      <p id="d1e3273">This near constancy of the noise level suggests that the noise-creating
processes are independent of the timescale. This seems plausible for
stratigraphic noise as it is also indicated by the observed small memory in the
interannual variations of the surface topography at EDML
<xref ref-type="bibr" rid="bib1.bibx36 bib1.bibx42" id="paren.70"/>. Furthermore, we would not expect strong changes
in surface wind regimes or depositional characteristics for the rather stable
climatic conditions over the studied time periods. To test whether the effect of
precipitation intermittency additionally contributes to the noise spectrum, as
suggested from the decorrelation scales of the ERA-Interim precipitation fields,
we apply our spectral analysis to the available isotope profiles on the local
scale (<inline-formula><mml:math id="M193" display="inline"><mml:mrow><mml:mo>∼</mml:mo><mml:mn mathvariant="normal">100</mml:mn></mml:mrow></mml:math></inline-formula> m) at EDML <xref ref-type="bibr" rid="bib1.bibx43 bib1.bibx44" id="paren.71"/> and compare the
estimated noise spectra between the local scale and the array scale
(Fig. <xref ref-type="fig" rid="Ch1.F5"/>). Although the spectral estimates do not overlap,
the results indicate an offset between the noise levels at both spatial
scales. For the 5-year period, the PSD of the noise on the array scale is about
<inline-formula><mml:math id="M194" display="inline"><mml:mn mathvariant="normal">1.7</mml:mn></mml:math></inline-formula> times higher than at the local scale. Some increase in the noise level is
expected from the small contribution of uncorrelated temperature variability,
but the <inline-formula><mml:math id="M195" display="inline"><mml:mrow><mml:mo>∼</mml:mo><mml:mn mathvariant="normal">1.7</mml:mn></mml:mrow></mml:math></inline-formula>-fold increase suggests that most of the additional noise
arises from spatially incoherent precipitation intermittency.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F5"><caption><p id="d1e3314">Comparison of DML noise spectra as a function of intersite distance. The red
curve (array scale, <inline-formula><mml:math id="M196" display="inline"><mml:mrow><mml:mo>∼</mml:mo><mml:mn mathvariant="normal">100</mml:mn></mml:mrow></mml:math></inline-formula> km) shows the section for periods
<inline-formula><mml:math id="M197" display="inline"><mml:mo>≤</mml:mo></mml:math></inline-formula> 50 years
of the composite noise spectrum from the DML1 and DML2 firn-core records
(Fig. <xref ref-type="fig" rid="Ch1.F2"/>b and text). The blue curve (local scale,
<inline-formula><mml:math id="M198" display="inline"><mml:mrow><mml:mo>∼</mml:mo><mml:mn mathvariant="normal">100</mml:mn></mml:mrow></mml:math></inline-formula> m) depicts the noise spectrum estimated from 22 shallow
(<inline-formula><mml:math id="M199" display="inline"><mml:mrow><mml:mo>∼</mml:mo><mml:mn mathvariant="normal">3.5</mml:mn></mml:mrow></mml:math></inline-formula> m depth) trench profiles from EDML
<xref ref-type="bibr" rid="bib1.bibx43 bib1.bibx44" id="paren.72"/>. The depth scale of the trench data has been
converted into time units using a constant accumulation rate of 25 cm of
snow per year, neglecting the small compression by densification
<xref ref-type="bibr" rid="bib1.bibx43" id="paren.73"/>. Blue shading denotes the spectral range from an assumed
<inline-formula><mml:math id="M200" display="inline"><mml:mrow><mml:mn mathvariant="normal">20</mml:mn><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mi mathvariant="italic">%</mml:mi></mml:mrow></mml:math></inline-formula> uncertainty of the accumulation rate. Note that the trench noise
spectrum is not corrected for the diffusional smoothing, which has a negligible effect
on the trench records for the 5-year period and thus does not
affect the comparison of the noise levels.</p></caption>
          <?xmltex \igopts{width=236.157874pt}?><graphic xlink:href="https://cp.copernicus.org/articles/14/2053/2018/cp-14-2053-2018-f05.png"/>

