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<article xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:oasis="http://docs.oasis-open.org/ns/oasis-exchange/table" dtd-version="3.0"><?xmltex \makeatother\@nolinetrue\makeatletter?>
  <front>
    <journal-meta>
<journal-id journal-id-type="publisher">CP</journal-id>
<journal-title-group>
<journal-title>Climate of the Past</journal-title>
<abbrev-journal-title abbrev-type="publisher">CP</abbrev-journal-title>
<abbrev-journal-title abbrev-type="nlm-ta">Clim. Past</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1814-9332</issn>
<publisher><publisher-name>Copernicus Publications</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>

    <article-meta>
      <article-id pub-id-type="doi">10.5194/cp-12-75-2016</article-id><title-group><article-title>Hydroclimatic variability in the Levant during the early last glacial
(<inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 117–75 ka) derived from micro-facies analyses <?xmltex \hack{\newline}?>of deep Dead
Sea sediments</article-title>
      </title-group><?xmltex \runningtitle{Hydroclimatic variability in the Levant during the early last glacial}?><?xmltex \runningauthor{I. Neugebauer et al.}?>
      <contrib-group>
        <contrib contrib-type="author" corresp="yes" rid="aff1">
          <name><surname>Neugebauer</surname><given-names>I.</given-names></name>
          <email>inaneu@gfz-potsdam.de</email>
        <ext-link>https://orcid.org/0000-0002-8612-6573</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>Schwab</surname><given-names>M. J.</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff2">
          <name><surname>Waldmann</surname><given-names>N. D.</given-names></name>
          
        <ext-link>https://orcid.org/0000-0003-4627-208X</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>Tjallingii</surname><given-names>R.</given-names></name>
          
        <ext-link>https://orcid.org/0000-0002-9723-3622</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>Frank</surname><given-names>U.</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff2">
          <name><surname>Hadzhiivanova</surname><given-names>E.</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff3">
          <name><surname>Naumann</surname><given-names>R.</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff2">
          <name><surname>Taha</surname><given-names>N.</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff4">
          <name><surname>Agnon</surname><given-names>A.</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff4">
          <name><surname>Enzel</surname><given-names>Y.</given-names></name>
          
        <ext-link>https://orcid.org/0000-0001-8367-9255</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1 aff5">
          <name><surname>Brauer</surname><given-names>A.</given-names></name>
          
        </contrib>
        <aff id="aff1"><label>1</label><institution>GFZ German Research Centre for Geosciences, Section 5.2 – Climate
Dynamics and Landscape Evolution, <?xmltex \hack{\newline}?>Telegrafenberg, 14473 Potsdam, Germany</institution>
        </aff>
        <aff id="aff2"><label>2</label><institution>University of Haifa, Department of Marine Geosciences, Leon H. Charney
School of Marine Sciences, <?xmltex \hack{\newline}?>Mount Carmel 31905, Israel</institution>
        </aff>
        <aff id="aff3"><label>3</label><institution>GFZ German Research Centre for Geosciences, Section 3.1 – Inorganic and
Isotope Geochemistry, <?xmltex \hack{\newline}?>Telegrafenberg, 14473 Potsdam, Germany</institution>
        </aff>
        <aff id="aff4"><label>4</label><institution>The Hebrew University of Jerusalem, The Fredy &amp; Nadine Herrmann
Institute of Earth Sciences, <?xmltex \hack{\newline}?>Givat Ram, Jerusalem 91904, Israel</institution>
        </aff>
        <aff id="aff5"><label>5</label><institution>University of Potsdam, Institute of Earth and Environmental Science,
Karl-Liebknecht-Str. 24–25, <?xmltex \hack{\newline}?>14476 Potsdam-Golm, Germany</institution>
        </aff>
      </contrib-group>
      <author-notes><corresp id="corr1">I. Neugebauer (inaneu@gfz-potsdam.de)</corresp></author-notes><pub-date><day>18</day><month>January</month><year>2016</year></pub-date>
      
      <volume>12</volume>
      <issue>1</issue>
      <fpage>75</fpage><lpage>90</lpage>
      <history>
        <date date-type="received"><day>18</day><month>June</month><year>2015</year></date>
           <date date-type="rev-request"><day>11</day><month>August</month><year>2015</year></date>
           <date date-type="rev-recd"><day>17</day><month>December</month><year>2015</year></date>
           <date date-type="accepted"><day>30</day><month>December</month><year>2015</year></date>
      </history>
      <permissions>
<license license-type="open-access">
<license-p>This work is licensed under a Creative Commons Attribution 3.0 Unported License. To view a copy of this license, visit <ext-link ext-link-type="uri" xlink:href="http://creativecommons.org/licenses/by/3.0/">http://creativecommons.org/licenses/by/3.0/</ext-link></license-p>
</license>
</permissions><self-uri xlink:href="https://cp.copernicus.org/articles/12/75/2016/cp-12-75-2016.html">This article is available from https://cp.copernicus.org/articles/12/75/2016/cp-12-75-2016.html</self-uri>
<self-uri xlink:href="https://cp.copernicus.org/articles/12/75/2016/cp-12-75-2016.pdf">The full text article is available as a PDF file from https://cp.copernicus.org/articles/12/75/2016/cp-12-75-2016.pdf</self-uri>


      <abstract>
    <p>The new sediment record from the deep Dead Sea basin (ICDP core 5017-1)
provides a unique archive for hydroclimatic variability in the Levant. Here,
we present high-resolution sediment facies analysis and elemental
composition by micro-X-ray fluorescence (<inline-formula><mml:math display="inline"><mml:mi mathvariant="normal">µ</mml:mi></mml:math></inline-formula>XRF) scanning of core
5017-1 to trace lake levels and responses of the regional hydroclimatology
during the time interval from ca. 117 to 75 ka, i.e. the transition between the
last interglacial and the onset of the last glaciation. We distinguished six
major micro-facies types and interpreted these and their alterations in the
core in terms of relative lake level changes. The two end-member facies for
highest and lowest lake levels are (a) up to several metres thick, greenish
sediments of alternating aragonite and detrital marl laminae (aad) and (b)
thick halite facies, respectively. Intermediate lake levels are
characterised by detrital marls with varying amounts of aragonite, gypsum or
halite, reflecting lower-amplitude, shorter-term variability. Two intervals
of pronounced lake level drops occurred at <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 110–108 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 5 and <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 93–87 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 7 ka. They likely coincide with stadial
conditions in the central Mediterranean (Melisey I and II pollen zones in
Monticchio) and low global sea levels during Marine Isotope Stage (MIS)
5d and 5b. However, our data do not support the current hypothesis of an
almost complete desiccation of the Dead Sea during the earlier of these lake
level low stands based on a recovered gravel layer. Based on new
petrographic analyses, we propose that, although it was a low stand, this
well-sorted gravel layer may be a vestige of a thick turbidite that has been
washed out during drilling rather than an in situ beach deposit. Two
intervals of higher lake stands at <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 108–93 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 6 and
<inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 87–75 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 7 ka correspond to interstadial conditions in
the central Mediterranean, i.e. pollen zones St. Germain I and II in
Monticchio, and Greenland interstadials (GI) 24<inline-formula><mml:math display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula>23 and 21 in Greenland, as well as to sapropels S4
and S3 in the Mediterranean Sea. These apparent correlations suggest a close
link of the climate in the Levant to North Atlantic and Mediterranean
climates during the time of the build-up of Northern Hemisphere ice shields
in the early last glacial period.</p>
  </abstract>
    </article-meta>
  </front>
<body>
      