        </fig>

      <?pagebreak page2061?><p id="d1e3380">This supports the interpretation of the estimated DML signal spectra
(Fig. <xref ref-type="fig" rid="Ch1.F2"/>a) as temperature variability, assuming that
the influence of atmospheric circulation changes is small. Fitting a power law
of the form <inline-formula><mml:math id="M201" display="inline"><mml:mrow><mml:msup><mml:mi>f</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mi mathvariant="italic">β</mml:mi></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>, where <inline-formula><mml:math id="M202" display="inline"><mml:mi>f</mml:mi></mml:math></inline-formula> denotes frequency, yields a slope of the
DML2 signal spectrum of roughly <inline-formula><mml:math id="M203" display="inline"><mml:mrow><mml:mi mathvariant="italic">β</mml:mi><mml:mo>∼</mml:mo><mml:mn mathvariant="normal">0.6</mml:mn></mml:mrow></mml:math></inline-formula> for variations above the 20-year
period. This is higher than the slopes of the mean spectra of the single records
(<inline-formula><mml:math id="M204" display="inline"><mml:mrow><mml:mi mathvariant="italic">β</mml:mi><mml:mo>∼</mml:mo><mml:mn mathvariant="normal">0.2</mml:mn></mml:mrow></mml:math></inline-formula> for DML2, <inline-formula><mml:math id="M205" display="inline"><mml:mrow><mml:mi mathvariant="italic">β</mml:mi><mml:mo>∼</mml:mo><mml:mn mathvariant="normal">0</mml:mn></mml:mrow></mml:math></inline-formula> for DML1), which underlines again that the
high noise level in individual records strongly masks the true spectral shape of
the signal. Such a power-law increase in temperature variability is not
unexpected since it was also observed in spectra from marine-proxy-inferred sea
surface temperature variations <xref ref-type="bibr" rid="bib1.bibx34" id="paren.74"/> and from other proxy and
instrumental temperature records <xref ref-type="bibr" rid="bib1.bibx49 bib1.bibx20" id="paren.75"><named-content content-type="pre">e.g.</named-content></xref>.</p>
      <p id="d1e3452">The resulting SNR (Fig. <xref ref-type="fig" rid="Ch1.F3"/>) of the DML data illustrates on which
timescales the signal dominates the isotope variability recorded in individual
records, and how this translates into the representativity of isotope variations
when averaging records in space and time (Fig. <xref ref-type="fig" rid="Ch1.F4"/>). We can
test the validity of our spectral approach by comparing the estimated SNR to
published estimates. <xref ref-type="bibr" rid="bib1.bibx14" id="text.76"/> analysed the same data set as the present
study and found an SNR at annual resolution of <inline-formula><mml:math id="M206" display="inline"><mml:mrow><mml:mover accent="true"><mml:mi>F</mml:mi><mml:mo mathvariant="normal">‾</mml:mo></mml:mover><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.14</mml:mn></mml:mrow></mml:math></inline-formula> based on the
average intercore correlations (<inline-formula><mml:math id="M207" display="inline"><mml:mrow><mml:mi>r</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.35</mml:mn></mml:mrow></mml:math></inline-formula>). Similar values have been obtained
using a larger set of cores from the same region that cover a shorter time
period <xref ref-type="bibr" rid="bib1.bibx1" id="paren.77"/>. From integrating the estimated signal and noise
spectra up to the minimum averaging period constrained by the diffusion
correction (<inline-formula><mml:math id="M208" display="inline"><mml:mo lspace="0mm">∼</mml:mo></mml:math></inline-formula> 2.5 years), we find an SNR of <inline-formula><mml:math id="M209" display="inline"><mml:mrow><mml:mover accent="true"><mml:mi>F</mml:mi><mml:mo mathvariant="normal">‾</mml:mo></mml:mover><mml:mo>∼</mml:mo><mml:mn mathvariant="normal">0.2</mml:mn></mml:mrow></mml:math></inline-formula> (correlation
<inline-formula><mml:math id="M210" display="inline"><mml:mrow><mml:mi>r</mml:mi><mml:mo>∼</mml:mo><mml:mn mathvariant="normal">0.4</mml:mn></mml:mrow></mml:math></inline-formula>, Fig. <xref ref-type="fig" rid="Ch1.F4"/>a), which is, as expected, slightly
higher than the published estimates, since we corrected for the effect of time
uncertainty, as well as due to the effect of the slightly different underlying
averaging periods. Our results further explain the strong agreement between
individual ice cores on glacial–interglacial timescales. Averaging to
multi-decadal resolution results in a correlation between a single core and the
signal of around <inline-formula><mml:math id="M211" display="inline"><mml:mn mathvariant="normal">0.6</mml:mn></mml:math></inline-formula> (Fig. <xref ref-type="fig" rid="Ch1.F4"/>a), which rises to
<inline-formula><mml:math id="M212" display="inline"><mml:mrow><mml:mo>∼</mml:mo><mml:mn mathvariant="normal">0.7</mml:mn></mml:mrow></mml:math></inline-formula> for the available centennial averaging periods. Moreover, the steady
increase in SNR on the analysed timescales (Fig. <xref ref-type="fig" rid="Ch1.F3"/>) might indicate a
further increase in SNR towards even longer timescales. However, clearly our
results also underline again that for assessing Holocene temperature variability
on timescales shorter than multi-decadal, the averaging of records is essential
to increasing their representativity (Fig. <xref ref-type="fig" rid="Ch1.F4"/>a).</p>
      <p id="d1e3553">For WAIS, the higher SNR at interannual timescales compared to DML (average
SNR between 5 and 10-year periods of <inline-formula><mml:math id="M213" display="inline"><mml:mn mathvariant="normal">0.43</mml:mn></mml:math></inline-formula> for WAIS compared to <inline-formula><mml:math id="M214" display="inline"><mml:mn mathvariant="normal">0.13</mml:mn></mml:math></inline-formula> for
DML; Fig. <xref ref-type="fig" rid="Ch1.F3"/>) is consistent with the general notion that higher
accumulation rates (on average, <inline-formula><mml:math id="M215" display="inline"><mml:mrow><mml:mo>∼</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:math></inline-formula> times as high as at DML;
Table <xref ref-type="table" rid="Ch1.T1"/>) result in higher SNR <xref ref-type="bibr" rid="bib1.bibx10 bib1.bibx59" id="paren.78"/>. However, one would expect, to a first approximation, a
similar increase in SNR with timescale in both regions. In contrast to this
expectation, the WAIS results show strongly different timescale dependencies
with the tendency of a decrease in signal power and an increase in noise level
on longer timescales (Fig. <xref ref-type="fig" rid="Ch1.F2"/>), resulting in an
overall decrease in SNR (Fig. <xref ref-type="fig" rid="Ch1.F3"/>). This explains the only slightly
higher correlations at interannual timescales of a stacked isotope record with
the common signal at WAIS compared to DML (Fig. <xref ref-type="fig" rid="Ch1.F4"/>),
since the correlation is based on the integrated value of the SNR
(Eqs. <xref ref-type="disp-formula" rid="Ch1.E6"/> and <xref ref-type="disp-formula" rid="Ch1.E7"/>). If they are correct, these findings
suggest that there is, in general, no simple scaling of the SNR with
accumulation rate but that additional effects need to be involved.</p>
      <p id="d1e3598">The shape of the signal and noise spectra at subdecadal timescales is sensitive
to the diffusion and time uncertainty corrections
(Fig. <xref ref-type="fig" rid="Ch1.F2"/>), which could thus contribute to the
discrepant SNR estimates. While the diffusion correction for DML led to a
consistent white-noise level of both noise estimates
(Fig. <xref ref-type="fig" rid="Ch1.F2"/>b) at these timescales, lending support to
our approach, the WAIS noise spectrum keeps decreasing towards higher
frequencies, even after applying the diffusion correction
(Fig. <xref ref-type="fig" rid="Ch1.F2"/>d). This result could be caused either by a
too weak diffusion correction or by an overestimation of the<?pagebreak page2062?> time
uncertainty leading to an excessive reduction in high-frequency noise levels that cannot be
compensated by the low diffusion correction. To test both hypotheses, we varied
the strengths of the diffusion and time uncertainty corrections. This has
different impacts on the estimated spectra: while the diffusion correction
equally applies to both raw signal and noise spectra, the time uncertainty
correction has a proportional influence on the signal spectrum but only an
indirect influence on the noise spectrum (Eq. <xref ref-type="disp-formula" rid="Ch1.E4"/>). Indeed,
halving the time uncertainty would increase the noise spectrum close to the cut-off frequency only by a maximum
factor of <inline-formula><mml:math id="M216" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula>1.4, and this therefore cannot
reconcile the remaining decrease in the corrected noise spectrum. By contrast,
an overall doubling of the diffusion length for all WAIS records would amplify
the noise spectrum much more strongly with a maximum factor of <inline-formula><mml:math id="M217" display="inline"><mml:mrow><mml:mo>∼</mml:mo><mml:mn mathvariant="normal">4</mml:mn></mml:mrow></mml:math></inline-formula> at the cut-off
frequency, leading to interannual noise levels similar to those observed for
centennial periods. However, a much stronger diffusional smoothing at WAIS
compared to the expectation seems implausible given that the same physical
mechanisms of the diffusion process should be valid for East Antarctica as well as West
Antarctica, and no anomalously high diffusional smoothing has been observed for
the upper part of the WAIS Divide ice core <xref ref-type="bibr" rid="bib1.bibx25" id="paren.79"/>. Additionally, a
much stronger diffusion correction would also imply a much steeper decrease in
the signal spectrum towards longer timescales
(Fig. <xref ref-type="fig" rid="Ch1.F2"/>c), contrary to the expectation. We conclude
that there is no obvious reason for the applied correction approach to strongly
over- or underestimate the WAIS signal and noise spectra on the interannual
timescales. Moreover, by also taking into account the shape of the spectra for the signal
and noise on the longer timescales (periods from <inline-formula><mml:math id="M218" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula>30 to 100 years), our results might therefore indicate a true increase in
local variability at the WAIS sites across the timescales studied and a
close-to-constant, or even decreasing, coherent signal variability.</p>
      <p id="d1e3639">These results suggest firstly that an additional noise process, apart from
stratigraphic noise and precipitation intermittency, must contribute to the
noise spectrum towards longer timescales. Secondly, the shape of the signal
spectrum either implies a nearly white-noise temperature signal or some process
that destroys the coherence of the large-scale temperature field on longer
timescales upon recording by the firn-core isotope records. Since there is no
obvious reason for a fundamentally different Holocene climate variability in
West compared to East Antarctica, the second possibility seems more likely.</p>
      <p id="d1e3642">WAIS isotope data have been reported to covary with local temperatures, but also
with the large-scale atmospheric circulation and the sea-ice cover of the
adjacent oceans <xref ref-type="bibr" rid="bib1.bibx45 bib1.bibx33 bib1.bibx63" id="paren.80"/>. A pronounced regional
imprint on the recorded isotope variability is also suggested from the spatial
differences in intercore correlations for an extended set of the available WAIS
firn cores <xref ref-type="bibr" rid="bib1.bibx33" id="paren.81"/>. In particular, cores east of the WAIS Divide display
strong differences in the recorded isotope variability despite their rather
small spatial separation <xref ref-type="bibr" rid="bib1.bibx16" id="paren.82"/>, which is suggested to be related
to slow variations in the dominant circulation patterns. While such differences
have not explicitly been reported for the core sites west of the divide studied
here, we hypothesise that signatures of sea-ice variations or meridional inflow
could affect the isotopic composition at the individual firn-core sites to
different extents. This is motivated by model-based results <xref ref-type="bibr" rid="bib1.bibx45" id="paren.83"/>
linking an increase in sea-ice cover to an earlier ascent of long-range
transported air masses to the continent, reducing the influence of local air
from the surface, while less sea ice inhibits this early ascent and allows more
mixing of surface air. Variations in sea ice could thus influence the isotopic
composition of air masses by controlling the influence of local moisture, which
might only be recorded by certain WAIS cores depending on the elevation of the
air mass transport and characteristics of the core positions, such as their
surrounding topography, elevation, or distance to the coast. Decadal trends or
slower changes in these variations could then destroy the recording of the
large-scale coherent temperature field by the firn cores and thus cause a loss
in spectral signal power in the isotope record towards longer timescales and an
increase in the noise level (Fig. <xref ref-type="fig" rid="Ch1.F2"/>c, d). In
contrast, the East Antarctic Plateau including the DML firn-core sites is higher
in elevation and might be more shielded from marine influences by the steep
topographic slopes leading to a more coherent signal. This might also explain,
besides differences in core quality, the rather low agreement among deep West
Antarctic cores on millennial timescales compared to East Antarctic cores
<xref ref-type="bibr" rid="bib1.bibx68" id="paren.84"/>. However, since our inferences are
speculative, further studies are needed to help disentangle the role of
variations in West Antarctic temperature, atmospheric circulation and sea ice on
the recorded isotope variability.</p>
</sec>
</sec>
<sec id="Ch1.S5" sec-type="conclusions">
  <title>Conclusions</title>
      <p id="d1e3671">We presented a simple spectral method to separate the variations recorded by
isotope records into a local (noise) and a common (i.e. spatially coherent)
signal component. We applied this method to firn cores from the East
Antarctic Dronning Maud Land (DML) and the West Antarctic Ice Sheet (WAIS) to
estimate, for the first time, the isotopic signal-to-noise ratio (SNR) as a
function of timescale. This is of fundamental interest for interpreting isotope
records obtained from individual ice cores, since it provides an upper limit on
the SNR of the temperature signal recorded by the cores. For DML, the SNR at the
interannual timescale is very low, but it steadily increases with timescale
reaching values above <inline-formula><mml:math id="M219" display="inline"><mml:mn mathvariant="normal">0.5</mml:mn></mml:math></inline-formula> for multi-decadal and slower variations. Therefore,
only on these timescales should isotope changes from individual cores be
interpreted in terms of regional climate variations.<?pagebreak page2063?> For WAIS, the results are
counterintuitive. On interannual to decadal timescales, the estimated SNR is
higher than <inline-formula><mml:math id="M220" display="inline"><mml:mn mathvariant="normal">0.5</mml:mn></mml:math></inline-formula>, which would support the regional climate interpretation of
the isotope records. For longer timescales, however, the estimated SNR
decreases, suggesting that local variations start to dominate the recorded
isotope variability.</p>
      <p id="d1e3688">Our method further allows the estimation of the power spectra of the coherent
isotope signal. For DML, the spectra of single cores largely resemble white
noise. In contrast, the derived signal spectrum shows increasing variability
towards longer timescales. Such an increase is also observed in instrumental
temperature records and other climate proxies. The marked difference between the
raw interpretation of single cores – as it is usually done – and the signal
spectra derived from the core array demonstrates the relevance of the signal and
noise separation. The interpretation of the WAIS isotope signal is more
challenging, since the signal shows a close-to-constant spectral power even after
applying our method. We speculate that this might be due to atmospheric
circulation variations that create a local imprint at the different firn-core
sites. This might prevent a coherent recording of the large-scale atmospheric
temperature field. To test this hypothesis, we suggest to analyse firn-core
arrays as a function of the average separation distance between the individual
core sites within each array. This could allow us to investigate whether the
stable-isotope data record a stronger coherent signal on a regional scale (e.g.
<inline-formula><mml:math id="M221" display="inline"><mml:mrow><mml:mo>∼</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:math></inline-formula>–<inline-formula><mml:math id="M222" display="inline"><mml:mn mathvariant="normal">10</mml:mn></mml:math></inline-formula> km) than on the larger scales analysed here. A similar approach in
DML would also help to better constrain the spatial correlation scales of the
precipitation intermittency.</p>
      <p id="d1e3708">We conclude that the pronounced differences seen between East and West
Antarctica could thus be related to the differences in the topographic settings
and the different marine influences
<xref ref-type="bibr" rid="bib1.bibx45 bib1.bibx68" id="paren.85"/>. Attempts to reconstruct the
temperature variability in these regions based on firn and ice cores should thus
not only aim to average as many records as possible, but also consider the
spatial coherence of the circulation and precipitation patterns in order to
establish an optimal strategy for averaging or obtaining new firn-core isotope
records. Additionally, extending our analyses to data derived from
non-isotope-based temperature proxies could give further insights into the true
spectral shape of temperature variability in Antarctica.</p>
      <p id="d1e3714">Finally, our approach of separating signal and noise from a set of spatially
distributed records is also applicable beyond Antarctic ice cores. The challenge
of low and timescale-dependent SNR is common to many high-resolution climate
archives, and the number of nearby core sites is continuously
increasing. Therefore, we envision our approach to better constrain the
reliability of proxy records as a function of timescale in general and to allow
a significant improvement of our knowledge of past climate variability.</p>
</sec>

      
      </body>
    <back><notes notes-type="codedataavailability">

      <p id="d1e3721">Software for the spectral analyses, the implementation
of the method and the plotting of the results is available as the R package
<italic>proxysnr</italic>; source code for the package is hosted in the public Git
repository at <uri>https://github.com/EarthSystemDiagnostics/proxysnr</uri> (last access: 17 December 2018), a
snapshot of the code used for this publication (version <inline-formula><mml:math id="M223" display="inline"><mml:mn mathvariant="normal">0.1.0</mml:mn></mml:math></inline-formula>) is archived
under <ext-link xlink:href="https://doi.org/10.5281/zenodo.2027639" ext-link-type="DOI">10.5281/zenodo.2027639</ext-link> <xref ref-type="bibr" rid="bib1.bibx40" id="paren.86"/>. Software that models the
time uncertainty of the isotope records is based on the MATLAB code by
<xref ref-type="bibr" rid="bib1.bibx5" id="text.87"/>, which has been adapted for this publication and
implemented in R as the package <italic>simproxyage</italic>; its source code is
available from the public Git repository at
<uri>https://github.com/EarthSystemDiagnostics/simproxyage</uri> (last access:
17 December 2018); a snapshot of
the code used for this publication (version <inline-formula><mml:math id="M224" display="inline"><mml:mn mathvariant="normal">0.1.1</mml:mn></mml:math></inline-formula>) is archived under
<ext-link xlink:href="https://doi.org/10.5281/zenodo.2025833" ext-link-type="DOI">10.5281/zenodo.2025833</ext-link> <xref ref-type="bibr" rid="bib1.bibx41" id="paren.88"/>. The diffusion length
calculations have been performed with the R package <italic>FirnR</italic>, which is
available on request from the authors.</p>

      <p id="d1e3770">The original DML firn-core and trench oxygen isotope data are archived at the
PANGAEA database under
<ext-link xlink:href="https://doi.org/10.1594/PANGAEA.728240" ext-link-type="DOI">10.1594/PANGAEA.728240</ext-link> <xref ref-type="bibr" rid="bib1.bibx15" id="paren.89"/> and
<ext-link xlink:href="https://doi.org/10.1594/PANGAEA.876639" ext-link-type="DOI">10.1594/PANGAEA.876639</ext-link> <xref ref-type="bibr" rid="bib1.bibx44" id="paren.90"/> respectively. PANGAEA is
hosted by the Alfred Wegener Institute Helmholtz Centre for Polar and Marine
Research (AWI), Bremerhaven and the Center for Marine Environmental Sciences
(MARUM), Bremen, Germany. The original WAIS firn-core oxygen isotope data are
archived at the U.S. Antarctic Program Data Center (USAP-DC;
<uri>http://www.usap-dc.org/</uri>, last access: 17 December 2018) under <ext-link xlink:href="https://doi.org/10.7265/N5QJ7F8B" ext-link-type="DOI">10.7265/N5QJ7F8B</ext-link>
<xref ref-type="bibr" rid="bib1.bibx60" id="paren.91"/>. USAP-DC is hosted by Lamont-Doherty Earth Observatory of
Columbia University, Palisades, USA. The processed isotope data used in
this study, together with generating code, are provided with the package
<italic>proxysnr</italic>. The ERA-Interim reanalysis data are available from the
European Centre for Medium-Range Weather Forecasts (ECMWF) under
<uri>http://apps.ecmwf.int/datasets/data/interim-full-moda/levtype=sfc/</uri>
<xref ref-type="bibr" rid="bib1.bibx9" id="paren.92"/>. All relevant site parameter data for the diffusion
length calculations are available from the publications referenced in
Table <xref ref-type="table" rid="Ch1.T1"/> and, together with the simulated diffusion length
estimates, provided with the package <italic>proxysnr</italic>.</p>
  </notes><?xmltex \hack{\clearpage}?><app-group>