      <?xmltex \hack{\newpage}?>
<sec id="Ch1.S1" sec-type="intro">
  <title>Introduction</title>
      <p>The Dead Sea and its Pleistocene precursor lakes Amora, Samra and Lisan
(e.g. Bartov et al., 2003; Torfstein et al., 2009; Waldmann et al., 2009)
experienced major lake level fluctuations in the past as a sensitive
response to changing hydroclimatic conditions in the lake's watershed
(e.g. Enzel et al., 2008). The lakes expanded during glacial
intervals due to up to twice modern precipitation, whereas interglacials are
generally characterised by a lake contraction due to reduced precipitation
and runoff (Enzel et al., 2008; Rohling, 2013). Hence, the last glacial
Lake Lisan, which occupied the Dead Sea basin between <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 70 and
14 ka, reached up to <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 270 m higher lake stands than the
Holocene Dead Sea and the last interglacial Lake Samra (e.g. Bartov et
al., 2002, 2007; Waldmann et al., 2007; Torfstein et al., 2013). The highest
amplitudes of lake level drops occurred at the glacial to interglacial
transitions triggered by lower rainfall (e.g. Yechieli et al., 1993;
Bartov et al., 2007; Waldmann et al., 2009; Stein et al., 2010). For
example, the fresher Lake Lisan water body turned into the hypersaline
Holocene Dead Sea during the last termination leading to the deposition of a
thick halite sequence during the early Holocene
(<inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 11–10 ka; e.g. Stein et al., 2010).</p>
      <p>Less information is available about lake level changes during the transition
from interglacial to glacial climate conditions. Previous studies from
exposed sediment sections of the Samra Formation at the south-western margin
of the Dead Sea suggested a relatively shallow Lake Samra from ca. 135 to 75 ka (Waldmann et al., 2007, 2009, 2010). The main lake level rise at the
transition from Lake Samra to Lake Lisan was assumed from a sedimentological
change from sand deposits to sediments of alternating fine laminae of
aragonite and detritus at a major unconformity <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 75–70 ka
(e.g. Waldmann et al., 2009; Torfstein et al., 2013). However, the early
glacial time interval between the last interglacial low stand (Lake Samra)
and the full glacial high stand (Lake Lisan), i.e. coinciding with Marine Isotope Stage (MIS) 5d to
5a, is not well represented in the exposed sediments
(Waldmann et al., 2009).</p>
      <p>Sediments from this time interval have been for the first time recovered by
the
ICDP Dead Sea Deep Drilling Project (DSDDP) from the deepest part of the Dead Sea basin
(Neugebauer et al., 2014). Based on a new chronology and
interpretation of a well-sorted gravel deposit, Torfstein et al. (2015) inferred an almost complete drawdown of the Dead Sea
leading to a sedimentary hiatus between 116 and 110 ka at around MIS 5d,
which is considered the most extreme lake level drop during the last
<inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 220 ka, i.e. the time period covered by the DSDDP sediment
record. Furthermore, Torfstein et al. (2015) suggest moisture
supply through the African monsoon to the southern Levant during more humid
intervals in the early last glacial, which are considered to coincide with
MIS 5c and 5a, whereas marine and terrestrial records from across the
Mediterranean region responded to long-term orbitally induced temperature
fluctuations, ice sheet waxing and waning in the Northern Hemisphere and
climatic changes in the North Atlantic (e.g. Tzedakis, 2005;
Martin-Puertas et al., 2014).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F1" specific-use="star"><caption><p><bold>(a)</bold> Location of Mediterranean records discussed in the text; EM
marine – eastern Mediterranean marine cores (Cheddadi and
Rossignol-Strick, 1995; Almogi-Labin et al., 2009); Negev speleothems –
various caves in the northern, central and southern Negev (Vaks
et al., 2010); for references of the other records the reader is referred to
the text. <bold>(b)</bold> Map of the Dead Sea (NASA image by R. Simmon using Landsat
data, 2011, from USGS, <uri>www.visibleearth.nasa.gov/</uri>), with bathymetry of the
northern Dead Sea basin from Sade et al. (2014), 5017-1 coring
location, Perazim Valley Samra outcrop PZ-7 (Waldmann et al.,
2009).</p></caption>
        <?xmltex \igopts{width=341.433071pt}?><graphic xlink:href="https://cp.copernicus.org/articles/12/75/2016/cp-12-75-2016-f01.jpg"/>

      </fig>

      <p>In this study, we apply a combination of petrographic, micro-facies and
high-resolution X-ray fluorescence (XRF) analyses to investigate in more detail the
sedimentological changes in the new ICDP Dead Sea record between the last
interglacial and the onset of Lake Lisan (<inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 117–75 ka). These
sediments and their alterations serve as indicators for hydroclimatic
variations in the southern Levant. In addition, we focus on the
sedimentology of the gravel layer to add information on the drawdown
hypothesis of the Dead Sea (Stein et al., 2011; Torfstein et al., 2015).</p>
</sec>
<sec id="Ch1.S2">
  <title>Regional setting</title>
      <p>With a lake level of 429 m (in 2015) below mean sea level (m b.m.s.l.) and a
water depth of ca. 300 m the Dead Sea is located in one of the lowest
continental depressions on earth. The basin is bounded by the Judean
Mountains on the west and the Jordan Plateau on the east, rising to heights
of <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 1000 and <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 1200 m above mean sea level,
respectively (Fig. 1). The modern watershed of the lake, which is one of the
largest in the Levant (<inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 40 000 km<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:math></inline-formula>),
experiences subhumid (&gt; 1000 mm yr<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> in the northernmost
point) to semiarid Mediterranean climate in its north and arid to hyperarid
(<inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 30 mm yr<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> in the southernmost point) conditions in
the southern part characterised by winter rain of the Saharo-Arabian
environment. These climate conditions combined with the particular steep
topography of the basin margins create hyperarid conditions at the lake
itself. The modern Dead Sea is a hypersaline calcium chloride brine (e.g. Katz
et al., 1977; Lensky et al., 2005) and a terminal lake, mainly fed by the
Jordan River (Fig. 1). Precipitation primarily arrives in the watershed in
autumn to late spring (October–May) through eastern Mediterranean mid-latitude
cyclones (Cyprus Lows; Ziv et al., 2006; Enzel et al., 2008) and tropical
plumes in winter and spring (also termed subtropical jet storms by Kahana
et al., 2002; Rubin et al., 2007). Occasionally, the region is influenced by
the Active Red Sea Trough from the south during autumn and winter
(e.g. Enzel et al., 2008) with sources of its moisture also
in the Mediterranean. The geology of the catchment is predominantly
characterised by Cretaceous carbonate sedimentary rocks, with some
Palaeozoic to Mesozoic sandstones and Pleistocene volcanic units
(Bentor, 1961; Sneh et al., 1998).</p>
</sec>
<sec id="Ch1.S3">
  <title>Material and methods</title>
<sec id="Ch1.S3.SS1">
  <title>Dead Sea deep-basin core 5017-1</title>
      <p>The 5017-1 sediment core from the deep Dead Sea basin (31<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>30<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>′</mml:mo></mml:msup></mml:math></inline-formula>29<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>′</mml:mo><mml:mo>′</mml:mo></mml:mrow></mml:msup></mml:math></inline-formula> N, 35<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>28<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>′</mml:mo></mml:msup></mml:math></inline-formula>16<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>′</mml:mo><mml:mo>′</mml:mo></mml:mrow></mml:msup></mml:math></inline-formula> E; ca. 300 m water depth in 2010; sediment surface
<inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 725 m b.m.s.l.; Fig. 1) was obtained during the drilling
campaign of the ICDP Dead Sea Deep Drilling Project (DSDDP) in winter
2010–2011 (Stein et al., 2011). The record is <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 455 m
long and comprises two full glacial–interglacial cycles (Neugebauer et
al., 2014; Torfstein et al., 2015). Here, we focus on a <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 65 m
long section from <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 180 to <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 245 m below lake
floor (m b.l.f.). Sediment facies were described with an accuracy of 1 cm based
on line-scanning images of the split sediment cores. Magnetic susceptibility
data in 1 mm resolution were routinely obtained for the entire 5017-1 record
(see Neugebauer et al., 2014, for details).</p>
</sec>
<sec id="Ch1.S3.SS2">
  <title>Micro-facies analyses</title>
      <p>For micro-facies analyses we applied a combination of petrographic thin-section microscopy and high-resolution <inline-formula><mml:math display="inline"><mml:mi mathvariant="normal">µ</mml:mi></mml:math></inline-formula>XRF element scanning. A total
of 26 large-scale thin-section samples (10 <inline-formula><mml:math display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 2 cm) were prepared
representing changes in facies types along the section. Preparation largely
followed the standard procedure for soft sediments (e.g.
Brauer et al., 1999) but were performed under dry conditions to avoid salt
crystallisation during the preparation process. Thin sections were analysed
with a petrographic microscope (<?xmltex \hack{\mbox\bgroup}?>Leica<?xmltex \hack{\egroup}?> DMLP) and images were taken with a
digital camera (Olympus DP72). Fluorescence was analysed using a Nikon
AZ100M microscope, operated with violet and polarised light conditions, and
Nikon photo software (NIS Elements AR 4.3).</p>
      <p>The <inline-formula><mml:math display="inline"><mml:mi mathvariant="normal">µ</mml:mi></mml:math></inline-formula>XRF measurements were acquired every 200 <inline-formula><mml:math display="inline"><mml:mi mathvariant="normal">µ</mml:mi></mml:math></inline-formula>m for 10 s
using the ITRAX <inline-formula><mml:math display="inline"><mml:mi mathvariant="normal">µ</mml:mi></mml:math></inline-formula>XRF core scanner at GFZ, Germany. The core scanner
is equipped with a Cr tube operated at 30 kV and 30 mA to irradiate the
split-core sediment surface. This non-destructive method acquires element
intensities of Si, S, Cl, K, Ca, Ti, Fe, Br and Sr
(Neugebauer et al., 2014), which are presented as count
rates (counts per second – cps). The element intensity records reflect
relative changes in the composition of the Dead Sea sediments, but they are also
influenced by physical sediment properties (e.g. density, water content,
grain size) and the sample geometry. The easiest and most convenient way to
minimise the physical and geometrical sample effects is by the
transformation of element intensities into ratios or log ratios
(Weltje and Tjallingii, 2008).</p>
</sec>
<sec id="Ch1.S3.SS3">
  <title>Grain size analyses and gravel petrography</title>
      <p>Laminated sediments were sampled for grain size distributions with 1 cm<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msup></mml:math></inline-formula> sample volume at 1–3 cm vertical resolution and a total of 363
samples. Sample preparation included decomposing organic matter using 30 mL
H<inline-formula><mml:math display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>O<inline-formula><mml:math display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula> (30 %) and distilled water (<inline-formula><mml:math display="inline"><mml:mrow><mml:mn mathvariant="normal">1</mml:mn><mml:mo>:</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:math></inline-formula> concentration) and
breaking aggregates with Calgon detergent ((NaPO<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub><mml:msub><mml:mo>)</mml:mo><mml:mn mathvariant="normal">6</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>, 1 %) and
ultrasonic bath. The particle size distribution was measured using an LS 13
320 laser diffraction particle size analyser for (1) the total sample and
(2) the carbonate-free sample after dissolution through HCl (32 %,
dilution of <inline-formula><mml:math display="inline"><mml:mrow><mml:mn mathvariant="normal">1</mml:mn><mml:mo>:</mml:mo><mml:mn mathvariant="normal">9</mml:mn></mml:mrow></mml:math></inline-formula> with distilled water). Less than 1 g of sediment was
required for measurement.</p>
      <p>In total, 22 gravel layers detected in core 5017-1 were sampled for
petrographic analyses. The samples were wet-sieved for five grain size
fractions (&gt; 4, 2–4, 1–2, 0.5–1 and &lt; 0.5 mm), for which strewn slides were prepared for microscopic inspections.
Here, we focus on two gravel units occurring within the studied core section
(180–245 m b.l.f.).</p>
</sec>
<sec id="Ch1.S3.SS4">
  <?xmltex \opttitle{XRD and TOC/CaCO${}_{{3}}$ measurements}?><title>XRD and TOC/CaCO<inline-formula><mml:math display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:math></inline-formula> measurements</title>
      <p>For X-ray powder diffraction (XRD) measurements 25 samples were collected
from about the same depths as thin sections to complement microscopic
inspections. Powder X-ray patterns were collected using a PANalytical
Empyrean powder diffractometer with Cu K<inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">α</mml:mi></mml:math></inline-formula> radiation, automatic
divergent and antiscatter slits and a PIXcel<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mtext>3D</mml:mtext></mml:msup></mml:math></inline-formula> detector. The
diffraction data were recorded from 5<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> to 85<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> 2<inline-formula><mml:math display="inline"><mml:mi mathvariant="normal">Θ</mml:mi></mml:math></inline-formula>
via a continuous scan with a step size of 0.013 and a scan time of 60 s per
step. The generator settings were 40 kV and 40 mA.</p>
      <p>Total organic carbon (TOC) and calcium carbonate (CaCO<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> contents have
been determined from 19 of these samples using an elemental analyser
(EA3000-CHNS Eurovector). First, 5–10 mg dried and homogenised sample
material was weighed in Sn capsules for total carbon (TC) determination.
Subsequently, second sample aliquots of 3–4 mg of the samples were
decalcified in Ag capsules in three steps through treatment with (1) 3 %
HCl, (2) 20 % HCl and (3) drying at 75<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> C for TOC determination.
Data were calibrated with standards (BBOT, sulfanilamide, and for TOC
additionally Boden3) and empty Sn and Ag capsules. The relative standard
deviation is &lt; 1 %. CaCO<inline-formula><mml:math display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:math></inline-formula> contents were calculated from the
difference of TC–TOC.</p>