<?pagebreak page2064?><app id="App1.Ch1.S1">
  <title>Theoretical spectra for site-specific diffusion</title>
      <p id="d1e3819">We derive the effect of site-specific diffusion on the estimates of the mean
spectrum and the spectrum of the stack given a core array consisting of <inline-formula><mml:math id="M225" display="inline"><mml:mi>n</mml:mi></mml:math></inline-formula>
isotope records.</p>
      <p id="d1e3829">The spectrum of a time series <inline-formula><mml:math id="M226" display="inline"><mml:mrow><mml:mi>x</mml:mi><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> is given by the absolute square of its
Fourier transformation, <inline-formula><mml:math id="M227" display="inline"><mml:mrow><mml:mi mathvariant="script">X</mml:mi><mml:mo>=</mml:mo><mml:mi mathvariant="script">F</mml:mi><mml:mo>(</mml:mo><mml:mi>x</mml:mi><mml:mo>)</mml:mo><mml:msup><mml:mi mathvariant="script">F</mml:mi><mml:mo>*</mml:mo></mml:msup><mml:mo>(</mml:mo><mml:mi>x</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>, where
<inline-formula><mml:math id="M228" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="script">F</mml:mi><mml:mo>*</mml:mo></mml:msup><mml:mo>(</mml:mo><mml:mi>x</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> denotes the complex conjugate of <inline-formula><mml:math id="M229" display="inline"><mml:mrow><mml:mi mathvariant="script">F</mml:mi><mml:mo>(</mml:mo><mml:mi>x</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>. Given an
isotope record at site <inline-formula><mml:math id="M230" display="inline"><mml:mi>i</mml:mi></mml:math></inline-formula>, <inline-formula><mml:math id="M231" display="inline"><mml:mrow><mml:msub><mml:mi>x</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo><mml:mo>=</mml:mo><mml:mi>c</mml:mi><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo><mml:mo>+</mml:mo><mml:msub><mml:mi mathvariant="italic">ε</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>, where <inline-formula><mml:math id="M232" display="inline"><mml:mrow><mml:mi>c</mml:mi><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>
denotes the common signal, and <inline-formula><mml:math id="M233" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">ε</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> is noise, the time series
after diffusion is
<inline-formula><mml:math id="M234" display="inline"><mml:mrow><mml:msubsup><mml:mi>x</mml:mi><mml:mi>i</mml:mi><mml:mo>′</mml:mo></mml:msubsup><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo><mml:mo>=</mml:mo><mml:msub><mml:mi>g</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>⋆</mml:mo><mml:mfenced close=")" open="("><mml:mrow><mml:mi>c</mml:mi><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo><mml:mo>+</mml:mo><mml:msub><mml:mi mathvariant="italic">ε</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:mfenced></mml:mrow></mml:math></inline-formula>. Here, <inline-formula><mml:math id="M235" display="inline"><mml:mo>⋆</mml:mo></mml:math></inline-formula> denotes
convolution and <inline-formula><mml:math id="M236" display="inline"><mml:mrow><mml:msub><mml:mi>g</mml:mi><mml:mi>i</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is a Gaussian convolution kernel, the standard deviation
of which is the diffusion length <inline-formula><mml:math id="M237" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi>i</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> that is a function of depth (or,
equivalently, time since deposition) and depends on site <inline-formula><mml:math id="M238" display="inline"><mml:mi>i</mml:mi></mml:math></inline-formula> due to its
dependence on local temperature, atmospheric pressure and accumulation rate
(Appendix <xref ref-type="sec" rid="App1.Ch1.S2"/>). The spectrum of <inline-formula><mml:math id="M239" display="inline"><mml:mrow><mml:msup><mml:mi>x</mml:mi><mml:mo>′</mml:mo></mml:msup></mml:mrow></mml:math></inline-formula> is then

              <disp-formula specific-use="align" content-type="numbered"><mml:math id="M240" display="block"><mml:mtable displaystyle="true"><mml:mtr><mml:mtd><mml:mrow><mml:mstyle class="stylechange" displaystyle="true"/><mml:msub><mml:mi mathvariant="script">X</mml:mi><mml:mi>i</mml:mi></mml:msub></mml:mrow></mml:mtd><mml:mtd><mml:mrow><mml:mstyle displaystyle="true" class="stylechange"/><mml:mo>=</mml:mo><mml:mi mathvariant="script">F</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi>g</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>)</mml:mo><mml:mi mathvariant="script">F</mml:mi><mml:mo>(</mml:mo><mml:mi>c</mml:mi><mml:mo>+</mml:mo><mml:msub><mml:mi mathvariant="italic">ε</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>)</mml:mo><mml:mo>⋅</mml:mo><mml:msup><mml:mi mathvariant="script">F</mml:mi><mml:mo>*</mml:mo></mml:msup><mml:mo>(</mml:mo><mml:msub><mml:mi>g</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>)</mml:mo><mml:msup><mml:mi mathvariant="script">F</mml:mi><mml:mo>*</mml:mo></mml:msup><mml:mo>(</mml:mo><mml:mi>c</mml:mi><mml:mo>+</mml:mo><mml:msub><mml:mi mathvariant="italic">ε</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:mtd></mml:mtr><mml:mlabeledtr id="App1.Ch1.E1"><mml:mtd/><mml:mtd><mml:mstyle displaystyle="true" class="stylechange"/></mml:mtd><mml:mtd><mml:mrow><mml:mstyle class="stylechange" displaystyle="true"/><mml:mo>=</mml:mo><mml:msub><mml:mi mathvariant="script">G</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mfenced open="(" close=")"><mml:mrow><mml:mi mathvariant="script">C</mml:mi><mml:mo>+</mml:mo><mml:msub><mml:mi mathvariant="script">N</mml:mi><mml:mi>i</mml:mi></mml:msub></mml:mrow></mml:mfenced><mml:mo>,</mml:mo></mml:mrow></mml:mtd></mml:mlabeledtr></mml:mtable></mml:math></disp-formula>

          with <inline-formula><mml:math id="M241" display="inline"><mml:mrow><mml:mi mathvariant="script">C</mml:mi><mml:mo>=</mml:mo><mml:mi mathvariant="script">F</mml:mi><mml:mo>(</mml:mo><mml:mi>c</mml:mi><mml:mo>)</mml:mo><mml:msup><mml:mi mathvariant="script">F</mml:mi><mml:mo>*</mml:mo></mml:msup><mml:mo>(</mml:mo><mml:mi>c</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>,
<inline-formula><mml:math id="M242" display="inline"><mml:mrow><mml:mi mathvariant="script">N</mml:mi><mml:mo>=</mml:mo><mml:mi mathvariant="script">F</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant="italic">ε</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>)</mml:mo><mml:msup><mml:mi mathvariant="script">F</mml:mi><mml:mo>*</mml:mo></mml:msup><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant="italic">ε</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> and where
the linear site-specific diffusion transfer function was defined as
<inline-formula><mml:math id="M243" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="script">G</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>:=</mml:mo><mml:mi mathvariant="script">F</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi>g</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>)</mml:mo><mml:msup><mml:mi mathvariant="script">F</mml:mi><mml:mo>*</mml:mo></mml:msup><mml:mo>(</mml:mo><mml:msub><mml:mi>g</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula><fn id="App1.Ch1.Footn1"><p id="d1e4298">We note that there is no closed form expression for <inline-formula><mml:math id="M244" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="script">G</mml:mi><mml:mi>i</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>; however, in
case of a constant diffusion length the transfer function is a Gaussian
<xref ref-type="bibr" rid="bib1.bibx67" id="paren.93"/>.</p></fn>.
Assuming that the statistical properties of the individual noise terms are the
same for all sites, <inline-formula><mml:math id="M245" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="script">N</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>≡</mml:mo><mml:mi mathvariant="script">N</mml:mi></mml:mrow></mml:math></inline-formula>, the mean across <inline-formula><mml:math id="M246" display="inline"><mml:mi>n</mml:mi></mml:math></inline-formula> such
spectra is
          <disp-formula id="App1.Ch1.E2" content-type="numbered"><mml:math id="M247" display="block"><mml:mrow><mml:mi mathvariant="script">M</mml:mi><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mn mathvariant="normal">1</mml:mn><mml:mi>n</mml:mi></mml:mfrac></mml:mstyle><mml:munderover><mml:mo movablelimits="false">∑</mml:mo><mml:mrow><mml:mi>i</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow><mml:mi>n</mml:mi></mml:munderover><mml:msub><mml:mi mathvariant="script">X</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:mover accent="true"><mml:mi mathvariant="script">G</mml:mi><mml:mo mathvariant="normal">‾</mml:mo></mml:mover><mml:mfenced close=")" open="("><mml:mrow><mml:mi mathvariant="script">C</mml:mi><mml:mo>+</mml:mo><mml:mi mathvariant="script">N</mml:mi></mml:mrow></mml:mfenced></mml:mrow></mml:math></disp-formula>
        with the average diffusion transfer function
<inline-formula><mml:math id="M248" display="inline"><mml:mrow><mml:mover accent="true"><mml:mi mathvariant="script">G</mml:mi><mml:mo mathvariant="normal">‾</mml:mo></mml:mover><mml:mo>:=</mml:mo><mml:mstyle displaystyle="false"><mml:mfrac style="text"><mml:mn mathvariant="normal">1</mml:mn><mml:mi>n</mml:mi></mml:mfrac></mml:mstyle><mml:msubsup><mml:mo>∑</mml:mo><mml:mrow><mml:mi>i</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow><mml:mi>n</mml:mi></mml:msubsup><mml:msub><mml:mi mathvariant="script">G</mml:mi><mml:mi>i</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>.</p>
      <p id="d1e4423">The average in the time domain of <inline-formula><mml:math id="M249" display="inline"><mml:mi>n</mml:mi></mml:math></inline-formula> independent noise signals subject to
site-specific diffusion,
<inline-formula><mml:math id="M250" display="inline"><mml:mrow><mml:msub><mml:mi>y</mml:mi><mml:mi mathvariant="normal">noise</mml:mi></mml:msub><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo><mml:mo>=</mml:mo><mml:mstyle displaystyle="false"><mml:mfrac style="text"><mml:mn mathvariant="normal">1</mml:mn><mml:mi>n</mml:mi></mml:mfrac></mml:mstyle><mml:msubsup><mml:mo>∑</mml:mo><mml:mrow><mml:mi>i</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow><mml:mi>n</mml:mi></mml:msubsup><mml:msub><mml:mi>g</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>⋆</mml:mo><mml:msub><mml:mi mathvariant="italic">ε</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>,
has a spectrum of

              <disp-formula specific-use="align"><mml:math id="M251" display="block"><mml:mtable displaystyle="true"><mml:mtr><mml:mtd><mml:mrow><mml:mstyle displaystyle="true" class="stylechange"/><mml:msub><mml:mi mathvariant="script">S</mml:mi><mml:mi mathvariant="normal">noise</mml:mi></mml:msub></mml:mrow></mml:mtd><mml:mtd><mml:mrow><mml:mstyle displaystyle="true" class="stylechange"/><mml:mo>=</mml:mo><mml:mi mathvariant="script">F</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi>y</mml:mi><mml:mi mathvariant="normal">noise</mml:mi></mml:msub><mml:mo>)</mml:mo><mml:msup><mml:mi mathvariant="script">F</mml:mi><mml:mo>*</mml:mo></mml:msup><mml:mo>(</mml:mo><mml:msub><mml:mi>y</mml:mi><mml:mi mathvariant="normal">noise</mml:mi></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:mtd></mml:mtr><mml:mtr><mml:mtd><mml:mstyle displaystyle="true" class="stylechange"/></mml:mtd><mml:mtd><mml:mrow><mml:mstyle class="stylechange" displaystyle="true"/><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mn mathvariant="normal">1</mml:mn><mml:mrow><mml:msup><mml:mi>n</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:mfrac></mml:mstyle><mml:munder><mml:mo movablelimits="false">∑</mml:mo><mml:mi>i</mml:mi></mml:munder><mml:munder><mml:mo movablelimits="false">∑</mml:mo><mml:mi>j</mml:mi></mml:munder><mml:mi mathvariant="script">F</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi>g</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>)</mml:mo><mml:msup><mml:mi mathvariant="script">F</mml:mi><mml:mo>*</mml:mo></mml:msup><mml:mo>(</mml:mo><mml:msub><mml:mi>g</mml:mi><mml:mi>j</mml:mi></mml:msub><mml:mo>)</mml:mo><mml:mi mathvariant="script">F</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant="italic">ε</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>)</mml:mo><mml:msup><mml:mi mathvariant="script">F</mml:mi><mml:mo>*</mml:mo></mml:msup><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant="italic">ε</mml:mi><mml:mi>j</mml:mi></mml:msub><mml:mo>)</mml:mo><mml:mo>.</mml:mo></mml:mrow></mml:mtd></mml:mtr></mml:mtable></mml:math></disp-formula>

          We have <inline-formula><mml:math id="M252" display="inline"><mml:mrow><mml:mi mathvariant="script">F</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant="italic">ε</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>)</mml:mo><mml:msup><mml:mi mathvariant="script">F</mml:mi><mml:mo>*</mml:mo></mml:msup><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant="italic">ε</mml:mi><mml:mi>j</mml:mi></mml:msub><mml:mo>)</mml:mo><mml:mo>≠</mml:mo><mml:mn mathvariant="normal">0</mml:mn></mml:mrow></mml:math></inline-formula> only for
<inline-formula><mml:math id="M253" display="inline"><mml:mrow><mml:mi>i</mml:mi><mml:mo>=</mml:mo><mml:mi>j</mml:mi></mml:mrow></mml:math></inline-formula>, and hence
          <disp-formula id="App1.Ch1.E3" content-type="numbered"><mml:math id="M254" display="block"><mml:mrow><mml:msub><mml:mi mathvariant="script">S</mml:mi><mml:mi mathvariant="normal">noise</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mn mathvariant="normal">1</mml:mn><mml:mi>n</mml:mi></mml:mfrac></mml:mstyle><mml:mover accent="true"><mml:mi mathvariant="script">G</mml:mi><mml:mo mathvariant="normal">‾</mml:mo></mml:mover><mml:mi mathvariant="script">N</mml:mi><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>
        which shows that averaging <inline-formula><mml:math id="M255" display="inline"><mml:mi>n</mml:mi></mml:math></inline-formula> independent noise records reduces the spectral
power by <inline-formula><mml:math id="M256" display="inline"><mml:mrow><mml:mn mathvariant="normal">1</mml:mn><mml:mo>/</mml:mo><mml:mi>n</mml:mi></mml:mrow></mml:math></inline-formula>, as expected.</p>
      <p id="d1e4710">By contrast, the spectrum of the average of <inline-formula><mml:math id="M257" display="inline"><mml:mi>n</mml:mi></mml:math></inline-formula> coherent signals subject to
site-specific diffusion,
<inline-formula><mml:math id="M258" display="inline"><mml:mrow><mml:msub><mml:mi>y</mml:mi><mml:mi mathvariant="normal">coh</mml:mi></mml:msub><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo><mml:mo>=</mml:mo><mml:mstyle displaystyle="false"><mml:mfrac style="text"><mml:mn mathvariant="normal">1</mml:mn><mml:mi>n</mml:mi></mml:mfrac></mml:mstyle><mml:msubsup><mml:mo>∑</mml:mo><mml:mrow><mml:mi>i</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow><mml:mi>n</mml:mi></mml:msubsup><mml:msub><mml:mi>g</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>⋆</mml:mo><mml:mi>c</mml:mi><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>, is

              <disp-formula specific-use="align" content-type="numbered"><mml:math id="M259" display="block"><mml:mtable displaystyle="true"><mml:mtr><mml:mtd><mml:mrow><mml:mstyle displaystyle="true" class="stylechange"/><mml:msub><mml:mi mathvariant="script">S</mml:mi><mml:mi mathvariant="normal">coh</mml:mi></mml:msub></mml:mrow></mml:mtd><mml:mtd><mml:mrow><mml:mstyle displaystyle="true" class="stylechange"/><mml:mo>=</mml:mo><mml:mi mathvariant="script">F</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi>y</mml:mi><mml:mi mathvariant="normal">coh</mml:mi></mml:msub><mml:mo>)</mml:mo><mml:msup><mml:mi mathvariant="script">F</mml:mi><mml:mo>*</mml:mo></mml:msup><mml:mo>(</mml:mo><mml:msub><mml:mi>y</mml:mi><mml:mi mathvariant="normal">coh</mml:mi></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:mtd></mml:mtr><mml:mtr><mml:mtd><mml:mstyle displaystyle="true" class="stylechange"/></mml:mtd><mml:mtd><mml:mrow><mml:mstyle class="stylechange" displaystyle="true"/><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mn mathvariant="normal">1</mml:mn><mml:mrow><mml:msup><mml:mi>n</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:mfrac></mml:mstyle><mml:mi mathvariant="script">F</mml:mi><mml:mo>(</mml:mo><mml:mi>c</mml:mi><mml:mo>)</mml:mo><mml:msup><mml:mi mathvariant="script">F</mml:mi><mml:mo>*</mml:mo></mml:msup><mml:mo>(</mml:mo><mml:mi>c</mml:mi><mml:mo>)</mml:mo><mml:munder><mml:mo movablelimits="false">∑</mml:mo><mml:mi>i</mml:mi></mml:munder><mml:munder><mml:mo movablelimits="false">∑</mml:mo><mml:mi>j</mml:mi></mml:munder><mml:mi mathvariant="script">F</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi>g</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>)</mml:mo><mml:msup><mml:mi mathvariant="script">F</mml:mi><mml:mo>*</mml:mo></mml:msup><mml:mo>(</mml:mo><mml:msub><mml:mi>g</mml:mi><mml:mi>j</mml:mi></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:mtd></mml:mtr><mml:mlabeledtr id="App1.Ch1.E4"><mml:mtd/><mml:mtd><mml:mstyle class="stylechange" displaystyle="true"/></mml:mtd><mml:mtd><mml:mrow><mml:mstyle displaystyle="true" class="stylechange"/><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mn mathvariant="normal">1</mml:mn><mml:mi>n</mml:mi></mml:mfrac></mml:mstyle><mml:mi mathvariant="script">C</mml:mi><mml:mfenced open="(" close=")"><mml:mrow><mml:mover accent="true"><mml:mi mathvariant="script">G</mml:mi><mml:mo mathvariant="normal">‾</mml:mo></mml:mover><mml:mo>+</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mn mathvariant="normal">1</mml:mn><mml:mi>n</mml:mi></mml:mfrac></mml:mstyle><mml:munder><mml:mo movablelimits="false">∑</mml:mo><mml:mrow><mml:mi>i</mml:mi><mml:mo>≠</mml:mo><mml:mi>j</mml:mi></mml:mrow></mml:munder><mml:mi mathvariant="script">F</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi>g</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>)</mml:mo><mml:msup><mml:mi mathvariant="script">F</mml:mi><mml:mo>*</mml:mo></mml:msup><mml:mo>(</mml:mo><mml:msub><mml:mi>g</mml:mi><mml:mi>j</mml:mi></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:mfenced><mml:mo>.</mml:mo></mml:mrow></mml:mtd></mml:mlabeledtr></mml:mtable></mml:math></disp-formula>