      <?xmltex \floatpos{p}?><fig id="Ch1.F2" specific-use="star"><caption><p>Micro-facies (core photos, polarised thin-section scans and
microscopic images with varying magnification and polarisation conditions)
and <inline-formula><mml:math display="inline"><mml:mi mathvariant="normal">µ</mml:mi></mml:math></inline-formula>XRF characteristics (element ratios): <bold>(a)</bold> green aad facies with
peaks in Sr <inline-formula><mml:math display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> Ca typical for aragonite layers and peaks in Ti <inline-formula><mml:math display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> Ca and
Ca <inline-formula><mml:math display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> (Sr<inline-formula><mml:math display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula>S) indicating detrital layers; <bold>(b)</bold> aad-II facies containing greyish
detritus and thicker aragonite layers than the green aad facies; <bold>(c)</bold> example
of a mass-waste deposit: graded layer with high Ti <inline-formula><mml:math display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> Ca ratio and increased
S <inline-formula><mml:math display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> Ca at the base due to diagenetic gypsum; <bold>(d)</bold> gd facies characterised
by a high S <inline-formula><mml:math display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> Ca ratio; <bold>(e)</bold> lh facies with high Cl <inline-formula><mml:math display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> Br and positively correlated
S <inline-formula><mml:math display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> Ca, but peaks of all other elements only in the thin detrital laminae;
<bold>(f)</bold> fluorescence (violet light) microscope images of greenish detrital laminae
(upper photo, core section 5017-A-1-87-1, at <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 72 cm) with
very strong fluorescence (red colour) and greyish-brownish detrital laminae
(lower photo, core section 5017-1-A-78-1, at <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 140 cm) that
are characterised by a weaker fluorescence; <bold>(g)</bold> correlation plot of TOC
against CaCO<inline-formula><mml:math display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:math></inline-formula> contents of 19 samples distinguished for different
micro-facies types; <bold>(h)</bold> correlation plot of the two detrital fractions as
derived from <inline-formula><mml:math display="inline"><mml:mi mathvariant="normal">µ</mml:mi></mml:math></inline-formula>XRF element scanning, exemplary for lithological unit
(LU) II: Ti <inline-formula><mml:math display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> Ca as proxy for the siliciclastic detrital fraction and
Ca <inline-formula><mml:math display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> (Sr<inline-formula><mml:math display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula>S) as proxy for the detrital carbonate fraction, <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup><mml:mo>=</mml:mo></mml:mrow></mml:math></inline-formula> 0.4.</p></caption>
          <?xmltex \igopts{width=426.791339pt}?><graphic xlink:href="https://cp.copernicus.org/articles/12/75/2016/cp-12-75-2016-f02.jpg"/>

        </fig>

</sec>
</sec>
<sec id="Ch1.S4">
  <title>Results</title>
<sec id="Ch1.S4.SS1">
  <title>Micro-facies, sedimentology and geochemistry</title>
      <p>The sediments of the analysed <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 65 m long section of core
5017-1 mainly consist of laminated marl of the aad facies
(alternating aragonite and detritus; e.g. Machlus et al.,
2000), gypsum and halite deposits (Neugebauer et al.,
2014). Commonly, detrital material is composed of clay to silt-sized
calcite, quartz, dolomite and minor feldspar and clay minerals. The
thickness of detrital layers ranges from &lt; 1 mm to several centimetres and
their colour is greyish to black, if iron sulfides are present (pyrite or
greigite), or brownish and greenish, if terrestrial organic or algal remains
are dominant. Aragonite formed as 5–15 <inline-formula><mml:math display="inline"><mml:mi mathvariant="normal">µ</mml:mi></mml:math></inline-formula>m small stellate aggregates
of orthorhombic crystals building <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 0.1–4 mm thick white
laminae. Monoclinic, euhedral <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 10–60 <inline-formula><mml:math display="inline"><mml:mi mathvariant="normal">µ</mml:mi></mml:math></inline-formula>m gypsum
crystals build <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 0.2–3 cm thick beige layers. Larger, up to 1 mm gypsum crystals appear scattered within detrital layers. Cubic halite crystals
ranging in length from <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 1 mm to several centimetres are either embedded
in predominantly detrital marl or build thick deposits. These thick halite
deposits contain only minor detrital material and are often layered.</p>
      <p>Six micro-facies types were identified (Fig. 2):
<list list-type="order"><list-item><p>green aad: alternating white aragonite and greenish detrital marl laminae
(<inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 1 mm thick couplets; Fig. 2a), the greenish laminae exhibit
some diatoms and very strong fluorescence pointing to a significant amount
of chlorophyll preserved in the sediment (Fig. 2f);</p></list-item><list-item><p>aad-n: alternating white aragonite and greyish detrital marl laminae
(<inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 1 mm thick couplets, occurrence as normal type;
defined by Machlus et al., 2000);</p></list-item><list-item><p>aad-II: alternating white aragonite and greyish detrital marl laminae
with thicker aragonite layers than normal type (<inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 1–5 mm thick
couplets, Fig. 2b);</p></list-item><list-item><p>gd: well laminated to massive, centimetre-thick gypsum deposits and detrital
marl (Fig. 2d);</p></list-item><list-item><p>hd: cubic halite crystals (mm–cm) scattered in detrital marl;</p></list-item><list-item><p>lh/hh: layered or homogeneous consolidated halite; the layered type
often alternates with thin detrital marl laminae (Fig. 2e).</p></list-item></list>
In addition, up to 1.7 m thick graded layers and up to 3 m thick slump
deposits are predominantly associated with the aad micro-facies types and less
frequent and thinner in the halite-dominated sections. In centimetre to tens of
centimetre thick basal layers of 22 thick turbidites and slump deposits,
matrix-supported <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 2–8 mm sized, angular to rounded gravels
occur. In the studied section of core 5017-1, four such mass-waste
deposits with gravel-rich basal layers were identified at composite depths
of <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 233.5, <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 192.8, <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 183.5
and <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 183 m (Fig. 4), of which the <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 58 cm thick
turbidite at <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 233.5 m depth was analysed in detail (Fig. 3).
The matrix-supported gravels are composed of carbonates (limestone,
dolomite, with a presence of aragonite) in the form of sparite, (bio)micrite
or peloid, and sulfates (gypsum, anhydrite) as well as halite and minor
quartz. The fine and medium gravel fractions constitute <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 40 % of the total dry weight (Fig. 3b).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F3" specific-use="star"><caption><p><bold>(a)</bold> Lithological profile from 233 to 242 m composite depth (cc –
core catcher), two gravel deposits in core sections (1) 5017-1-A-90-1
(233.17 m composite depth) and (2) 5017-1-A-92-1 (239.27 m composite depth)
and strewn thin slide scans (polarised light) of the 2-4 mm grain fractions;
yellow bars indicate sampling positions in the two core sections. <bold>(b)</bold> Table
of grain size fractions after sieving for one example of a mud-supported
gravel occurrence and the pure gravel layer, both as shown in <bold>(a)</bold>.</p></caption>
          <?xmltex \igopts{width=398.338583pt}?><graphic xlink:href="https://cp.copernicus.org/articles/12/75/2016/cp-12-75-2016-f03.jpg"/>