          For small differences in the diffusion lengths between the sites, the
transfer functions are approximately the same and we can simplify the second
term in brackets in Eq. (<xref ref-type="disp-formula" rid="App1.Ch1.E4"/>),
          <disp-formula id="App1.Ch1.E5" content-type="numbered"><mml:math id="M260" display="block"><mml:mrow><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mn mathvariant="normal">1</mml:mn><mml:mi>n</mml:mi></mml:mfrac></mml:mstyle><mml:munder><mml:mo movablelimits="false">∑</mml:mo><mml:mrow><mml:mi>i</mml:mi><mml:mo>≠</mml:mo><mml:mi>j</mml:mi></mml:mrow></mml:munder><mml:mi mathvariant="script">F</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi>g</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>)</mml:mo><mml:msup><mml:mi mathvariant="script">F</mml:mi><mml:mo>*</mml:mo></mml:msup><mml:mo>(</mml:mo><mml:msub><mml:mi>g</mml:mi><mml:mi>j</mml:mi></mml:msub><mml:mo>)</mml:mo><mml:mo>≈</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mn mathvariant="normal">1</mml:mn><mml:mi>n</mml:mi></mml:mfrac></mml:mstyle><mml:munder><mml:mo movablelimits="false">∑</mml:mo><mml:mrow><mml:mi>i</mml:mi><mml:mo>≠</mml:mo><mml:mi>j</mml:mi></mml:mrow></mml:munder><mml:mi mathvariant="script">F</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi>g</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>)</mml:mo><mml:msup><mml:mi mathvariant="script">F</mml:mi><mml:mo>*</mml:mo></mml:msup><mml:mo>(</mml:mo><mml:msub><mml:mi>g</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>)</mml:mo><mml:mo>.</mml:mo></mml:mrow></mml:math></disp-formula>
        From rearranging the summation terms we find that this is identical to
<inline-formula><mml:math id="M261" display="inline"><mml:mrow><mml:mo>(</mml:mo><mml:mi>n</mml:mi><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn><mml:mo>)</mml:mo><mml:mover accent="true"><mml:mi mathvariant="script">G</mml:mi><mml:mo mathvariant="normal">‾</mml:mo></mml:mover></mml:mrow></mml:math></inline-formula>, and Eq. (<xref ref-type="disp-formula" rid="App1.Ch1.E4"/>) becomes
          <disp-formula id="App1.Ch1.E6" content-type="numbered"><mml:math id="M262" display="block"><mml:mrow><mml:msub><mml:mi mathvariant="script">S</mml:mi><mml:mi mathvariant="normal">coh</mml:mi></mml:msub><mml:mo>≈</mml:mo><mml:mover accent="true"><mml:mi mathvariant="script">G</mml:mi><mml:mo mathvariant="normal">‾</mml:mo></mml:mover><mml:mi mathvariant="script">C</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></disp-formula>
        In this approximation, the average over diffused coherent signals does not
reduce the spectral power, as one would expect. We tested the approximation for
our core arrays by comparing simulation results with surrogate data between the
cases of independent and coherent noise. We find
that Eq. (<xref ref-type="disp-formula" rid="App1.Ch1.E6"/>) is a reasonable approximation for the full
expression Eq. (<xref ref-type="disp-formula" rid="App1.Ch1.E4"/>). However, we note that
Eq. (<xref ref-type="disp-formula" rid="App1.Ch1.E4"/>) has slightly less power on the high-frequency end
compared to Eq. (<xref ref-type="disp-formula" rid="App1.Ch1.E6"/>), since the site-specific diffusion
destroys part of the coherence between the sites.</p>
</app>