        </fig>

      <p>In one exceptional case at <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 239 m composite depth, a
<inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 35 cm thick layer of well-sorted gravels with &lt; 2 % clay to sand matrix appears (Figs. 3 and 4). The petrographic
composition of this gravel deposit is identical to that of the other
mud-supported gravels (Fig. 3). This gravel layer is from a core section
that suffered a major loss of core material during the drilling process
(core 5017-1-A-92-1). From the 130 cm long core drive only a cumulative
thickness of 35 cm gravels and almost no fine material were recovered in the
liner. Therefore, the sedimentological contacts to over- and underlying
sediments are not preserved and are unknown (Fig. 3). Unfortunately, this
prevents investigation of sediment structures in the context of the
complete depositional environment. Interestingly, in the 10 cm wide core
catcher of this core drive, matrix-supported gravel has been caught. This
core catcher sample largely resembles the basal layers of the above-mentioned
thick turbidites and slumps.</p>
      <p>Median grain size values of the laminated sediments, excluding the
halite-facies types hd and lh/hh, vary between <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 7 and
<inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 10 <inline-formula><mml:math display="inline"><mml:mi mathvariant="normal">µ</mml:mi></mml:math></inline-formula>m for samples with and without CaCO<inline-formula><mml:math display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:math></inline-formula> (i.e.
after dissolution of CaCO<inline-formula><mml:math display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:math></inline-formula>; see the Supplement), respectively. These grain size
distributions indicate mainly clay (<inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 54 and
<inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 43 % with and without CaCO<inline-formula><mml:math display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:math></inline-formula>, respectively), very fine
silt (<inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 45 and <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 55 % with and without
CaCO<inline-formula><mml:math display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:math></inline-formula>, respectively) and very little sand (<inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 0.1 and
<inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 0.9 % with and without CaCO<inline-formula><mml:math display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:math></inline-formula>, respectively).
Gypsum-detritus samples (gd facies) revealed the coarsest mean grain size of
<inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 8 <inline-formula><mml:math display="inline"><mml:mi mathvariant="normal">µ</mml:mi></mml:math></inline-formula>m (<inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 12.5 <inline-formula><mml:math display="inline"><mml:mi mathvariant="normal">µ</mml:mi></mml:math></inline-formula>m without
CaCO<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> and the highest sand fraction (<inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 0.5 and
<inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 2.2 %, with and without CaCO<inline-formula><mml:math display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:math></inline-formula>, respectively) due to
gypsum which was not removed during sample treatment. The aad-n and aad-II
micro-facies show similar and low mean grain sizes of <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 6 <inline-formula><mml:math display="inline"><mml:mi mathvariant="normal">µ</mml:mi></mml:math></inline-formula>m (<inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 9 <inline-formula><mml:math display="inline"><mml:mi mathvariant="normal">µ</mml:mi></mml:math></inline-formula>m without CaCO<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>, while the green
aad type exhibits a slightly higher mean value of <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 7 <inline-formula><mml:math display="inline"><mml:mi mathvariant="normal">µ</mml:mi></mml:math></inline-formula>m (<inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 11 <inline-formula><mml:math display="inline"><mml:mi mathvariant="normal">µ</mml:mi></mml:math></inline-formula>m without CaCO<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>. Also, the silt and sand
fractions of the green aad type are enhanced in comparison to the other two
aad types (see the Supplement).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F4" specific-use="star"><caption><p>Lithology of the <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 65 m long 5017-1 core section:
lithostratigraphic units, U–Th ages (from Torfstein et al.,
2015), with extrapolated ages in italic, <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>*</mml:mo></mml:msup></mml:math></inline-formula> – interpolated age (see text for
explanation), magnetic susceptibility (1 mm resolution, 10<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">6</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> SI);
event-free lithology, <inline-formula><mml:math display="inline"><mml:mi mathvariant="normal">µ</mml:mi></mml:math></inline-formula>XRF data (grey: 200 <inline-formula><mml:math display="inline"><mml:mi mathvariant="normal">µ</mml:mi></mml:math></inline-formula>m steps, black:
101-steps running means of counts) and the relative lake level changes
inferred from the changing micro-facies. All mass-waste deposits thicker
than 1 cm were excluded from the event-free lithological profile and data;
event-free sediment depth starts with zero at 180 m below lake floor.
<inline-formula><mml:math display="inline"><mml:mi mathvariant="normal">µ</mml:mi></mml:math></inline-formula>XRF data of normalised ratios: Cl <inline-formula><mml:math display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> Br representing halite, Ca <inline-formula><mml:math display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> (Sr<inline-formula><mml:math display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula>S)
<inline-formula><mml:math display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> Ti <inline-formula><mml:math display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> Ca indicating the total carbonate and siliciclastic detritus, and Sr <inline-formula><mml:math display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> Ca
indicating aragonite.</p></caption>
          <?xmltex \igopts{width=455.244094pt}?><graphic xlink:href="https://cp.copernicus.org/articles/12/75/2016/cp-12-75-2016-f04.jpg"/>

        </fig>

      <p>The differentiation of the laminated micro-facies types gd, aad-II, aad-n
and green aad is supported by total organic carbon and calcium carbonate
contents (Fig. 2g). The gd facies is characterised by lowest TOC values of
0.25–0.5 and <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 18 % CaCO<inline-formula><mml:math display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:math></inline-formula>, whereas the aad-II
facies (0.35–0.57 % TOC, 30–47 % CaCO<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> and the aad-n facies
(0.6–0.7 % TOC, <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 47 % CaCO<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> exhibit higher values.
The green aad facies is characterised by highest TOC (0.65 and
<inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 0.9 %) and CaCO<inline-formula><mml:math display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:math></inline-formula> contents (<inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 40–50
and 62 %).</p>
      <p>The elements Si, S, Cl, K, Ca, Ti, Fe, Br and Sr were obtained by <inline-formula><mml:math display="inline"><mml:mi mathvariant="normal">µ</mml:mi></mml:math></inline-formula>XRF scanning and used to characterise the Dead Sea sediments (Fig. 2; see
also Neugebauer et al., 2014, 2015). Aragonite laminae are revealed by high
Sr <inline-formula><mml:math display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> Ca values, gypsum is represented by high S <inline-formula><mml:math display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> Ca values and halite is best
characterised by the Cl <inline-formula><mml:math display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> Br ratio (Fig. 2). The elements Si, K, Ti and Fe are
constrained to siliciclastics in the detrital sediment fraction. More
ambiguous is the interpretation of Ca that occurs in aragonite, gypsum and
detrital calcite. The Ca <inline-formula><mml:math display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> (Sr<inline-formula><mml:math display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula>S) ratio indicates the detrital carbonate
fraction because the authigenic Ca sources, i.e. aragonite and gypsum, are
removed. The Ti <inline-formula><mml:math display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> Ca ratio represents the relative siliciclastic fraction
(Fig. 2). The sum of Ca <inline-formula><mml:math display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> (Sr<inline-formula><mml:math display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula>S) and Ti <inline-formula><mml:math display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> Ca ratios best represents the total
amount of carbonate and siliciclastic detritus (Fig. 4). A correlation plot
of these two element ratios shows low, but significant, correlation
(<inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0.4) for the carbonate and siliciclastic detrital fractions
(Fig. 2h); the plot also indicates an additional Ca-bearing detrital
fraction.</p>
</sec>
<sec id="Ch1.S4.SS2">
  <title>Lithostratigraphy</title>
      <p>The analysed section of core 5017-1 is subdivided into four main
lithostratigraphic units (Fig. 4). Units I and III are predominantly
composed of halite (controlled by hd and lh/hh facies), some gypsum and
detrital marl. Units II and IV present primarily aad (green aad, aad-n and
aad-II) and gd facies. These lithostratigraphic units are tied to the
stratigraphic framework (Neugebauer et al., 2014) and the
U–Th chronology (Torfstein et al., 2015) of the 5017-1 core.</p>
      <p>The lowermost unit I (245–237.5 m composite depth) is the upper part of a
ca.
40 m thick halite sequence, the thickest halite deposit in the entire core,
and is part of the last interglacial Samra Formation
(Neugebauer et al., 2014). This unit has very low magnetic
susceptibility values and Sr <inline-formula><mml:math display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> Ca ratios with high Cl <inline-formula><mml:math display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> Br ratios (Fig. 4). The
above-mentioned well-sorted gravel deposit, mainly composed of limestone and
dolomite clasts and halite, was identified <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 2 m below the top
of this halite unit (Figs. 3 and 4). U–Th ages proposed a sedimentary hiatus
between ca. 116 and 110 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 3 ka marked by this gravel layer
(Torfstein et al., 2015).</p>
      <p>The <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 25 m thick unit II (237.5–212.5 m) presents mainly aad
and gd facies. It is divided into two subunits: (1) subunit II-a
(237.5–228 m) comprises aad-II, aad-n and gd facies and is characterised by
low Sr <inline-formula><mml:math display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> Ca and Cl <inline-formula><mml:math display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> Br ratios and distinct peaks in magnetic
susceptibility. (2) Subunit II-b (228–212.5 m) differs from subunit II-a as, in addition to
the above facies, it presents three thick sequences characterised by green
aad facies and partly high Sr <inline-formula><mml:math display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> Ca ratios. Unit II is characterised by
frequent, up to several metres thick, graded detrital layers and slump deposits
(Fig. 4). U–Th ages place unit II between ca. 108 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 5 and 93 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 7 ka (Torfstein et al., 2015), i.e. an interval of
<inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 3–27 000 years. Preliminary varve counting on the core
photographs of this unit reveals a minimum of 4050 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 250 varves, which
is at the lower end of the range and uncertainty of the U–Th ages. It is
likely that much of the sediment was eroded through the frequent
mass-waste events. Unit II builds the upper part of the Samra Formation of
core 5017-1 as defined by Neugebauer et al. (2014).</p>
      <p>Unit III (212.5–201.5 m) is dominated by halite deposits of the hd and lh/hh
facies, which is well reflected in high Cl <inline-formula><mml:math display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> Br ratios. The lower ca. 4 m of
this unit could not be recovered due to the hardness of the salt. Some
centimetre- to decimetre-thick occurrences of aad-n, aad-II and gd facies are intercalated in
the halite deposits, as reflected by higher magnetic susceptibility,
Ca <inline-formula><mml:math display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> (Sr<inline-formula><mml:math display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula>S) <inline-formula><mml:math display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> Ti <inline-formula><mml:math display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> Ca and Sr <inline-formula><mml:math display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> Ca ratios. Unit III was deposited between ca. 93
and 87 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 7 ka (Torfstein et al., 2015) and probably
marks the transition between the Samra and Lisan formations in the
deep-basin core 5017-1 (Neugebauer et al., 2014). Compared
to the chronology of the outcrops at the margin where the Samra–Lisan
transition has been traditionally considered at 75–70 ka
(e.g. Waldmann et al., 2009), probably because of
transgressive truncation, the deep core may indicate that the transition
occurred ca. 15 000 years earlier (Torfstein et al.,
2015).</p>
      <p>The uppermost unit IV (201.5–180 m) compares to unit II and is characterised
by the three aad facies, as indicated by higher Ca <inline-formula><mml:math display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> (Sr<inline-formula><mml:math display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula>S) <inline-formula><mml:math display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> Ti <inline-formula><mml:math display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> Ca and
Sr <inline-formula><mml:math display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> Ca ratios and the absence of halite (Fig. 4). In contrast to unit II,
where magnetic susceptibility values strongly fluctuate, constantly low
magnetic susceptibility characterises unit IV (Fig. 4). This unit can be
divided into three subunits: (1) subunit IV-a is composed of aad-n, aad-II
and gd facies; (2) subunit IV-b is a green aad section; and (3) subunit
IV-c is composed of aad-n and aad-II. Several centimetre- to metre-thick slumped
deposits and graded detrital layers occur in unit IV. At a composite core
depth of <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 195 m the sediment is ca. 85.5 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 8 ka, and 6 m above unit IV (i.e. at 174.5 m depth) an age of 70.5 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 5 ka has been
reported (Torfstein et al., 2015). The interpolated age of the
upper boundary of unit IV at 180 m depth is ca. 75 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 6 ka. Unit IV
builds the lowermost part of the Lisan Formation of core 5017-1
(Neugebauer et al., 2014).</p>

      <?xmltex \floatpos{p}?><fig id="Ch1.F5" specific-use="star"><caption><p>Comparison of the Dead Sea to other records: <bold>(a)</bold> the relative Dead
Sea lake level curve inferred from micro-facies analysis of the deep-basin
core 5017-1 (this study; right <inline-formula><mml:math display="inline"><mml:mi>y</mml:mi></mml:math></inline-formula> axis) and from site PZ-7 from the Perazim
Valley (dashed line; left <inline-formula><mml:math display="inline"><mml:mi>y</mml:mi></mml:math></inline-formula> axis, indicating maximum or minimum relative
lake levels; Waldmann et al., 2009); <bold>(b)</bold> sum of normalised
ratios of Ca <inline-formula><mml:math display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> (Sr<inline-formula><mml:math display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula>S) and Ti <inline-formula><mml:math display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> Ca as proxies for carbonate and siliciclastic
detritus, respectively, and of Sr <inline-formula><mml:math display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> Ca, proxy for aragonite, subtracted by the
Cl <inline-formula><mml:math display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> Br ratio, which is a proxy for halite, [Ca <inline-formula><mml:math display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> (Sr<inline-formula><mml:math display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula>S) <inline-formula><mml:math display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> Ti <inline-formula><mml:math display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> Ca <inline-formula><mml:math display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> Sr <inline-formula><mml:math display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> Ca
– Cl <inline-formula><mml:math display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> Br] indicating the water balance of the lake and agreeing well with
the relative lake level curve; <bold>(c)</bold> mean summer (JJA) insolation at
30<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N (after Laskar et al., 2004); <bold>(d)</bold> <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O of Soreq and Peqin speleothems, Israel (Bar-Matthews
et al., 2003), and eastern Mediterranean sapropel events S3 and S4
(according to Bar-Matthews et al., 2000); <bold>(e)</bold> humidity index of
continental North Africa (core GeoB7920-2) and “green Sahara” phases
(Tjallingii et al., 2008); <bold>(f)</bold> Monticchio (southern Italy)
pollen record of mesic woody taxa and Mediterranean pollen zones Melisey (M)
I and II, and St. Germain I and II (Brauer et al., 2007; Martin-Puertas
et al., 2014) – note a possible chronological shift of 3500 years to the older
for 92–76 ka according to Martin-Puertas et al. (2014); <bold>(g)</bold> Greenland ice core <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O record on GICC05<inline-formula><mml:math display="inline"><mml:msub><mml:mi/><mml:mtext>modelext</mml:mtext></mml:msub></mml:math></inline-formula> timescale
(Wolff et al., 2010) – also indicated are Greenland
interstadials (GI) after Rasmussen et al. (2014) and North Atlantic ice-rafting events C21 to C24 (Chapman and Shackleton, 1999).
Marine isotope stages are given according to Wright (2000). Grey
vertical bars indicate periods of negative water balance in the Dead Sea;
obliquely banded bars: no core recovery.</p></caption>
          <?xmltex \igopts{width=355.659449pt}?><graphic xlink:href="https://cp.copernicus.org/articles/12/75/2016/cp-12-75-2016-f05.jpg"/>