<app id="App1.Ch1.S2">
  <title>Estimates of the transfer functions for diffusion and time uncertainty</title>
      <p id="d1e5117">To estimate the transfer functions for diffusion (<inline-formula><mml:math id="M263" display="inline"><mml:mover accent="true"><mml:mi mathvariant="script">G</mml:mi><mml:mo mathvariant="normal">‾</mml:mo></mml:mover></mml:math></inline-formula>) and
time uncertainty (<inline-formula><mml:math id="M264" display="inline"><mml:mi mathvariant="normal">Φ</mml:mi></mml:math></inline-formula>), we simulate for each core array <inline-formula><mml:math id="M265" display="inline"><mml:mi>n</mml:mi></mml:math></inline-formula> surrogate records
of the same time duration as the original isotope records. For each record, we
simulate the effects of diffusion and time uncertainty and then
calculate in each case and for each core array the spectrum of the average
record (<inline-formula><mml:math id="M266" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="script">S</mml:mi><mml:mi mathvariant="normal">diffusion</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> or <inline-formula><mml:math id="M267" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="script">S</mml:mi><mml:mi mathvariant="normal">time</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>). At the
same time, the spectrum of the average record of the initial surrogate data
(<inline-formula><mml:math id="M268" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="script">S</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>) is calculated without applying diffusion or time
uncertainty. The entire process is repeated <inline-formula><mml:math id="M269" display="inline"><mml:mi>k</mml:mi></mml:math></inline-formula> times and the resulting spectra
are averaged to reduce the spectral uncertainty. We report
<inline-formula><mml:math id="M270" display="inline"><mml:mrow><mml:mover accent="true"><mml:mi mathvariant="script">G</mml:mi><mml:mo mathvariant="normal">‾</mml:mo></mml:mover><mml:mo>=</mml:mo><mml:mo>〈</mml:mo><mml:msub><mml:mi mathvariant="script">S</mml:mi><mml:mi mathvariant="normal">diffusion</mml:mi></mml:msub><mml:mo>〉</mml:mo><mml:mo>/</mml:mo><mml:mo>〈</mml:mo><mml:msub><mml:mi mathvariant="script">S</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub><mml:mo>〉</mml:mo></mml:mrow></mml:math></inline-formula> and
<inline-formula><mml:math id="M271" display="inline"><mml:mrow><mml:mi mathvariant="normal">Φ</mml:mi><mml:mo>=</mml:mo><mml:mo>〈</mml:mo><mml:msub><mml:mi mathvariant="script">S</mml:mi><mml:mi mathvariant="normal">time</mml:mi></mml:msub><mml:mo>〉</mml:mo><mml:mo>/</mml:mo><mml:mo>〈</mml:mo><mml:msub><mml:mi mathvariant="script">S</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub><mml:mo>〉</mml:mo></mml:mrow></mml:math></inline-formula> as
the transfer functions, where <inline-formula><mml:math id="M272" display="inline"><mml:mrow><mml:mo>〈</mml:mo><mml:mo>⋅</mml:mo><mml:mo>〉</mml:mo></mml:mrow></mml:math></inline-formula> denotes the average over the
<inline-formula><mml:math id="M273" display="inline"><mml:mi>k</mml:mi></mml:math></inline-formula> simulations where we use <inline-formula><mml:math id="M274" display="inline"><mml:mrow><mml:mi>k</mml:mi><mml:mo>=</mml:mo><mml:msup><mml:mn mathvariant="normal">10</mml:mn><mml:mn mathvariant="normal">5</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>.</p>
      <p id="d1e5283">For the diffusion simulations, each surrogate record is smoothed by convolution
with a Gaussian kernel of width <inline-formula><mml:math id="M275" display="inline"><mml:mi mathvariant="italic">σ</mml:mi></mml:math></inline-formula>, where <inline-formula><mml:math id="M276" display="inline"><mml:mi mathvariant="italic">σ</mml:mi></mml:math></inline-formula> is the diffusion
length, measured in years, sensitive to ambient temperature, pressure and the
density of the firn <xref ref-type="bibr" rid="bib1.bibx69" id="paren.94"/> and therefore site-specific<?pagebreak page2065?> and a
function of depth. We treat the dependency on density according to
<xref ref-type="bibr" rid="bib1.bibx13" id="text.95"/> with diffusivity after <xref ref-type="bibr" rid="bib1.bibx22" id="text.96"/>; firn density is
modelled according to the Herron–Langway model <xref ref-type="bibr" rid="bib1.bibx19" id="paren.97"/>. Surface air
pressure is calculated from the barometric height formula using the local
elevation and firn temperature. For the surface firn density we assume a
constant value of <inline-formula><mml:math id="M277" display="inline"><mml:mrow><mml:mn mathvariant="normal">340</mml:mn><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mi mathvariant="normal">kg</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> for all sites. The range of input
parameters and their references are given in Table <xref ref-type="table" rid="Ch1.T1"/>.
Missing temperature information for the cores FB9807, FB9811 and FB9815 are
filled with the temperatures from the nearby cores B32 (<inline-formula><mml:math id="M278" display="inline"><mml:mn mathvariant="normal">1</mml:mn></mml:math></inline-formula> km), FB9812
(<inline-formula><mml:math id="M279" display="inline"><mml:mn mathvariant="normal">19</mml:mn></mml:math></inline-formula> km) and FB9805 (<inline-formula><mml:math id="M280" display="inline"><mml:mn mathvariant="normal">28</mml:mn></mml:math></inline-formula> km) respectively. We simulate diffusion lengths
measured in centimetres for core lengths of <inline-formula><mml:math id="M281" display="inline"><mml:mn mathvariant="normal">500</mml:mn></mml:math></inline-formula> m at a resolution of <inline-formula><mml:math id="M282" display="inline"><mml:mn mathvariant="normal">1</mml:mn></mml:math></inline-formula> cm, convert
the values into years and interpolate them onto a regular time axis at a
resolution of 0.5 years. This higher temporal resolution compared to the annual
target resolution of the isotope records is necessary for numerical stability of
the diffusion results at the high-frequency end. The diffusion transfer
functions are then interpolated in frequency space onto the frequency axis of
the isotope records.  Simulated diffusion lengths at a depth corresponding to
200 years after deposition of the snow range, across the firn-core sites, from
0.6 to 1.3 years (<inline-formula><mml:math id="M283" display="inline"><mml:mn mathvariant="normal">8.3</mml:mn></mml:math></inline-formula>–<inline-formula><mml:math id="M284" display="inline"><mml:mn mathvariant="normal">11.4</mml:mn></mml:math></inline-formula> cm) for DML and from 0.3 to 0.6 years
(<inline-formula><mml:math id="M285" display="inline"><mml:mn mathvariant="normal">8.9</mml:mn></mml:math></inline-formula>–<inline-formula><mml:math id="M286" display="inline"><mml:mn mathvariant="normal">11.4</mml:mn></mml:math></inline-formula> cm) for WAIS; for DML and 1000 years after deposition of the
snow, diffusion lengths range from 1.1 to 1.6 years (<inline-formula><mml:math id="M287" display="inline"><mml:mn mathvariant="normal">8.2</mml:mn></mml:math></inline-formula>–<inline-formula><mml:math id="M288" display="inline"><mml:mn mathvariant="normal">9.1</mml:mn></mml:math></inline-formula> cm).</p>
      <p id="d1e5414">To simulate the effect of time uncertainty, we apply the modelling approach by
<xref ref-type="bibr" rid="bib1.bibx5" id="text.98"/>. This model represents an unconstrained process, meaning
that the time uncertainty monotonically increases with modelled age, thus deeper
in the core. To account for volcanic tie points, where the chronologies of the
isotope records are fixed (neglecting time uncertainties of the volcanic
chronologies themselves), we modify the Comboul approach by forcing the model
back to zero time uncertainty at the reported volcanic tie points (constrained
process) in the form of a Brownian Bridge process. In contrast to diffusional
smoothing, it is not a priori clear whether time uncertainty acts as a linear
transfer function on the spectrum of the average record. We tested this by using
different spectral characteristics of the surrogate data, adopting the cases of
white noise as well as power laws with spectral slopes of <inline-formula><mml:math id="M289" display="inline"><mml:mrow><mml:mi mathvariant="italic">β</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.5</mml:mn></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M290" display="inline"><mml:mn mathvariant="normal">1</mml:mn></mml:math></inline-formula>,
<inline-formula><mml:math id="M291" display="inline"><mml:mn mathvariant="normal">1.5</mml:mn></mml:math></inline-formula> and <inline-formula><mml:math id="M292" display="inline"><mml:mn mathvariant="normal">2</mml:mn></mml:math></inline-formula>, and found that the modelled effect of time uncertainty is
insensitive to the spectral shape of the input data and indeed acts as a linear
transfer function. The Comboul model includes as parameters the rates of missing
and double-counted annual layers. We assume equal rates for these processes,
which we set so that the yielded maximum time uncertainties (maximum
standard deviation over simulated chronologies) match the reported time
uncertainties of the isotope records. The reported value of the DML records
(<inline-formula><mml:math id="M293" display="inline"><mml:mrow><mml:mo>∼</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:math></inline-formula> % of the time interval to the nearest tie point, <xref ref-type="bibr" rid="bib1.bibx14" id="altparen.99"/>)
erroneously implies that the uncertainty increases linearly with time
<xref ref-type="bibr" rid="bib1.bibx5" id="paren.100"/>. Here, as a best guess, we choose a process rate that
yields a maximum standard deviation of <inline-formula><mml:math id="M294" display="inline"><mml:mn mathvariant="normal">2</mml:mn></mml:math></inline-formula> % for a constrained process of
duration equal to the mean interval length between the tie points. In summary,
we use process rates of <inline-formula><mml:math id="M295" display="inline"><mml:mrow><mml:mi mathvariant="italic">γ</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.013</mml:mn></mml:mrow></mml:math></inline-formula> for the DML and of <inline-formula><mml:math id="M296" display="inline"><mml:mrow><mml:mi mathvariant="italic">γ</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.027</mml:mn></mml:mrow></mml:math></inline-formula> for the
WAIS cores.</p>
      <p id="d1e5501">The resulting transfer functions used for the main results are shown in
Fig. <xref ref-type="fig" rid="App1.Ch1.F1"/>. Diffusion shows a stronger smoothing for the
longer records of DML2 than for DML1 as it had more time to act. WAIS shows less
smoothing compared to DML1 due to the higher accumulation rates. The
influence of diffusion is negligible for frequencies below the decadal period
for all core arrays. The effect of time uncertainty is negligible for
frequencies below the decadal period for DML1 and WAIS, but only for frequencies
below the 20-year period for DML2 due to the longer distances between the
volcanic tie points.</p>

      <?xmltex \floatpos{t}?><fig id="App1.Ch1.F1"><caption><p id="d1e5509">Estimates of the spectral transfer functions for the effects of site-specific
diffusion <bold>(a)</bold> and time uncertainty <bold>(b)</bold> for the three
studied core arrays, DML1 (black), DML2 (red) and WAIS (blue). The estimates
are based on simulations with surrogate data as explained in the text. Both
effects are largely negligible beyond the decadal period. The horizontal
dashed line in <bold>(a)</bold> at 0.5 denotes the transfer function value, which
was chosen in order to constrain the diffusion correction (see main text). It
corresponds to minimum time periods for the analysis of the respective spectral
data that are indicated by the vertical dashed lines.</p></caption>
        <?xmltex \igopts{width=241.848425pt}?><graphic xlink:href="https://cp.copernicus.org/articles/14/2053/2018/cp-14-2053-2018-f06.png"/>