        </fig>

</sec>
</sec>
<sec id="Ch1.S5">
  <title>Discussion</title>
<sec id="Ch1.S5.SS1">
  <title>Micro-facies as relative lake level indicators</title>
      <p>Lake levels of the water bodies occupying the Dead Sea basin are sensitive
responders to changing hydro-climatic conditions in the lake's catchment
(Enzel et al., 2003, 2008; Bookman et al., 2006). Lake
level reconstructions based on onshore sequences indicate a total amplitude
of lake level fluctuation of at least <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 270 m, with lowest
levels of <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 430 m b.m.s.l. occurring during parts of the last
interglacial, the last termination, potentially the Holocene and – anthropogenically induced – in modern times (e.g. Bookman (Ken-Tor) et al.,
2004; Bartov et al., 2007; Waldmann et al., 2009; Stein et al., 2010). The
highest lake level of Lake Lisan of <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 160 m b.m.s.l. was reached
during the last glacial maximum (Bartov et al., 2003). These
exposed sediments at the Dead Sea margins also showed that in general
different lake levels resulted in different sedimentary facies (e.g.
Machlus et al., 2000; Migowski et al., 2006). Hence, facies types can be
considered relative lake level indicators, but without assigning an
absolute level change (Figs. 4 and 5). Unlike the near-shore environment,
where lateral changes can alter the sedimentary facies, which may lead to
erroneous relative lake level interpretations, in the deep basin such
lateral changes are uncommon and, therefore, facies changes are better
related to changes in relative lake levels. These relative lake levels are
crucial to infer regional, basin-scale hydroclimatic changes that control
the direction of lake level trends (i.e. rising or falling), which are the
net product of the respective positive or negative lake budget over decades
to millennia. To avoid complexities in inferring minor relative lake level
changes and to remain reasonable within the resolution of the U–Th
chronology, we concentrated only on reconstructing the millennial-scale
facies alterations and interpret them in terms of relative lake level
variations.</p>
      <p>The typical sediment facies during rising levels and the resulting episodic
high stands of both the deep last glacial Lake Lisan and the much shallower
Holocene Dead Sea is the aad facies composed of alternating aragonite and
detritus (e.g. Machlus et al., 2000; Bookman (Ken-Tor) et al., 2004). As
the lake is devoid of bicarbonate, deposition of aad requires large amounts
of bicarbonate supply by freshwater reaching the lake through runoff during
the winter rainy season to trigger precipitation of primary aragonite
(Stein et al., 1997; Barkan et al., 2001). Three different subtypes of
aad were distinguished in the investigated sediment section through
micro-facies analyses. (i) Green aad (Fig. 2) comprises greenish detrital
laminae containing green algae remains and represents highest lake levels
and less salty limnological conditions. This facies depicts the sediments
deposited in core 5017-1 during the Last Glacial Maximum high stands
(Neugebauer et al., 2014), when Lake Lisan reached its
maximum extent (e.g. Begin et al., 1974; Bartov et al.,
2002). (ii) The aad-n and (iii) the aad-II facies are similar, except that
aad-II is characterised by commonly thicker but irregularly spaced
aragonite laminae (Fig. 2). This may indicate insufficient supply of
bicarbonate to support regular annual aragonite formation. Therefore, the
aad-II facies was likely deposited during episodes of somewhat lower lake
levels compared to the aad-n facies. The aad-II facies also differs from the
ld facies type (laminated detritus), which exhibits coarser detritus (50–60 <inline-formula><mml:math display="inline"><mml:mi mathvariant="normal">µ</mml:mi></mml:math></inline-formula>m) than aad (8–10 <inline-formula><mml:math display="inline"><mml:mi mathvariant="normal">µ</mml:mi></mml:math></inline-formula>m; Haliva-Cohen et al., 2012)
and which is a characteristic facies for intermediate lake levels of the
interglacial Samra and Ze'elim formations (e.g. Migowski et al., 2006;
Waldmann et al., 2009; Neugebauer et al., 2014). The ld facies type was,
however, not detected in the studied core section, which is supported by the
constantly very fine grain sizes of the sediments (Supplement).</p>
      <p>The deposition of well-laminated or massive gypsum (gd facies, Fig. 2) is
associated with mixing of the water body due to lake level fall and a
thinning of the upper freshwater layer (Torfstein et al.,
2008). Halite deposition is related to a negative water balance during times
of decreased lake levels (e.g. Lazar et al., 2014).
Here, we distinguish between a mixed halite-detritus facies (hd) and layered
or homogeneous, consolidated halite (lh/hh facies, Fig. 2). Whereas the
presence of detritus suggests freshwater influx during extreme runoff
events, deposition of thick halite indicates episodes of lowest lake levels.</p>
      <p>Lake level trends inferred from micro-facies analysis are supported by
<inline-formula><mml:math display="inline"><mml:mi mathvariant="normal">µ</mml:mi></mml:math></inline-formula>XRF element scanning data (Figs. 4 and 5). Halite sequences
associated with a negative water balance are well expressed in increased
Cl <inline-formula><mml:math display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> Br ratios. The detrital input depends on the erosion in the catchment,
aeolian deposition over the lake and the catchment, and freshwater supply to
the lake. The relative detrital input can be estimated using the Ca <inline-formula><mml:math display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> (Sr<inline-formula><mml:math display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula>S)
ratio (for carbonate fraction) and the Ti <inline-formula><mml:math display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> Ca ratio (for siliciclastic
fraction). The Sr <inline-formula><mml:math display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> Ca ratio resembles the aragonite amount that increases
with enhanced supply of freshwater. The combination of these ratios by
summing up both detrital fractions and aragonite and subtracting halite
results in a curve that can be interpreted as a proxy for water balance
(Fig. 5), with negative values for halite and gypsum deposits and positive
values for detritus and aragonite.</p>
</sec>
<sec id="Ch1.S5.SS2">
  <title>Gravel deposits in the deep basin</title>
      <p>Gravel deposits are rather common in the deep basin and have been identified
as matrix-supported material mainly in basal layers of turbidites and slumps that are up to several metres thick and reflect mass-waste deposits, which can be
triggered by either extreme runoff or seismic events and slope instabilities
(Kagan and Marco, 2013; Neugebauer et al., 2014; Waldmann et al., 2014).
Only in one case at <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 239 m composite sediment depth has a 35 cm
thick well-sorted gravel deposit lacking fine-grained components been
documented (Figs. 3 and 4). This gravel has been interpreted as beach
deposit and in turn used to argue for a major drawdown or even almost
desiccation of the lake at the end of the last interglacial (Stein et
al., 2011; Torfstein et al., 2015). Combined U–Th ages and oxygen isotope
stratigraphy suggest a <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 116 to 110 ka hiatus at around the
position of the gravel deposit, which is assumed to support the drawdown
hypothesis (Torfstein et al., 2015). However, both
petrographic composition and grain characteristics of the well-sorted gravel
are identical to gravel in basal layers of thick slumps and turbidites as
the one deposited only 6 m above (at <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 233 m composite
sediment depth; Fig. 3). This suggests the possibility of a similar source
and even the same transport mechanism. Due to the massive core loss of
65 % in the core section where the well-sorted gravel was found, no
direct information about the in situ contacts of this gravel to over- and
underlying sediment units is available (Fig. 3a) and its primary
sedimentological context remains unknown. However, the core catcher material
supports the interpretation of even the well-sorted gravel as the vestige of
a major mass-waste deposit, since it consists of matrix-supported gravel
exactly resembling basal layers from at least 22 turbidites and slumps
occurring in the entire record. It is likely that the fine-grained sediment
components of the turbidite were washed out during the drilling process. Low
core recoveries and loss of material often occurred in sediment sections
with alternating hard halite and soft mud (Neugebauer et
al., 2014) as in this section of the record above the major halite deposit.
Therefore, we are convinced that the well-sorted gravels are the result of a
drilling artefact and should not be interpreted as an in situ beach layer
but rather as the washed-out relict of the basal sediments of a major mass-waste
deposit. The deposition of a thick turbidite could have also caused the
supposed hiatus, although its length should be critically tested.</p>
      <p>Accepting our reinterpretation of the well-sorted gravel as primarily a
drilling relict of a turbidite instead of an in situ beach deposit implies
that the Dead Sea was not necessarily desiccated at the end of the last
interglacial, although it might have been at a low stage. This consideration
accords better with thermodynamic calculations and water balance simulations
concluding that the chemistry of the brine and the geometry of the basin
should prevent the lake from drying up (Yechieli et al., 1998; Krumgalz
et al., 2000). First, the specific chemical composition of the Dead Sea
brine (mainly Mg, Na, Ca and Cl) allows for a very high salinity with a
low water activity and vapour pressure to be reached. Therefore, the rate of evaporation
decreases with increasing salinity. Second, the low surface-area-to-volume
ratio of the lake basin limits the amount of evaporated water. In addition,
the relative humidity of the air above the brine has to be close to zero in
order to further evaporate a highly concentrated brine, which, however, was
never observed (Katz and Starinsky, 2015) and is considered
unlikely, especially at very low lake levels, due to the wind-protected
topography of the deep Dead Sea basin.</p>
</sec>
<sec id="Ch1.S5.SS3">
  <?xmltex \opttitle{Relative lake level fluctuations between $\sim$\,117 and 75\,ka}?><title>Relative lake level fluctuations between <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 117 and 75 ka</title>
      <p>Relative lake levels have been reconstructed for the <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 117–75 ka interval based on the six micro-facies types introduced above (Figs. 4
and 5). Relatively lower lake levels are reflected by the halite-dominated
units I (<inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 117–108 ka) and III (<inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 93–87 ka).
Intermediate to relatively higher lake levels are inferred for the aad facies-dominated units II (<inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 108–93 ka) and IV (<inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 87–75 ka) because this facies indicates increased fresh water inflow.</p>
      <p>The age estimate of unit I indicates that the low stand of Lake Samra
commenced during the later part of the last interglacial and may have
continued until <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 108 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 5 ka (Fig. 5). However, there
is no information for the time interval from <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 116 to 110 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 4 ka, due to the erosional unconformity revealed from the
chronological data (Torfstein et al., 2015). The deposition of
ca. 2 m of halite above the hiatus indicates that low levels of the lake
continued until <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 108 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 5 ka because, for times of halite
deposition in the Dead Sea basin, a lake level below 400 m b.m.s.l. can be
assumed (Neev and Emery, 1967; Bookman (Ken-Tor) et al., 2004; Waldmann
et al., 2009; Stein et al., 2010).</p>
      <p>During <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 108–93 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 6 ka (unit II) a trend of general
increase in lake level is indicated by the succession from aad-II to aad-n
and finally to the green aad facies (Fig. 4). Intercalated gypsum deposits
from <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 108 to 100 ka indicate frequent short-term drops in lake
levels. In the last glacial Lisan Formation such gypsum deposits were
associated with reduced precipitation, intensified winds and probably
increased evaporation during Heinrich events (Bartov et al., 2003;
Torfstein et al., 2008, 2013; Rohling, 2013). A Lake Samra
high-stand between <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 100 and 93 ka is in agreement with a level
from exposures at the lake's margins, where a relatively high level of
<inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 320 m b.m.s.l. was proposed (Fig. 5; Waldmann et al., 2009,
2010).</p>
      <p>An abrupt lake level decline and a subsequent millennial-scale low stand,
probably below 400 m b.m.s.l., is inferred from the <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 7 m thick
halite deposit during the <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 93–87 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 7 ka interval (unit
III, Figs. 4 and 5). Within this unit some aad-n, aad-II and gd facies
alternate with the thick and mainly layered halite deposits indicating
superimposed, probably centennial-scale, lake level fluctuations. This
halite sequence represents the final stage of the Samra Formation and marks