      </fig>

<?xmltex \hack{\clearpage}?>
</app>

<?pagebreak page2066?><app id="App1.Ch1.S3">
  <title>ERA-Interim temperature and precipitation field decorrelation scales</title>
      <p id="d1e5535">To estimate the present-day spatial decorrelation scales of the atmospheric
temperature and the precipitation fields in our study regions, we resort to
ERA-Interim reanalysis data <xref ref-type="bibr" rid="bib1.bibx7 bib1.bibx9" id="paren.101"/>, since direct
observations are sparse. ERA-Interim is in general regarded to be the most reliable
reanalysis product, both for temperature and precipitation in Antarctica; the
reanalysis temperatures are, despite significant biases in mean values, well
correlated with station observations at monthly to interannual timescales
<xref ref-type="bibr" rid="bib1.bibx2 bib1.bibx23" id="paren.102"/>, and the reanalysis produces the closest match
to Antarctic snowfall, regarding both mean values and seasonal-to-interannual
variability <xref ref-type="bibr" rid="bib1.bibx3 bib1.bibx48" id="paren.103"/>.</p>
      <p id="d1e5547">To obtain decorrelation scales, we calculate the correlations between reanalysis
time series from the grid box closest to the location of the EDML site
(<inline-formula><mml:math id="M297" display="inline"><mml:mn mathvariant="normal">75</mml:mn></mml:math></inline-formula><inline-formula><mml:math id="M298" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> S, <inline-formula><mml:math id="M299" display="inline"><mml:mn mathvariant="normal">0</mml:mn></mml:math></inline-formula><inline-formula><mml:math id="M300" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> W) with the respective time series of
all other grid boxes of the data set south of <inline-formula><mml:math id="M301" display="inline"><mml:mn mathvariant="normal">60</mml:mn></mml:math></inline-formula><inline-formula><mml:math id="M302" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> S. Using an
exponential fit to the correlations of the form <inline-formula><mml:math id="M303" display="inline"><mml:mrow><mml:mi>exp⁡</mml:mi><mml:mo>(</mml:mo><mml:mo>-</mml:mo><mml:mi>d</mml:mi><mml:mo>/</mml:mo><mml:mi mathvariant="normal">Δ</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>, where <inline-formula><mml:math id="M304" display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula>
is the distance between EDML and a particular grid box, yields the decorrelation
scale through the fit parameter <inline-formula><mml:math id="M305" display="inline"><mml:mi mathvariant="normal">Δ</mml:mi></mml:math></inline-formula>. The same approach is applied to the
WDC site (<inline-formula><mml:math id="M306" display="inline"><mml:mn mathvariant="normal">79.5</mml:mn></mml:math></inline-formula><inline-formula><mml:math id="M307" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> S, <inline-formula><mml:math id="M308" display="inline"><mml:mn mathvariant="normal">112</mml:mn></mml:math></inline-formula><inline-formula><mml:math id="M309" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> W).</p>

      <?xmltex \floatpos{h!}?><fig id="App1.Ch1.F2"><caption><p id="d1e5662">Present-day temperature decorrelation across DML and WAIS. Shown are the
correlations (grey dots) of ERA-Interim annual-mean temperatures
<xref ref-type="bibr" rid="bib1.bibx7" id="paren.104"/> at <bold>(a)</bold> EDML and <bold>(b)</bold> WDC with all other
grid boxes below <inline-formula><mml:math id="M310" display="inline"><mml:mn mathvariant="normal">60</mml:mn></mml:math></inline-formula><inline-formula><mml:math id="M311" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> S. Black lines show an exponential fit to the
data; dashed lines indicate the point at which the correlations in the model
have dropped to <inline-formula><mml:math id="M312" display="inline"><mml:mrow><mml:mn mathvariant="normal">1</mml:mn><mml:mo>/</mml:mo><mml:mi>e</mml:mi></mml:mrow></mml:math></inline-formula> – at <inline-formula><mml:math id="M313" display="inline"><mml:mrow><mml:mn mathvariant="normal">1202</mml:mn><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mo>(</mml:mo><mml:mn mathvariant="normal">1232</mml:mn><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> km for EDML (WDC). Coloured
shading indicates the range of site distances of the studied firn-core arrays
(Table <xref ref-type="table" rid="Ch1.T1"/>); the average correlation across each range is
marked by the filled diamond – average correlation of <inline-formula><mml:math id="M314" display="inline"><mml:mn mathvariant="normal">0.87</mml:mn></mml:math></inline-formula> (<inline-formula><mml:math id="M315" display="inline"><mml:mn mathvariant="normal">0.94</mml:mn></mml:math></inline-formula>) for EDML
(WDC).</p></caption>
        <?xmltex \hack{\hsize\textwidth}?>
        <?xmltex \igopts{width=369.885827pt}?><graphic xlink:href="https://cp.copernicus.org/articles/14/2053/2018/cp-14-2053-2018-f07.png"/>

      </fig>

      <p id="d1e5741"><?xmltex \hack{\newpage}?>For annual mean temperatures, the analysis yields decorrelation scales of
around <inline-formula><mml:math id="M316" display="inline"><mml:mn mathvariant="normal">1200</mml:mn></mml:math></inline-formula> km for both regions (Fig. <xref ref-type="fig" rid="App1.Ch1.F2"/>). The
decorrelation scales of precipitation intermittency are expected to depend
on the decorrelation scales of the seasonal precipitation distribution rather
than on the total annual precipitation amount <xref ref-type="bibr" rid="bib1.bibx51" id="paren.105"/>. However, our
analysis suggests that the precipitation decorrelation scales are actually more
or less insensitive to the chosen variable, with estimates between roughly
<inline-formula><mml:math id="M317" display="inline"><mml:mn mathvariant="normal">300</mml:mn></mml:math></inline-formula> and <inline-formula><mml:math id="M318" display="inline"><mml:mn mathvariant="normal">500</mml:mn></mml:math></inline-formula> km for both regions for a variety of chosen fields (total
precipitation amount, the difference between summer (months DJF) and winter (months
JJA) precipitation amounts, the fraction of the summer amount over the winter (winter over summer)
precipitation amount and the fraction of the summer amount (winter) over the total precipitation
amount).</p><?xmltex \hack{\clearpage}?>
</app>
  </app-group><notes notes-type="authorcontribution">

      <p id="d1e5776">TM and TL designed the research, developed the methodology and interpreted the
results. TM reviewed the relevant literature, established the database and performed
all analyses. TM wrote a first version of the manuscript, which was revised by
both authors.</p>
  </notes><notes notes-type="competinginterests">

      <p id="d1e5782">The authors declare that they have no conflict of
interest.</p>
  </notes><notes notes-type="sistatement">

      <p id="d1e5788">This article is part of the special issue “Paleoclimate data synthesis and analysis of associated uncertainty
(BG/CP/ESSD inter-journal SI)”. It is not associated with a conference.</p>
  </notes><ack><title>Acknowledgements</title><p id="d1e5794">We thank all scientists, technicians and the logistic personnel who contributed
to the sampling of the firn cores and the measurement of the used stable-isotope
data, and we are grateful for making the data publicly available. We are
thankful for valuable discussions with and comments by Torben Kunz,
Jürgen Kurths, Johannes Freitag and Maria Hörhold. All plots and numerical analyses
were carried out using the open-source software R: A Language and Environment
for Statistical Computing. This project was supported by Helmholtz funding
through the Polar Regions and Coasts in the Changing Earth System (PACES)
programme of the Alfred Wegener Institute, by the Initiative and Networking Fund
of the Helmholtz Association Grant VG-NH900 and by the European Research Council
(ERC) under the European Union's Horizon 2020 research and innovation programme
(grant agreement no. 716092). It further contributes to the German BMBF project
PalMod. We thank Lukas Jonkers for his kind handling of the manuscript as well
as Dmitry Divine and one anonymous referee for their detailed review and helpful
comments.
<?xmltex \hack{\newline}?><?xmltex \hack{\newline}?>
The article processing charges for this open-access <?xmltex \hack{\newline}?> publication  were covered by a Research <?xmltex \hack{\newline}?> Centre of the Helmholtz Association.
<?xmltex \hack{\newline}?><?xmltex \hack{\newline}?>
Edited by: Lukas Jonkers<?xmltex \hack{\newline}?>
Reviewed by: Dmitry Divine and one anonymous referee</p></ack><ref-list>
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    <!--<article-title-html>What climate signal is contained in decadal- to centennial-scale isotope variations from Antarctic ice cores?</article-title-html>
<abstract-html><p>Ice-core-based records of isotopic composition are a proxy for past
temperatures and can thus provide information on polar climate variability
over a large range of timescales. However, individual isotope records are
affected by a multitude of processes that may mask the true temperature
variability. The relative magnitude of climate and non-climate contributions
is expected to vary as a function of timescale, and thus it is crucial to
determine those temporal scales on which the actual signal dominates the
noise. At present, there are no reliable estimates of this timescale
dependence of the signal-to-noise ratio (SNR). Here, we present a simple
method that applies spectral analyses to stable-isotope data from multiple
cores to estimate the SNR, and the signal and noise variability, as a
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a common signal and from local variations and includes a correction for the
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spectrum of climate variability also shows increasing variability towards
longer timescales, contrary to what is traditionally inferred from single
records in this region. In contrast, the inferred variability spectrum for
WAIS stays close to constant over decadal to centennial timescales, and the
results even suggest a decrease in SNR over this range of timescales. We
speculate that these differences between DML and WAIS are related to
differences in the spatial and temporal scales of the isotope signal,
highlighting the potentially more homogeneous atmospheric conditions on the
Antarctic Plateau in contrast to the marine-influenced conditions on WAIS. In
general, our approach provides a methodological basis for separating local
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