the last appearance of halite for the next <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 70 000 years
(Neugebauer et al., 2014) until the early Holocene salt
formation (e.g. Yechieli et al., 1993; Stein et al., 2010). The late Lake
Samra halite indicates a more pronounced lake level drop than the limited
lake level decline inferred from coarser clastic deposits in the exposed
lake margin sediments (Fig. 5; Waldmann et al., 2009).</p>
      <p>During <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 87–79 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 7 ka (units IV-a and IV-b) lake level
increased again as evidenced from the succession from aad-II and aad-n
facies, intercalated by some gd facies, to green aad facies (Fig. 4). At
<inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 79 ka (unit IV-c) the lake probably shortly declined
again as indicated by aad-II facies, before continuing to rise again at
<inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 77 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 6 ka (Fig. 5). Earlier studies of the exposed
sediments of the Samra and Lisan formations suggested that a depositional
unconformity between <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 75 and 70 ka separated these two
formations at the lake's margins (Bartov et al., 2003; Waldmann et al.,
2009; Torfstein et al., 2013). Above this assumed unconformity, aad facies
characterise the lower and upper members of the Lisan Formation
(e.g. Bartov et al., 2002). Below the unconformity, the
onshore Samra Formation is composed of reddish ld facies, sands and gravels
(Waldmann et al., 2009). In the deep core, however, there is
no obvious sedimentological indication for a low stand of the lake at around this
time, but aad facies apparently continuously deposited since <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 87 ka. This suggests that Lake Lisan commenced ca. 10–15 kyr earlier than was
assumed from the exposures where its deposits were in part truncated. This
difference between shallow- and deep-basin sediments might be explained by
(1) the abundant occurrence of slumping deposits and graded layers in the
deep core (Fig. 4) or (2) by a lake level rise from a lower level to the
level of the observed unconformity at the margins during that time.
Combining these two possibilities suggests that these slumping deposits
might indicate transgressive erosion at the outcrop locations during times
of lake level rise of the early Lake Lisan (Bartov et al., 2007).
This is likely causing unconformities in the near-shore marginal areas of
the basin. The large number of slump deposits within this sediment section
might point to several short-term level oscillations during this generally
rising level trend, but there is no further evidence for this proposition.</p>
</sec>
<sec id="Ch1.S5.SS4">
  <title>Hydroclimatic implications</title>
      <p>The Dead Sea is situated at a key transitional zone between predominantly
Atlantic and tropical-influenced climates. The zone of interaction between
both climate regimes is expected to have changed during major climatic
transitions like from glacial to interglacial modes and vice versa. In
contrast to the scarce and sometimes contradicting information from the
Levant, several records from the entire Mediterranean realm provide evidence
for teleconnections of large-scale climate variations with the North
Atlantic climate regime during the early last glacial. The alternation of
cold stadial intervals from <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 111 to 108 ka (GS 25) and
<inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 90 to 85 ka (GS 23<inline-formula><mml:math display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula>22; Rasmussen et al., 2014), as
reflected in Greenland ice cores (Fig. 5; Wolff et
al., 2010) and North Atlantic ice-rafting events C24 and C22<inline-formula><mml:math display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula>C21
(Chapman and Shackleton, 1999), and warmer interstadials (GI
24<inline-formula><mml:math display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula>23 and GI 21; Rasmussen et al., 2014) are well expressed in the western
(marine core MD952042 off the Iberian margin; Sánchez
Goñi et al., 1999), central (Lago Grande di Monticchio; Fig. 5;
Brauer et al., 2007; Martin-Puertas et al., 2014) and eastern
Mediterranean (Tenaghi Philippon: Tzedakis, 2005; Lake Van: Litt et al., 2014; and marine sediments: Cheddadi
and Rossignol-Strick, 1995). The same pattern of large-scale fluctuations
is proposed from Lebanon (Lake Yammoûneh; Develle et al., 2011;
Gasse et al., 2015) and the Soreq and Peqin speleothem records in Israel
(Fig. 5; Bar-Matthews et al., 1999, 2000, 2003). Finally, the Dead
Sea record also reveals low water levels at <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 110–108 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 5
and <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 93–87 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 7 ka, reflecting dry periods corresponding
to Northern Hemisphere stadials, and higher lake levels at <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 
108–93 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 6 and <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 87–75 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 6 ka coinciding with
Greenland interstadials (Fig. 5).</p>
      <p>The long interstadials interrupted by short stadials in the North Atlantic
realm during the build-up phase of the large continental ice sheets (e.g.
Mangerud et al., 1996, 1998; Clark et al., 1999; Svendsen et al., 2004) are
related to changes in Northern Hemisphere orbital insolation
(Fig. 5; Laskar et al., 2004). At the same time, orbital
insolation-driven changes of the Intertropical Convergence Zone controlled the monsoon system and led
to a strengthening of the African summer monsoon and widespread vegetation
cover in the Sahel and in the southern Sahara regions (Fig. 5; deMenocal
et al., 2000; Tjallingii et al., 2008; Herold and Lohmann, 2009). Enhanced
precipitation in eastern Africa induced the formation of organic-rich
sapropel layers S4 and S3 (Fig. 5) in the eastern Mediterranean Basin due to
enhanced Nile River runoff (e.g. Rossignol-Strick, 1985; Rohling et al.,
2015). These changes in freshwater flow further influenced the isotopic
composition of the eastern Mediterranean Sea water, i.e. the source region
for precipitation in the region of the Soreq and Peqin speleothems (Fig. 5; Bar-Matthews et al., 2000, 2003). This is an indirect mechanism
explaining a monsoonal influence in the speleothem records of the Levant.</p>
      <p>Two issues must be discussed when precipitation increase and decrease are
considered for explaining rising and falling trends in lake levels and their
maxima: (a) winter vs. summer precipitation, and (b) tropical vs.
Atlantic–Mediterranean sources. Different scenarios have been proposed but
the source of moisture for the precipitation leading to higher Dead Sea lake
levels during the early glacial and related atmospheric teleconnections is
still debated. Northward shifts of the tropical rain belt as far north as
the Levant have been excluded (Tzedakis, 2007, and references
therein), and Enzel et al. (2015) also argued that summer rains
associated with either the African or Indian monsoons are unlikely even in
the southernmost point of the Dead Sea watershed. Based on hyperarid soils,
Amit et al. (2006, 2011) demonstrated that the southern Negev, including
the southern watershed of the Dead Sea, has been hyperarid since the early
Pleistocene. This is further supported by a diminishing speleothem growth
southward and a proposal for a predominating Atlantic–Mediterranean source
of winter precipitation in the Negev during relatively short episodes of the
last interglacial (Vaks et al., 2010). This apparently
contradicts the hypothesis that a northward shift of summer rains from
monsoonal sources to the southern Levant contributed to the slightly
increased Dead Sea lake level during the early last glacial
(Torfstein et al., 2015). Less attention has been paid to
seasonal shifts in precipitation as a factor for lake level fluctuations.
One reason is that most model studies focus on the summer season (e.g.
Liu et al., 2004; Herold and Lohmann, 2009), while information about the
winter season atmospheric circulation during intervals of maximum insolation
is still scarce. One exception is the study by Kutzbach et al. (2014), which suggests that an increase in winter storm tracks
could have caused the wetter intervals in the Levant during maximum Northern
Hemisphere seasonality.</p>
      <p>Present-day observations identified a third possible mechanism of moisture
supply to the southern Levant. Winter to spring tropical plumes originating
from the tropical eastern Atlantic and western Africa usually transport moisture
across the Sahara into the southern Levant deserts when the
subtropical jet is at a southern latitudinal position (e.g. Kahana et
al., 2002; Rubin et al., 2007; Tubi and Dayan, 2014). Increasing the frequencies of
such atmospheric circulation patterns that cause widespread ample rainstorms
is probably the only way to increase the runoff yield in southern Negev
drainage basins (e.g. Enzel et al., 2012) to a volume that
will be noticed as a level change, although minor, in the Dead Sea.
Low-latitude tropical plumes have been also proposed as a moisture source in
the past when Northern Hemisphere insolation reached maxima during times of
the last interglacial Lake Samra (Waldmann et al., 2009, 2010).</p>
      <p>Disentangling the interactions of low-latitude/tropical and mid-latitude
(Atlantic and Mediterranean) moisture sources and related mechanisms that
triggered the reconstructed long-term and large-scale lake level
fluctuations of the Dead Sea during the first 40 millennia of the last
glacial is challenging and remains partly speculative. One reason for this
difficulty might be that orbital-driven changes in insolation and
seasonality are the common external trigger for both high- and low-latitude
climatic fluctuations during that time. Nevertheless, the striking
coincidence with palaeoclimatic records across the Mediterranean suggests a
strong role of the Atlantic–Mediterranean atmospheric circulation for the
moisture supply to the Levant during the last glacial inception.</p>
      <p>The observed coincidence of a cold North Atlantic and dry southern Levant
during the last glacial inception is apparently in contradiction with the long-term
observations of glacial high stands and interglacial low stands at the Dead
Sea. This apparent difference in the Dead Sea lake level response to North
Atlantic climate changes at different timescales might be explained by
threshold effects in the growth of the Fennoscandian ice sheet. Once the ice
shield reached a certain height, it became a morphological barrier causing a
major system shift in the atmospheric circulation pattern
(Webb III et al., 1993) which, in turn, forced the
Mediterranean storm tracks to shift southward and be funnelled and
intensified towards the central Levant. This would explain the proposed doubling of
annual rainfall in this region (Enzel et al., 2003, 2008) and the high
Lake Lisan levels during the last glacial (Rohling, 2013). During the
glacial inception, different atmospheric boundary conditions prevailed, likely
because the ice shield elevation was still below the threshold, which forces
the large-scale circulation pattern to change. To test this hypothesis, more
high-resolution proxy records from the southern Levant and advanced
modelling studies are needed.</p>
</sec>
</sec>
<sec id="Ch1.S6" sec-type="conclusions">
  <title>Conclusions</title>
      <p>Investigation of a <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 65 m long sediment section of the 5017-1
core from the deep Dead Sea basin confirmed the sensitivity of sediment
deposition to lake level variations. Therefore, micro-facies is a suitable
proxy for relative lake level variations and water balance allowing for
changing hydroclimatic conditions to be traced in the southern Levant during the early
last glacial from <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 117 to 75 ka.</p>
      <p>Matrix-supported gravel deposits are more common in the deepest part of the
Dead Sea basin than previously documented. They are probably transported by
mass-waste events during major lake level fluctuations. We propose that the
appearance of one well-sorted gravel deposit, which was previously suggested
as an in situ beach deposit, is likely an artefact of the drilling process
and that this gravel was originally deposited by mass-wasting as well.
Therefore, we conclude that there is, at this time, no proof for an almost complete
drying of the Dead Sea at the end of the last interglacial.</p>
      <p>We suggest that the first phase of an early Lake Lisan commenced ca. 15 kyr
earlier than was suggested from the main sedimentological shift in exposed
sediments at the lake's margins at <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 75–70 ka. In the deep
basin, Lisan-type sediments, i.e. aad, have been deposited since as early as
<inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 108–93 ka, but again interrupted by a final period of halite
deposition marking the end of Lake Samra at <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 87 ka.</p>
      <p>Large-scale lake level fluctuations of the Dead Sea during the early last
glacial (MIS 5d–5a) are in concert with Mediterranean records and climate
conditions in the North Atlantic. This suggests that the insolation-driven
Atlantic–Mediterranean cyclone activity and seasonality changes are the main
cause of the observed lower lake levels during colder intervals. On longer
timescales, this pattern changed and highest lake levels during the Lake
Lisan phase occurred during the cold Pleniglacial (MIS 4–2). This might be
related to a southward shift and intensification of Mediterranean cyclones
towards the Levant due to a shift in atmospheric circulation boundary
conditions caused by the growth of Northern Hemisphere ice sheets.</p>
</sec>

      
      </body>
    <back><app-group>
        <supplementary-material position="anchor"><p><bold>The Supplement related to this article is available online at <inline-supplementary-material xlink:href="http://dx.doi.org/10.5194/cp-12-75-2016-supplement" xlink:title="pdf">doi:10.5194/cp-12-75-2016-supplement</inline-supplementary-material>.</bold></p></supplementary-material>
        </app-group><ack><title>Acknowledgements</title><p>We would like to thank the editor and the two anonymous reviewers for their
constructive comments, which helped to improve the quality of the
manuscript. Funding by the International Continental Scientific Drilling
Program (ICDP), the German Science Foundation (DFG grants FR 1672/2-1 and BR
2208/10-1), the GFZ German Research Centre for Geosciences and the Israel
Science Foundation (ISF) Dead Sea Core-Center of Excellence Research (grant
no. 1436/14 to Y. Enzel) is gratefully acknowledged. A. Agnon was supported by the DESERVE
Helmholtz Virtual Institute. We thank G. Arnold, D. Berger and B. Brademann
for preparing excellent thin sections and for technical support; P. Dulski
and F. Ott for help with <inline-formula><mml:math display="inline"><mml:mi mathvariant="normal">µ</mml:mi></mml:math></inline-formula>XRF; B. Plessen and P. Meier for TOC and
CaCO<inline-formula><mml:math display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:math></inline-formula> measurements; J. Mingram for support with the fluorescence
microscope; G. Schlolaut (all GFZ German Research Centre for Geosciences)
and K. Schorling (HU Berlin) for grain size sampling; S. Baltruschat (TU
Darmstadt) for assistance with XRD samples; and all people involved in the drilling, core opening and sampling campaigns of the Dead
Sea Deep Drilling Project. This study is a contribution to the Helmholtz
Association (HGF) climate initiative REKLIM Topic 8 “Rapid climate change
derived from proxy data”.
<?xmltex \hack{\newline}?><?xmltex \hack{\newline}?>
The article processing charges for this open-access <?xmltex \hack{\newline}?> publication  were covered by a Research <?xmltex \hack{\newline}?> Centre of the Helmholtz Association.
<?xmltex \hack{\newline}?><?xmltex \hack{\newline}?>
Edited by: L. Skinner</p></ack><ref-list>
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    <!--<article-title-html>Hydroclimatic variability in the Levant during the early last glacial
(  ∼  117–75 ka) derived from micro-facies analyses of deep Dead
Sea sediments</article-title-html>
<abstract-html><p class="p">The new sediment record from the deep Dead Sea basin (ICDP core 5017-1)
provides a unique archive for hydroclimatic variability in the Levant. Here,
we present high-resolution sediment facies analysis and elemental
composition by micro-X-ray fluorescence (µXRF) scanning of core
5017-1 to trace lake levels and responses of the regional hydroclimatology
during the time interval from ca. 117 to 75 ka, i.e. the transition between the
last interglacial and the onset of the last glaciation. We distinguished six
major micro-facies types and interpreted these and their alterations in the
core in terms of relative lake level changes. The two end-member facies for
highest and lowest lake levels are (a) up to several metres thick, greenish
sediments of alternating aragonite and detrital marl laminae (aad) and (b)
thick halite facies, respectively. Intermediate lake levels are
characterised by detrital marls with varying amounts of aragonite, gypsum or
halite, reflecting lower-amplitude, shorter-term variability. Two intervals
of pronounced lake level drops occurred at  ∼  110–108 ± 5 and  ∼  93–87 ± 7 ka. They likely coincide with stadial
conditions in the central Mediterranean (Melisey I and II pollen zones in
Monticchio) and low global sea levels during Marine Isotope Stage (MIS)
5d and 5b. However, our data do not support the current hypothesis of an
almost complete desiccation of the Dead Sea during the earlier of these lake
level low stands based on a recovered gravel layer. Based on new
petrographic analyses, we propose that, although it was a low stand, this
well-sorted gravel layer may be a vestige of a thick turbidite that has been
washed out during drilling rather than an in situ beach deposit. Two
intervals of higher lake stands at  ∼  108–93 ± 6 and
 ∼  87–75 ± 7 ka correspond to interstadial conditions in
the central Mediterranean, i.e. pollen zones St. Germain I and II in
Monticchio, and Greenland interstadials (GI) 24+23 and 21 in Greenland, as well as to sapropels S4
and S3 in the Mediterranean Sea. These apparent correlations suggest a close
link of the climate in the Levant to North Atlantic and Mediterranean
climates during the time of the build-up of Northern Hemisphere ice shields
in the early last glacial period.</p></abstract-html>
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